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By Simon C. Dominy, Patrick R. Stephenson, Alwyn E. Annels

Abstract - The often complex, erratic, and localized nature of gold is a common feature of many vein-style gold deposits. This style of mineralization is often referred to as being nuggety or possessing a high-nugget effect. As a result of these complexities resource estimation is difficult and in general, only Exploration Results can be provided or an Inferred Mineral Resource estimated from surface drilling data alone. Underground development, further drilling, and probably bulk sampling will be required to delineate Indicated and Measured Resources. Tonnages can generally be estimated from diamond drill and development information with a reasonable degree of confidence. Grade is much more difficult to define with confidence because it is commonly highly erratic and discontinuous in nature. The dependency of higher confidence Resource categories on development information may create a Catch 22 situation, with funding for such development often depending on the prior definition of at least Indicated Resources. There are no easy solutions to these challenges posed by high-nugget effect deposits, and it is important when classifying and reporting not to downplay the uncertainties often associated with Mineral Resource and Ore Reserve estimates for such deposits. However, in common with all deposit types, if the principles that underpin the estimation, classification, and reporting procedures are borne in mind and common sense applied, most issues can be satisfactorily resolved. This paper discusses the classification and reporting of Mineral Resources for high-nugget effect gold vein deposits within the framework of the JORC Code (JORC, 1999).

Jan 1, 2001

By Jean-Guy L. Gauthier

"With the Ontario Ministry of the Environment stipulating that the cumulative concentration of copper, lead, zinc and nickel in mine mill effluent must be no greater than 1.0 milligram per litre, it has become necessary for the mining industry of find some form of treatment for the removal of heavy metals from effluent waters.To comply with these guidelines, it became necessary for Mattabi Mines Ltd., which is situated 50 miles Northeast of Ignace in Northwestern Ontario, to develop a compact, cost effective and technically sound treatment process to remove heavy metals from their tailings overflow. A design committee consisting of mine metallurgists, environmental engineers, a Dutch research and development team and the equipment supplier engineering staff was set up to accomplish this.Using some new and innovative wastewater treatment equipment, the guidelines established by the Ontario Ministry of the Environment can now be met. The sludge produced from the precipitated heavy metals is sent directly to the concentrator, thus eliminating the danger of re-dissolution of the metals in a landfill site, while recovering some of the valuable metals that would otherwise be wasted in a sludge landfill."

Jan 1, 1980

By James Ransford Dankwah

High sulphur carbonaceous materials like petroleum coke and rubber tyre are unsuitable as reductants in ironmaking because part of the sulphur is transferred to the reduced metal. Globally, while large amounts of petroleum coke are produced annually from the industrial processing of crude oil, billions of end-of-life rubber tyres are held in landfills and stockpiles. This work therefore investigates the potential feasibility of utilising these high sulphur carbonaceous materials as reductants in ironmaking without transferring the sulphur into the reduced metal. Composite pellets of iron oxide containing end-of-life rubber tyre (RT), petroleum coke and blends of RT/petroleum coke and petroleum coke/high density polyethylene (HDPE) were heated under argon atmosphere in a horizontal tube furnace. Reduced pellets were analysed after 10 minutes of reduction for their sulphur content. The results showed that sulphur-free metallic iron can be successfully synthesized using RT and petroleum coke as reductants. The level of desulphurisation depends on the nature of blending of the carbonaceous materials.

Jan 1, 2014

By Neri Roux, Ross Gilders, Yemi Oyediran, Leo Cheung

Quest Rare Minerals Ltd. is developing their Strange Lake B Zone REE deposit located in Northern Quebec. An extensive batch bench scale testing program was launched to investigate open circuit rougher flotation performance under different conditions. The objective of the flotation study was to demonstrate the effectiveness of rejecting gangue minerals to flotation tailings while concentrating rare earth elements as well as yttrium, zirconium, and niobium into a concentrate suitable for further hydrometallurgical processing. Mineralization of interest at Strange Lake occurs within peralkaline granite-hosted pegmatites and minor aplite. The REE and high field strength element (HFSE)-bearing phases are hosted primarily in pegmatites as relatively fine-grained phases or pseudomorphs. The gangue phases comprise of quartz, feldspar, amphibole, and pyroxene. Potential ore minerals comprise predominantly of kainosite, gerenite, gadolinite, zircon, pyrochlore, and gittinsite. These complex mineralogical characteristics increase the difficulty for processing and provide a challenge for choosing the correct reagent scheme in rougher flotation. Process options including reverse flotation to reject the gangue minerals and de-sliming prior to the direct rougher flotation were investigated. Optimization trials were conducted using various reagent regimes and under different flotation conditions. Encouraging results were found using a combination of collector reagents supplied by Cytec Canada Inc.

Jan 1, 2014

By Mark Stephenson, Paul Henharen

"The objective in the mineral processing of primary ores is to liberate and effectively recover each individual economically viable diamond with minimal reduction in its potential value.There are three distinctive phases in diamond processing:Feed PreparationWhere the diamonds are liberated and waste material finer than the economically selected cut-off size is rejected. In this section we will discuss the various techniques utilised worldwide to effect feed preparation.Primary ProcessingWhere the diamonds are recovered into a high grade concentrate suitable for the more expensive and selective final recovery process. In this section we will discuss the development of primary processing from jigs and pans to the more current techniques utilised worldwide.Final RecoveryWhere there is selective rejection of waste particles until only diamonds remain. The diamonds may then be acidised prior to packing and marketing.Within these distinct phases a variety of unit processes have been utilised and this paper will discuss their relative merits, limitations and suitability in respect to the various stages of diamond project development from prospecting through to production.Basic capital and operating costs are compared for the autogenous milling route developed in the CIS and the crushing and scrubbing route utilised in the west."

Jan 1, 1994

By S. Suzuki, C. Tokoro, S. Owada, T. Sakakibara

Acid mine drainage (AMD) has been actively treated by neutralization from about 80 abandoned or closed mines in Japan. More efficient and cost effective treatment processes has been demanded for AMD due to the government investment of billions of yen every year to protect the environment from these discharges. In this study, quantitative modeling was conducted for actual AMD to predict pH or residual concentration of toxic elements after neutralization/co-precipitation process. Simple chemical equilibrium calculation was not adequate for quantitative prediction of pH after neutralization, because residual concentration of major elements of AMD, such as Fe or Si, could not be quantitatively calculated. When oxidation rate of Fe(II) to Fe(III) and precipitation rate of kaolinite were added to the model, quantitative prediction of pH and Fe or Si concentration was achieved. Surface complexation at the interface between hydroxide such as ferrihydrite or aluminum hydroxide and AMD was the most important mechanism for removal of dilute toxic ions. When surface complexation model at the interface of ferrihydrite was added to the model, residual As (V) and Pb (II) concentration after neutralization/coprecipitation process was successfully calculated. On the other hand, surface complezation model of aluminum hydroxide was also necessary for quantitative prediction of residual Zn(II) concentration after neutralization/co-precipitation process.

Jan 1, 2014

By T. Junne, L. Eltrop, S. Moreno-Leiva, J. Haas, W. Kracht

The energy systems of the future will be highly renewable. The flexibility that is consequently required can be provided with many options, the main ones being energy storage, transmission reinforcement, and demand side management. The role of the latter is explored for the copper industry, using the scheduling of maintenance services as an example of Solar-Paced Design - the coupling of energy demand with solar resource availability. We used a linear energy optimization model to define the minimum-cost configuration for a fully renewable energy system of a copper concentration plant under different scenarios for the scheduling of maintenance services. For the case we studied, (total) costs were 4% lower when the maintenance was scheduled in winter. We expect that exploring the potential of such Solar-Paced Design in the copper industry will allow new potentials for a more cost-effective full renewable energy supply of this critical industry. INTRODUCTION The mitigation of climate change requires a worldwide transformation of the energy system by the significant expansion of renewable energies and the electrification of various sectors and processes (Teske et al., 2015)(International Energy Agency IEA, 2018). Moreover, considering the decreasing costs of renewable energy technologies and the intensive use required to deliver the goals in the Paris Agreement, we can expect to have highly renewable energy systems in the near future. However, to rebuild and expand our energy systems, we need certain materials, including copper. Also, energy systems based on renewables are more copper-intensive than conventional ones (Kleijn, van der Voet, Kramer, van Oers, & van der Giesen, 2011). The mineral industry, in turn, needs clean energy to achieve a better environmental performance (e.g. solar energy for copper production (Moreno-Leiva et al., 2017)) and to avoid negative secondary effects induced by the strong expansion of clean technologies. But there is something else the minerals industry can offer in this bi-directional relation with energy systems.

Jan 1, 2019

The successful application of color sorting machines has established sensor-based sorting in the mineral industry in recent years and is considered today as a significant innovation in processing technology. However, we are only at the beginning of (market) introduction. New sensor systems have been developed, which exploit material properties such as electrical conductivity, magnetization, molecular structure, thermal conductivity etc. This opens up new exciting pre-concentration and upgrading possibilities for many applications such as nickel, gold, copper and other ores as well as for industrial minerals, diamonds and other gem stones.

Oct 1, 2009

By S. A. Kenzap

This paper provides an overview and discussion of key aspects of operating risk valuation in underground metal mining systems, with impact on project economics, using stochastic computer modelling in Discounted Cash Flow (DCF) analysis. Mine operating risk classification and assessment for ground, equipment and scheduling aspects are presented with an overview of available risk valuation tools that have been developed in engineering disciplines. The classification is organized by keeping in perspective the mine design needs and constraints, as well as the potential economic impact that operating problems can have on an underground development and production system. These sources of cost, revenue and time delays are tabulated to enable the hierarchization of potentially hazardous unplanned events occurring during the mining project life cycle. In complex technological systems, like the underground mining systems, the decision-making process involve a wide range of uncertainties, and often this is based on subjective and qualitative expert evaluations. Whether a qualitative or quantitative analysis is conducted, it is often the case that the probability of a certain project parameter value needs to be estimated. This requires use of methods and techniques to handle subjective, qualitative measures and to combine them with quantitative stochastic modelling in order to evaluate mine operations-related issues on DCF economic performance measure parameters. Links are established between decision making and the risk-based mine planning process for evaluation of design alternatives, with emphasis on the need of introducing flexibility in mine design. Finally, challenges of risk-based mine planning and design implementations are discussed and the call for an integrated risk-based real options systems valuation (ROV) ?in? projects analysis is made.

Aug 1, 2013

By Xuehui Xia

Abstract -There are a number of sedimentary exhalative massive sulfide (SEDEX) deposits in the Proterozoic Langshan-Zhaertai rift at the western segment of the northern margin of the North China platform in China, including more than ten large, medium and small deposits located in a belt of 300 km EW by 50 km to 100 km NS, with large Cu, Pb, Zn, Ag, and S reserves. In several representative SEDEX deposits in the rift, the mineralizing elements are prominently zoned, horizontally or vertically, with Cu decreasing but Pb increasing from west to east, Cu decreasing but Zn increasing from bottom to top, and Zn restricted to the bottom half. The ore-hosting rocks, characterized by a clear manganese halo, have developed a polymetallic mineralization in positive relation with their carbon contents. Their isotopic aspects are: ?34S has relatively large positive values, fluctuating between +5‰ and +35‰, compared with Pb isotopic compositions which are less variable, with a model age of 1600 Ma to 1800 Ma, showing that they are mantle-derived. The mineralizing materials were associated undoubtedly with the contemporaneously faulting events in the rift. The deposits owe their origin to seafloor exhalation, with sedimentary rocks as their hosts.

Jan 1, 1999

By Zhigao Xu, Ruan Chi, Zhenyue Zhang, Yaoyang Ruan, Zhengyan He

Thorium is frequently the main radioactive element in rare earth ores and is a resource that can potentially substitute for uranium. Thorium must be separated from rare earths in order to obtain products with low radioactivity. There are abundant resources of thorium in the rare earth ores in China, especially in Baiyunebo mixed ores. As an associated element coexisting in rare earth ores, thorium is, or can be, separated from rare earth concentrate, iron concentrate, as well as from waste water and slag to achieve recovery of thorium. The methods of separation include ion exchange resin, liquid-liquid extraction, and liquid-solid extraction. TBP extraction has been the main method applied to separate thorium by domestic and foreign scholars. This paper presents a comparison of different processes for the separation of thorium from rare earth ores, especially Baiyunebo mixed ores, single bastnaesite and monazite ore, and provides suggestions for the future recovery of thorium resources.

Jan 1, 2014

By Charlie Graham

Our Approach ? Industry Trends ? New Forces at Work in Mining ? Deep Mining ? Energy projects ? Air power ? Hydraulics ? Electric alternatives ? Drilling ? Productivity ? Conclusions ? Transportation ? References

Oct 1, 2010

By T. Krumins, L. Zunti, R. Frischmuth

Titanium and titanium alloys are commonly selected for pressure oxidation autoclave vent piping and pressure control valve components, as well as autoclave internals, in high-temperature operations. In a vent application, titanium ignition risk is reduced by limiting oxygen concentration, and preventing high gas velocity gas impingement on surfaces. Oxygen concentration is dependent on the autoclave pressure and temperature conditions and therefore titanium ignition risk is dependent on standard operating procedures, and process control interlocks and permissive conditions. It is not uncommon for standard controls to be deficient during atypical operating conditions, or for operations to deviate from the operating procedures, increasing the potential for titanium ignition incident. Titanium ignition risk caused by elevated oxygen concentration in autoclave vent systems can be reduced with the introduction of an online autoclave overpressure calculation and the configuration of associated interlocks and permissive conditions.

Jan 1, 2014

By J. Fournier

A novel sol ? gel (SG) synthesis procedure utilizing varying ratios of glycine and ethylene glycol to total metal cations has been developed to create high purity nanometer sized La0.65Sr3.5MnO3 powders. X-ray powder diffraction (XRD), transmission and scanning electron microscopy (TEM, SEM), and dynamic light scattering (DLS) have confirmed that the crystallite sizes of such powders are ~ 20 nm, and the aggregate particle sizes vary between 100 to 300 nm. Mixing varying weight percents of SG LSM powders with commercially available Praxair LSM in a composite LSM/YSZ functionally graded cathode has been shown, through the use of electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV), to exhibit enhanced oxygen reduction kinetics vs. at conventional cathode materials.

Jan 1, 2005

By Ken G. Stowe, Stephen L. Chryssoulis, Christian Bendel, Joe Y. Kim, Ewald Niehuis

"TOF-SIMS (Time-of-flight secondary ion mass spectrometry) was used to detect collectors sorbed onto the surface of mineral particles in concentrate and tailings samples from the Brunswick, Matagami and Kidd Creek concentrators. This technique uses ion beams from either Cs or Ga sources to sputter the particle surface, a method which reduces fractionation of the collector molecule during sampling.In the Brunswick Zn circuit, sphalerite particles lost to the scavenger tails had less amyl xanthate and isobutyl xanthate compared to sphalerite recovered to the Zn final concentrate. Xanthates were detected on the surface of sphalerite particles floating to the CuPb final concentrate.At Matagami, significantly more isopropyl xanthate and isobutyl dithiophosphate were detected on sphalerite recovered to the Zn final concentrate, compared to sphalerite lost in the Zn rougher tails.In the Zn circuit of Kidd Creek, sphalerite lost to the tails had on average ten times less xanthate compared to sphalerite recovered into the Zn final concentrate. Xanthate was also detected on the floated pyrite particles. In addition to isobutyl xanthate, amyl xanthate was also detected on the floated sphalerite and pyrite particles.This preliminary investigation has (a) demonstrated the ability of TOF-SIMS to detect individual collectors on particle surfaces from plant samples and (b) shown that TOF- SIMS is an excellent tool, complimentary to TOF-LIMS, in establishing the surface chemistry of minerals as related to mineral processing."

Jan 1, 1995

By V. I. Birss

Planar solid oxide fuel cells (SOFCs) offer great promise as stationary power generation devices, primarily due to their flexibility in terms of fuels, high energy conversion efficiency (when both electricity and heat are captured), and their relatively low fabrication costs. However, the anode performance can be compromised by such factors as exposure to certain sulfur-containing fuels and the deposition of coke when using hydrocarbon fuels. In terms of the cathode, its performance is limited primarily by the slow kinetics of the oxygen reduction reaction, while its lifetime can be negatively affected by factors related to the corrosion of currently used stainless steel interconnect materials. This talk will present an overview of these challenges and some possible solutions to these problems. The presentation will also focus on how electrochemical methods can be used to evaluate and improve the performance of SOFC anodes, cathodes, and interconnect materials. In addition, recent promising research efforts directed towards performance enhancement of SOFCs through the use of nanoscale electrocatalysts will be discussed.

Jan 1, 2005

By John Eggert, Paul Benford

"Since 1982, Placer Dome Inc. -Dome Mine has steadily increased mill throughput. Tonnage has increased from a nominal design capacity of 3000 short tons per day, attained in 1985, to 4130 stpd by the end of 1992. Many minor and major circuit adjustments were tried to maximize tonnage.Having utilized most conventional means of increasing tonnage, further increases required a newer approach. This paper discusses the Dome experience in the development and implementation of an expert system.The Comdale/C system was chosen for a controlled trial. The criteria for acceptance were: increased tonnage had to be sufficient to pay for the system; the increase had to be visibly sustainable and the mill operators had to be willing to accept the system.The criteria for purchase were met during the trial and the system was purchased. The system continues to perform well. The tonnage throughput increase has been sustained while operator acceptance remains high.IntroductionPlacer Dome Inc. -Dome Mine is Canada's oldest operating gold mine. The mine was among the first established in the Porcupine camp in what is now Timmins, Ontario. The City of Timmins is located approximately 500 miles or 800 kilometres north of Toronto. Figure 1 shows a map of the province of Ontario and the mine location.In 1912, milling began at a rate of 350 short tons per day. With two minor exceptions, milling has been continuous since this time. The first of these shut downs was in 1918 during the first world war. The war created labour shortages which forced the mine to stop production for more than a year. The second was in 1930 when fire destroyed the mill."

Jan 1, 1994

By F. Simon, A. Roth, M. F. Zaeh

Applying Friction Stir Welding in an industrial environment requires knowledge about the robustness of the welding process against imperfections in the joint line resulting from production deviations of the parts to be joined or from improper clamping devices. In this work the influence of gaps on the weld quality of friction stir welded butt joints of the aluminum alloy EN AW-5083-H111 is investigated in detail using the method Design of Experiments. As independent input variables, the rotation speed, the feed rate, the tilt angle, the lateral tool offset and the gap width were chosen. Tensile strength was selected as a measure for the joint quality. Moreover, the fundamental response variables of the FSW process, such as weld temperature, axial force and spindle torque, were recorded and integrated in the empirical process model derived by regression analysis. It was found that each response variable decreases with increasing gap width, whereas the largest impact was identified for the axial force and the temperature at the weld surface. In order to improve the joint strength for a given gap width, increasing the rotation speed and the tilt angle or lowering the feed rate, respectively, proved to be a suitable approach. However, interactions between the tilt angle and the rotation speed have to be considered.

Jan 1, 2014

By M. Leroux, C. J. Martin, S. R. Rao, J. A. Finch

"The effect of nitrogen on the flotation separation of sulphides from complex ores from Brunswick Mining and Smelting (New Brunswick) and Mattabi Mines (Ontario) was investigated. The most significant finding was enhanced pyrite floatability after as little as 3 minutes nitrogen conditioning. This was used in a novel sphalerite/pyrite separation process developed on the Brunswick ore. After aeration and Cu/Pb bulk flotation in air using xanthate the slurry was nitrogen conditioned, xanthate added and the pyrite floated in nitrogen. As an example up to 70% pyrite recovery with about 20% sphalerite recovery was achieved. Sphalerite was recovered from the pyrite tailings and the pyrite concentrate by copper-activation, raising the pH to 10 and floating in air. About 65-70% recovery at 35-40% Zn grade was achieved compared to 25% Zn grade by the conventional route. The process offers a promising alternative to current practice which seeks to depress pyrite at all stages. A possible mechanism of the effect of nitrogen is presented. INTRODUCTIONUse of gases other than air in froth flotation has been reported from time to time. [Podobnik and Shirley, 1982; Lin and Metzer, 1975]. Of all the gases, nitrogen would appear to hold the greatest practical promise because of its easy availability and chemical inertness. It is used in froth flotation in chalcopyrite-molybdenite separation [Redfearn, 1983]. The use of nitrogen in polysulphide chalcopyrite. this case is mainly to reduce the oxidation of a compound (Nokes reagent) used as a depressant for There is no reported use of nitrogen in the flotation of other sulphide minerals."

Jan 1, 1988

By A. Ghahreman

Activated carbon is proven to be able to catalyze arsenic oxidation in aqueous solution under acidic conditions. A commercially available granular coconut shell based activated carbon (AC) has been evaluated for catalysis of arsenic oxidation in this study. The rapid small-scale column test (RSSCT) has been developed to simulate and predict the performance of a carbon-based arsenic treatment system in a pilot scale reactor. Effects of residence time, aeration rate, and initial arsenic concentration in the influent solution on the AC catalysis of arsenic oxidation under dynamic and continuous conditions were studied by manipulating these parameters during RSSCTs. The effectiveness of the AC on arsenic oxidation was examined over the course of constant diffusivity based RSSCT operation. Residence time and initial arsenite concentration are proven to be the most effective impacting parameters on the arsenic oxidation process. For the 218 min residence time, the highest steady-state arsenic oxidation efficiency achieved was 98% with 1 g/L As(III) being treated at pH=1 under 0.05 L/min oxygen aeration. In a long-running RSSCT, the oxidation efficiency did not seem to deteriorate over a course of 666 hours operation, corresponding to 13986 mL total influent throughput volume. INTRODUCTION Arsenic is toxic to both animals and plants and inorganic arsenicals are proven carcinogens in humans. The increased extraction of low grade and complex mineral resources has introduced high ratios of arsenic into metallurgical processes. Discharge of arsenic by acid mine drainage resulting from mining activities has added intensive pressure on the need for proper treatment (Lawrence & Higgs, 1999). Since trivalent arsenite is more toxic and has lower affinity to solid surfaces for adsorption, many treatment systems initiate with an oxidation step to convert arsenite to arsenate and reach the ultimate immobilization of arsenic by the following precipitation of arsenate (Nazari, Radzinski, & Ghahreman, 2016). Scorodite precipitation has been studied extensively as a means of arsenic immobilization due to its high stability and negligible potential of releasing arsenic (Filippou & Demopoulos, 1997). As a stable ferric arsenate mineral, crystalline scorodite can contain up to 30 wt% arsenic (Paktunc, Dutrizac, & Gertsman, 2008). Arsenic must be in its pentavalent oxidation state in order for scorodite to be precipitated via oxidizing ferrous ions (Clancy, Hayes, & Raskin, 2013).

Jan 1, 2019