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By R. L. Montgomery

The literature has been surveyed and values recalculated for the heats and free energies of formation of solid rare-earth compounds at 298° K. In most instances it was necessary to estimate the entropies. Thermodynamic properties of aqueous rare-earth ions have also been calculated. INTRODUCTION The accumulation of thermochemical data on rare-earth compounds in recent years makes it possible to review the subject and to obtain more consistent and more reliable information than was available previously.

Jan 1, 1959

By E. J. White

Data from oil well logs and core analyses were used to quantitatively evaluate formation porosity and water saturation of heterogeneous carbonates and to study the pore geometry and performance characteristics of cores from these formations. Logs and cores from the Madison limestone from 233 wells in three fields in the Williston basin were used in the investigation. A comparison of log and core analyses shows that log porosities are consistently larger than core porosities, and the differences are correlatable with core porosity ranges. Water saturations from logs are usually smaller than the corresponding core saturations by summation of fluids, but the difference is attributable to mud filtrate invasion into the cores during drilling. Petrophysical studies show that the low permeabilities and high residual water saturations in these reservoir rocks are due to their fine crystalline texture and complex pore geometry (heterogeneity). It is concluded that both log and core analyses must be used for reliable evaluation of these carbonate formations.

Jan 1, 1971

By H. G. Lucas

A feeder screw supplied at constant pressure by a hopper-orifice arrangement was developed for feeding solids in size ranges up to several hundred micrometers at constant flow rates. Performance of the feeder was evaluated by measuring the flow rates obtained with 3-to 7-micrometer coal ash, 70 percent through 200-mesh coal, and minus 325-plus 400-mesh coal ash. Constant feed rates within a few percent of set values were achieved for half-hour periods for the larger particles and for 5-minute periods for the finer particles. Suggestions are given for feedstock preparation and feeder operation for optimum performance.

Jan 1, 1974

By John D. Corrick

A dilute sulfuric-acid leach was developed for extracting lead and copper from lead blast furnace mattes and the chemistry was defined. The possible application of Ferrobacillus ferrooxidans to the problem of salvaging lead and copper from blast furnace mattes was also investigated. Operating conditions were varied to determine their effect on the oxidation and hence extraction of lead and copper from the matte. Conditions varied were temperature, pH, reaction time, aeration in the slurry, and particle size of the matte. A set of optimum conditions were developed that resulted in maximum lead and copper sulfide oxidation. Tests employing these optimum conditions resulted in 82.3 percent of the lead and 98.7 percent of the copper being extracted by a dilute acid leach, while maximum lead and copper extracted using F. ferrooxidans was 69.8 percent of the lead and 78.4 percent of the copper. Tests conducted with a different sample of blast furnace matte indicated that the dilute acid leach might have wide application in extracting lead and copper from other such blast furnace mattes.

Jan 1, 1968

By R. W. Smith

The Bureau of Mines is engaged in systematic evaluation of the thermodynamic properties of combustion gases. These studies are designed to provide basic thermodynamic information of high accuracy that will facilitate the theoretical study of flame and combustion phenomena. This report is the second of a series3/ presenting results of the study for particular fuel-oxidant sys tans. These calculations had as their objective evaluation of the constant pressure flame temperatures of methane-air and propane-air flames at atmospheric pressure as functions of the mixture ratio and inlet temperature of the fuel-air stream.

Jan 1, 1953

By R. E. Lindstrom

Separation efficiency of a 4 percent divinylbenzene (DVB) resin is not altered over a wide range in temperature. A 12 percent DVB resin, however, exhibits a marked sensitivity to temperature. When flow rates are high at ordinary temperatures, 4 percent DVB resin exhibits higher efficiency, but at 200° F. both resins are equal in performance. Effective separation of rare-earth mixtures may be obtained with hydrogen as a retaining ion by maintaining column temperatures above the solubility of ethylenediaminetetraacetic acid (EDTA) in the free acid form. Slightly lower separation characteristics were obtained with this method as compared with copper as a retaining ion, Recovery of 99 percent of the EDTA from spent eluting solutions that contain copper has been accomplished by a calcium-copper displacement reaction followed by EDTA precipitation. Impurities in the product are correspondingly low. Recoveries of EDTA from holmium solutions with sulfuric acid are substantial; however, those from yttrium solutions are quite modest. Radiotracer experiments show the presence of approximately 0.1 percent yttrium contamina¬tion in the recovered material. The study presented is one phase of a broad research program designed to assist the technology of separating and purifying rare-earth elements.

Jan 1, 1961

By d&apos, Kathleen J. Amico

THIS summary appears in Minerals Yearbook volumes I and III, which cover mineral production in the United States, its island possessions, the Canal Zone, and the Commonwealth of Puerto Rico, as well as the principal minerals imported into and exported from the United States. The several commodity and area chapters contain further details on production. A summary table comparing world and U.S mineral production also is included.

Jan 1, 1964

The Mine Safety and Health Administration (MSHA) defines an independent contractor as "any person, partnership, corporation, subsidiary of a corporation, firm, association or other organization that contracts to perform services or construction at a mine." Contractors that perform specific types of work are required to report the number of employees who perform work at coal mines and at noncoal mines.

Feb 1, 2005

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Jan 1, 2012

By L. B. Pankratz

The heat content above 298.15° K was determined for crystalline vanadium silicide of the composition V3Si. This substance has a minor thermal anomaly (probably a heat-capacity maximum) near 560° K; the extra heat absorption is about 50 cal/mole. The original heat-content data are presented, and smooth values of the heat content and the corresponding entropy increments are listed for the temperature range from 298.15° to 1,500° K. Equations representing the heat- content values and derived heat capacities are also included.

Jan 1, 1963

By Edward P. Barrett

[Iron oxides, when reduced at temperatures below 900° form a dark gray substance, very porous bait otherwise in almost the same form as the original particles. In the temperature ire range of 1,000 to 1,100° the product is pertly sintered but still shows the outlines of the original particles. Those products are known as "sponge iron." At temperatures of 1,100 to 1,2000 the metallic iron begins to flow together and to a semifused, pasty, porous mass called a "bloom," which can he worked under a hammer to form a product similar to wrought iron; it contains slag inclusions and is too low in carbon to make steel. If the temperature is 1,300 to 1,300°, part of the iron will fuse enough to absorb more carbon. The dissolved carbon lowers the melting point and still more carbon is absorbed. The melted portion acts a flux for the unmelted metallic particles until the entire mass becomes a high-carbon fluid known as "cast iron." Sponge iron was probably the form in which the first iron was recovered from the ores. As early as the eighth century the Catlan forge3 developed into a low-shaft furnace known as the "high bloomary," in which iron eras produced in the form of a pasty mass. In 1340 the first blast furnace was built in Belgium. The greater part of the iron was made into wrought-iron blooms by crude puddling processes. Charcoal was used as the fuel until tie latter part of the 17th century when coke was used in England. In 1865 Bessemer built his first converter in. England, and within a few years the Siemen's regenerative open-hearth furnace was developed, also in England. Enormous expansion in the metallurgy of iron followed. The idea of "direct processes" for the production of iron arid steel has persisted throughout all this time. The production of steel from sponge iron has theoretical advantages over the present-day standard methods, and handreds of so--called "direct processes" have been proposed or tried during the past century.4]

Jan 1, 1929

By J. E. Pahlman

One of the goals of the Bureau of Mines is to develop metallurgical pro-cesses that conserve energy and/or that take advantage of abundant domestic energy sources. Western lignites and subbituminous coals can be used for firing pellet induration and metallization furnaces. However, the refractory linings of these furnaces must be able to withstand attack from corrosive alkali metal oxides present in the ash of many of the low-rank fossil fuels. The Bureau of Mines conducted dynamic and static slag tests on high-alumina and alumina-silica refractories to determine their resistance to lignite ash slags. The investigations showed that increased alkali content in the lignite ash caused increased corrosion and erosion of the tested refractories. The degree of corrosion decreased with increasing alumina content, with the 99-percent-alumina refractories having the highest resistance. In general, the matrix phase was attacked preferentially to the alumina grains. Also, porosity reduction and tar impregnation enhanced the corrosion and erosion resistance. The 90-to 99-percent-alumina refractories are recommended for use as furnace linings in alkali slag environments.

Jan 1, 1979

By J. Roger Loebenstein

ASARCO Incorporated, the only domestic arsenic producer, terminated copper-smelting operations and the associated recovery of byproduct arsenic trioxide at Tacoma, W A. in 1985. It still shipped small quantities of trioxide from its remaining stocks in 1987. Imports for consumption of arsenic trioxide were slightly higher than in 1986. Domestic Data Coverage.-Shipments of small amounts of arsenic trioxide from remaining stocks by Asarco were reported voluntarily to the Bureau of Mines.

Jan 1, 1989

By C. M. McCulloch

Examination of several coalbeds in Walker County, Ala., Cambria, Greene, and Fayette Counties, Pa., and Raleigh and Wyoming Counties, W. Va., indicates that cleat orientations are similar throughout a vertical sequence of strata. Studies of cleat orientation were carried out in underground mines that are operating in separate coalbeds vertically above one another. The data show that over a vertical separation of 100 to 400 feet, the average difference in coal cleat orientation between mines is 04° for the face and 08° for the butt cleat. Variations of coal cleat direction between coalbeds examined in strip-mined areas show similar values. Cleat orientations measured at outcrops agree well with the directions measured underground, suggesting that the amount of vertical separation between coalbeds has little effect on the resulting differences in cleat directions. The largest variation of cleat directions between adjacent coalbeds occurs where a large horizontal distance separates two sample locations. Cleat orientations for deeper coalbeds are most reliable where the data are taken from directly above.

Jan 1, 1976

By Thomas E. Marshall, Timothy Batchler, Anthony T. Iannacchione

As the amount of new fractured surfaces or "damaged rock layers" within roof rock increases, the stability of the rock mass decreases. While direct measurements of this phenomenon are not easily made, there is good circumstantial evidence to support this hypothesis. For example, it is common to observe increased cracks or fractures in the immediate mine roof rock before a roof fall. Likewise, roof drill holes placed in areas that later fail often reveal increased numbers and/or separations of fractures within the rock column through time. And finally, the frequency of microseismic activity, representative of rock fracturing, increases before a roof fall. For this study, more than 700 microseismic emissions were collected from two underground limestone mine roof fall areas in southwestern Pennsylvania. Microseismic events were located and magnitudes determined using the moment magnitude technique. Moment magnitude is based on the event seismic moment, which is a measure of the seismic deformation. The amount of new fracture surface length was calculated based on the stored strain energy within the rock prior to fracture. In the two case studies presented, a significant amount of microseismic activity was observed as much as two days before the first signs of failure in the roof fall areas. Additionally, results from this analysis reveal much about the behavior of strata prone to failure and allows for the construction of hazard maps based on microseismic emissions. The potential use of this technique as a means of anticipating roof falls is analyzed and discussed.

By Charles Sabine

The 27,960-acre Newberry Mountains Wilderness Study Area (WSA) is located in the Mojave Desert, 17 miles east-southeast of Barstow. In 1983, the U.S. Bureau of Mines, in conjunction with the U.S. Geological Survey, investigated mineral resources of the area as part of the wilderness review process. The Newberry Mountains are underlain by Paleozoic metamorphic rocks, Mesozoic plutonic rocks, and Tertiary volcanic rocks. Eleven mines and prospects were examined. Of the seven sites within the WSA, only the Northrup Prospect is mineralized. Only a few tons of manganese-bearing rock, containing 49% manganese oxide (MnO), are exposed, but exploration may disclose larger deposits. The Azucar Mine, a past producer of gold, is the only site examined outside the area that appears mineralized. Sample data from quartz veins exposed at the surface do not indicate that resources are present; however, the occurrence could not be fully evaluated because underground workings were not accessible. Sand, gravel, and stone are plentiful in the WSA, but alternate sources outside the WSA are available.

Jan 1, 1985

By Mridul Gautam, Alex Bugarski

Size Distribution and Deposition in Human Respiratory Tract: Particle Mass and Number Aleksandar Bugarski and Mridul Gautam National Research Center for Alternative Transportation Fuels, Engines and Emissions Department of Mechanical and Aerospace Engineering West Virginia University TOXICITY OF ULTRAFINES (MAUDERLY et al.) ? FINER PARTICLES PENETRATE MORE READILY INTO CELLS AND TIXROUGH TISSUE BARRIERS ? FINER PARTICLES HAVE GREATER SURFACE AREA PER UNIT MASS, AND A LARGE NUMBER OF TOXIC REACTIONS OCCUR AT THE SURFACE ? FINER PARTICLES DISSOLVE MORE READILY THAN LARGER PARTICLES THUS ENHANCING THE BIO- AVAILABILITY OF SOLUBILIZED COMPOUNDS EPIDEMIOLOGICAL STUDIES INDICATE THAT THE IMPORTANCE OF ULTRAFINES REMAINS SPECULATIVE

By John Durkin

Information on vertical magnetic noise in the voice frequency band, both within and above coal mines, is needed for the evaluation of through-the-earth baseband electromagnetic communications at mines where horizontal loop antennas are used. This report discusses the theory of the source of electromagnetic noise, the propagation of this noise to an observation point above a mine, and its interaction with the local earth conductivity structure, which gives rise to vertical magnetic noise. The relationship of surface noise to underground noise is also discussed. Bureau of Mines investigators made surface and underground vertical magnetic noise measurements at a number of coal mines located through- out the United States. These data were modeled through regression analysis to characterize expected noise levels. The results are presented, including results in one-third octaves for use in evaluating the expected performance of through-the-earth communication systems by articulation-index studies.

By Rose L. Ballard

This chapter summarizes data on crude nonfuel mineral production for the United States, its island possessions, and the Commonwealth of Puerto Rico. Included also are tables that show the principal nonfuel mineral commodities exported from and imported into the United States, and that compare world and U.S. mineral production. The detailed data from which these tables were derived are contained in the individual commodity chapters of volume I and in the State chapters of volume II of this edition of the Minerals Yearbook. Although crude mineral production may be measured at any of several stages of extraction and processing, the stage of measurement used in this chapter is what is normally termed "mine output." It usually refers to minerals or ores in the form in which they are first extracted from the ground, but customarily includes the output from auxiliary processing at or near the mines.

Jan 1, 1982

By Martin Hertzberg

In this Bureau of Mines report, the optical detection of fires and explosions is considered fundamentally. The measured spectral radiances from methane-air ignitions are compared with the background irradiances from stray and ambient sources, and with the spectral sensitivites of various sensors. The comparison naturally suggests the optimum spectral ranges and signal processing logic that can uniquely characterize the ignition event. Both ultraviolet (UV) and infrared (IR) are considered. Several alternate sensing methods are proposed and discussed. The development and testing of an IR system designed for use in ignition suppression devices in mines is described.

Jan 1, 1975