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By B. McFadzean, P. E. Ngoepe, P. P. Mkhonto, J. Taguta

The adsorption of heterocyclic collectors such 2-mercaptobenzothiazole (MBT), 2-mercaptobenzoxazole (MBO), 2-mercaptobenzimidazole (MBI) and their derivatives on pyrite form a basis in understanding the flotation reactivity that may be applicable in a wide range of sulphide minerals. This study uses a computational and experimental approach to determine the heat of adsorption of MBT, MBO, MBI and modified MBT collectors onto pyrite surfaces. Computational calculations found that the adsorption energies were in the order: MBO > MBI > MBT. The heterocyclic collectors were adsorbed in their thiolate form on the surface. In the case of the pyrite (100) surface, the MBT adsorbed through the exocyclic sulphur atom, while MBO and MBI adsorbed through the exocyclic sulphur and N atoms onto the 5-coordinated Fe atom. The (111) surface was found to be more reactive and different adsorption mechanisms were predicted, where the MBT exocyclic sulphur atom bridged on the 5- coordinated Fe and surface 2-coordinated sulphur atoms, while the N atom adsorbed on the 5-coordinated Fe atom. In the case of MBO and MBI, dissociation of the exocyclic sulphur atom from the collector occurred with subsequent interaction with the surface 5-cordinated Fe and 2-coordinated S atoms. This resulted in the collector carbon atom adsorbing on the surface 2-coordinated S atom, while the N atom adsorbed on the 5-coordinated Fe atom. The adsorption of the modified MBT was found to be more exothermic than the MBT, which showed that introduction of a –CS2 group on the exocyclic sulphur atom improved the affinity of MBT on the surface, and was thus a better flotation collector. The computational results were supported by experimental enthalpy of adsorption measurements and microflotation tests. The chemistry of the heterocyclic thioamides is complicated by the fact that they can exist in a number of tautomeric and ionic forms at different pH’s. This is discussed in relation to the flotation and calorimetric data.

Jan 1, 2018

By S. Titkov

At present, Russia is engaged in processing, 3new plants of hard-to-process potash ores with increased content (up to 10 - 12%) of insoluble impurities (insoluble residue ? I.R.). This required additional research to improve the process of potash ores flotation. Based on the study of the effect of dispersive properties of frother and its flow rate on the efficiency of aliphatic amines with different length of the hydrocarbon radical (as sylvite collector) there was showed the possibility to apply high molecular amine with length of hydrocarbon radical C20 ? C26 by normal temperature of circulated plant salt solution (saturated solution KCl ? NaCl ? H2O). There was designed and tested in plant conditions the modified amine collector with the length of the hydrocarbon radical C16 - C26, improving flotation of Sylvite under normal temperature of circulating salt solutions at potash flotation plants. There was made the study of the influence of the hydrocarbon radical length of alkylmorpholine on the Halite flotation from intermediate products of sylvite recleaner flotation with different content of I.R. (silicate-carbonate slimes), at normal and elevated temperature of salt solution. On the basis of the application of modified alkylmorpholine for Halite flotation, there was developed the process of further beneficiation for the intermediate products of sylvite recleaner flotation from potash ores with increased content of insoluble impurities, which can eliminate the circulation of the intermediate products in the process flow sheet of sylvinite ore processing and increase the KCl recovery into the finished product. Keywords: flotation, potash, halite, alkylamine, alkylmorpholine

Sep 1, 2012

By Bertil I. Pålsson

The most common REE containing mineral that is worked today is bastnäsite. It means that mineral processes are adapted to it and that the metallurgical separation techniques for winning of individual REE are adapted to bastnäsite concentrates. For all other deposit types, suitable mineral processing methods and separation technologies need to be adapted and/or developed. Preliminary mineralogical analyses indicate that slightly less than half of the REE in the tailings dumps at LKAB/Kiruna are associated to apatite. The rest is in the minerals monazite (maybe associated to apatite) and allanite. At least allanite is probably not floatable with reagents commonly used for apatite. Mass and element distributions for the tailings sand reveal that very little apatite is present above 300 µm, and that approx. 30 % is below 20 µm. REE does not follow P2O5 completely and are also present in coarser fractions. Flotation results show that the best condition for both apatite and REE winning is pH 9, high collector addition and low dosage of water glass. Under these conditions, the lab-scale flotation gives an apatite concentrate with at least 30 % P2O5 at 70 % recovery. REE follows apatite in the cleaner steps but only partly. Its recovery is approx. half compared with apatite. The reason for the low REE recovery is likely to be that REE to a large extent is trapped in non-winnable minerals, especially allanite. The REE grades in the concentrate are expected to be in the range 3000 ? 4500 g/ton. Keywords: flotation, REE, apatite, monazite, allanite

Sep 1, 2012

By Herman D. Mendoza

A rapid recovery/recycling process was introduced utilizing the surface-chemical properties of finely dispersed mercury and alumina (Al2O3) fibers in aqueous environment. The conventional method of amalgamation or .ball milling. involves the mixing of a substantial amount of mercury to collect free gold during the grinding stage. In effect, a portion of the mercury is transformed into minute droplets that readily float and disperse in the amalgamation effluent. The fine droplets of mercury in the dispersion readily attached onto the positively charged macroscopic alumina fibers (i.e. = pH 9.8) at conditions pH 3 to 10. When an effluent from settling procedure after an amalgamation-grinding stage is passed through a column-bed packed with alumina fibers, maximum collection of negatively charged finely dispersed mercury occurred at pH 3 to 6. The collection/attachment efficiency was 99.5%. The collected droplets of mercury, which are left in the column-bed of alumina fibers, were subsequently rinsed with alkaline solution at pH 10 to 11.5. At these conditions, both mercury and alumina fibers carry negative surface potentials and resulted in the partial detachment of mercury from the alumina fibers. The detachment efficiency was only 30-35%. The attachment/detachment mechanisms in this study were analyzed using the DLVO theory.

Jan 1, 2003

By Komar Kawatra, Joseph Halt

"Bentonite clay has been the traditional binder for iron ore pellets. However, bentonite increases pellets’ silica contents and is expensive. Researchers have proposed lowering bentonite doses by mixing it with other common binders. These mixtures may only be successful if the fundamental bonding mechanisms are understood. For example, what happens when bentonite (physical bonding) is mixed with fly-ash (chemical bonding)? What happens when bentonite is mixed with cornstarch (physical bonding)? In this paper, experiments are described where bentonite was mixed with various ratios of cornstarch and fly-ash, and pellets were agglomerated using 0.66 % w/w binder. Ca(OH)2 and CaCl2 were added as activator and accelerator, respectively, to the bentonite-fly ash mixture. Curves of pellet dry strength vs. bentonite-starch ratio were linear, suggesting the physical-physical bonding mechanisms were compatible - acceptable strengths (> 22 N) were produced at all bentonite-to-starch ratios. This was contrary to bentonite-fly ash mixtures, which displayed dry strength curves with a noticeable minimum due to competing binding mechanisms. Bentonite alone and fly ash alone produced acceptable strengths (> 22 N), but their mixtures resulted in weak pellets. Due to the positive results using cornstarch (CS) binders, the effects of CS solubility in water were investigated using two CS with high and low solubility (60 and 7.5 %). CS was premixed with bentonite at various ratios (0, 20, 40, 60, 80, 100 %). Pellets were agglomerated using 0.66 % w/w binder. The dry strength of pellets ranged from 50-300 N using the high solubility CS mixtures, and from 50-85 N using the low solubility CS mixtures. Fired strengths exceeded 2200 N/pellet at all bentonite-cornstarch ratios. This research showed that cornstarch solubility is an important factor in determining its effectiveness as a binder for iron ore concentrates, but significant work is still necessary before it can be used as a bentonite replacement."

Jan 1, 2014

By Lang Shiping

The criteria for designing a crushing chamber are presented and a program for designing the shape of the chamber is proposed. During the chamber shape design, major design parameters are analyzed first, optimized parameters are determined next and the basic shape of chamber is figured out finally. In the basic chamber design program, the influence of abrasion of basic chamber shape and material characteristic are not accounted for usually. Here, based on the minimum abrasion of chamber shape and uniform particle size theory, the equation for chamber surface curve and the transcending function were formulated and a low-abrasion chamber was designed. Since the chamber shape designed based on experience and experiments is not necessarily the best, optimal design of the crushing chamber shape was carried out. Cubic spline function was used to represent the chamber shape curve and a mathematical model was formulated. The optimal shape solution was obtained using a complex method. Finally, the optimal chamber shape was determined by matching the moving cone stroke S, moving cone speed N and the moving cone bottom angle Thus, superior technical performance of the cone chamber was achieved.

Sep 1, 2012

By Tuan V. Nguyen, Kosta Simic, Louis Mittoni, Murray Rudman, Jean D. Swift, John B. Farrow, Phillip D. Fawell

"Research projects towards developing a sound understanding of the factors controlling the performance of gravity thickeners have been conducted by the AJ Parker Cooperative Research Centre for Hydrometallurgy since 1988 through AMIRA International. The current phase of this work, the three year P266D .Improving Thickener Technology. project, has 27 sponsors comprising mineral processing companies, reagent suppliers and thickener manufacturers.These projects have resulted in the development of a range of tools and techniques to address flocculation, thickening and associated dewatering issues. A number of Computational Fluid Dynamics (CFD) models have been developed to predict likely full-scale thickener performance under various process conditions, based upon a knowledge of thickener design, plant flows and assessment of the flocculation behaviour of the feed slurry. At the same time, various laboratory and plant studies have been used to quantify important thickener processes, and to provide validation of the CFD models. These numerical and experimental capabilities have been applied to various thickener issues across a broad range of mineral processing operations, leading to significant process improvements and substantial financial benefits.This paper presents an overview of the work conducted during these projects, focussing on the research tools, the nature of the information that has been gained and the implications for thickener performance."

Jan 1, 2003

By Minna Päällysaho

For the first time, the idea of sustainable development was recognised at a high political level at the UN Conference on Environment and Development held in Rio de Janeiro in 1992 (UNEP, 1992). Then the governments of the world committed themselves to promote sustainable development in their national activities and international co-operation. In 2001, the European Council approved the EU Strategy for Sustainable Development (European commission, 2011). This complements and supports the EU?s so-called Lisbon Strategy (European council, 2000) on competitiveness. The revised Strategy for Sustainable Development was approved in June 2006. Recently sustainability has had an important role in policy and decision-making while the public awareness towards limits of the environment has been rising. However, the indicators of industrial sustainability satisfy primarily the needs of corporate management and global investors. The information is often broad and non-specific and might occasionally even give a false impression. Moreover, contradictions between environmental, economical and social aspects also point out the unreliability of existing sustainability indexes. Therefore, the current state of affairs serves the interests of neither the industry nor the policy makers. Current corporate sustainability indexes and indicator systems need to be assessed with scientific methods encompassing the identification of their strengths and weaknesses. This requires quantitative and qualitative assessment and synthesis of existing indexes and indicator systems, providing new data on the functionality of existing corporate sustainability indicators. Therefore, the assessment lays the foundation for the development of new, more balanced sustainability index. Our first aim in this multidisciplinary article is to analyse existing global sustainability indexes for process industry. Second, we will introduce a first version of a new sustainability index for process industry, which includes the environmental, social and economic impacts of the plant, as well as legislation aspects.

Sep 1, 2012

By F. Q. Cheng

As the important potash, the product yield of KCl in winter is low and the resources waste is serious according to the deficiency of collectors, which can be used in this condition currently. This paper studied on the change of contact angle, turbidity, and flotation recovery of KCl particles when different chain lengths, ratios of amines were used as collectors in KCl flotation process to get a new mixed collector. The contact angle values of KCl crystal in its brine solution added different amine collectors were first measured by captive bubble method. The turbidity of brine solutions were then measured by the laboratory turbidimeter at room temperature when different amine collectors were contained. In the end micro-flotation experiment using mixed amine with fixed ratios and ODA as collectors respectively at 5 °C, 23 °C were performed. The results show when the ratio of the mixed amine is DDA- 20%, ODA-60%, C20-20%, the contact angle at KCl surface is the maximum and the hydrophobic state is best. Meanwhile the result of turbidity measurement indicates that the dispersion of mixed amine colloids is better than the ODA collector due to the addition of DDA, which plays the role of frother. The flotation results also prove that the mixed amine is not only fit for the KCl flotation at room temperature but also fit for its flotation at low temperature. This study provides strong technical support to extend the production time of potash business in Chaerhan areas in China.

Sep 1, 2012

By R. S. Wang

The flotation of pyrite which be pretreated by electrochemical ways under external controlled voltages in different pH is explored. The floatability of pyrite is increased indistinctively after being pretreated in acidic and xanthate environment; Whereas, it is increased obviously between 400~800 millivolt in alkaline and xanthate condition. The reason for higher recovery of pyrite is that oxida-tion reaction, which results in S0 and S02, takes place on its surface, and that ethyl xanthate is oxi-dized into dixanthogen. In the meantime, the kinetics and mechanism is also studied.

Jan 1, 2014

By F. C. Araújo, T. Tavares, J. Leite

"This work presents the small-scale mining cluster of kaolin in Rio Grande do Norte (RN) and Paraiba (PB), both Brazilian states, including the following information: number of companies, process flowcharts, production numbers, mineralogical (XRD) and chemical (XRF) composition, granulometric distribution (screen and laser granulometer) and image analysis (SEM). Some social indicators in the region of the RN and PB States are presented in association with these data. The number of companies and their flowsheet were obtained through in situ visits and sample collection for technological characterization. The comparative study of the different flowsheets for kaolin production in the world was done using the databases and presenting the state of the art of kaolin processing. The results indicated that the mean feed typically contains 35-39% kaolin with quartz, muscovite and kaolinite as main mineralogical components and SiO2 (65.83%), Al2O3 (21.19%), K2O (3.9%), and Fe2O3 (0,63%) as main chemical constituents. The products of mineral processing are twofold, one between 74 µm and 37 µm, and the other smaller than 37 µm. The wastes of operation had major quantities of kaolin. The average Human Development Index (HDI) of the cluster region is approximately of 0.61, which shows an association between mineral processing plant and social indicators. The kaolin recovery, however, is between 30-55% for the three most common types of flowsheets that are currently used in the small kaolin mining cluster, indicating a need for technological improvement to achieve regional development. These data could be used incrementally to adapt the process plant currently used in the small-scale mining cluster of kaolin."

Jan 1, 2014

By M. Karamoozian

Modelling and optimisation of the power draw of large SAG mills are important due to the large power draw which modern mills require (5~10 MW). The cost of grinding is the single biggest cost within the entire process of mineral processing. Traditionally, modelling of the mill power draw has been done using empirical models. Although these models are reliable, they cannot model mills and operating conditions, which are not within the model database boundaries. Also, due to their static nature, the impact of the changing conditions on the power draw, within the mill, cannot be deter-mined using such models. Despite advances in computing power, on-line modelling of large plant scale mills could be a time consuming task. On the other hand, using on-line parameters for model-ling, result in more reliable control of SAG mill without performing any more costly tests. In this paper, SAG mill power draw is modelled using neural network approach. Six inputs, namely: solid percent, two bearing pressures, noise, recycle and feed rate were used to model the power draw. The produced model shows an acceptable correlation coefficient, R2 =0.9623.

Jan 1, 2014

By Mario Gerards, Marco Steinberg, Jan Huben

"Wet high intensity magnetic separation or WHIMS is a widely used technical process for the recovery of magnetic susceptible iron ore particles, mostly for fine and ultrafine grain sizes. The JONES® WHIMS - Wet High Intensity Magnetic Separator, has been used for many years and in countries all around the world. This paper outlines the physical principles utilized for the separation inside the unit, as well as some of the recent changes and developments on the design. It will also give an outlook on the theoretical potential of different alternative yoke materials. The aim of this paper is to analyse the suitability of different yoke materials to improve the equipment. This will be done comparing the magnetic and mechanical parameters and analysing availability and price to find the best compromise regarding cost and benefit. As far as the different kinds of materials are concerned, a special material has been identified as suitable during the comparison exercise. After running the economical calculations, especially with respect to the reduction of the total power consumption of the equipment, a tremendous reduction of the total power consumption has been determined. In addition, to the theoretical exercises and due to the promising results of the same, the Pilot Unit P 40 of the JONES® WHIMS has been manufactured with the special material in order to get practical results as well. Finally, this paper outlines the theoretical and practical results focused on the power consumption. The results are showing that the total power consumption can be reduced tremendously. Hence, the way for a new generation of JONES® WHIMS - environmentally friendly - has been paved."

Jan 1, 2014

By Claudio L. Schneider, Peter R. King, Reiner Neumann

"Predicting the liberation spectra that are produced from breakage of two-phase ores under the random fracture assumption can be accomplished by measuring the conditional, on length, linear grade distribution directly from images obtained from a representative sample of the unbroken texture. The technique tremendously simplifies the prediction problem by avoiding the multiple convolutions that arise from the traditional method based on a description of texture from a measurement of the chord length distributions associated with each phase in the unbroken texture. For a 3-phase system, the phase transition probabilities associated with the textural information make the traditional calculation an almost insurmountable mathematical problem. The direct measurement procedure on the other hand can be expanded to three phases comparatively easily.A coal sample is used here to demonstrate the procedure. It is concluded that the conditional, on length, linear grade distribution can be predicted in the same fashion for multi-phase systems. Accurate stereological conversion is the practical hurdle to be overcome for multi-phase systems, but it is already a reality for 3- phase systems."

Jan 1, 2003

By E. Yigit

In the flotation process the physical factors such as agitation intensity air flow rate and pulp solid concentration are very important parameters affecting grades and recoveries of the products. The flotation tests were performed on the samples of Bigadic colemanite ore to investigate these factors at different agitation intensities ranging from 1000 rpm to 1400 rpm and air flow rates from 1000 cm3 ? min-1 to 2000 cm3 ? min-1 with 2 L and 4 L cells using Denver laboratory flotation machine. The tested collectors were Cytec Aero 825, Aero 848N and their mixtures. Agitation intensity and air flow rises resulted in more floated material although sometimes being not selective. These effects can be attributed to powerful collisions between air bubbles and mineral particles. The first observation was the effect of pulp solid concentration on the floatability of minerals, while the flotation in 2 L cell (0.125 g.L-1 solid concentration) at 1000 rpm (0.176 wattcm-3), and with 1000 cm3.min-1 air flow rate was possible, the flotation in 4 L cell (0.0625 g.L-1 solid concentration at 1000 rpm. (0.176 wattcm-3) and with 1000 cm3 ? min-1 air flow rate was not possible. However at 4 L cell after increasing agitation intensity to 1200 rpm (0.201 wattcm-3) keeping 1000 cm3 ? min-1 air flow rate, flotation was possible again. This shows that these factors such as agitation intensity have some critical role on flotation. Another interesting observation was on the selective effect of pulp solid concentration. In the flotation with 1 L cell at different agitation intensities, collector Aero 848N was selective against calcite, while in the flotation with 2 L cell at different agitation intensities the same collector Aero 848N was selective against colemanite.

Jan 1, 2014

By Luis G. Bergh

Today, large size mechanical flotation cells of 100 to 300 m3 are used in rougher operation in different flotation industrial plants, in Chile and worldwide. However, in spite of the advances in fundamental research and the notable growing in equipment size, with more complete instrumentation systems, there are still a lack of reliable data for industrial flotation modeling and simulation to advance in better control systems design. In this work, a model of a rougher flotation circuit, based on operating variables and parameters fitted from industrial data, obtained in some previous work, is used to develop a set of logic rules in order to aid operating decisions. The simulator was first used to sensitize the effect of changing the froth depth profile on target variables, and then to find out the best profile to reject common disturbances coming into the plant. The flotation circuit simulator was redesigned to incorporate an expert system following the proposed control algorithm. Several tests were performed to evaluate the control responses to different correlated series of input variables, such as feed grade, tonnage, particle size distribution, and solid percentage. Control alternatives are discussed based on the circuit simulator. Keywords: modeling, industrial data, flotation control, mineral processing.

Sep 1, 2012

By L. Filippov

"Nickel is an important metal with the total global consumption of about 2 million tons per year. It is sourced from both sulfide and laterite ore, but currently laterites are becoming more attractive for nickel production due to the depletion of high grade nickel sulfide ores. Laterites are generally processed by hydro or pyro-metallurgy and therefore, pre-concentration of nickel before such processes is very important. In this paper the effect different physical methods (including flotation) on the pre-concentration of nickel in laterite ores will be discussed. The ore used in this study was a laterite from South East Asia. Nickel was upgraded using different methods such as magnetic separation, flotation and sizing. The effect of ore mineralogy on choosing the best strategy to upgrade nickel will be discussed. The findings of this project will help to unlock a substantial volume of nickel with significant value from laterite ores.INTRODUCTION Nickel is an important metal with the total global consumption of about million tons per year which has grown rapidly during last decades (Mackey, 2011). Nickel is sourced from two different types of ores, sulfide and laterite. The majority (about 70%) of the world’s nickel resources occur as laterite ores which are often complex, and low grade, and therefore expensive to treat using conventional methods (Xu et al., 2013). Today, nickel laterites are more attractive for production of nickel as the amount of high grade nickel sulfide ores has diminished (Janwong, 2012). Therefore more economic processes to recover nickel from these resources should be developed.It should be noted that nickel laterite mineralogy is complex, and nickel often presents as ultrafine inclusions in a number of mineral phases. Because of the low nickel concentration and variable distribution in these phases, effective upgrading by physical separation processes would be challenging. Researchers have tried to improve nickel laterite flotation recovery by using a number of feed preparation techniques. A summary of the nickel grades obtained using flotation and magnetic separation as reported in the literature is presented in Table 1. It can be seen that only minor nickel upgrades have been reported. Quast et al. (2015) have concluded that the complex mineralogy of nickel laterite ores makes it difficult to achieve any significant nickel upgrading by physical techniques, including flotation. They achieved 40% increase in the nickel content (from 1.0% to 1.4%) at a nickel recovery of 43% (Quast et al., 2015). Various attempts in USA, New Caledonia, India and Australia, to upgrade nickel in laterite using magnetic separation have not been successful (Quast et al., 2015). A recent comprehensive review on topics influencing nickel laterite flotation has shown that further investigations in the flotation of laterite ores are undoubtedly warranted (Farrokhpay & Filippov, 2016)."

Jan 1, 2018

Compressive crushing is applied in crushing plants used in mineral, mining, and aggregate in-dustry for fragmentation of rock materials. From a global perspective, the total volume of crushed rock is massive and corresponds to several billion tons. All societies have to fulfil a daily need of rock material products and its derivatives such as metals and minerals. The business for metals and minerals is global while the aggregates production is mainly a local industry. This paper presents a broader overview of optimisation with respect to product yield, use of natural resources and energy consumption. High level plant optimisation of compressive crushing plants is covered as well as real-time optimisation and optimisation of single production units. Each of three optimisation areas are presented and a discussion around how these three areas will be able to communicate with each other is given. Several models, e.g. process performance behav-iour with respect to wear, as well as fitness functions can be common for all three areas. Well-defined and representative fitness functions are of the utmost importance in order to assure that the optimisation results reflect the production targets. It is concluded that great benefits can be achieved by linking together different areas of optimisa-tion. The future for compressing crushing lies, without a doubt, in tailored processes both with re-spect to machines optimised for each customer, plant parameters and operation routines as well as an on-line adjustment, which takes into account current information and control possibilities.

Jan 1, 2014

By O. A. Bascur

"In recent years, metal producing companies have increased their investment in automation and technological innovation, embracing new opportunities to enable transformational change. Internet of Things (IoT) is one of many transformational initiatives, which can fundamentally revolutionize how industrial complexes operate. Whatever the issue, the answer is in the abundant and growing quantity of real time data and events collected in the grinding and flotation circuits in a mineral processing plant. Based on earlier work, today a grade recovery model permits identifying the best operating conditions in real time. We will review the strategy for increasing the value of the abundance instrumentation in current plants. An optimal Gaudin size distribution model provides augmented information from traditional sensors to find the optimal grind cut to reduce metal losses in the flotation circuits. The large amount of sensors in a flotation circuits permits to estimate the recovery and to find the optimal froth depth and aeration using an air holdup flotation model. The paper will describe the strategy of classifying data for on line generation of insights to using operational intelligence tools. We will discuss the implementation Recovery/Grind strategy with industrial examples in non-ferrous mineral processing and iron beneficiation.INTRODUCTIONThe declining supplies of high grade ores and increasing consumption of mineral and metal products have demanded higher operational efficiencies with minimum capital investments. The objective of copper flotation objectives are based on maximizing the dollars return on the concentrate produced. The economic efficiency is maximized by manipulating the circuit along the grade/recovery curve relationship. To achieve such objective improved stabilization of the grinding and flotation circuits are required (Oosthuizen, Craig, and Jamsa-Jounela, 2017)."

Jan 1, 2018

By Xing Yang, Zhen Peng, Guangwen Zhang, Haifeng Wang, Yaqun He

"Triboelectric separation of ilmenite ore based on the tribocharge differences between ilmenite and gangue minerals was conducted in this study. Triboelectric characteristics of ilmenite and its associated minerals were studied using polyvinyl chloride (PVC), pentatricopeptide repeats (PPR), copper, polymethyl methacrylate (PMMA), stainless steel (SS), teflon and quartz glass (QG) tribochargers in lab triboelectric unit. Results demonstrated that the ilmenite particles tribocharged positively while gangue minerals tribocharged negatively using PVC as tribocharger. The particle size also has a significant effect on tribocharge, and the -0.125+0.074 mm is the optimal size fraction of triboelectric separation. Charge-mass ratios of minerals increase with the increases of tribocharging length, but the increasing rate gradually reduce. At 1.5 m tribocharging length, charge-mass ratios of ilmenite, quartz, feldspar and mica are up to 6.07 nC/g, -6.05 nC/g, -4.30 nC/g and -4.56 nC/g, respectively. Based on the triboelectric characteristics of each mineral, triboelectric separation of ilmenite was conducted, and the grade of ilmenite ore increased from 15.47% to 28.40%. INTRODUCTION As a transition metal titanium plays an irreplaceable role in medical, aerospace and materials due to its light weight, high strength and corrosion resistance. Pure titanium dioxide is an excellent white pigment and is widely applied in industries of paint and textile. Ilmenite is the main raw material for titanium industry. For the beneficiation of ilmenite, series methods have been proposed, such as the application of dry magnetic and wet gravity separations to separate the ilmenite from the zircon and rutile. Electrostatic separation is extensively used in the beneficiation of heavy mineral sands for the recovery of rutile, zircon and ilmenite while flotation is used to separate fine ilmenite (Mehdilo et al., 2014; Fan et al., 2014). Compared with flotation and gravity separation, electrostatic separation does not consume water, and native properties of materials will not be changed and energy consumption will be reduced (Wang et al., 2014). Thus, the wide application of electrostatic separation and other dry separation methods is a trend in separation and purification industry, especially in water-scarce areas."

Jan 1, 2018