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By V. S. Papezik

Pyrophyllite, a hydrous aluminium silicate, is used mainly in the ceramic industry and to a lesser extent as a filler in the manufacture of paper, rubber, insecticides and baby powders. Commercial deposits of pyrophyllite in North America are restricted to the "Avalon Zone" , a belt of late Precambrian volcanic and sedimentary rocks that extends along the eastern flank of the Appalachian orogenic belt f rom Georgia to Newfoundland. The only commercial Canadian pyrophyllite deposit lies near Foxtrap on the A valon Peninsula of Newfoundland. Here, steeply dipping lenses of altered pyrophyllite rock occur in a north-trending rhyolite belt near the contact with a granitoid pluton. The altered rock is massive, light greenishyellow and contains varying proportions of pyrophyllite, sericite and quartz with lesser amounts of diaspore and traces of barite and rutile. A lteration was produced by acid solutions, either derived from or activated by the intruding pluton, at temperatures of 250° to 270°C and pressures not exceeding 2 kbr. The largest of the Foxtrap pyrophyllite lenses, discovered in 1897, was mined intermittently f rom 1903 until the early 1950s. The present owner of the mine, Newfoundland Minerals Limited, acquired the property in 1959 and ships between 27, 000 and 36,000 tonnes annually to th e company plant in Lansdale, Pennsylvania, for use in ceramic tile.

Jan 1, 1984

By S. McCarthy, K. E. Waters, A. Jordens

The beneficiation of rare earth (RE) element bearing minerals has become an active area of research as applications for these elements grow while the supply to non-Chinese consumers is restricted by export quotas. One of the most interesting beneficiation techniques for RE minerals is froth flotation as their unique chemistry suggests that collectors with a specific affinity for RE cations should be able to selectively recover these minerals. Existing literature, focusing mainly on bastnäsite flotation, identifies hydroxamic acids as excellent collectors for RE minerals. The high stability of hydroxamate-RE cation complexes is the explanation most often offered for the observed selectivity of these reagents in bastnäsite flotation however some research has also suggested that mineral solubility plays a crucial role in the success of hydroxamic acid flotation of RE minerals. This work investigates the interaction of allanite, a relatively insoluble RE-silicate mineral, with benzohydroxamic acid using zeta potential measurements and microflotation. The effects of Fe(III) and Fe(II) ions as potential activating ions (cations that form stable hydroxamate complexes) on benzohydroxamic adsorption to the allanite surface are investigated as a potential solution to promote hydroxamic acid adsorption. The results indicate that the optimum conditions for separation of allanite from quartz occur at pH 4 using FeCl2 as an activator for benzohydroxamic acid adsorption.

Jan 1, 2014

By Pierre Gy

"Abstract - This paper deals with industrial complexes such as: (1) a mine producing metal-bearing ore and a furnace(s)/converter(s) where the ore is melted into metal, either directly, or after a mineralurgical concentration; and (2) quarries producing the raw materials required for the manufacturing of cement and the kilns to which they are fed.Each mine or quarry operation results from the exploitation of a mineral deposit. This deposit is never homogeneous. The raw materials which are extracted from the mine/quarry can never be safely fed to a "process" such as a cement kiln or a metal smelter, because the devices involved lack the flexibility required to absorb a very inhomogeneous feed. Furnaces and kilns are known to be very sensitive, sometimes dangerously so, with regard to deviations from a certain ideal feed composition.The purpose of this paper is to present the conditions required to optimize the operation of such a complex, so as to maximize the production, the quality of the product, as well as the profit generated. Two key operations are involved: sampling (to know accurately the materials being dealt with) and bed-blending (to achieve the desired degree of homogeneity). The theories of sampling and bedblending have been developed by the author and presented in various books (Gy, 1992, 1998)."

Jan 1, 1998

By M. Leroux, S. R. Rao, J. A. Finch

"Poor Pb/Zn selectivity during Pb flotation in laboratory tests on a Mississippi Valley-type Pb/Zn ore was traced to a pH effect. In the pH range 9.5-11 sphalerite floated readily without copper activation. Compared to sphalerite flotation with copper activation this procedure gave equivalent selectivity but reduced flotation rate.Possible mechanisms of this sphalerite flotation without copper activation are discussed. Activation by Fe(OH) 2 is suggested, the Fe++ions being derived from superficial oxidation of pyrite in the ore.INTRODUCTIONGalena and sphalerite commonly occur together. The usual practice is to float galena first followed by the flotation of sphalerite after activation with copper (II) sulphate. If ores contain pyrite it is depressed by maintaining an alkaline pH (9- 10) and using NaCN as depressant.In flotation tests with a Pb/Zn ore from Polaris selective flotation of galena could not be achieved consistently as a considerable amount of sphalerite, even though unactivated, floated. A systematic study was carried out to determine the cause of this problem. This led to the unexpected finding that sphalerite floated in the alkaline pH range 9.5-11.0 without preactivation with Cuso 4 . This paper describes the results of this study and discusses a possible mechanism of the flotation of sphalerite."

Jan 1, 1987

By R. H. Duval

"In May 1936, Pamour started producing gold by cyanidation of flotation concentrates, and in 1939 was milling about 1, 600 tons per day.Refining records dating from 1939 show two oil-fired furnaces in use, (Rockwell type 46 11 x 29 11 inside oval shell).Refining time averaged 7. 83 hours during the year 1939, indicating a complete refining shift of about 9. 33 hours. That year appears to be characteristic of the period with regard to time required and results obtained.For that year total fineness (gold + silver) of the bars averaged 940 (approx.), but it frequently dropped below this figure, sometimes far below.Furnace lining life varied widely from three to seven or more months. Sillimanite was the standard lining but Mullfrax 41 was frequently used.For many years refining practice remained practically unchanged, and in 1960 procedure still consisted essentially of mixing a flux(% Composition Borax 41, Silica 11, Soda-Ash 11, Nitre 15, Mn02 22) with cyanidation precipitate in the ratio of l. 2 to l and heating to a medium heat (yellowishred, 2000° F) with a low flame for a long time. Time required was about 10. 5 hours per refining. Results were still much as detailed above.At this time it was decided to revise refining procedure, in an effort to shorten refining time and obtain consistently good bullion fineness."

Jan 1, 1965

By d&apos, F. Elia

Hot cracking of magnesium (Mg) alloys during welding creates a barrier to enhancing the use of these alloys in automotive applications. As a result, it is imperative to understand the mechanisms responsible for hot cracking of Mg alloy welds in order to develop means of eliminating this problem. In this study, the hot cracking susceptibility of AZ91E and AE42 magnesium alloys were assessed using the moving torch Varestraint test method. Plates of 3 mm thickness were extracted from AZ91E and AE42 ingots and subsequently tested. Quantitative cracking data in terms of maximum crack length (MCL) was used for evaluating the cracking susceptibility. Scanning electron microscopy was carried out. The results suggest that AE42 showed a higher resistance to hot cracking in comparison to the AZ91E alloy. This was attributed to the difference in microstructure between the two alloys. In the fusion zone and HAZ of AE42, the brittle needle-like A1IIRE3 phase was seen to decompose to the more ductile particle-like Al2RE phase, thereby increasing the alloy's resistance to hot cracking. In contrast, SEM fractography revealed that brittle A16Mn and Mg17A112 intermetallic particles segregated to grain boundaries and triggered hot cracking in AZ91E.

Jan 1, 2011

By M. Mirnezami, J. A. Finch

The McGill component of the consortium contributed detailed examination of the electrokinetic properties of the constituent minerals, primarily pentlandite and serpentine. Mineral specimens were derived from an ore sample; mineralogical examination showed the serpentine was predominantly clinochrysotile, a fibrous mineral responsible for much of the flotation separation problem. The study included design of a novel sedimentation potential measuring device to classify the surface charge of the ore and electrophoresis measurements on single and mixed minerals which progressively approached flotation conditions. The sedimentation potential measurements provided a general association between surface charge and the visual state of aggregation as a function of pH. The electrophoresis experiments started with single minerals in a background of indifferent electrolyte and progressed to mixed minerals in a background of supernatant derived from an ore sample. The single mineral tests supported the suspected electrostatic interaction, i.e., hetero-coagulation, at flotation pH 9-10. The mixed mineral tests demonstrated this interaction and also revealed hetero-coagulation with Mg(OH)2 precipitates, derived from the supernatant. This interpretation was confirmed by optical and electron beam imaging. A series of agents, CMC, polyphosphate, soda ash, EDTA, were examined to disperse the system. To accommodate the small mass of single mineral available a novel turbidity measurement using a UV/Vis spectrophotometer was introduced. Selected conditions were used in contact angle and small-scale flotation tests.

Jan 1, 2011

By Isabelle Demers, Audrey Jalce

L’industrie minière génère chaque année une quantité considérable de rejets miniers, principalement sous forme de stériles ou de résidus de l’usine de traitement. Les stériles sont des roches sans valeur économique, excavées pour atteindre la roche minéralisée. Ils sont usuellement empilés en surface formant des haldes à stériles. Les résidus miniers sont des roches finement broyées, mélangées avec de l’eau, résultant du traitement du minerai. Ils sont généralement pompés et entreposés en surface dans des parcs à résidus. Cependant, leur stockage peut être sujet à des instabilités géotechniques, mais également géochimiques, pouvant entrainer des problèmes environnementaux majeurs, tels que le drainage minier acide (DMA). Le DMA se produit lorsque des minéraux sulfureux, contenus dans ces deux types de rejets, s’oxydent au contact de l’eau et de l’oxygène [1]. Le DMA se caractérise par une solution acide (pH inférieur à 6) riche en métaux, contaminant les eaux souterraines et de surface et représentant alors un danger pour la faune, la flore et la santé humaine [2]. La remise en état et la fermeture des sites miniers doivent donc être pensées dès la phase d’étude du projet d’exploitation, afin de proposer une méthode de gestion des rejets qui permettra de limiter les impacts environnementaux pendant et après l'exploitation.

May 2, 2024

By Rodolfo Zanella

Au/TiO2 catalysts were prepared by deposition-precipitation using NaOH (DPN) (~3 wt % Au) and urea (DPU) (~8 wt % Au), and calcined at various temperatures between 100 and 400 °C. They were characterized by UV-Visible, XANES, EXAFS and TEM. Their activity were tested in the reaction of CO oxidation at 5°C. After preparation, the gold species are in the oxidic state III. They begin to transform into metallic gold under air at ~100 °C for DPN and ~150 °C for DPU. At 200 °C, all the gold is metallic for the two preparation methods. The particle size increases from 1.5 to 3.5 nm with the calcination temperature. The catalytic activity for CO oxidation increases with the percentage of metallic gold, and it is maximum at 200°C for both types of samples. The activities (per mole of Au) are the same for the two types of catalysts. At higher temperatures, the catalytic activity drops. The decrease of activity is mainly due to a change of particle shape with the calcination temperature rather than to the increase of the particle size. At a calcination temperature of 200°C, the particles present small facets with rounded parts, and their outer surface contains a large proportion of low coordinated sites (steps and corners) while at high temperature of calcination, they are truncated octahedra with smooth facets.

Oct 1, 2003

By C. W. Eggert

"The idea for this talk came to me last year when I was attending the Canadian Gold Metallurgists Meeting. I talked about it to a friend of mine who is an authority on mineral dressing, particularly the theoretical end of the business. He remarked that this was an excellent technical note, why don't you write it up. This is what I have for presentation this morning. I hope in presenting this type of idea in this way it is in keeping with the tradition of the Canadian Gold Metallurgists which was to function on a not too sophisticated level and where operators could get together and trade ideas in an informal way.My basic thesis is that it should be possible to evaluate screen analyses by the application of the standard statistical probability theory. In any statistical analysis the sample is the first consideration. If we look at existing methods of size evaluation we find it is usually based on the fact that a given particle will pass one square aperature and not another. One system of standardizing how these aperatures will be set up is based on Rittenger' s work with the ratio of hole sizes proportional to the square root of 2. Keeping in mind the limitation we have accepted this as our method of 11 sizing"" in attempting to apply standard statistical methods to screen analysis."

Jan 1, 1968

By George P. Demopoulos

In a departure from the traditional domain of hydrometallurgical extraction processes we consider new R&D opportunities for innovative application of solution processing into the advanced green energy and clean technology fields. It would not be an exaggeration if we state that protection of the environment via advancement of clean technologies on the one hand, and harvesting and utilizing renewable energy in a sustainable and cost-effective way on the other hand are clearly among the top pressing global priorities. When hydrometallurgy is approached on the basis of its aqueous chemistry and reactive processing fundamentals, it can indeed provide a highly fertile ground for innovation outside the "box". In this context therefore we will present highlights from our recent research that is directed towards the development of new generation HCl recycling, environmental, and solar energy conversion/storage technologies. In all systems the research is approached via the innovative integration of aqueous process engineering and material chemistry principles. The presentation will include discussion of (i) the development of crystallization-based HCl regeneration technologies; (ii) the supersaturation-controlled production and encapsulation of scorodite that was recently commercialized; (iii) the aqueous synthesis of nano-TiO2 and its electrophoretic deposition into solar cell electrodes; and (iv) the hydrothermal synthesis of nanostructured lithium titanate and lithium iron phosphate materials to make lithium-ion batteries destined for electric cars.

Jan 1, 2014

By U. Troncoso

Mantoverde is a heap leach-SX-EW operation that was commissioned in December 1995 at a production rate of 42,130 ton of copper per year and 5.4 million ton of ore per year. Copper production has been steadily increased to reach 62,000 ton in 2005. The forecast copper production for 2006 is 60,300 ton for an ore treatment rate of 9.5 million ton. A first dump leach operation was started in 1999 at a production rate of 1,922 ton of copper. A second dump leach operation was started in early 2002 at a production rate of 2,805 ton of copper. Dump leach production will be increased over time to as much as 24,000 ton of copper. Several improvements in the heap leach process have been implemented to cope with the higher ore throughput and copper production. However, the solvent extraction plant has remained unchanged which has resulted in a lower availability of raffinate solution and, as a consequence, in longer leach cycles. Different studies have been undertaken in order to optimize the solution management system at Mantoverde, including column test work aimed to reduce the leach cycle and solvent extraction plant modifications aimed to increase the raffinate solution availability. The test work program and the economical evaluations carried out, as well as the conclusions and recommendations obtained, are discussed in this paper.

Jan 1, 2007

By A. McLean, J. Hou

Waste slag is a major environmental concern within the metallurgical industry. In the steel industry, about 100 kg of slag is produced in making one tonne of liquid steel from iron in addition to that produced during ironmaking. The amount of slag from the steelmaking converter can be significantly reduced when charging hot metal with low phosphorus and sulphur contents. In this context, hot metal pretreatment is known as an effective means of preparing high quality charge material for the converter thus limiting the generation of residual slag during the steelmaking process. In the aluminum industry, about 2-4 tonnes of slag, including red mud from alumina production and dross from aluminum electrolysis and casting, are generated during the production of one tonne of aluminum. In recent years, reuse of waste slag from the aluminum industry is a topic that is receiving increasing attention. In this paper, the possibilities of using waste slag and by-products from the aluminum industry as a refining flux in the steel industry are discussed. Several successful processes to convert waste materials from the aluminum industry to steel refining fluxes are described. Some theoretical aspects of using calcium aluminate based flux for desulphurization are outlined together with results obtained from laboratory experiments on sulphur removal from hot metal. By intelligent use of waste materials, the disposal of solid waste from the metallurgical industries can be reduced.

Jan 1, 2004

By Y. H. Hatzor

"This is an extended abstract for a keynote lecture delivered by the author during the 2015 ISRM congress in Montreal on the application of the numerical discontinuous deformation analysis (DDA) method in rock mechanics practice. Due to the large scope of the topic this lecture will focus on studies performed by the rock mechanics group at Ben-Gurion University, alone or in collaboration which other research groups, and is not intended to provide a comprehensive review of everything that has been done on the subject worldwide during the past two decades. A forthcoming textbook (Hatzor et al., in preparation) will attempt to provide such comprehensive coverage.DDA has been developed by Dr. Gen-hua Shi while he was doing his PhD studies under the supervision of Professor R. E. Goodman at U. C. Berkeley (Shi, 1988). Dr. Shi has invented a new numerical discrete element method which provides a solution for dynamic deformation of block systems, hence its applicability to rock mechanics practice. The method is similar in essence to the finite element method in its implicit formulation of the time integration scheme and where in every time step the minimum potential energy of the entire system is sought, but here every element is a finite block with six degrees of freedom. The blocks are assumed to be stiff (simply deformable) so that most of the energy is consumed by slip along pre-existing discontinuities, the frictional resistance of which is assumed to obey the Coulomb-Mohr failure criterion for rock joints. The greatest advantage of DDA over alternative numerical discrete element methods is its robust area (volume) integration which ensures great accuracy even when the blocks are of irregular shapes, including non-convex blocks which may contain holes. The greatest disadvantage is the necessity to solve in every time step very large matrices of unknowns, imposing great CPU demand when the block system involves a large number of blocks. Another disadvantage is the sensitivity of the solution to the choice of the penalty parameter which is implemented in DDA in the form of stiff springs that are attached to contacts once detected automatically.The inherently dynamic formulation of the DDA method lends itself to solution of dynamic problems in rock mechanics. Dynamic analysis with DDA can be performed in different ways corresponding to different rock mechanics problems and loading conditions. Three main classes of loading conditions which are relevant to rock mechanics applications are discussed here: 1) dynamic loading of a single bock which rests on a stationary foundation, 2) response of a block to dynamic loading of the foundations, 3) wave propagation through a block system.The most common approach is to introduce the dynamic force to a specific block in an otherwise fixed block system and check the resulting deformation, typically the time dependent displacement or rotation of the loaded block. This approach is particularly useful for dynamic rock slope stability studies when a stability of a specific rock block against earthquake vibrations is in question. The first 2D-DDA benchmark test of this approach was performed by Hatzor and Feintuch (2001) who introduced harmonic acceleration functions into a block which rests on an inclined plane. The analytical solution proposed for this problem by Hatzor and Feintuch (2001) was later generalized by Kamai and Hatzor (2008). The first 3D-DDA benchmarking for this approach was presented by Bakun-Mazor et al. (2012) who studied single and double face sliding of blocks which rest on stationary foundations and subjected to harmonic input acceleration functions."

Jan 1, 2015

By Michel Dagbert, Mohammed Harfi

"Abstract - The Draa Sfar polymetallic deposit, at about 16 km NW of Marrakech in Morocco, is a massive sulfide zone at the contact between an underlying volcanic and an overlying clastics sequence. The mineralized body is a flat lens with schistosity and "boudinage," tilted to the west and with a strong dip to the east. The lens extends over a strike length of about 2 km and from surface to a depth of about 1 km, with thickness varying from 1 m to almost 30 m. It has been intersected by about one hundred surface drill holes and, in its south part, by about thirty underground fan holes from two exploration levels at depths of 300 m and 400 m. On these two levels, the massive sulfide zone has been channel sampled over a cumulative length of about 0.7 km. Results from drill and channel samples are used to estimate the resources of the orebody according to several methods: sections, polygons around intercepts on a longitudinal plan, grids on the same longitudinal plan with various distance weighting methods including kriging and, finally, a 3D grid with the same range of interpolators. A comparison of the various estimates delineates the important factors in deriving resources for this type of deposit. Those factors are mostly geological and related to the interpretation of the geometry of the two limiting surfaces of the zone. For the 3D gridding, the authors have devised a new and original method that constrains the interpolation of blocks from samples to a geometry of limiting surfaces. The resulting model shows internal grade variations that parallel fluctuations of zone thickness and orientation without having to re-orientate the search window in each block. Résumé - Le gisement polymétallique de Draa Sfar, situé à environ 16 km au NW de Marrakech est un horizon de sulfure massif au contact d’une formation volcano-sédimentaire de base et d’une formation détritique sur-jacente. Le corps minéralisé se présente sous forme d’une méga-lentille aplatie, schistosée, boudinée et déversée vers l’ouest avec un fort pendage vers l’est s’étendant sur une longueur de 2 km et une profondeur de près de 1 km avec une épaisseur variant de moins d’un mètre à près de 30 m. Il a été reconnu par plus d’une centaine de sondages de surface et, dans sa partie sud, par une trentaine de trous souterrains en éventail à partir de deux niveaux à des profondeurs respectives de 300 m et 400 m. Sur ces mêmes niveaux, des traçages ont permis de rainurer le minerai sur une longueur cumulée de 0.7 km. Les données de sondage et de rainurage ont servi à estimer les ressources du gisement selon plusieurs méthodes : sections, polygones sur longitudinale, grille sur longitudinale avec différentes pondérations en fonction des distances incluant le krigeage et enfin grille tridimensionnelle avec le même éventail de pondérateurs. La comparaison des estimés obtenus permet de mettre en évidence les facteurs importants dans l’estimation des ressources de ce type de gisement. Ces facteurs sont essentiellement géologiques et relatifs à l’interprétation de la géométrie des limites des corps minéralisés. Pour l’estimation sur grille tridimensionnelle, on a mis au point une technique originale qui calque l’interpolation des blocs à partir des échantillons sur cette géométrie des surfaces de contact. Le modèle résultant montre des variations internes de teneurs qui épousent les fluctuations d’épaisseur et d’orientation de la zone sans qu’il soit nécessaire de ré-orienter les fenêtres de recherche dans chaque bloc."

Jan 1, 2002

By A. MacKinnon, P. W. Kingston, W. F. Caley

"Wollastonite (CaSiO3]) is experiencing increased usage in a variety of applications, such as fillers in paints, plastics and resins, as an extender to replace both non-fibrous and fibrous materials (e.g. asbestos), and in the glass and ceramics industries. Significant new deposits of wollastonite have been discovered in Marmora Township, about 175 km northeast of Toronto. The geological setting of these large-tonnage. High grade deposits has recently been investigated to assess the possibility of their development. A preliminary study of the chemistry, as well as the mineralogy of six occurrences is presented. Based upon this information, it is suggested that several of the deposits have an excellent development potential.INTRODUCTIONWollastonite is an anhydrous calcium metasilicate (CaSiO3), with a theoretical composition of 48.3% CaO and 51.7% SiO2; the calcium may be partially replaced by iron, manganese, magnesium, and strontium. Commonly associated minerals include diopside, tremolite, idocrase, grossularite andradite, quartz, and calcite. Wollastonite forms as a contact metamorphic mineral within impure limestone near intrusive bodies of granite, or other acidic rocks, as the result of metasomatism of calcareous sedimentary rocks, or by the crystallization of certain magmas (e.g. carbonautes). Generally, the reaction of calcite with silica to produce wollastonite occurs when siliceous hydrothermal fluids from a granitic intrusion or primary silica in the limestone/marble react with calcite in limestone at temperatures between 450°C and 600°C."

Jan 1, 1989

By S. W. Brooksbank, R. A. Benkis

"IntroductionThe Republic of Indonesia is a developing Southeast Asian country that unites the Indian and Pacific oceans, and spreads across nearly 14000 islands with a total land area of about two million km-. The distance across the country approximates the distance across Canada: Indonesia extends for more than 6000 km from the northern tip of Sumatra to the eastern border of Irian Jaya in the middle of New Guinea. With a population of around 180million, Indonesia is one of the world's most populous countries. A mix of 366 ethnic groups populates the country and there are some 250 distinct languages spoken. The topography of Indonesia generally is quite rugged because of its numerous volcanos. For example, the island of Java has 121 volcanos, of which 15 rise above 3000 m and another 44 reach heights between 2000 m and 3000 m.Indonesia has a diversified resource base, with plentiful energy resources (coal, oil, gas and hydroelectric), significant mineral deposits, large timber potential and a developed system of agricultural commodity production and export. A high proportion of the primary resources are on the sparsely populated islands of Sumatra and Kalimantan, whereas 7'3 of Indonesia's people reside on Java, or on 70/0 of the country's land area. Around Jakarta in western Java the population density is around 8000 per krn2. This contrasts with less than nine people per km- on Sulawesi (Fig. I)."

Jan 1, 1992

By M. C. Villeneuve, P. A. Siratovich

We present an integrated analysis of laboratory-based thermally induced fracturing and results of numerical models to give insight to the role of thermal shock fracture on geothermal reservoir rocks. Thermal stimulation is a reservoir permeability enhancement technique applied to commercial geothermal reservoir rocks to enhance fluid injection capabilities for spent power plant working fluids. The process is well known to enhance permeability but the thermodynamic and physical constraints of the process are less certain. In an attempt to constrain the interaction and the ideal conditions that lead to permeability enhancement, experimental procedures were carried out to mimic the conditions that a reservoir rock would experience during a thermal stimulation using temperature differentials ranging from 50-300°C. Samples underwent such thermal gradients under controlled laboratory conditions and were characterized for the changes to permeability, porosity, ultrasonic velocities, dynamic elastic moduli and petrological changes. The thermal stimulation was simulated in a FLAC2D thermal numerical model to investigate the nature of the thermally induced changes in the sample. The development of this model also allows us to investigate the relationship between geological characteristics and the ability to thermally stimulate any type of rock. The results indicate that numerical thermal shocking experiments are corroborated by laboratory-based results. The implication of this study is that the refined numerical models present an insight to the conditions and constraints under which thermal stimulation can prove to enhance permeability that could not be gained through purely laboratory-based studies.

Jan 1, 2015

By James Stenhouse

Abstract The aqueous oxidation of pyrite in caustic solutions under oxygen pressure was investigated by measuring that effect of reaction variable on oxygen consumption by the reactions. From the results of this investigation, a model for the process has been proposed. In this model, sulphur diffuses as a positive ion through an oxide layer which forms on the sulphide particles and is then oxidized to sulphate ion. Iron is oxidized by substitutional diffusion of oxygen atoms into the oxide layer. The effect of most reaction variables on the rate of oxygen consumption can be explained with this model. Introduction Recent investigations (1,2,3) have shown that certain sulphide ores can be readily leached by agitating the ore in the form of a pulp under pressure in the presence of oxygen. Since very little was known of the mechanism of this oxidation, a programme of investigation was inaugurated in 1949 in the laboratories of the Department of Mining and Metallurgy of the University of British Columbia. Financial support for the investigation was received from the National Research Council in the form of student grants and bursaries, from the Canadian Liquid Air Company, Limited, and from the Consolidated Mining and Smelting Company of Canada, Limited. The first objective was to devise a technique to study the primary oxidation reactions in aqueous solutions and to apply the technique to a detailed study of the oxidation of pyrite in caustic solutions.

Jan 1, 1952

By B. S. W. Buffam

"The property of Moneta Porcupine Mines, Limited, consists of a group of eight claims in Tisdale township, Ontario. It includes part of the townsite of the town of Timmins, and adjoins the west boundaries of the Hollin_ger Consolidated and Mace properties. The Moneta property was first staked in 1909, about a year after the first discovery of gold in the Porcupine camp. In 1910 the Moneta Company was incorporated and some preliminary exploratory work performed by Nova Scotia Mines of Cobalt. In 1912 English interests advanced $90,000 for diamond drilling and underground work. One drill hole gave high assays, but apparently the records were poorly kept or the cores were interchanged. As a consequence, when underground exploration was undertaken in 1923 it was directed south rather than west and no ore was found . In 1924 about 5,000 feet of diamond drilling was done in the southern part of the property, but without intersecting ore.In 1931 W. E. Segsworth assumed the direction of the property. Diamond drilling commenced on August 18, 1936. The first hole intersected 9.9 feet of ore averaging 1.23 oz. gold a ton. Underground work was started early in 1937. A mill was erected in the autumn and the first gold brick was poured January 29, 1938.The Moneta mill began operation on January 2, 1938, and the following table gives a summary of the production to June 30, 1943, when the mill was closed."

Jan 1, 1954