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By Carlton E. Brown, William P. Yant

"INTRODUCTION Direct visual microscopic determination of particle-size distribution and number concentration of atmospheric dust is time-consuming and trying to the eyes. By using the microscope to project images of the particles at high magnification onto a screen much of the eyestrain can be eliminated and particle-size distribution results obtained with less effort and at a considerable saving in time. It also permits simultaneous observation of the images by more than one person. Microprojection requires no more skill and very little more apparatus than is required in the use of the microscope. Anyone familiar with the microscope should be able to obtain as perfect images on the projection screen as in direct visual microscopy since the same laws and limitationsThe theory and practice of microprojection are described in detail in texts. 5/6/ The procedure has been used and found to be satisfactory for measuring the particle-size distribution of sub-sieve-size substances, such as pigments and powder 7/8/ in the same size range as that of atmospheric dust. The Bureau of Mines has used the microprojector and found it to be quite satisfactory for (1) the determination of the number concentration of atmospheric dust R.I. 3289 in samples collected by the Owens jet dust counter; (2) particle-size distribution in samples of atmospheric dust collected by the Owens jet dust counter and by the electric precipitator; and (3) the particle-size distribution of dusts, blood cells, bacteria, and pollen. Work is in progress at this Bureau on the use of the microprojector in counting impinger samples. The use of different kinds of illumination, such as reflected (dark field), polarized, monochromatic, and ultraviolet, in the projection of images of atmospheric dust particles is being considered."

Oct 1, 1935

By M. Viswanathan, M. J. Jorgensen, N. K. Kittusamy

Operating heavy construction equipment is often associated with elevated rates of low back discomfort (LBD). However, there have been few formal studies that dealt with evaluating controls that can reduce the LBD among these workers. The objective of this study was to determine the effectiveness of using a continuous passive lumbar motion system (CPLMS) in reducing low back discomfort among operators of heavy earthmoving equipment. The CPLMS is an additional seat support that has a lumbar support bladder and a pump to provide cyclic inflation and deflation. Two groups of operators were identified as potential subjects for this intervention study, the intervention group with a mean age of 41.2 years and experience of 9.7 years used the CPLMS, and the control group with a mean age of 37.5 years and experience of 7.6 years did not use the CPLMS. Body part discomfort surveys were collected from both groups. In addition, the intervention group completed a CPLMS preference survey. The body part discomfort survey was collected up to eight days at three different times of the day. Results from the body part discomfort survey showed a decreasing trend the longer the CPLMS was used, for both the upper and low back region. A decreasing trend for the low back was also found comparing morning to evening discomfort scores across the days when using the CPLMS. When compared to their regular seat, 54% of the operators felt very comfortable in using the CPLMS, 36% of them wanted one for their equipment, and 54% showed interest in experimenting with the CPLMS for a longer time period. Results from this study indicate that the use of a CPLMS can effectively reduce the low back discomfort experienced by operators of heavy construction equipment.

To develop a quick, safe, and effective method that allows workers at mineral processing operations to clean their dust-soiled clothing periodically throughout the workday. Background Reducing workers' respirable dust exposure to silica and other harmful dusts and contaminants is an ongoing goal in the U.S. mining industry. One area of known worker exposure is from contaminated work clothes. A U.S. Bureau of Mines report documented a number of cases where a tenfold increase in a worker's dust exposure was measured from contaminated work clothes. In these cases, the dust emitted from clothing caused the worker's dust exposure to exceed the permissible exposure limit in less than 2 hours. The most effective way to eliminate this dust source is to have workers clean or change their work clothes. There are two federal regulations that impact the clothes-cleaning process. The first states that at no time shall compressed air be directed toward a person, but that when compressed air is used, then all necessary precautions shall be taken to protect persons from injury. The second regulation states that compressed air should only be used for cleaning purposes when it is less than 30 psi and used along with personal protective equipment. For the mining industry, by default, the only approved method to perform clothes cleaning is to have workers vacuum their clothes using a HEPA filter system. This is very difficult and time-consuming and, in most instances, not very effective. Most workers would prefer to use a single compressed air hose to blow dust from their work clothes. However, not only is this method prohibited by law, it usually creates a significant dust cloud in the work environment and contaminates coworkers.

May 1, 2005

Provide a means for continuous measurement and display of respirable dust concentrations in a mine so that when high dust levels occur, timely, corrective measures can be taken. Approach Develop a personal dust monitor that (1) is small and light enough to be worn by a miner, (2) has the capability to continuously measure the respirable fraction of coal dust, (3) will display the respirable dust concentration in mg/m3, and (4) can store the average respirable dust concentration and sampling time of several sampling shifts for later play-back. How It Works The personal dust monitor (PDM-1) uses light scattering and convection air currents to sample the respirable fraction of coal dust. Convective air currents cause dust laden air to pass through an open-celled sampling chamber (light sensing chamber). A near infrared light emitting diode (LED) located in the PDM-1 emits pulses of light. The pulsed light passes through a focusing lens and glass window into the sampling chamber. The light is then reflected, scattered, and refracted by the airborne dust particles. Light scattered within the angles of 450 to 900 (the angles within which the intensity of the scattered light is most closely related to respirable-size dust particles) passes through another window and is focused on a light detector. The light detector signal is amplified and presented as analog output voltage for conventional recording. This signal is also converted to a digital signal which the microprocessor uses with its crystal clock to calculate the 10-second average dust concentration, the shift average concentration, the time-weighted average concentration, and the elapsed sampling time. The microprocessor also stores dust concentrations of the seven most recent sampling periods, controls the operation of the LED and detector, and operates the liquid crystal display (LCD).

Jan 1, 1983

By Robert J. Willard

This chapter includes tables for 1982 that were not available in time for publication of the 1982 Minerals Yearbook, but does not include corresponding tables for 1983. The value of raw nonfuel minerals produced in the United States during 1988 was estimated at $21.1 billion, an increase of $1.5 billion over the value for 1982. This is a reversal of last year's downturn in value from that of 1981, which was the only decrease noted since 1971; hence, an overall trend of increasing values has been maintained for 12 years, except for 1982. Although the reversal is a basis for cautious economic optimism, it is tempered by continued problems in the domestic mining industry: inadequate funds for capital investment and competition with other countries that have lower production costs. Output of metal commodities in 1983 increased for 8 out of 21 metals, and metal values, in general, increased for 9 of the metals. Output of nonmetal commodities was mixed, with 24 nonmetals showing increases, 20 showing decreases, and 2 unchanged. Nonmetal values were also mixed in 1982: 25 showed increases, 20 declined, and 1 was unchanged. Improvements in the international metals market have not been forthcoming because of the continued depressed prices for major metals. Governments in foreign producing countries have been concerned with maintaining employment and continuing foreign exchange flows through mineral exports. Consequently, the excess of supply in the face of shrinking demand brought downward pressure on metal prices in general, except for the precious metals. On the domestic front, this situation means U.S. mining companies must become even more cost efficient. The major trend in the mining industry in 1983 was to cut costs further, reduce or stabilize total production, reduce outlays for major capital equipment, modify existing systems and equipment, and streamline operations. Most of the accomplishments reported herein reflect this trend.

Jan 1, 1984

By R. V. Ramani, A. S. C. Owili-eger

The origin of gaseous hydrocarbons in coal, predominantly methane, can be traced to the natural processes of coalification. The higher rank coals or the more deeply buried seams retain more gas than low rank coals or shallow seams. It is estimated that up to 460,000 cubic feet of all types of gases are produced during the formation of one ton of coal (Cervik, 1969). The chief components of these gaseous products are methane, carbon dioxide, nitrogen and water vapor. Most of these gases escape during the various stages of decomposition but with eventual presence of overlying impermeable beds, there may be as much as 2,000 cubic feet of gas retained per ton of coal. Over geologic time, diffusion and other processes such as geologic disturbances in the earth's crust remove all but 500 to 2000 cubic feet of gas per ton of coal (Cervik, 1969). It is this residual methane which is of primary concern when mine openings are made in coal measures. Extensive data compiled by the United States Bureau of Mines reveal that some coal mines in this country emit up to 20 million cubic feet of methane per day (Spencer, 1970; Irani et al, 1972). Toxic, poisonous and respirable gaseous pollutants and explosive gases, predominantly methane, are injected into the ventilation stream from active sections and gobs. The liberation of methane in gob areas may, under certain circumstances, become extremely large. In some instances it may constitute up to 70 percent of the total yield of gas in a mine. The basic physical factor which determines the yield of gas into the mine environment is the gas content of the seam. The influence of the gas content of a seam on the overall yield of gas

Jan 1, 1974

By C. W. Davis

"A copper-palladium-gold-silver ore is being mined at Salt Chuck, Prince of Wales Island, Alaska, from which a concentrate is produced that contains 40 to 50 per cent copper, and considerable amounts of palladium, gold and silver. There has been much difficulty in obtaining assays for palladium, gold and silver from the mine, smelter, sampler, and umpire that check within reasonable limits. While the results for copper content have not been unusual, the results for palladium have varied as much as 0c8 oz. on 3 oz. material, results for gold differed by 0.1 oz. on 1.6 oz. materials, and for a silver content of 7 oz., results differed by as much as 4.0 oz.The Bureau of Mines was requested to determine the causes of variation in the results of the different assayers, and to develop a satisfactory procedure for analyzing such ore.Three samples of concentrate were received for analysis, two small lots that had previously been assayed by the various laboratories, and one large sample. The large sample was dried and ground in a ball mill, put through a 150-mesh screen, and then returned to the ball mill for thorough mixing. The small samples were ground to pass a 150-mesh screen and then mixed on a mixing wheel.The large sample (No. 1) was analyzed by five different procedures, one of the small samples (No.2) by three procedures, and the other (No. 3) by two procedures (the two small samples being too small for further tests). The different procedures tried and the results obtained arc presented below. The samples of concentrate were from ore mimed and milled by the Alaska palladium Co. at Salt Chuck."

Feb 1, 1926

By Maurice Deul, Herbert H. Fields, John H. Perry

The Bureau of Mines has been promoting health and safety in mining since its establishment in 1910. One area of research covers methane control in coalbeds; this report describes a multipurpose borehole used for both degasification and the production of commercial-quality gas. The multipurpose borehole was drilled into a barrier pillar, and seven horizontal degasification holes and one pressure point hole were drilled radially out from its perimeter. On January 28, 1974, after 505 days of degasification, a compressor was installed to the exhaust stack of the multipurpose borehole (2), and pipeline--quality gas was introduced into a commercial pipeline. As of February 4, 1975, over 171 million cubic feet of gas had been purchased by the gas company. The in situ pressure at a depth of 200 feet into the coalbed and the average gas flow and water flow from the degasification holes as they were completed and closed off were 203 psig, 1,200,000 cfd, and 6.8 gpm, respectively. Twenty-four hours after the seven holes were connected through individual pipes to the atmosphere, the total gas and water flows and the in situ pressure dropped, respectively, to 971,000 cfd, 1.3 gpm, and 18 psig. Five hundred days later, the corresponding values were 620,000 cfd, 0.15 gpm, and 10.5 psig. Daily flows have been as high as 800,000 cfd, and as low as 360,000 cfd, during the last 500 days. On February 4, 1975, after 882 days of degasification, 576 million cubic feet of gas had been removed from the Pittsburgh coalbed; apparently a much larger area of virgin coal is being degasified than is defined by the holes. This study indicates that horizontal boreholes drilled into a coalbed from the bottom of any shaft will effectively remove gas from the Pittsburgh coalbed.

Jan 1, 1975

By Samuel W. McNary

In August 1984 the U.S. Bureau of Mines conducted a study of the mineral resource development potential of the Badger Canyon-Antelope Creek area, within the Boulder-Pioneer wilderness study area, about 5 miles northeast of Ketchum, 10. The purpose of this study was to investigate in greater detail an area which was designated by the U.S. Geological Survey (USGS) and the Bureau as having a moderate mineral resource potential for zinc, molybdenum, lead, and silver, and a low potential for copper. One hundred twenty-eight soil samples were taken along a 6,2S0-ft traverse on the ridge separating Badger Canyon and Antelope Creek. 5 Five rock samples were collected from old prospect pits and mineralized outcrops. All samples were analyzed for gold. Silver, copper, lead, zinc, molybdenum, arsenic, antimony, vanadium, and mercury. The metal concentrations in the soil samples along the traverse are irregularly distributed. Samples collected near old prospect pits tend to be high in lead and zinc, undoubtedly a reflection of underlying galena-and sphalerite-bearing quartz veins. All of the copper and mercury values in the soils are less than the detection limit, as are most of the lead, molybdenum, and antimony values. Except for lead and zinc values, the metal concentrations in the rock samples are low. Galena and sphalerite were observed in quartz vein samples collected at the old prospects. The results of the study indicate that the galena-sphalerite-bearing quartz veins and veinlets are too narrow, widely-spaced, and low in metal values to be economic. Low concentrations of metals in the soil and rock samples, combined with the lack of major mining activity in the past, indicate that the area has a low likelihood for economic development.

Jan 1, 1986

By R. Hogg, T. F. Dumm

"It is generally agreed that dust characteristics play a role in the development of Coal Workers' Pneumoconiosis (CWP). Unfortunately, there is a serious lack of information on what the characteristics of mine dust actually are and how they vary among different mining regions, coal seams, etc. This paucity of data can generally be attributed to the serious problems encountered in collecting sufficiently large quantities of dust for conventional analytical procedures.Personal samplers are widely used in coal mines for regulatory and enforcement purposes. Generally, these provide information only on the total (respirable) dust loading in the mine atmosphere and on the mineral matter (primarily quartz) content of the respirable dust. A procedure has been developed by which samples collected with a slightly modified personal sampler can be analyzed for particle size distribution, total mineral matter content and elemental composition, in addition to the standard mass and quartz measurements. These analyses could readily be performed on a routine basis. Shape analysis by Scanning Electron Microscope (SEM) could easily be included if appropriate shape criteria are established. Extension of the procedure to include the determination of complete size/specific gravity (composition) distributions is quite straightforward provided sufficiently large samples (at least 10 mg) can be collected. Typical sample sizes for a personal sampler carried by a miner for one shift range from about 0.5 to 2 mg.The basic procedure was developed and evaluated using synthetic mine dust prepared in the laboratory. Field tests in three working mines in Pennsylvania and West Virginia have confirmed the applicability of the approach to the real world. Particle size distribution measurements on mine dust collected in the modified personal sampler were found to agree closely with the results of simultaneous in situ measurements obtained using cascade impactors."

Mar 1, 1989

By Fred N. Kissell

In This Chapter [Early indicators of a gas problem How the methane hazard is reduced Ventilation principles for gassy tunnels Monitoring for gas Eliminating ignition sources and The all-important human factors component] This chapter gives guidelines for preventing methane gas explosions during tunnel construction. Emphasis is placed on assessing the hazard potential, on ventilation principles, and on monitoring for gas. The chapter also emphasizes the importance of human factors in reducing explosion risk. Ensuring safe conditions is much more than just good engineering design. It also involves the every-day vigilance of those working underground. This does not imply that the engineering design can be ignored, only that the job of providing safe conditions has just begun with design. EARLY INDICATORS OF A GAS PROBLEM For the engineer planning a tunnel project, reliable early indicators of methane are scarce. How-ever, the local geology can often provide some information.2 Carbonaceous rocks and tar sands are a likely methane source. Gas is also a distinct possibility if it is known to be present else-where in the same sequence of geologic formations. Swampy areas, sewerage systems, and landfills are also candidates because the decomposition of organic materials produces methane. The gas in a tunnel can originate in the strata being excavated, or it can migrate a considerable distance from adjacent strata. Test borings at the project site can also serve as initial indicators of gas. Methane has no odor, but may be emitted along with gases that do. If gas is emitted from the borehole, a sample may be collected by inserting a tube into the hole as far as possible and pumping the gas out. The gas sample should be collected in a sampling bag or canister for later analysis by a chemical laboratory.3

Jan 6, 2006

By Donald P. Tuchman, Robert P. Vinson, Steven J. Page

Researchers at the National Institute for Occupational Safety and Health (NIOSH) have long used stationary tapered element oscillating microbalances (TEOMs®) in laboratory settings. They have served to assess the mass concentration of laboratory-generated particulates in experimental , dust chambers and they provide a reference method for comparison with other particulate- measuring instruments. Current NIOSH research is focused on further adapting TEOM technology as a wearable personal dust monitor (PDM) for coal mining occupations. This investigation's goal is to help identify, quantify, and provide means for resolving certain TEOM- related error. The present research investigated bias caused by thermal effects on filter assemblies. New filters used in the PDM for 8 h tests show an average positive bias of 25.5 pg, while similar tests of equivalent filters used in two 1400A model TEOMs show an average positive bias of 34.3 µg. The derived bias values allow correction of previously collected biased data. Also, pre- heating the filters for 24 h at 46° C shows significant bias reduction, with PDM pre-heated filters subsequently averaging -3.3 µg and 1400A TEOM filters averaging 5.9 µg. On a single-point comparison to gravimetric sampling, a 25.5 µg bias is only significant at low mass loadings. At 2.5 mg, this bias represents a negligible 1 % of the mass measurement. If ordinary linear regression is used, the bias is still insignificant. However, if the more valid weighted linear regression is used, it gives more weight to the smaller dependent variable values, which are more impacted by the bias. Consequently, what is 1% bias on a single high-mass value can translate into a larger bias percentage at high-mass values when performing a weighted regression on data that include a large number of low-mass values.

By J. W. Paul, A. C. Fieldner

"In cooperation with the New York and New Jersey State Bridge and Tunnel Commissions, the Bureau of Mines has just completed the construction of an experimental tunnel in the Bureau's experimental mine at Bruceton, Pa., near Pittsburgh, Pa. The purpose of this tunnel is to make a final study of the ventilation problems arising in the adequate ventilation of vehicular tunnels for automobiles and trucks, especially the 9000-foot tubes that are being designed. to handle the traffic between New York City and New Jersey under the Hudson River.Chief engineer, Clifford M. Holland, of the Tunnel Commissions has shown that there are three principal problems involved in planning the ventilation of this tunnel, namely - (1) The amount and composition of exhaust gases from motor vehicles; (2) The dilution necessary to render these exhaust gases harmless; (3) Determination of coefficients of airflow and horse-power required in ducts, bends and openings.Composition of automobile exhaust gases.The answer to the first problem was obtained by making road tests on 101 automobiles and trucks at the Pittsburgh experiment station. These machines were taken from service without any previous adjustment so that the composition and amount of the exhaust gas may be taken as representative of actual operating conditions prevailing in the tunnel. A report covering the results of these tests was submitted to the chief engineer of the Tunnel Commissions, on November 1, 1920, and 411 be published in the report of the commissions. Several papers a have also been published in the technical journals summarizing the important results as regards tunnel ventilation and also with reference to gasoline losses in present-day motor car operation due to the general use of unnecessarily rich mixtures"

Oct 1, 1921

By E. D. Gardner

"It has only been in recent years that the proper ventilation of metal mires has received serious consideration. Increasing temperature and humidity with greater depth in some of the larger mines of the West prevented the efficient operation of the mines and made the installation of mechanical ventilation systems necessary. Doors that interfere with tramming are generally needed to control properly the mechanically induced air currents and are one of the inherent disadvantages of the system. In fact the necessity for the use of doors in the main haulageways has discouraged the installation of mechanical ventilation in some metal mines.A number of mining companies in Arizona are using ventilation doors which can be opened and shut mechanically by the motorman without leaving his seat or stopping his train, end thus interfere very little with the transportation of the ore. The Copper Queen Branch of the Phelps-Dodge Corporation at Bisbee introduced these ventilation doors and adapted them from those in use in the company's coal mine at Dawson, New Mexico. Other mining companies have installed the same type of door and it is now being used in a number of districts in Arizona.The doors at the Calumet and Arizona mine in the Bisbee district are representative of those in use. The doors at this mine are substantially built of 2-inch lumber, are air tight, are well placed and have two openings or passageways. The main door, which is used for the motor trains, is 5 feet wide by 6 feet high and is opened by compressed air and closed by a counterweight. At the side of the motor door is the man door, which is 16 inches wide by 5 feet high and is opened and closed by hand."

Aug 1, 1921

By S. H. Katz, J. J. Bloomfield

In studies of mine and tunnel ventilation conducted by engineers of the Bureau of Mines , various smokes are used to determine flow of air , direction of the currents , and the rate of mixing . The instrument for generating streams of sulphur trioxide (SO ) smoke , shown in the drawing herewith, has been found helpful , convenient and practicable for such purposes ; it is also especially useful in some places where fire for generating smokes is not permissible . The apparatus consists simply of a glass tube containing fuming sulphuric acid on granular pumice stone , attached to a rubber syringe bulb . When a squeeze of the bulb blows air through the tube , a stream of dense white smoke evolves, which follows and makes visible the air currents . The tubes after preparation are hermetically sealed to prevent deterioration . When ready for use , they are easily broken open at a file scratch for the purpose on both tips , and inserted into a rubber nipple at the bulb . Sometimes it is of advantage to attach them to a longer rubber tube leading to the bulb . Tubes of the size shown (about 1/2 inch outside diameter by 5 inches long) are usually sufficient for the needs of a day . Thereafter they cease to fume because the acid absorbs moisture from the air and looses its effectiveness . Smaller sizes of tubes and larger have been made , but the size shown has proved most practicable . Immediately after a person has finished using a tube it should be buried or disposed of in a place where it will not be touched by shoes or clothing, or come in contact with wooden floors , furniture , or metals , because the acid , which will eventually leak from the tubes , is highly corrosive . -- Reports of Investigations , Department of the Interior , Bureau of Mines .

Jul 1, 1923

By G. L. Barlett, J .. D. Barry

Supernatant media of dust-exposed pulmonary alveolar macrophages (PAMs) were inactive in assays for both Interleukin-1 and fibroblast growth factors (FGF). We have begun to evaluate several factors that may interfere with dust-PAM interactions. To determine the effect of sterilization on the activity of dusts, PAMs were exposed to autoclaved dust, heat-sterilized dust or to dust that had not been heated. Supernatants from the first two groups were inactive in the FGF assay, but supernatant from PAMs exposed to unheated dusts stimulated growth of lung fibroblasts. Recent data have revealed that freshly crushed mineral dusts possess labile free radicals that are absent in dust that has been stored for more than a few days. Suspensions .were prepared of a "stale" sample of anthracite dust 867 and of a freshly ground sample of the same dust. These suspensions were instilled intratracheally into guinea pigs under general anesthesia. Two, five or eight days later, PAMs were collected from the lungs by bronchoalveolar lavage, and the cells were counted. At two and five days after instillation, all lavage suspensions contained 70 to 85% PAMs, of which 5 to 18% contained phagocytized dust particles. On day eight there were again 80-84% PAMs in all suspensions, but in the presence of "fresh'" dust, 48% of PAMs. had phagocytized particles in comparison to 16% in the presence of '"stale'" dust. A similar experiment was performed in short-term cell culture. During 24 hours, >95%. of PAMs phagocytized dust particles, whether or not the dust was "stale" or '"fresh". Our studies are being extended to determine the effect of (1) removing surface oil contaminants by organic extraction and (2) suspending dusts without surfactant.

Jan 1, 1988

By Charles L. Kimbell

The estimated value of world crude mineral production in 1989 was nearly $1,420 billion in terms of current dollars or more than $1,168 billion in terms of constant 1983 dollars. This latter figure was almost 4.7% above the 1988 level but did not attain the historic high of $1,207.1 billion 1983 dollars set in 1980. The accompanying tabulation provides the latest available revised time series for the value of world crude mineral production in terms of both constant 1983 dollars and current dollars. It also provides one of the two statistical bases for the estimation, this being the data on the value of production of a group of key commodities that was compiled for and published in the authoritative French language mineral industry periodical Annales des Mines for years up to 1983.l It should be stressed that the values just discussed and those presented in the tabulation are for crude minerals only and by no means reflect adequately the role of the entire mineral industry in the world economy. These figures represent only the value of mineral materials as they are mined or otherwise extracted from the earth. They do not reflect the value added to these materials through downstream processing within the facilities commonly accepted as mineral industry plants. That is, value added through beneficiation of ores, smelting, refining, and similar processing is not included in these figures. Comprehensive world data on the value added by such processing are not available; however, a conservative estimate of [ ] the total value of processed output from mineral industry plants derived wholly from primary (newly mined) materials would be on the order of about $2,800 billion constant 1983 dollars or $3,400 billion in terms of 1989 dollars.

Jan 1, 1992

By Bernard Lewis, Guenther von Elbe

"Explosive gas mixtures are characterized by their ability to undergo a self-accelerating reaction that may culminate in ignition. In the case of methane and air there are two interdependent causes of this acceleration. First, if a sufficiently fast reaction is induced, heat may be evolved faster than it is lost to the surroundings; consequently, the temperature rises and the reaction rate increases. Second, the reaction rate is determined not only by temperature but by the concentration of reactive intermediate products if the latter increases during the course of the reaction the rate will increase. To understand the role of these active intermediates, it should be realized that molecules of methane and oxygen, per se, show little tendency to react with each other even at high temperatures.(1) If, however, free radicals like OH and CH3, are present in the mixture, the methane and oxygen are attacked in the reactions(2):In these reactions the radicals are regenerated, and thus a chain of reactions is set up by an individual radical or chain carrier which is broken only if the latter is destroyed in some process. Not all collisions of a chain carrier with CH4 or 02 result in reaction, since one requirement for a successful collision is that the colliding particles have a certain minimum energy. The percentage of collisions in which this energy condition is fulfilled increases with temperature, so that for equal chain-breaking probabilities the length of the reaction chain increases with increasing temperature. Thus, there exists an interplay of temperature and concentration of chain carriers that determines the reaction rate. To carry the rate to the stage of self-acceleration, higher temperatures are required for lower than for higher chain-carrier concentrations, other conditions being equal."

Sep 1, 1939

By R. V. Ramani, C. B. Manula, A. Owili-Eger

The mine ventilation system consists of the fan, the roadways, and the regulatory devices. Sufficient fresh air must reach each working face in the mines to render harmless noxious, toxic, and respirable pollutants and to provide for the breathing of men. This is achieved by the proper selection of fan and regulatory devices. Because a mining system is dynamic, the mine ventilation system must also be dynamic. In short, mine ventilation engineers are frequently called upon to provide answers to the following questions: 1. Given a mine or the projected plan of a mine, what fan must be selected for the quantities specified in the section? At what point in its characteristic must it be operated? Are any speed changes or changes in blade settings warranted? 2. What should be the regulation in a section to insure cer¬tain desired quantity in that section? How does it affect the overall ventilation system? 3. What are the effects of driving a new shaft? Where should it be located? What size fan should be installed in the shaft? How does this affect the overall ventilation sys¬tem? 4. How much quantity increases can be obtained by cleaning up falls and streamlining roadways and by driving addi¬tional parallel airways? These questions are in no way exhaustive, nor are answers easy. Most of the operational and planning problems discussed above are to a cer¬tain extent solved by ventilation engineers using rules of thumb from experience. Both natural conditions and regulatory requirements have changed so drastically recently that use of scientific methods in ventilation planning and of faster methods in evaluating the plans is a must. Fortunately, computers offer the greatest hope for good

Jan 1, 1975

By Launa Mallett, Michael J. Brnich

The first step to emergency preparedness is defining and analyzing hazards. Although all hazards should be addressed, resource limitations usually do not allow this to happen all at once. Risk assessments are used to establish priorities so that the most dangerous situations are addressed first and those least likely to occur and least likely to cause major problems can be considered later. While the examples provided in this training package are specific to mine fires, the concepts and tools can be applied to any mine hazard. Purpose: This training package was developed to assist instructors, as they: 1) determine how to use risk assessment to improve preparedness for mine fire emergencies and 2) present risk assessment concepts and tools to trainees. Audience: This package is appropriate for workers/trainees from all types of mines. A risk analysis can be conducted by anyone familiar with the location(s) being studied. Why Conduct a Fire Risk Assessment? During a risk assessment, hazards are evaluated in terms of the likelihood that a problem may occur and the damage it might cause. Mine fire preparedness requires consideration of all possible fires that could occur. However, at a given mine some fires are more likely than others and some would result in greater damage than would others. Conducting a risk analysis identifies these differences. The results can be used to target resources at the types of fires that are most likely and/or are most destructive. Hazards that are very likely to result in fires that would do considerable damage to people and property should be targeted first for remediation and/or effective response if remediation isn't possible. Potential fires that are less likely or that would have less severe consequences are identified for attention later, after the more serious situations have been addressed.

Jan 10, 1992