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By N. E. Mkadmi

Backfilling increases the stability of underground stopes and may help reduce the environmental footprint from the mining operation. The barricades holding the backfill in place must be designed to prevent failure based on the total and effective stress states, which depend on fill properties, stope geometry, and filling rate. This paper presents results from a numerical study aimed at analyzing the stress states associated with the response of paste backfill following stope filling, with an emphasis on the short term behavior. The simulations illustrate how stresses evolve with backfill drainage and filling rate in a vertical stope.

May 1, 2011

By Hannu J. Häkkinen

Metal clusters exhibit unique size-dependent physical and chemical properties that differ from those of bulk materials or large particles. Here we discuss recent theoretical investigations of the catalytic properties of free and MgO-supported gold clusters. The catalytic activity of gold clusters depends sensitively on the environment, charge state, and chemical composition of the catalyst. Relativistic bonding effects stabilize large planar structures for gas-phase gold clusters, and non-compact ?quasiplanar? structures are present as important isomers also for surface-supported clusters. The hybridization of the atomic 5d and 6s states is significantly enhanced by the relativistic effects, and large spatial variations in the nature of the local electronic structure make the low-coordinated gold atoms preferable adsorption sites for oxygen molecules. The adsorbed oxygen molecules are activated to superoxo- and peroxo-states via charge-transfer from gold, and Eley-Rideal and Langmuir-Hinshelwood reactions with CO proceed via low-barrier formation of intermediates, which do not require O-O dissociation as precursors. This facilitates the low-temperature (below 300 K) activity of gold nanocatalysts in CO oxidation. Other gold nanostructures, such as mono-atomic gold nanowires, may also become important prototype systems in chemical sensing and nanocatalysis; here we show that they are active promoters of hydrogen dissociation.

Oct 1, 2003

By Richard Peaker, Jens Lichter, Alexander V. Potapov

"The recent combination of Computational Fluid Dynamics (CFD) and Discrete Element Modeling (DEM) can provide considerable insight into the performance of flotation cells. One area of interest from a fundamental equipment design perspective has been the influence of flotation cell size and the inflow rate on the metallurgical performance of the cell. One of the specific design objectives when increasing the size of flotation cells, or increasing the feed flow to the flotation cell, is to ensure that the feed stream flowing into the cell does not have an opportunity to bypass the mechanism.This paper describes the initial modeling efforts to quantify the inter-relationship of cell size, inflow rates, and feed and discharge box placement, on the retention time distribution of solids in the flotation cell, and the fraction of particles that bypass the mechanism on a size by size basis.INTRODUCTIONThe great majority of newly installed cells in mineral processing plants world-wide are of the cylindrical tank design and this tank shape offers a number of hydraulic advantages over the older style of square cells. Cylindrical cells give symmetrical flow patterns and by careful design of the mechanism and tank internals, the flow patterns generated can concentrate the more intense mixing in the lower portion of the cell to promote good solids suspension and particlebubble contact. Simultaneously, cylindrical tank design gives a more quiescent upper zone for particle-bubble transport into the froth zone. These symmetrical flow patterns are naturally disturbed in normal operation by the slurry inflow and outflow from the individual cells. The challenge for flotation cell designers is to determine the magnitude of these flow disturbances, and to assess whether or when the inflow and outflow rates have a sufficient impact on the hydraulic flow patterns so as to potentially affect the metallurgical performance of the flotation cell."

Jan 1, 2007

By Hugo Julien

According to OSHA 29 CFR Part 1910.119 (Process safety management of highly hazardous chemicals), Canadian Provincial Safety Standard Acts or Federal laws, the owner of stationary equipment (Boilers, stacks, piping, pressure vessel, etc.) should follow a complete inspection plan and follow an Integrity Operating Windows (IOW’s) adapted for each of them. Some important variables shall be included in the inspection plan such as specific damage mechanisms versus alloy used in the original design, process conditions, etc. Some North American’s standards exist, like the one listed in ASME PTB-2-2009, to help owner to create such inspection program. The new API RP 584, Integrity Operating Windows (IOW’s) can guide Mining & Metals owners to find out their specific IOW’s. Inspection frequencies are often described in the Jurisdiction Safety Acts such as the British Columbia B.C. Reg. 104/2004, etc. but often left in the owner representative responsibility (Bill C-21, federal Act to amend the Canadian Human Rights Act). Every deficiency should be repaired according to recognized Codes such as ASME PCC-2, etc.. If flaws not conforming to the original Code of construction are found, this article will introduce the Fitness-For- Service assessment principles to be able to accept it without any repairs.

Jan 1, 2014

By Jan W. Merks

"The settlements between mines and smelters are based on the mass of metal contained in concentrate lots. The mass of contained metal is a function of the wet mass of a lot, and its moisture content and metal grade while the variance of the mass of contained metal is a function of the same variables and their variances. Uncertainties in the measurement procedure applied to estimate each variable are quantified in terms of precision and bias. The absence of bias and an acceptable degree of precision are the keys to effective risk analysis and loss control.ISO Technical Committee 183-Copper, Lead and Zinc Sulfide Concentrates, has developed standard methods for sampling and weighing, estimating precision and testing for bias, the determination of mass loss on drying, the calculation of the mass of contained metal and its variance, and various analytical methods for major and minor metals. The variance for wet mass is calculated from the precision of the scale while the total variances of moisture and grade are estimated from pairs of interpenetrating primary samples. The variance of contained metal can be calculated either from mine data or from smelter data but the risk associated with the settlement is largely determined by the absence or presence of bias and the variance of differences between exchange assays.ISO/TC 183 does not deal with precision and bias for exchange assays but is developing guidelines to determine realistic splitting limits. Given that the exchange of assays between mines and smelters accounts for a large part of the risk associated with the settlement, precision and bias for exchange assays should be measured and monitored. The need for umpire services can be reduced by applying statistical quality control (SQC).Calibrating static scales, moisture balances and analytical balances, bias testing of sampling methods and sample preparation procedures, estimating the variance of a single variable or the variance of a function that a set of variables defines, and monitoring precision and bias for exchange assays, are the quintessence of metrology, the science of measurement, when applied in mining and metallurgy."

Jan 1, 1995

By D. J. McLaws

"Recent innovations in metal smelting technology utilize continuous oxygen-enriched smelting and converting processes which are capable of producing off-gases containing up to 60% SO2 or more. Other SO2 recovery processes, involving solvent absorption and steam or vacuum regeneration, can produce off-gases with SO2 concentrations nearing 100%.Processing of these high-concentration SO2 off-gases in conventional sulfuric acid plants can cause excessively high catalyst bed temperatures and poor SO2 conversion. In order to avoid these problems, a conventional acid plant design must dilute these high SO2 process gasses with dilution air in order to provide the required oxygen to effectively convert the SO2 and provide a heat sink (via the inert N2) such that the exothermic reaction, SO2 + ½ O2 ???SO3, does not exceed the temperature limit of the catalyst or the converter vessel.MECS, Inc. (MECS) has proven that a high SO2 feed gas design can be a viable option which can increase energy recovery, reduce energy consumption and potentially reduce capital costs."

Jan 1, 2014

By Paul R. Clark

Outline of Presentation ? Brief review of gasification and IGCC ? Polygenerationand its potential ? Why gasification today ? Major technology providers and their activities ? US initiatives ? Alberta Energy Resources and application of gasification ? CO2 management ? Advantages and barriers to gasification ? Conclusions

May 1, 2006

By Y. Nakamura, T. H. Okabe, S. A. Sunkar, K. Nose

Ruthenium (Ru) is known as a platinum group element with a very small production volume. In fact, the worldwide annual production of primary Ru metal is only about 20-30 tons, and it depends on the amount of Pt produced, since Ru is a byproduct from Pt smelting. The primary uses of Ru are as a material for resistors, as a catalyst for electrode materials, and as a sputtering target for hard disk memory storage. In order to recover Ru from the spent sand-blasting abrasive media generated during the cleaning of the apparatus used for Ru sputtering, a hydrometallurgical recovery process using hypochlorite solution has been investigated. In this study, various types of recycling processes that are presently under development are also introduced, and their features and differences are discussed. The advantages and disadvantages of the new recycling processes are evaluated, and the possibility of establishing new recycling processes in the future is discussed from a multilateral perspective.

Jan 1, 2014

By Jacob Masliyah, Zhiang Zhou, Dharamdat Christendat, Tshitende Kasongo, Kevin Hyland, Zhenghe Xu, Ted Kizior, Douglas Cox

"A novel on-line visualization system, previously developed at Syncrude Canada Ltd., has been modified to characterize rising bubbles, particles and particle-bubble aggregates in a flotation process. With this system, the bubble size and rise velocity in a laboratory flotation cell can be determined. The technique allows the loading of solids on bubbles to be visualized, thereby providing an in-depth understanding of sub-processes of flotation. A step-by-step data processing procedure is presented. The applicability of the developed system to mineral flotation and bitumen extraction is discussed. Under batch flotation conditions in a laboratory Denver cell, three main bubble-particle attachment patterns are observed. They are: i) single particles attached to single bubbles, ii) particle aggregates loaded on single bubbles; and iii) a group of particles aggregated with a group of bubbles. The results demonstrate that the on-line visualization system is a powerful tool for understanding and diagnosing flotation processes.INTRODUCTIONAir (Gas) bubbles are an indispensable component in a flotation system. Both industrial practice and theoretical analysis indicate (Yoon, 1993; Diaz-penafiel and Dobby, 1994) that the size and population of bubbles are two important process parameters in modeling flotation. More recent investigations (Finch, et al., 1999; Gorain, et al., 1997) suggest that for a given flotation system, bubble surface area flux, defined as the air liquid interfacial area per unit time and unit cross-sectional area of flotation cell, showed a better correlation with the flotation rate constant. As a result, the bubble surface area flux is now being considered as a key parameter to account for the combined effect of bubble size and population in evaluating the performance of flotation machines and modeling flotation processes. However, the success of using bubble surface area flux in flotation process modeling largely depends on how accurate it can be determined or estimated (Finch, et al., 1999)."

Jan 1, 2000

By W. T. Martson

ABSTRACT Sooner or later, every producing mine faces the question of fill. This paper invites consideration of mill tailings as an economical, efficient, and quantitatively adequate source of such fill. Some of the advantages, disadvantages, methods of utilization, and methods of treating mill tailings for sand recovery are covered. ADVANTAGES AND DISADVANTAGES OF SAND FILL DISREGARDING economic com-promise, that material which supports the greatest applied load with the least compression is the best choice for fill. Table I, reproduced from U. S. Bureau of Mines Bulletin 60, is offered as evidence of the adequacy of hydraulically placed sand. Table II gives the results of tests made in an effort to determine the reason for the difference between load hearing qualities of dry-placed and hydraulically-placed sand. From these, it would appear that hydraulic placing gives a denser initial packing, with corresponding higher, and faster development of, load bearing qualities. Assuming this to be true, then if sand from mill tailings can be placed underground economically, it is the superior fill material. Table III summarizes cost data available. The most cursory glance through the available references (2, 5, 6, 7, 8, 9) will show .that the major benefit from the adoption of sand fill is a decrease in the non-productive fill ?cycle of a working place. This, it is estimated, increases the output of an individual stope by from 25 to 50 per cent. The advantage of reducing the number of required working places for a constant daily production is obvious.

Jan 1, 1951

By R. Tipman, T. C. Burnett

"A general computer program has been written to calculate material balances using multiple regression techniques. The program can handle metal assays or size distribution data obtained in multiple surveys of the flotation circuit. The ""best fit"" weight split is calculated between the input and product streams by minimizing the sum of squares of the residual errors using all of the available data. The program includes an assay adjustment feature in which each assay is recalculated to fit the ""best fit"" mass balance. Thus assay or sampling errors can be easily identified. Also the assays can be statistically weighted so the most precise measurements are given the most influence on the material balance. The computer output reports the mass balance, the actual and corrected assays, the percent metal recoveries and the significance and confidence levels for the weight splits.The program enables a rapid and accurate evaluation of mass balances from large masses of data obtained in multiple surveys around a flotation circuit. The effects of changing process variables can be quickly evaluated with statistical confidence."

Jan 1, 1978

By Terry A. Kirk

"This paper describes Derrick High Frequency Vibrating Screens and their process performance in grinding circuit applications. The benefits of screen sizing in closed circuit grinding are illustrated by case histories from a wide spectrum of mineral industries.INTRODUCTIONHigh capacity, reliable wet screening equipment is increasingly in demand by the mining and allied industries for separations finer than 1/.7 5mm (I/ mesh). The continuing search for improved energy efficiency and reduced steel consumption in comminution has Jed to greater scrutiny of every aspect of circuit design and operation, including the classifier efficiency (selectivity) function.Derrick Manufacturing Corporation has been developing high frequency screening machines designed specifically for grinding circuit applications since 1973. Successful installations are currently operating in iron ore, copper, coal, uranium, phosphate and other extractive industries."

Jan 1, 1984

By Sergei Decterov, Peter Hayes, Evgueni Jak, Taufiq Hidayat, Denis Shishin

Copper smelter operations around the world are under sustained pressure to reduce costs and increase output. Through the provision of reliable data on fundamental properties of the chemical systems the opportunities for improvements of industrial copper production can be identified. Experimental and modelling studies on phase equilibria, thermodynamics of copper slag/matte/metal/gas systems have been combined into an integrated research program undertaken at PYROSEARCH. Experimental phase equilibria studies involve high temperature equilibration in controlled gas atmospheres, rapid quenching and direct measurement of compositions of equilibrium phases with electron probe X-ray microanalysis (EPMA). Thermodynamic databases development and modelling is undertaken using the computer package FactSage in conjunction with advanced models used for complex solution phases. Progressive development of these research methodologies has brought significant advances in characterisation of these complex systems, including a new optimised thermodynamic database for the copper-containing slag system Cu2O-Al2O3-CaO-FeO-Fe2O3-MgO-S-SiO2.The new data and models can now be applied to assist in improvements of the processes. The effects of changes to chemistry and process conditions within the smelting reactor can be examined. Several examples of new descriptions of the phase chemistry of the Cu2O-CaO-SiO2 and Cu2O-FeO-Fe2O3-SiO2 systems in equilibrium with metallic copper showing calculated and experimental data are presented.

Jan 1, 2014

By A. M. Childs, R. F. Mather, K. R. Rawling

"The challenges encountered in the design and construction of mines and their process facilities today are becoming more intense and the engineering more competitive. The need to incorporate new techno1ogy to compensate for ever rising costs is always present, but its application in the harsh environment of Northern Canada increasingly requires the inclusion of new proven methods and innovative approaches to arrive at economically attractive projects.This paper deals with the development of the process design for the Cullaton Lake Gold Mine in the Northwest Territories. Particular emphasis is given to the interaction of the imposed construction and testwork schedules, and their effect on certain process decisions.The challenge that faced the project team may be defined by the following factors:1. A schedule which required that metallurgical testing, engineering, and procurement and delivery of all equipment and construction supplies should be complete within a period of ten months.2. Transportation of all personnel, equipment and supplies to the site by airlift, as no road was available or affordable.3. A six week period when transportation to the site was impossible.4. The extremes of temperature beyond the tree line in the Northwest Territories.5. A complete lack of infrastructure in the area."

Jan 1, 1983

By Peter L. Sheehan, David A. Fawcett, Dennis C. Martin

"Smoky River Coal Limited has successfully completed a major program involving the pattern rock anchoring of a high, steeply dipping footwall slope. The slope dips at approximately 65 to 70 degrees to the north, is benched for the upper 200 feet, is supported with rock anchors for another 240feet, and is unsupported at the pit bottom. In addition to the height and steepness, several structural features including shears, rolls and stratigraphic pinch- outs complicate footwall stability.This paper presents an overview of the project with descriptions of the engineering geology and footwall design, anchor installation, instrumentation and monitoring and a cost summary.IntroductionSmoky River Coal's mines are located in the foothills of the Rocky Mountains near Grande Cache, Alberta, approximately 200 miles west of Edmonton. The Smoky River coal leases were initially developed in the late 1960s and, except for minor shutdowns, have been in continuous operation since 1969 producing a low volatile metallurgical coal, mainly for the export market. Initial coal production was from underground mines; sur face mining started in 1971, and a large surface mine, No.9 Mine, was opened in 1974. Since that time, a number of open pits have been mined within the No.9 Mine area. Surface mining is by conventional shovel-truck method s with the use of a backhoe for mining the narrow pit bottoms.Coal recovery is mainly from the No.4 seam, which has a typical unstructured thickness of 20 feet. The most attractive opportunities for open-pit mining exist in areas of over thickening of the coal seam in the hinge zones of synclines and anticlines and in dip-slope situations. The mining of the more structurally complex pits and steeply-dipping footwall slopes requires that consideration be given to footwall stability."

Jan 1, 1988

By Roger Payne, John R. Goode, Feng Gao, James Brown

The Eco Ridge deposit is located in the Elliot Lake mining camp in Northern Ontario, Canada. Between 1955 and 1996, the area produced more than 138,000 t (300 million pounds) of U3O8 and very significant amounts of thorium and heavy rare earths. Based on the NI 43-101 Preliminary Economic Assessment by Roscoe Postle Associates (RPA) dated June 2012, and the economic review by RPA as announced in Pele Mountains’ Press release dated September 12, 2013, the Eco Ridge Mine Project would extract and process 46 Mt of material to produce about 19,000 t (42 million pounds) of U3O8 and about 65,000 t of rare earth oxide (REO) over a 14-year life. This paper discusses process optimization studies including beneficiation and hydrometallurgical testwork. The proposed modified flowsheet includes the flotation and processing of 1) a pyrite concentrate, 2) a dominantly light rare earth elements (LREE) concentrate, 3) a concentrate containing most of the balance of the uranium and heavy rare earths (HREE), and 4) a relatively inert tailings.

Jan 1, 2014

By T. Deng

Flotation of rare earths is complicated by the number of mineral classes that carry rare earth elements, including carbonates, phosphates, and silicates that often co-occur within the same deposit. Gangue constituents often belong to the same mineral classes as the rare earth minerals themselves. Chemical regimes developed for specific separations employ customized combinations of collectors, modifiers, and depressants that are not directly translatable to other operations. In this rougher flotation case study, a reagent suite including phosphate ester and sulfosuccinamate, originally developed for the recovery of bastnasite and monazite from silicate hosted ore, could not be applied to a synchysite ore hosted in carbonate gangue because the suite was aimed at silicate gangue rejection only. The separation of a fluorocarbonate mineral from carbonate gangue required a different chemical regime involving the use of hydroxamate and sodium silicate. Maximizing rare earth recovery was complicated by the presence of slimes. The effect of desliming and the increase in grind size was explored.

Jan 1, 2014

By A. Vasenev

The quality and durability of asphalted roads strongly depends on the final step in the road construction process; the profiling and compaction of the fresh spread asphalt. During compaction machine operators continuously make decisions on how to proceed with the compaction accounting for project specific aspects as: ambient conditions, road geometry, roller type, asphalt mixture characteristics and behavior of other machines. In discussions over quality improvement in road construction it is often suggested to robotize rollers. To operate such robots would of course require operational strategies and routines. The reality of this moment is that these operational strategies and routines are not documented. To identify the existing best working practices and, ultimately, to proceed with developing automated robotized compactors, the knowledge of machine operators should at first be explored and described in a formalized way. Unfortunately operators have difficulty verbalizing their expertise. Observation of behavior, as machine movement patterns, could be helpful to extract the operational strategies, but such observations are time and labor consuming. To overcome this burden we developed a Virtual Reality (VR) environment. In this VR environment operators perform compaction virtually, and their operational choices are traced and analysed. This paper describes this VR development and explains how it helps in following machine operators and extracting their (tacit) professional knowledge. The road geometry and the working conditions are visually represented; the operators show - rather than explain - how they would proceed with the compaction process in the given conditions. Movements of virtual machines are documented, analysed, visualised and discussed. This VR approach is expected to contribute to learning, to more formal description of operational strategies; stepping stones towards compaction algorithms for roller robotisation.

Aug 1, 2013

By Christoph Mueller

Mining operations today are characterized by a high degree of mechanization and single machine automation. However, their potential for cost cuttings and increase of productivity in the future is quite limited. Enabled by newest IT and networking technology, the operation of underground mines more and more can be seen from a process related point of view: Standardized Ethernet and Wireless LAN are the basis for a seamless and unified communication backbones providing an integrated infrastructure for data, telephony and video. All the components are available as off-the-shelf devices leading to an excellent cost efficiency. Basing on this standardized infrastructure, the equipment is able to become part of the infrastructure. To enable machines to be integrated smoothly into IT networks, the machine also has to have enhanced networking capabilities. This results in a new system architecture for the on board machine electronics separating real time control from IT and networking level functionality which can be implemented by a Machine Server. This machine server communicates with all kinds of above ground systems using mainly standardized formats like html or the IREDES standard. This information is made available mainly in 3D mine visualization tools. The paper explains this technology and shows implementations by two working examples.

May 1, 2006

By A-A. Bogno, Ch. -A. Gandin, A. Maitre, H. Henein

Most metallic materials are produced from their liquid state. In order to control the properties of industrial products, it is very important to understand their solidification path and the resulting microstructures which can be significantly affected by melt undercooling. High undercooling results in rapid solidification and a refined microstructure with minimal microsegregation. This paper reports on the analysis of rapidly solidified Al-Cu droplets obtained by a single fluid atomization process, Impulse Atomization. A quantitative analysis by Rietveld refinement method of the Neutrons Diffraction data was carried out to determine the fraction of the intermetallic Al2Cu. Knowing the fraction of Al2Cu, the eutectic fractions and corresponding dendritic and eutectic undercoolings were estimated using the metastable extensions of solidus and liquidus lines of the Al-Cu system calculated by Thermo-Calc. In addition to this work, a model of microsegregation coupled with ThermoCalc software via TQ (application programming interface of ThermoCalc) and the Wang-Beckerman model for dendritic growth velocities has been developed for binary alloys. This has led to the development of a phenomenological relationship between primary phase undercooling and initial growth velocity. A comparison of estimated primary undercoolings using a coarsening model with the adiabatic undercoolings for each alloy composition has confirmed that solidification occurs under adiabatic conditions during recalescence.

Jan 1, 2014