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By Liguang Wang

The froth phase in flotation has received much less attention than the pulp phase despite the fact that froth stability plays an important role in determining flotation performance. Froth stability is largely determined by the stability of thin foam films, which in turn has a strong correlation with the critical rupture thickness (Hcr) of the films. In the present work, a new approach to predicting the Hcr values of thin foam films in flotation froth phase was proposed and examined. The Hcr values were calculated using an advanced capillary wave model with input parameters being surface tension, film radius, capillary suction pressure, and intersurface force. The intersurface force was estimated by using the Stefan-Reynolds lubrication approximation to fit the measured thinning rates of single foam films formed in a Scheludko ring cell, where the film radii were less than 50 microns and were kept constant during the film-thinning process. A comparison between the predicted and experimental Hcr values was made for the films with the use of sodium chloride as background electrolyte and in the presence of various frothing reagents such as methyl isobutyl carbinol (MIBC), polypropylene glycol with an average molecular weight of 400 (PPG400), and sodium dodecyl sulphate (SDS), at different concentrations and film radii. It was found that the model correctly predicted the trends of Hcr-versus-concentration and Hcr-versus-film radius curves. Moreover, the predicted Hcr values matched well with the experimental ones of the foam films containing either SDS or PPG400. For the foam films containing MIBC, however, the model overpredicted the Hcr values. The reason for this discrepancy was discussed.

Jan 1, 2016

By V. Bonilla-Sierra, M. Elmouttie, L. Scholtès, F. V. Donzé

In the presence of joint sets sub-parallel to a slope face, the stability of the rock mass is controlled by the shear strength of the joints. On one hand, if the joints are persistent their shear strength can be assessed according to Mohr-Coulomb criterion, assuming appropriate values for the cohesion and the friction angle on the joint surface. On the other hand, if the joints are non-persistent with their continuity being interrupted by the presence of rock bridges, their shear strength will increase considerably. In this latter case, the contribution of the rock bridges to the shear strength of the joint has to be accounted for in order to better assess the stability of the rock mass. A numerical analysis of the progressive failure of a rock slope involving a non-persistent joint has been set up based upon simulations performed using a Discrete Element Method (DEM) algorithm specifically enhanced for the modeling of jointed rock masses. Pre-existing discontinuities are explicitly accounted for in the model by using a modified contact logic that ensures an explicit and constitutive mechanical behavior of the joint planes. In addition, rock bridges can be spatially distributed along these joint planes following a prescribed probabilistic technique. Jennings’ formulation (Jennings, 1970) is considered as one of the first rock slope analysis that evaluates the shear resistance to sliding as a weighted combination of the shear resistance of the intact rock and the joint planes. The validity of this formulation is discussed in the present study. Contrary to the Jennings’ formulation, we show that tensile failure is an important mechanism, particularly as the dip angle of the sliding plane increases.

Jan 1, 2015

Why innovate? ? How are we doing in Canada? ? How can we do better? ? Why now? ? What?s next? ? Lowering production costs ? Improving productivity ? Increasing value-added ? Discovering new mines, extending life of existing ore bodies ? Reducing environmental footprint ? Improving health and safety

May 1, 2008

By Takashi Nakamura, Atsushi Iizuka, Yong Fan, Etsuro Shibata

Magnetic separation of precipitated magnetite as iron resources in copper slag is one of the potential effective ways to recycle the slag. It is preferable to convert molten fayalite slag after copper smelting process to magnetite slag via oxidation. With a TTT (Time-Temperature-Transformation) diagram, the crystal composition of the slag obtained after air isothermal oxidation could be estimated through a designed cooling path. The crystallization behaviors concerned with molten oxidation was studied for better understanding of the trade-off relationship between magnetite and hematite during molten heat treatment. Moreover, a brief consideration was implemented of the reaction mechanism.

Jan 1, 2014

By D. G. Macintyre

Thick westward prograding clastic wedges were deposited along the margin of ancestral North America from Mid-Proterozoic to Mid-Paleozoic time. Periodic rifting and tectonic subsidence resulted in the formation of starved sub-basins along this otherwise passive continental margin. These sub-basins host important sedimentary exhalative barite-zinc-lead-silver deposits. In northeastern British Columbia, a thick succession of Paleozoic basinal facies clastic rocks is preserved within the northwest-trending Kechika Trough. Within the trough, sedimentary exhalative barite and barite-sulfide deposits occur in starved basin sediments of Middle Ordovician, Early Silurian, and Late Devonian age. The last are the most economically sigrrificant and are hosted by carbonaceous cherty argillites and siliceous shales of the Middle to Late Devonian Gunsteel Formation of the Lower Earn Group. The largest deposit, Cirque, has reserves in excess of 35 million tonnes averaging 100J0 (Pb +Zn) and 47 g/t Ag. Other potentially significant deposits include Driftpile Creek, Bear, Mt. Alcock, Fluke, Pie and Elf. Stratiform barite deposits are also common, particularly near the basin-to-shelf transition zone. The Late Devonian barite-sulfide deposits typically are zoned: interlarninated barite-sphalerite-galena-pyrite occurring near suspected vent areas grades outward into bedded barite. Laminated beds of pyrite typically occur in hangingwall siliceous shales, particularly above the inferred vent zone. The apparent absence of epigenetic stringer sulfide zones and footwall alteration implies that the deposits were formed from ponded brines at relatively low temperature. Away from the main deposits, the favourable stratigraphic interval is marked by the presence of thin beds of nodular and laminated barite and thin laminae of pyrite. Thin tuff beds also occur locally in this stratigraphic interval and are evidence for a Late Devonian volcanic event. A paleogeographic reconstruction of the Kechika Trough in Late Devonian to Mississippian time suggests that the barite-sulfide deposits formed in third-order starved basins between uplifted, northwest-trending horst blocks that were capped by shallow-water carbonate banks. The presence of intraformational breccias suggests that fault movement accompanied barite-sulfide precipitation. This tectonic activity may have allowed the escape of heated, overpressured metalliferous brines from permeable reservoirs within the sedimentary pile. Sedimentary exhalative deposits formed where these brines were exhaled as buoyant plumes onto the seafloor, cooled, and ponded in anoxic seafloor depressions.

Jan 1, 1992

By Malcolm Scobie

"This paper reviews the evolution of Canadian surface and underground mining automation, principally relating to: advances in communications, initial development of machine teleoperation from line-of-sight remote control, and islands of automation. The eventual role of teleroboties and minewide robotic mining remains to be resolved. The progress and approaches adopted have tended to vary within each sector of the mining industry. Recent information technology advances have made possible the Digital Mine; in which information associated with all mining processes, however dispersed, would be integrated with support systems using new communications technology. The Digital Mine will provide the information infrastructure to serve as the foundation for minewide automation. This paper concludes by reviewing the issues likely to govern implementation success, relating to: mining process design, machine design, machine intelligence, and mine planning and control.IntroductionSignificant advances have recently been made in underground hardrock mine communications and teleoperation. Subsequent R&D efforts are mainly focussing on control systems for various types of machines. In underground potash mining, the realization of automated continuous mining systems appears to be imminent. Recent advances in surface mine dispatching, machine monitoring and global positioning systems (GPS) have tended to reactivate some of the initial R&D enthusiasm developed in the '70s for surface mine automation. Mines at large are approaching a major milestone: the implementation of comprehensive communications infrastructure which proves to be sufficiently reliable and economical to support the automation of routine mine production, either using teleoperated or autonomous machines. This then should motivate a deeper commitment to real time monitoring and management. The communications advances make possible the Digital Mine; in which information associated with all mining processes, however dispersed, would be integrated with support systems using information engineering. The Digital Mine will provide the information infrastructure to serve as the likely foundation for a wide range of automation scenarios. This paper surveys the status and directions of automation development in both surface and underground Canadian mines, pointing to what are seen to represent key technology development issues."

Jan 1, 1995

By A. E. Reschke

Optimized mine planning of the Leeville Gold Mine, Nevada, necessitated the requirement for an average of 2540 tpd of high quality cemented rockfill (CRF) in primary stoping blocks and underhand cut and fill workings. To meet this requirement, a number of innovative design features were incorporated into the overall batching plant design. Foremost is the use of a dedicated skip to transfer crushed aggregate from surface down through the ventilation shaft to twin underground storage silos. Also, the use of a high shear colloidal mixer on surface to pre-slurry a cement/flyash binder with pipeline delivery to one of two separate underground CRF mixing stations was incorporated. Finally, the binder and aggregate are combined in a 9 m3 twin shaft compulsory type mixer before loading into teleram trucks for placement.

May 1, 2007

By F. Osmond, R. Kelly

"Malcolm Knowles, the famous adult educator once wrote: ""What a challenge we in human resources development face if we are to avoid the obsolescence of our workforce. I can foresee this challenge requiring that we reconceptualize (...) and redefine the role of HRD, away from that of managing the logistics of conducting training activities to that of managing a system of learning resources"".The context in which this was written surrounds the subject of adult education and the need for business and industry to change its approach to the treatment of adults as learners. In explaining what 'managing a system of learning resources' means, Knowles refers to line supervisors and managers as the most ubiquitous resources for day-in and day-out employee development. In many organizations training has been largely a staff rather than line responsibility. Even where trainers reported to line management, it was still seen as a staff function performed by a few specialists.This change referred to by Knowles places a much heavier responsibility on line supervisors and managers for the development of their personnel than has traditionally been the case. Managing that change - handing over the responsibility to the line organization - is the supreme challenge for the HRD function.Just why is this change necessary? Because too often, the learner does not effectively use on the job what he or she learned in the classroom. In fact, learners often discard new methods and revert to the older ways. The reason training does not stick is that the systems for training and work management are most often separate entities and while one may support the other, they need to be a single integrated system in order to ensure the transfer to the job effectiveness of training and some real value for the training dollars.Because much training can be wasted, steps have to be taken to ensure that it fulfills its intended purpose. The effective and continuing application of knowledge and skills that learners acquire can only be realized when line supervisors and managers are at the centre of the training system.This paper describes how such a systemis being developed at the Iron Ore Company of Canada (IOC) as a functional training program is introduced. The following text provides background information on the IOC - who they are and where they are located, a definition of functional training, an evaluation of the suitability of this approach for adults in industry, a description of how the program is being implemented at IOC and some observations that have been made as this change is experienced."

Jan 1, 1995

By E. Norton

"Even though the subject of this panel discussion is dust control, rather than dwell on the design aspects of dust collection systems which are well documented in numerous publications, :it was considered more pertinent to the present economics of mining to examine the energy costs involved.At the present time, the facts of shrinking fossil fuel reserves and spiralling fuel costs are being constantly brought to our attention. Industry is being motivated to consider the possibilities of incorporating heat recovery systems in areas where they prove to be economical. Unfortunately, it is not a simple exercise to determine if the installation and operation of heat recovery equipment is feasible and economical. Each process involving heat recovery potential must be thoroughly studied in all aspects.In a paper presented at the 1975 Annual General Meeting of the Canadian Institute of Mining and Metallurgy in Toronto, Ontario, entitled ""The Influence of Energy Conservation on Concentrator Design"", it was stated that the largest single energy consumer in winter is space heating with the largest portion of this supplied to crushing and screening plants. (1) Within the scope of this panel discussion we will study, as one example, a crushing and screening plant using natural gas heat in the province of British Columbia and we will explore the feasibility and economics of installing air-to-air heat recovery equipment."

Jan 1, 1976

By Jean-François Lagueux

Goldex Mine is an underground mine located near the town of Val-d?Or. Multiple innovations were required to work the mine. Due to its low grade, it was important to develop a bulk mining method to economically extract the ore. The method used is a combination between shrinkage stope and long hole stope methods. This modified method is more than adequate; however, all of the ore body must be liberated in a very short period of time. Therefore, to bring down 23 Mt of ore, large blasts up to 1.8 Mt are required. The situation is also complicated by the fact that the mine is located in a residential area. No less that 40 homes are built within a 1 km radius of the mine site. In addition to managing mass blasts, means must also be found to mitigate the vibrations produced by the blast to diminish the disturbance to the neighbourhood. Therefore, the mine used numerous tools to properly plan the blasts and reduce the impacts. A program to control vibrations was one of the first tools put in place. The program?s aim was to draw up an action plan to ensure a follow-up of the homes by inspecting them. The second tool was to develop a methodology to plot a reliable attenuation curve and to adequately determine the maximum charge weight for each blast. Finally, effective communication tools were developed to inform the neighbourhood. There was a huge amount of work to be done in relation to the bench. Reliable and fast loading techniques had to be found to load large blasts in a very short period of time. Adequate logistics had to be developed to send underground more than 20,000 kg of emulsion per day while performing the daily underground operations. Technology had to be developed to adapt the i-kon electronic blasting system to large blasts. Since the control of the charges was the major factor to reduce surface vibrations, it was important to employ loading techniques that would permit decking of the long holes to reduce the charge weight per delays without adversely affecting the loading. All of this work requires an enormous amount of energy but also close collaboration between the different stakeholders (various departments, suppliers and consultants).

May 1, 2011

By Victor A. Sowa

"Abstract - In 1938, a body of goethite and hematite was discovered beneath Steep Rock Lake near Atikokan, northwestern Ontario. This was at the time the largest and richest undeveloped iron ore body in North America. Mining began in 1944, fast-tracked by the needs of World War II, and through 1979 produced 79 Mt of 56.5% Fe. Production required the diversion of the Seine River, draining of Steep Rock Lake, building of a railroad, and a 25-fold increase of the local population. The mining project, at the time, was the largest project of its type undertaken in Canada. The current concepts of sustainable mine development and mine closures have advanced considerably since the period of operation and closure of the Steep Rock mines, and those operations would probably not have met current expectations of sustainability. However, some of the post-closure aspects of the mines provide illustrations of components of sustainability, which could form part of a basis for a post-mining sustainable land use plan. It is concluded that some of these components were successful in meeting current expectations of sustainable use, and although some aspects are unique to the circumstances at the Steep Rock mines, others could be applicable at other mine sites."

Jan 1, 2003

By A. Navarra, Norman Toro, T. Marín, Fernando Ayala

The quantitative techniques to evaluate the enhancement of a particular unit operation should consider the corresponding changes to the adjacent unit operations. For example, the expansion of off gas handling capacity should consider the corresponding changes in converter cycle times, matte grade, and other operational parameters, that can provide the optimal system-wide benefit. In general, the upgrading of smelter equipment is risky due to the size of capital investment, as well as any unforeseen impacts on rest of the operations. However, this risk can be mitigated by applying the principles of Front End Loading (FEL) in the formulation of multiphase re-engineering projects. The initial phases of engineering are relatively inexpensive, and determine whether or not to pursue the subsequent phases that are comparatively more expensive. Each phase of engineering depends on increasingly detailed descriptions regarding the critical phenomena that can effect design decisions; the increasing levels of detail may result from numerical simulations, as well as laboratory and plant trials. The quantitative framework should be sufficiently flexible to accommodate these increasing levels of detail, regardless of the particular phenomena, so that it may evolve throughout the project. The current article describes the combined usage of mass balancing, thermochemistry and multiphysics, in the development of discrete event simulation (DES) and finite differences (FD). The incorporation of finite differences into a DES framework depends on adaptive time-stepping, to determine threshold-crossing times, e.g. when the matte temperature surpasses a critical level that necessitates the addition of cold charge. The hybridization of DES and FD is appropriate for multiphase smelter development projects, as it supports semi-continuous material flows, operational policies and scheduling, as well as unexpected events and trends, in increasing levels of detail. This type of framework will support the installation and tuning of modern control systems, including state-of-the art sensors and machine learning algorithms.

Jan 1, 2019

By Simon Pelletier, Jose Delgadillo, Dave Page, Pramod Kumar, Raj Rajamani, Dilek Alkac, Martin Fillion

"In general, many past works examine mill load, mill power, shell lifter design etc with a view to improving the mill capacity. On the contrary, only a handful of papers have addressed the transport of fine slurry through the pulp lifters. We present the flow dynamics of pulp lifters via laboratory scale experiments, high speed photography and modeling with computational fluid dynamics. Next, the flow behaviour in ArcelorMittal’s Mont-Wright autogenous mill discharge flow is examined. In an effort to improve mill throughput, a comprehensive simulation and plant scale study of the mill was taken up with a focus on the shell and pulp lifter design. The shell lifter was found to be at its optimum limit for breakage of ore particles given the constraints of wear life and occupied volume. Next, the pulp lifter study was taken up with computational fluid flow code and discrete element code. The simulations directly showed that there was considerable carry-over of slurry. This effect was traced to the area restriction in the pulp lifter channels. Further, crash-stop studies confirmed slurry pooling within the mill. Thus it was readily apparent that mill throughput can be increased if the pulp-lifter could be redesigned. Consequently, the discharger section of the pulp-lifter was redesigned.First, this paper outlines the modeling in laboratory scale studies and plant scale studies leading up to the discharger design. Next, the discharge flow in seven different published mill surveys is predicted with computational fluid dynamics (CFD) methodology shown here. Finally, Mont-Wright mill circuit performance before and after the discharger redesign is described. The usefulness of fluid flow simulations in the design of pulp-lifters is emphasized."

Jan 1, 2012

By Joël P. T. Kapusta, Liam J. Watt

The last extended copper smelting and converting survey dates back to the 2003 International Copper Conference held in Santiago, Chile. The following year, the Minerals, Metals, and Materials Society of AIME (TMS) started a new series in its Journal of Metals (JOM) called JOM World Nonferrous Smelters Survey devoting its first Part to Copper. The copper smelting landscape has significantly changed in the past 15 years, both in geographical terms with the shift of copper smelting production from the Americas to China and in technological terms with the growing adoption rate of Top-Submerged Lancing (TSL) technologies and the development and implementation of Bottom-Blowing technologies. A copper smelting survey update, even if not as in-depth as the 2003 Copper Smelting Survey, is therefore in order. The authors will review the latest trends in copper smelting technologies and production worldwide in comparison to the landscape of the early 2000s. INTRODUCTION This 2019 copper smelting survey is different from previous surveys as our data does not originate exclusively from responses to a questionnaire sent to all the copper smelters. Our data comes from several sources. We are therefore very thankful to the International Copper Study Group (ICSG) and Wood Mackenzie for sharing some of their information and to ENFI, Outotec, and Glencore Technologies for helping us cross-check our numbers for the Chinese smelters, flash smelting, Ausmelt, and Isasmelt technologies. Our survey presents data reporting from a total of 96 operating copper smelters from around the globe, which is significantly higher than the 50 surveyed in 2003. Although secondary smelting numbers have steadily increased over time, this paper focuses on primary smelting operations with copper concentrate as feed material. The list in this survey is still far from complete, with missing information from several known smelting operations. The total primary copper production tonnage of the smelters we surveyed amounts to 18.3 million metric tonnes from 29 countries representing 92% and 94% of total world primary production for 2018 estimated by ICSG and Wood Mackenzie, respectively. This representation has increased from 2003 when the total was 9.71 million metric tonnes from 23 countries accounting for 73% of world production. The trends presented and analyzed within this paper have stronger significance because of the increase in production accounted for. The Chinese and Russian smelter information collected is more detailed than years past. Our complete dataset is summarized in Table 1 at the end of our paper.

Jan 1, 2019

By P. Latostenmaa, T. Veneranta, J. Järvi, E. J. Peuraniemi

Boliden Harjavalta has operated a copper flash smelter since 1949 thus the smelter celebrates 70th anniversary of flash smelting in 2019. This paper shortly describes the historical perspective of the smelter and gives an update of the current operational issues and process modifications made during the recent years. The plant has carried out several major investments lately providing a firm view on the future. A new landfill area for the final slag was commissioned in 2018. A modernization of the concentrate storage area, a new acid plant and a debottlenecking project of the smelting line have been recently commissioned. At the same time, the tankhouse capacity will be expanded. This paper focuses on smelter modernizations. INTRODUCTION Boliden is a metal company operating mainly in northern Europe with core competencies in the fields of exploration, mining, smelting and metal recycling. Boliden Harjavalta, located in Finland, is part of the Smelters Business area of the Boliden Group and operates a copper and nickel smelter with related sulphuric acid plant in Harjavalta, and a copper refinery in Pori. As a short historical review, Harjavalta’s history may be dated back to the year 1910 when the Outokumpu ore body in eastern Finland was discovered. By the end of 1913, a copper mine was in operation and a copper plant based on Hybinette process was ready for commissioning. Due to difficulties in metal recoveries and throughput the Hybinette process was permanently shut down in 1929, and 100% of the mining production was sold as concentrate abroad. As the mine production increased steadily, a decision of a new smelter was made in early 30’s. In 1936 Outokumpu’s copper smelter based on electric smelting was commissioned in Imatra. The smelter was dismantled and transferred to Harjavalta during the final stages of the Second World War. The copper refinery started in Pori already in 1941 and the first copper anodes were cast in Harjavalta in 1945. First sulphuric acid plant started operation in 1947. Due to the post-war shortage of electrical energy, the plant metallurgists initiated a major development work to start exploiting the latent heat of concentrates. Thus, the flash smelting method was developed in Harjavalta and commissioned in 1949. Ten years later, flash smelting was also applied for nickel concentrates. Table 1 summarizes major historical and technical milestones of Harjavalta. The history of flash smelting is described in details in another paper of this conference (Jåfs et al., 2019).

Jan 1, 2019

By H. E. Wilde

"Zinc has been used for many years as a galvanic coating for the protection of steel. Electrochemical measurements show that zinc actually overprotects steel. The corrosion rate of DQSK (drawing quality semi-killed) steel in air saturated salt water was determined as a Junction of applied cathodic potential. The resulting data indicate that at a critical cathodic over potential of - O. 725 Vsce an acceptably low corrosion rate of less than 1 mpy occurs. Using the developed criterion, alloys of Zn/X and AL/X were produced and evaluated in galvanic contact with steel in a standard laboratory test. The results indicate that Zn /Mn, Zn /Co, AI/Mg/Si and AI/Mg/Ge alloys offer excellent galvanic protection along with (a) no hydrogen evolution, and (b) improved dissolution life over Zn coatings.IntroductionZinc coated (galvanized) steel has been successfully used in applications where bare (or painted non-galvanized) steel would suffer corrosive attack. In general, galvanic coupling to zinc, as either an anode or a coating, is an effective means for combatting steel corrosion. Because of this, the use of galvanized steel has increased markedly, stimulated primarily by automobile manufacurers seeking to extend the corrosion warranties on automobiles(1).Although effective, zinc coatings are not without a number of drawbacks which warrant efforts to improve them. For example, because of the widely differing electrode potentials between zinc and steel ( - 1.05 Vsce and - 0.60 Vscc, respectively, in air saturated NaCl solutions), the zinc corrodes at a rapid rate to protect the steel. This is reflected in the limited lifetimes of galvanized unpainted siding. The basic electrochemistry controlling the situation is shown in Figure 1, for a system controlled by oxygen reduction. The zinc corrodes sacrificially to protect the steel, while cathodically polarizing the steel to a potential near that of zinc's open circuit anode potential."

Jan 1, 1990

Applications of proven real time, through-conveyor elemental analysis technology and benefits achieved will be discussed using case studies in base metals, iron ore and phosphate operations. PGNAA (Prompt Gamma Neutron Activation Analysis) technology and its background in minerals applications and applications which are expected to further improve its utilization will be reviewed. Short payback through operational benefits such as removal of waste from feed, increased feed grade and overall improved productivity will be demonstrated based on results achieved at several processing operations. PGNAA technology is most applicable to conveyed flows as it is unaffected by belt speed, particle size, segregation/layering, mineralogy or dust. As a transmission method able to penetrate in excess of 500mm of rock it provides extremely representative results continuously measuring through the full conveyed cross section and reporting results typically on one to five minute accumulated increments to the control room. Multi-elemental results and moisture content are used for active process control: diverting conveyed flow increments(bulk sorting), blending ore types in plant feed, and providing advance warning of significant quality changes to the downstream plant operators (e.g. flotation). Elements of interest may include deleterious components as well as target metals. Ore feed quality measurements are also useful in metal accounting, ore reconciliation and real time feedback to mining operations. Further benefits can result when combined with other technologies such as particle sorters, to upgrade diverted increments of subeconomic material to achieve higher feed grades and lower deleterious content to the main process. Measurement of elements (e.g. silica) which correlate with ore hardness or grinding characteristics can be used to moderate feed rate to grinding mills to prevent overload, hence optimizing grinding performance and reducing energy and grinding media consumption. Pebble flows can be analysed and uneconomic increments diverted to prevent recirculating flows consuming mill capacity unnecessarily. This also increases average feed grade.

Jan 1, 2016

By Blaycock. S. C.

WE should indeed feel proud and satisfied with the accomplishments of our great mining and metallurgical. industries during the past quarter of a century, for they have vastly exceeded those of any previous period of like duration. 1 feel that Canadians, and particularly those in the mining industry, should know more concerning the important role our industry will be called upon to play in the present war. Our Empire metals will be an outstanding factor in this conflict. Every man connected with the industry, from the lowest paid labourer to the highest official, can feel proud that his every effort results in more and more production of those metals which will help to give the Empire supremacy. He can feel assured that, by sticking to his job and by putting his whole heart into his work, he is making a contribution towards winning the terrible struggle in which our Empire and our gallant French allies are engaged. These two great peoples will have ro bear the brunt of the task of ridding the world of the menace of those who would set up force. and might in the place of right and justice in the settlement of international affairs. As the present European crisis developed, it became evident that they, alone, would have to accept the challenge and fight the enemies of Democracy to ensure the survival of the small nations of Europe and, indeed, of the great democratic powers themselves. The acquisitive eye of the German leaders had looked far ahead and they had realized that the eastern European states, already reeming with population, were no solution to Germany's space problem; but they thought that these states could be gobbled up one by one, each in turn strengthening Germany's might until it could successfully challenge France and England. No glimmer of doubt dimmed their vision. The two great democracies once subdued, they could proceed to seize Canada and the United States. This clone, they would have an abundance of room to expand, as well as those resources-grain, timber, cotton, nickel, iron, lead, zinc, copper, gold, silver, sulphur, oil-which German statesmen have always coveted. Von Ribbentrop, von Alvensleben, Bernstorff, and many others have made exhaustive studies of our resources. German rulers had been told that the French would not fight and that the British could not. They knew of the rust on the British war machine. There was no cloud in the sky; their fond dream was at last robe fulfilled.

Jan 1, 1940

By P. H. J. Mercier, M. Couillard

Aberration-corrected scanning transmission electron microscopy (STEM) allows for the nano-scale exploration of materials at unprecedented resolution and sensitivity. In this paper, we combine this approach with electron energy-loss spectroscopy (EELS) and energy dispersive X-ray spectroscopy (EDX) to analyze the carbon distribution in residual solids found in solvent-diluted bitumen product extracted from Alberta oil sands. Major components of these contaminant solids are ultrafine clays. Biwettable clays have been associated with the formation of solid-stabilized water-in-oil emulsion, which are known to increase the content of both water and mineral solids in the final bitumen product. We demonstrate that the residual solids present in bitumen product contain carbon intermixed with mineral particles of various size and shape. By probing the carbon content at the nanometer scale with the high chemical sensitivity of EELS, we provide direct evidence of carbon intermixing with clay platelets. This clay-organic association at the nanometer-scale will contribute to the biwettable, hydrophobic character of the platelets, and will therefore play a crucial role in the bitumen extraction process

Jan 1, 2014

By T. Sun, J. Kou, C. Sun, China Railway Resources Group Limited

"The polymetallic sulfide ore in Jiama county of Tibet contains 0.78% Cu, 0.046% Mo, 0.31 g/t Au and 17.9 g/t Ag in average. However, heavy loss of valuable metals was observed using high-pH process and Butyl xanthate as the collector. In this paper, the flotation was optimized through the adoption of a novel collector C-7, which is a mixture of xanthate ester and thionocarbamate. This collector showed better flotation performance under weak base conditions. The recoveries of Cu, Mo, Au and Ag increased to 93.24%, 84.60%, 78.13% and 75.41%, respectively, under 15 g/t of C-7 at pH of 8.0. The adsorption mechanism of C-7 was investigated by micro-flotation tests, zeta potential measurements, FTIR analysis and adsorption quantity measurements. Chemisorption of C-7 on chalcopyrite surface is demonstrated with adsorption density 3.8 times higher than on pyrite.INTRODUCTIONXanthates are the most commonly used collectors of strong collecting ability for separating copper sulfide minerals from gangue in froth flotation. However, the selectivity of xanthates themselves is poor to realize separation of chalcopyrite and pyrite whose floatability are quite similar (Heyes & Trahar, 1977; Chandraprabha, Natarajan, & Modak, 2004). High pH process with xanthates as collectors is proved effective in copper-sulfur separation and is widely used in treatment of copper sulfide ore flotation (Smith, 1996; Valdivieso, Cervantes, Song, Cabrera, & Laskowski, 2004). This method could get ideal separation results, but large amount of lime must be added, and could bring about increased cost, device corrosion and environmental pollution. In addition, there could also be high depression and heavy loss of associated noble metal such as Mo, Au and Ag. Consequently, a large amount of research has been conducted on substitutions of xanthates for selective flotation of copper sulfide ores under low pH conditions (Gholivand, Khodadadian, & Ahmadi, 2010; Li, 2010)."

Jan 1, 2016