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By Mohana Rao Andavarapu

Sandur Schist Belt of Karnataka Craton constitutes a hub of iron ore mining activity. The iron ore deposits of the region are closely associated with Banded Hematite Quartzite (BHQ), Shale, phyllites, & Graywackes. The gradual depletion of high-grade iron ores due to extensive utilization has necessitated the exploitation of low-grade iron ore including BHQ, which are available abundantly in different parts of India. In the present investigation, BHQ samples from Kammaturu mines of Sandur schist belt was studied to assess the possibility of upgrading the iron content to the maximum possible extent, so that it may find the better use in iron and steel industries. The sample collected from the study area analyzing 39.76% Fe, 39.8% SiO2, 0.66% Al2O3, and 1.92% LOI was subjected to beneficiation studies. The mineralogical studies reveals that the samples are predominately consists of hematite as an iron mineral and quartz as gangue mineral. Liberation studies and chemical analysis were carried out prior to the beneficiation process, which is flotation. Cationic Reverse flotation studies were carried out and discussed by varying different process variables such as feed size, depressant, collector cum frother dosage & pH. The results obtained are encouraging with an appreciable improvement in the iron content up to 62.8% Fe with Fe recovery of 50.43%. The concentrate obtained from the flotation can be used for pellet making process.

Sep 1, 2012

By V. F. Petrov

Today, sodium cyanide is extensively used for extracting gold, however it is highly toxic to the environment if not managed properly. This paper discusses the key challenges presented to gold operations in efforts to come into alignment with the Russian environmental regulations and suggests solutions to overcome these challenges. It is a fact that the major environmental threat cyanide poses to water sources. Therefore, natural water sources should be well protected from the adverse effect of cyanides used in hydrometallurgical processes. For this, the following site procedures and facilities are practiced: in-site and external water recycling systems, reclaim water treatment if required and tailings ponds with water impermeable screens (tailings ponds with controlled leakage). Cost comparison analysis of cyanide destruction methods was carried out. It was revealed that the aldehyde treatment method developed by Irgiredmet JSC demonstrated the best economics. Cyanide emissions are treated by mass-manufactured packed and membrane devices which allow to keep cyanides at the acceptable limiting values established by environmental regulatory agencies.

Jan 1, 2014

By C. Perez

In mineral processing plants it is important to estimate rock composition, size and grindability to improve control of the grinding process. It is well known that variation in ore grindability and size distribution directly affects mills power consumption and throughput. This paper extends a general machine vision approach for on-line estimation of rock mixture composition using color information. Our proposed rock lithological recognition method requires the following steps: division of each image into sub-images, color feature extraction using the Binary Quaternion-Moment-Preserving thresholding technique (BQMP) and support vector machines (SVM) for classification. The BQMP thresholding technique splits the image in two and chooses representatives of each half using the histogram as features. The statistical parameters of the color data can be expressed using the quaternion moments into the representatives. This method can be recursively applied to the sub-images, obtaining 5x2n features in n iterations. Once the feature vector has been computed, each vector is assigned to one of three classes using a classifier. The method was tested on a database containing 20480 sub-images (64x43 pixels) of five ore types as follows: massive sulphide (MS), disseminated sulphide (DS), net textured (NT), gabbro (G), and peridotite (P). These ore types were assigned to three grindability classes: soft (MS), medium (DS and NT) and hard (G and P). The database was divided in 2 subsets: 15360 sub-images used for training and cross validation and 5120 sub-images used for test. The classification accuracy was compared with a method previously published based on a mixture of principal components analysis (PCA) for color, and wavelet texture analysis (WTA) for texture feature extraction. WTA-PCA approach reached a 76% accuracy in test while our BQMP method reached 90% of classification accuracy using only color features. Experimental results show that our proposed method yields excellent results compared to previously published results. Keywords: rock classification, lithological classification, grindability estimation

Sep 1, 2012

By S. Banisi, A. Haji-Zadeh, H. Asadi, M. Maleki-Moghaddam

One area in AG/SAG milling field which has received a great attention is the optimization of liner design for any application to increase the availability of mills. The Gol-E-Gohar iron ore concentration plant uses three 9m × 2.05m autogenous mills (AG) in parallel in a dry operation. The AG mill shell is lined with three series (57 cm each) of 36-row liners. Due to large variations in feed characteristics and inadequate blending, the performance of AG mills has been lower than the target value. Therefore, to improve the comminution efficiency, the optimization of the design of AG mill shell liners was applied in this plant. By simulation it was found that increasing the liner lifter face angle from 7 to 30° while maintaining the original lifter height (i.e., 22.5 cm) could provide an appropriate charge trajectory. Measurement of the wear profiles of shell liners indicated that the wear along the liner length was not uniform and the highest wear occurred between 0.5 m and 1.2 m of the mill length. A new liner design was proposed by redistributing the metal from parts with a lower wear rate to the parts with a higher wear rate to arrive at a uniform wear profile along the liner length at the liner removal time. The non-uniform shell liner was constructed and installed in one of the three parallel dry AG mills. It was found that the first and second liner designs increased the mill throughput by 2.6 and 7.5%, respectively. After conversion to SAG milling on the account of liner change, 18% (from 413 to 489 t/h) increase in throughput was realized. It was predicted that the non-uniform liner designs will increase the liner life time by 10% and will reduce the scrap metal from the current value of 59% to 50%.

Jan 1, 2014

By E. Guerrini, M. Maccagni, J. Nielsen

"Lead is the most important material able to meet the current demand for energy storage. The lead acid battery is reliable, efficient and inexpensive. Continuous developments in battery construction are providing improvements in all aspects of the batteries’ performance. The lead acid battery is both the main lead product and the main raw material for lead production. More than half of the lead produced is from secondary smelters where batteries are the most important feed material. The environmental pressure on lead production has been increasing for many years, and continues to become stronger and stronger. The lead production processes and technologies themselves will require updating to meet the new regulations. Although they are very strict now, they will become even more so and current technologies may not be sufficient. Because recyclability is a strong point for the lead acid battery, the secondary smelters need to reduce the environmental impact as much as possible. In recent years, the secondary smelters underwent impressive changes in this direction, but some more improvements are possible. Electrochemistry can offer a step change improvement in making secondary lead production more environmentally friendly. Engitec has developed an electrochemical process base on a very high current density (high productivity) cell using an inexpensive electrolyte and at a relatively low cost. In this paper, the latest update on the technology is provided. INTRODUCTION The lead acid battery is considered the “walking dead” by some new technologies trying to replace it. It has played and will continue to play a very important role in our lives because it is inexpensive, fully recyclable and the existing lead and the mine reserves guaranty enough material for the extended future. According to the life cycle, the lead acid battery is the cheapest and the most effective system to store energy. Lead is practically a close loop where lead battery production consumes more than 80 % of the produced lead but contemporarily it is the most important raw material for the production of metallic lead. In fact, nowadays, the secondary production has overcome primary production and this trend is expected to continue. Primary lead is the make-up material for the existing battery production and the source of lead for the construction of the new ones."

Jan 1, 2018

By Jia Ma, Zhi-Chao Liu, Kang Liu, Chun-Feng Li, Bao-Bin Tang

"The geological environment of the certain uranium-molybdenum deposit is very complicated. While the study of process mineralogy is relatively few, which restricting the processing and leaching effect of ores. According to reaserch on process mineralogy of this mine, the basis of ore processing can be provided. The main contents of research are the uranium occurrence state and the influence of H2O2 in acid leaching. By various methods and experiments, the process of uranium mineralogical characteristics in this deposit are systematically studied. The results show that the uranium is mainly in the form of independent uranium minerals. The structures of these uranium minerals are venous and disseminated in mineral fissures, or microgranular inclusions in quartz and feldspar. It is not appropriate to concentrate the uranium minerals by flotation beneficiation because that the loss rate of target metals via water leaching process is very high. The ores are suitable for being acid leaching directly with 6% – 8% of H2O2, and the maximum leaching rate of uranium can be 96.88%. INTRODUCTION The uranium ores with associated elements have a large proportion in uranium resources (Lei, et al., 2014, Xing, et al., 2006; Ritchy and Wong, 1985). The uranium and molybdenum are easy to be paragenesis in nature enviroment because of their similar chemical properties. Therefor the uranium-molybdenum associated deposits are widely existing, such as the sedimentary sandstone uranium deposit in American with vanadium and molybdenum, the sedimentary sandstone uranium deposits in French with vanadium (Chen, et al., 2014; Lounis, 1997). A certain epithermal porphyry uranium-molybdenum deposit in China is mainly controlled by the subrhyolite- porphyry and the fault zone (Lv, 2012; Rui, 2010; Liu, et al., 2010). The ore properties of this deposit are complex, which include the high alteration degree, and the fine grain size of the target minerals (Ma, et al., 2013). The ore properties and occurrence state are quite different during each mining stage. As a consequence, the consumption of reagent increased and the leaching rate declined as long as the continuously mining. The author explored the best leaching rate of target elements According to the basic research on process mineralogy of present ores, experimental study of water leaching and oxidizing acid leaching on different particle sizes."

Jan 1, 2018

By R. C. Miranda

Artificial vision systems are increasingly used to assist humans to perform different tasks in different areas. These systems are able to recognize patterns in complex images, which can provide multiple data. Currently, vision systems are used in both; monitoring traffic - which uses radars for vehicular plate recognition- as in metallurgical and food industries for strict quality inspections. Their use in mining occurs in measuring the speed of froth over the lip of a cell, in determining the shape and size of pellets, in obtaining from the tendency of mineral content and as a replacement for laboratory analysis of particle size. With this advanced tool, it is possible to achieve significant improvements in quality, productivity, and especially in reducing costs in pelletizing plant of iron ore. The objective of this paper is to contemplate the current situation of image analysis in the pelleting plants and glimpse at the potential applications that are being developed. This paper also presents the conception and implementation of an automatic control system of the pellets size distribution applied on a pelletizing plant of iron ore. The article demonstrates the strategy used for measuring the size distribution of the iron ore pellets, based on image analysis and the strategy implemented on advanced process control, which shows substantial gain on plant performance.

Sep 1, 2012

By Jonas Addai-Mensah

In this paper, the results emerging from the several basic and applied studies performed to provide fundamental understanding of the interplay between clay pulp chemistry, orthokinetic flocculation performance, particle interactions, applied shear and dewaterability of fine clay mineral dispersions are presented, reconciled, and discussed. Modification of pulp chemistry and behaviour was achieved by using kaolinite and Na-exchanged (swelling) smectite clay minerals, divalent metal ions (Ca(II), Mn(II)) as coagulants and high molecular weight, anionic polyacrylamide copolymers: carboxylate substituted (PAM A) and 2-amido 2-methyl propane sulphonate (PAM S) (PAM S), non-ionic polyacrylamide homopolymer (PAM N) and non-conventional, non-ionic polyethylene oxide (PEO) as flocculants. Clear links between pulp interfacial chemistry, particle interactions and dewatering behaviour, resulting from the influence of hydrolyzable metal ion, pH, temperature, polymer structure type and shear, are established. Optimum conditions for improved, orthokinetic flocculation performance of negatively charged clay particles, reflecting faster settling flocs (>10 m/h) comprised: (i) coagulation, (ii) moderate agitation rate, (iii) shorter agitation time and (iv) anionic rather than non-ionic PAM. The optimum flocculation conditions did not, however, have a significant impact on the final sediment solid content of 20 ? 25 wt%. Further application of shear to pre-sedimented pulps improved consolidation by 5 - 15 wt % solid. Application of the findings and new knowledge gained to real plant tails? case studies for marked improvement in dewaterability through thickening is demonstrated.

Sep 1, 2012

By Behzad Vaziri Hassas, Firat Karakas, Mehmet Celik, Onur Guven

Since dewatering is a costly process, removal of moisture from relatively fine size lignites is an important industrial problem. As the lignite gets finer, the presence of micropores and relatively low hydrophobic nature of lignite lead to trapping of large quantities of water in the coal matrix. Lignites used in power stations need to be dried to a certain degree of humidity before it is transferred to the combustion chamber. It is generally wise to dewater coal as much as possible by physical means before it is dried. However, dewatering cost in some cases may be prohibitive. Thus, sometimes removal of even little percent moisture may be of great help in such operations. Surfactants have been used to increase the efficiency of coal dewatering. It is crucial to select appropriate type and amount of surfactants in order to get higher efficiency. Since the hydrophobic characteristic of coals increases with increasing the coal rank, dewatering of bituminous and anthracite can be accomplished using low HLB surfactants (Oily), however, these surfactants are not efficient in the case of low rank coals like lignites and brown coals. It is suggested that adsorption of low HLB surfactants on high rank coals is governed by Acid-Base interactions rather than electrostatic and van der Waals forces. Since this characteristic in lignites is not strong enough, low HLB surfactants could not be effectively adsorbed on low rank coals to make surface more hydrophobic. In this paper, a special set-up has been designed to study the effect of high HLB surfactants on dewatering of fine lignite particles. It is shown that high HLB surfactants function more efficiently on low rank coals than low HLB ones.

Jan 1, 2014

By Harri J. Lehto, Marja I. Oja

Empirical models used for predicting the performance of screens on the basis of capacity, cut size, water split and grade efficiency curves were evaluated. This paper reports experimental results obtained with single-deck Derrick screens. The performance of the screen was tested with limestone in a separate screen set-up, in a pilot plant and in industrial scale test runs. The results of pilot plant experiments showed that the measured water split was higher than the measured bypass. This is an indication to that water flow does not entrain the same proportion of all fine particles present in the feed which is advantageous for screening. The experimental design for the industrial test runs was made on the basis of the pilot plant tests. Suitability of the existing models has been checked and accuracy compared. The tests showed that best grade efficiency model was the Rosin-Rammler model. An empirical model for the evaluation of the model parameters as a function of pulp density of the feed and the load of the screen is suggested.

Jan 1, 2003

By Xu Wang, Bang Chen, Xiujian Luo, Wei Tang, Xiao’ou Xia, Fangming Liu

"The inertia cone crusher has lots of advantages, such as big crushing ratio, fine particle size, material layer crushing, good passing tramp iron performance and stable technical index, realized open crushing circuit and simplified crushing flowsheet. The crusher was input to China’s Beijing General Research Institute of Mining and Metallurgy (BGRIMM) from Russia’s Mekhanobr-Tekhnika Research & Engineering Corporation at the beginning of the 1990s. This paper introduces that after years of absorption and innovation how Chinese researchers optimized and creatively designed about transmission mechanism, bracing structure, kinetic parameters, lubrication system, dust sealing system, damping system and hydraulic control system etc on the basis of keeping its advanced theory and unique structure, therefore the crusher’s stability was raised and the usage cost was reduced greatly. Accordingly the inertia cone crusher in China has been widely used in many fields, such as mineral resources and the recycling of metallurgical slag. The achievement in cooperation was fully affirmed by governments of Russia and China, and cooperation of science and technology in the mining and metallurgy industry between Russia and China is promoted greatly. INTRODUCTION From the early 1950s, the former Mekhanobr Institite(now Mechanobr-Tekhnika Research & Engineering Corporation) devoted itself to the research of inertial cone crusher and put it into industrial application in the late 1980s. Inertial cone crusher is like a maverick flower in the field of crusher. With its excellent performance and excellent application effect, it shocks the world and is destined to shine with a bright future. In the early 1990s, the chief leaders of the Beijing General Research Institute of Mining and Metallurgy (BGRIMM), Academician Sun Chuan-yao and Professor Zheng Baochen, captured the extraordinary performance and strong vitality of inertial cone crusher with keen eyes. So the two big institutes started the cooperation to introduce inertial cone crusher to China. Since then, Inertia cone crusher has been able to flourish in China and have achieved impressive results with two institutes’ continuous effort."

Jan 1, 2018

By L. O. Filipov, N. E. Menad, A. Geneyton

"Zeta potential of synthetic monazites presenting various compositions were measured to investigate the effect of the main lanthanides substitutions on electrophoretic mobility and resulting IEP. The measurements are performed in a CO2 depleted and enriched solutions showing both reduced influence of monazite chemistry and strong influence of ions resulting from the solubilization and dissociation of CO2. The influence of oleic acid on the electrophoretic mobility of those monazites was also investigated. The influence of pH on oleate adsorption was studied using a bubble/particle adhesion system. Adhesion strength measurements were performed on pure synthetic monazite-(Ce) and monazite-(La). An extensive thermodynamic model of monazite in water was developed to highlight correlations between lanthanides hydroxides/carbonates species concentrations in the bulk solution and oleate adsorption. Based on electrophoretic measurements, advanced thermodynamic consideration and adhesion measurements, further details of the oleate adsorption model on monazite surface were proposed.INTRODUCTION Electrophoretic and potentiometric data on monazite and, a fortiori, other rare earth semi-soluble salts such as bastnaesite are extremely erratic (Chelgani et al. 2015). The isoelectric points measured with electrophoretic mobility methods range from 4.7 to 6.5 although sporadic data indicates an IEP (isoelectric point) far from that range. Different explanations are proposed in the literature to explain the IEP variability notably the numerous chemical substitutions that frequently occurred within monazite crystal lattice (Chelgani et al. 2015). Based on lanthanides speciation diagram, several authors highlighted the influence of specific lanthanide species on the flotation performance of rare earth semi-soluble salts when carboxylate or hydroxamate collectors are used. Although lanthanides ions have a great affinity for carbonates groups (Kragten et Decnop-Weever 1987), lanthanide (hydrogen) carbonates were not implemented in speciation diagrams. In this work, an advanced thermodynamic model is proposed to highlight correlation between flotation performance and lanthanide species predominance but also concentrations. Qualitative measurement of the monazite surface hydrophobicity are performed through tests of adhesion of coarse monazite particles onto bubbles. Since flotation and microflotation technics are highly influenced by hydrodynamic parameters, this method was investigated to obtain a sharp contrast between appropriate and inappropriate pH conditions. This paper is to investigate 1) the effect of lanthanides substitution on monazite surface properties through zeta potential measurements, 2) the mechanism of adsorption of carboxylates on monazite surfaces and 3) the effect of CO2 on monazite surface properties and carboxylates adsorption."

Jan 1, 2018

By Peter Ay, Florian Logsch, Satyanarayana Narra

"The traditional lignin separation process from the precipitated suspension creates severe filtration problems by plugging of the filter medium due to the small particle size (20 to 60 µm) of the suspended lignins. The plugging causes further problems in the successive processing of the filter cake. A new lignin separation process has been developed at the Brandenburg University of Technology (BTU) Cottbus as a part of the Research and Development and Demonstration (R & D & D) project "LignoBioFuel". The new developed process separates lignin in the form of granules with diameters ranging from 100 µm to 300 µm. The restrainment of the granule’s size in their successive treatments is expected to result in higher filtration efficiencies and reduction in plugging of filter mediums. To evaluate the filtration efficiency, the filtration resistance of the produced granules as well as the conventional suspensions has been investigated. The results show that there is a 60 to 80 % filtration efficiency increase and around 60 % reduction in plugging of filter mediums with the lignin granules in comparison to the conventional suspensions. Furthermore the successive processing of lignin granules was easier due to their porous structures removing the impurities such as adherent acids and salts. The purity of the separated lignin was measured with their sulphur (reduced from 7 % to 2.7 %) and ash (reduced from 46 % to 0.5 %) contents. The newly developed process has displayed better results in comparison to that of the conventional process. The new process displays high potentials in optimizing and improving the present state of the art treatments and is promising several ecological, economical and environmental improvements."

Jan 1, 2014

By Braulio Fernández, Gonzalo Montes-Atenas

The mechanisms taking place during the leaching of chalcopyrite when it is in contact with other sulphide minerals, particularly pyrite, is still a matter not fully solved. The GalvanoxTM process has been suggested as a technical solution to extract copper from chalcopyrite at commercial level inhibiting passivation phenomena widely reported in the field of hydrometallurgy. Although there are some rules of thumb to implement the process in fully flooded stirred conditions such as the optimum pyrite/chalcopyrite mass ratio should range between 2 and 4, among others; not many research studies have been focused on studying the effect of the surface contact area between chalcopyrite and pyrite to reach best copper extraction conditions. The aim of this research work is to determine the effect of the mass and surface area ratio between the minerals and the surface area of each of the mineral species effectively exposed to the leaching solution. Different particle size distributions of pure pyrite and chalcopyrite were contacted in a small column and subjected to leach tests using sulphuric acid in concentrations close those used in industrial leaching processes. The mass and surface area ratios which optimize the extraction of copper were obtained. It was found the best leaching conditions were attained when reducing the particle size distribution of pyrite regardless the particle size distribution of chalcopyrite. Further analysis concerning the impact of this conclusions on large scale operations is presented and discussed.

Jan 1, 2014

By M. Lundström, J. Aromaa, S. Seisko

"Gold dissolution was investigated in ferric chloride media, promoted as one of the most promising alternatives for cyanide-free gold leaching. The characteristics of gold open circuit potential (OCP) and its relation to gold dissolution rate was investigated. Furthermore, the reaction mechanism of gold dissolution in ferric chloride leaching was discussed. The effect of solution variables, [Fe3+] = 0.02–1.0 M, [Cl–] = 2–5 M, T = 25–95 °C and pH = 0–1.0, on OCP and dissolution rate were studied electrochemically using rotating disk electrode (RDE) and linear polarization resistance (LPR) method with ?cyc = 1000 RPM. The investigated gold OCPs in ferric chloride solutions were found to vary between 597 and 688 mV vs. saturated calomel electrode (SCE) and gold dissolution rates between 1.2·10–5–5.0·10–4 mol s–1 m–2. Increase in temperature (25–55 °C) and ferric concentration (0.02–1.0 M) changed OCP into more positive values, while increase in chloride concentration (2–5 M) decreased it. The logarithm of gold dissolution rate was shown to increase linearly with increasing OCP at the temperature range 25–95 °C, ferric concentration range 0.02–0.5 M and chloride concentration range 2–4 M. A notable increase in the gold dissolution reaction rate was evident at T > 55 °C. INTRODUCTION Currently cyanide leaching is the predominant method used in gold production from primary raw materials (Marsden and House, 2006). However, since the Baia Mare disaster in Romania in 2000, the use of cyanide has been the subject of international concern due to the toxic nature of the chemical posing a significant health threat if exposed to the ecological entities (Hilson and Monhenius, 2006; UNEP/OCHA, 2000). Therefore, several countries e.g., Costa Rica, Czech Republic, Germany, Hungary, Turkey, many states of the USA and provinces of Argentina, have started to ban or limit cyanidation via legislation (Laitos, 2012). Thus, alternative solutions, such as thiourea, thiosulphate, oil-coal agglomerates as well as halides have been investigated in order to replace cyanide as lixiviant (Adams, 2016; Aromaa et al., 2014; Aylmore, 2005; Hilson and Monhemius, 2006; Lampinen et al., 2015). Ferric and cupric chloride leaching have been reported to have advantage over cyanidation being capable to dissolve refractory gold minerals, without pre-treatment such as pressure oxidation or roasting (Angelidis et al., 1993; Lundström et al., 2014; Marsden and House, 2006; van Meersbergen et al., 1993). According to Aylmore (2005), 4% of publications for alternative lixiviants to cyanide in gold leaching were within category oxidative chloride processes including aqua regia and acid ferric chloride leaching. Further, some patents have been granted for ferric chloride leaching of gold (Abe and Hosaka, 2010; Lundström et al., 2016)"

Jan 1, 2018

By C. Çelik

Nowadays the optical sorting of industrial minerals is one of the most important processing methods which has cost efficient production possibilities. This method is used for industrial and raw materials that have different colour and brightness features. Initially this technology is used for sorting of foodstuffs and recovered glass, but for a long time also as physical mineral processing method for both industrial minerals like: limestone, marble, talc, basalt, flint, quartz and secondary raw materials like: building rubble, refractory materials, glass, plastic and household waste. In this study via optical sorting the separation of quartz out of a flint mix, which consists of the particles with different colors and brightness, is aimed. Experiments are performed on an optical sorting machine named CombiSense® 1200 at the institute of ?Aufbereitung mineralischer Rohs-toffe? RWTH Aachen. This automatic picking device was developed by the company ?Separation Systems Engineering (SSE), Wedel?. Hand picking method is used for product analysis and the efficiency tables are prepared on every step accordingly. This process enables to reach quartz products with purity up to 100%.

Jan 1, 2014

By L. Y. Zhang

The metallic sulphides in Jinchuan Mine are relative friable and the gangue minerals suffer of wide secondary change, the overgrinding of metallic sulphides and sliming of gangue minerals are the main cause that makes the mineral separation indexes difficult to improve. So changing the process of grinding, and classification, and optimizing the particle size distribution of grinding product is the key improving the separation performance of Jinchuan nickel and copper ore.

Jan 1, 2014

By Wei Sun, Ruolin Wang, Jianjun Wang, Xiaodong Li, Honghu Tang, Yuehua Hu, Anh V. Nguyen, Haisheng Han, Kefeng Chen, Zhao Wei

It is difficult to separate scheelite especially from fluorite with fatty acid collectors because the adsorption mechanism of these collectors occurs through chemisorption of the oleate ion onto the mineral surface. A simplified flotation process using Pb-BHA complexes was developed to replace the energy-inefficient Petrov’s process of using a fatty acid, increasing the recovery of scheelite and reducing the cost. The relationship between surface chemical properties (crystal chemistry, solubility, and Zeta potential) of minerals and flotation by using a fatty acid or Pb-BHA complexes was studied in detail to provide new insights into the selective separation mechanism. The results indicate that the scheelite surface exposes more O atoms than Ca and that they are negatively charged due to the anisometric dissolution of Ca and WO4, which provides the possibility for separation using selective interfacial reaction. The FTIR and Zeta potential results indicate that both chemical and electrostatic adsorption play an important role in the adsorption of Pb-BHA complexes on the scheelite surface. The XPS results of the atomic composition and binding energies confirmed the presence of the adsorbed Pb-BHA complexes and that O and Ca may be the active adsorption sites. Therefore, scheelite was able to be collected by forming either a Ca-O-Pbcollector or W-O-Pb-collector (BHA). However, fluorite was only able to be collected by a fatty acid collector and colloidal [H2SiO3]n -, and a high temperature was needed improve the selective desorption of the adsorbed fatty acid collector by forming Ca-[H2SiO3]n - on the fluorite surface, resulting in serious problems in industry. However, the Pb-BHA complexes significantly contribute to improving the recovery of scheelite minerals, simplifying the flotation process, and circulation of the residual reagents and water. The new process has been applied in Shizhuyuan Mine, and improved the recovery by almost 10%.

Jan 1, 2018

By Weiran Zuo, Narayan Krishnan, Frédéric von der Weid, Emmy Manlapig, Fengnian Shi, Klaas van der Wielen

Laboratory study has identified a new application of high voltage electrical pulse technology for pre-weakening ores. In recent years, the Julius Kruttschnitt Mineral Research Centre (JKMRC), Newcrest Mining and SELFRAG AG have conducted joint research in validation of pre-weakening of SAG mill feed through the pilot scale tests and comminution circuit simulations. Ten tons of SAG mill feed with a top particle size 150 mm were tested with two pilot scale SELFRAG machines installed in Switzerland. A simulation study using JKSimMet software was carried out to find where the high voltage pulses pre-weakening technique can be best applied in a gold-copper ore comminution circuit, based on the data of the pilot scale SELFRAG tests. A novel comminution circuit was designed, which incorporated SELFRAG to pre-condition part of SAG mill feed (9.5 to 150 mm) and to treat the circulating SAG mill pebbles. The high voltage pulse technology effectively reduced the amount of ‘critical size’ particles in the SAG mill and pre-weakened particle strength for grinding. Attributing to the nature of bi-modal size distribution and the significantly reduced F80, the simulations showed that the SAG mill had spare capacity to process part of hydrocyclone underflow from the secondary ball mill grinding circuit. The simulations indicated that the novel comminution circuit had the potential to remove two MP1000 pebble crushers and one 10 MW ball mill from the existing 2000 t/h grinding circuit. A 5 kWh/t energy reduction by adopting the novel comminution circuit in a gold-copper operation may be realized. This would result in substantial savings in operation costs.

Jan 1, 2014

By S. Banisi, A. R. Hasankhoei, A. R. Ghasemi, E. Razi, G. A. Parsapour

At the pelletizing plant of the Gol-E-Gohar mining and industrial company two parallel dry closed grinding circuits, each with the average throughput of 300 t/h, are used. Each grinding circuit consists of a burner, a dry ball mill (6.2 m×13 m) and an air separator. The ball mill consists of a 2 m-long drying and an 11 m-long grinding chambers. The iron ore concentrate is fed to the drying chamber by a feed chute. The first 1.35 m of the drying chamber consists of 56 flights in two rows to decrease the feed moisture from 5% to below 0.2% and the rest of dryer chamber consists of deflectors to pass the material to the grinding chamber. It was found that when the feed moisture content increased from 1.3% to 3.5%, the throughput decreased by 12% (35 t/h) indicating a low performance of the dryer. Monitoring the wear rate of flights for a period of 12 months showed that the first 0.8 m length of the flights length did not experience any wear. This means that about 59% of flights do not contribute in material distribution and drying. A DEM simulation of feed chute and the drying chamber demonstrated that due to the inappropriate design of feed chute most of materials do not get in touch with the first 0.8 m length of the drying chamber. To overcome this problem, various feed chute designs with different geometries were simulated by the KMPCDEM© software. With the aim of arriving at a proper material trajectory, where the total length of the flights are used, a new feed chute was selected. The simulation results indicated that if the height of the flights is increased from 1.60 to 2.26 m and the slope is increased from 45 to 48 degrees the material arrive at the first 0.48 m of drying chamber. In this manner, the unused part of the drying chamber decreases from 59% to 36% of the length. After installation of the new feed chute, during a period of three months the throughput increased by 36 t/h.

Jan 1, 2018