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By Michel Gamache

This paper describes a system that manages and assigns vehicles in real-time in an underground mine. Each dispatching decision takes into account the traffic on the road segments of the mine network, whether bi-directional or unidirectional, and ensures that each LHD (Load-Haul-Dump Vehicle) arrives in the right orientation at loading and dumping points. Such systems can be used for two main purposes: 1) as a strategic planning tool and 2) as a real-time managing and optimising system for operations. Using a simulator in conjunction with the fleet management system, it is possible to accurately estimate the impact on productivity of decisions such as the development of waiting areas (bays, sidings), or the addition (elimination) of vehicles to the fleet in operation. Moreover, when used in for real-time dispatching, routing and scheduling of vehicles, the system can optimise production with respect to various assignment criteria such as minimising the cycle time or minimising the deviation from an optimal production plan. Dispatching, routing, and scheduling are handled simultaneously, taking into account the mine status, operational constraints, and all available information.

May 1, 2001

By G. E. Joe

"This is a panel discussion on the milling experience with large volume flotation machines in Canada. Over the past ten years, the Canadian milling industry has been characterized by treatment of ever increasing tonnages of lower grade ores. In order to treat these ores efficiently, mineral processors have been employing increasingly larger volume flotation machines. In older established mills, standard flotation cells have been replaced by the larger volume models with very apparent savings in mill floor space as noted in the Opemiska copper mill.We are pleased to hear from four mill operators with extensive experience on large volume flotation machines. They are:1. I. E. Wahn, metallurgist with Falconbridge-Manibridge, who will describe their mill experiences with the Tank cell and the Maxwell cell.2. G. M. Hughes, mill superintendent of Sherritt Gordon-Ruttan, will detail recent experience with the Agitair cell.3. J. R. Maxwell, mill superintendent of Opemiska Copper, will report on their Maxwell cell installation and operation.4. A. H. Winckers, superintendent of Development and Technical Control, Sullivan Mill, will present a paper written by H. J. Chalmers describing Cominco's past experiences with large volume flotation machine installations including Denvers, Wemcos and Maxwells."

Jan 1, 1974

By M. Lundström

The Outotec HydroCopper® process is a novel technology, developed and registered by Outotec Technology Oy, for leaching copper from chalcopyrite using cupric chloride solution. The leaching process is operated at atmospheric pressure in a stirred tank reactor, at temperatures near the boiling point of water and pH values between 1.5 and 2.5. During the leaching of chalcopyrite in cupric chloride solution, a reaction product layer forms on the mineral surface. In the present work, the formation and the composition of the reaction product layer was studied in an environment similar to that of the HydroCopper® process. The effect of the process parameters on the reaction product layer was investigated. Electrochemical measurements, including A.C. impedance spectroscopy and microscopic observations were carried out and an equivalent circuit was used to determine the surface parameters, such as the reaction product layer capacitance and the charge transfer resistance. The results suggest that, at low pH, a passivating sulfur-rich layer forms, whereas at high pH, a more porous iron-rich layer was detected. The values measured can give useful information for optimising the leaching parameters of the HydroCopper® process. Cu2007

Jan 1, 2007

By B. Zhu, W. E. Lee, N. Li

Al powder is used extensively as an antioxidant in carbon-containing bricks, but it cannot be used directly in water-based carbon-containing castables due to its hydration tendency. To overcome this problem, in this work, SiO2-PVA (polyvinyl alcohol) inorganic-organic hybrid coatings have been prepared via sol-gel processing, and used to coat Al powder. The hydration behaviour of uncoated and coated Al powders has been investigated in water at 60 or 100°C for 36h by examining phase and microstructural changes. While significant hydration is detected in uncoated Al powder, no obvious hydration is detected in coated Al powder, indicating that its hydration resistance has been greatly improved. Oxidation resistance of graphite coexisting with uncoated or coated Al powder was also investigated in air at 1250°C for 1.5h. The oxidation ratio of graphite coexisting with coated Al powder was similar to that of graphite coexisting with uncoated Al powder, indicating that both powders showed similar antioxidising behaviour. This, along with the much improved hydration resistance, makes the coated Al powder a potential antioxidant in carbon-containing castables systems.

Jan 1, 2004

By E. Gervais

"In today's marketplace, heavy competition between materials is the norm. This is particularly true f or the base metals, which are being increasingly challenged by new or improved materials in all traditional applications. Current usage of base metals results from a combination of a metal's intrinsic properties, and technology. The future of the base metal industry rests with innovative, high-quality product development, its ability to take advantage of the results of worldwide, massive material R&D investments, and with the dynamism and effectiveness of its market development programs.The ZA casting alloys program is an illustration of the zinc industry’s efforts to protect and expand its market position in the casting field through state-of -the-art technological developments. The market potential f or these advanced engineering alloys is substantial, and their impact on traditional zinc die casting alloy consumption is particuarly important. The ZA alloys, in offering increased performance through zinc castings produced at low cost and by a wide range of moulding processes, have unlocked a multitude of new end-use applications.Following a review of the development of ZA alloys, of their key properties and of their performance characteristics, the numerous challenges that the alloys present to the zinc industry and to the R&D community are discussed.IntroductionZinc is anodic to steel and has a low, uniform rat e of corrosion; it has a low melting point, can be cast with precision , and is readily finished. In addition to its use in protecting steel and in the production of a wide range of castings, zinc is employed : (1) to produce brass, high-strength aluminum alloys and magnesium die casting alloys, (2) in the wrought state for coinage and in building products, particularly as roofing materials , and (3) as an oxide, in the rubber industry, in ceramics, glass, cosmetics, pharmaceutical products and as the starting materials for many chemicals.Zinc die castings are produced with accuracy at high speed, at low cost, are easily finished and have excel1ent mechnical properties . Car fuel economy, changes in automobile styling, competition from other materials, increased sophistication of design and miniaturization have all led to a dramatic change in the volume of zinc consumed for die-casting applications. This has been particularly notable in the United States. Throughout the 19505 and the I960s, casting was the fastest growing major use of zinc; it was firmly established, accounting for 35% of the total zinc consumption(1), By 1983, the volume of zinc being purchased for casting applications had dropped to less than 20% of all zinc consumed in the United States. In the western world(2), consumption for zinc casting application s is currently at about 15%; being nearly equal to the zinc consumed by the brass industry. Coating applications dominate with a consumption of more than 40% of the total market."

Jan 1, 1987

By D. E. M. Plaumann

"The wet grinding of asbestos has attracted the attention of engineers for many years as a means of improving fibre liberation from the ore. Today, added impetus for wet grinding has resulted from a need to minimize worker exposure to asbestos dust in conventional dry mills using air, as well as a need to provide a cleaner, technically superior fibre for use by product manufacturers. However, high viscosities of asbestos slurries create transport and grinding difficulties which have been a factor impeding use of a wet grinding process.Laboratory evaluation of reagents to reduce viscosities of asbestos slurries found that one reagent, XFS-4272.00, reduced the viscosity of a 35% (by weight) slurry by 75%. The impact of XFS-4272.00 on actual grinding parameters were evaluated using a pilot plant rod mill. Slurries containing 78% solids and XFS-4272.00 were successfully milled and asbestos fibres from that milling compared favourably in liberation and relative surface area to asbestos fibres obtained from milling a 4% slurry without additives. IntroductionAlthough the use of asbestos has been declining over the last few years, the large deposits of chrysotile in eastern Canada (Quebec in particular) remain very important. Asbestos production in Canada stands ninth in volume for mineral production with over 740 000 tonnes produced in 1985. Of this quantity, 722000 tonnes were exported with a value of $446 million. Canada is second in world production of asbestos behind the U.S.S.R. The milling of asbestos ore has been done primarily by a series of steps involving crushing, dry-grinding and aspiration using large quantities of air to release the fibres. Contrast this process to those practiced in the purification of virtually every other mineral. Ores other than asbestos are crushed and milled using an aqueous slurry in rod, ball or pebble mills. The finely ground mineral, still as a slurry, undergoes beneficiation by froth flotation, heavy media separation, hydrocyclones or any of the other aqueous techniques currently employed in mineral processing.One of the driving forces behind the use of air instead of water as a means of separating asbestos is the nature of the aqueous asbestos slurry. While most slurries of minerals contain as much as 80070 solids and can still be pumped and transported, asbestos slurries become highly viscous with as little as 10070 solids. These high viscosities reduce the pumpability of the slurry and create severe handling problems. Mills become prohibitively large and uneconomical due to having to handle slurries containing only 10% rock and 90% water.Health-related issues have affected the use of asbestos in many countries. In Canada, the asbestos-producing provinces have introduced stricter occupational legislation to improve safety in the workplace. This primarily means strict control minimizing release of air-borne asbestos fibres . Quebec and Ontario have set limitations of airborne asbestos at 2 (2) and 1(3) fibre per cubic centimetre of air. With present milling technology, maintaining these low levels in the workplace requires constant vigilance."

Jan 1, 1988

By China University of Mining and Technology, P. Zhang, C. Zhou, C. Duan

"Recovering pyrite from the gangue with high sulfur content is of great significance for both economic development and environment protection in China. Due to the global water shortage and high cost in wet separation processes, it is urgent to explore more efficient energy and water conservation method in mineral processing field. This study has proposed an innovative method based on density difference for fine pyrite enrichment by vibration fluidized bed. In this study, the total sulfur content (TSC) of the gangue sample is 19.18%, and the pyrite is disseminated with fine granularity in the gangue which should be crushed for dissociation. The combination and dissociation experiment of -6mm gangue shows that the dominant density of -6+3mm, -3+1mm and -1+0.5mm comminuted material is +2.9g/cm3. Based on the analysis of characteristic, the effects of various factors on the separation performance were experimental studied. The results show that gas velocity, vibration intensity and bed height all have the significant effects. With the increases of superficial gas velocity, vibration intensity and bed height, the separation performance all presents a decreasing tendency. Additionally, the TSC of -6+3mm, -3+1mm and -1+0.5mm materials are respectively up to 37.94% , 35.43% and 30.61% at the optimum conditions, which are the 1.72?1.90 and 2.29 times as much as the TSC of raw material, respectively. This study demonstrates the vibrated fluidized bed can recovery pyrite from the gangue effectively.INTRODUCTIONWith the increasing mining and separation of coal, the yield of gangue has a further growth tendency, which has become one of the largest reserves of industrial waste (Querol et al., 2008). However, many harmful elements, such as S?NOx and Hg, is existed in the gangue leading the serious damage to the soil and environment (Hao, Yun, Zhanyuan, Sen, & Song, 2013). In addition, the economic would be suffered from the loss resulting in the occupied of arable land caused by the accumulation of gangue (Yeheyis, Shang, & Yanful, 2009; Zhou, Liu, Yan, Fang, & Wang, 2012). Therefore, the government has put forward the policies of ""green mining"" in China (Xing & Gao, 2009; R. Zhang, Ai, Zhou, Ju, & Zhang, 2015; Zheng, Du, Li, Qiu, & Yang, 2015). Among different research areas of coal utilization, extracting the useful minerals has become one of hot topics (Ledin & Pedersen, 1996; P. Patra & Natarajan, 2003; Partha Patra & Natarajan, 2004). At present, many researchers has devoted to the desulfurization of coal all over the world. As result, the sulfur element, which is mainly existed in the presence of pyrite, would transferred in the tailings, namely the gangue. Meanwhile, the pyrite is important raw materials to produce rubber, paper, textile and match. Consequently, recovering the pyrite from the gangue is not only suitable to the requirement of ""green mining"", but it could turn the waste into the treasure having the important significance."

Jan 1, 2016

By W. Cholewa, T. S. Golosinski, J. Wedzicha

"Power requirements of belt conveyor drives are usually estimated based on the calculated belt tension which equals the sum of unit resistances to motion which the belt has to overcome. In most situations, the value of various unit resistances can be accurately predicted using published information (5,6,8,12). A simpler approach calls for use of standard formula and tabulated values of related factors which reflect various features of both the conveyor and the transported material (2,3,7) . None of these approaches is reliable when materials with unique properties are conveyed, nor if applied to conveyors working in extreme climatic conditions. Such is the case of oil sand mines in northern Alberta.There the bitumen content of oil sand causes it to behave in a unique manner. Furthermore the conveyors operate year around, with winter temperatures often lower than - 40°C. It was the objective of presented investigations to quantify the power requirements of conveyors, and related resistance to motion for the conveyors used in oil sand mines during winter operations.The other objective was to quantify the drive power requirements of oil sand conveyors during start-up. These requirements are usually much higher than those during norm al operation, and their quantification is of paramount importance for operation of large conveyors."

Jan 1, 1992

By G. Avramovic-Cingara, H. J. McQueen

The microstructure of commercially pure aluminum was investigated by using polarized optical microscopy (POM), orientation imaging microscopy (OIM), and transmission electron microscopy (TEM) techniques. Specimens were deformed in torsion at 400°C and equivalent strain rate of 0.1 s-1, to various strains of 0.2, 0.5, 1, 4, and 6. The results indicate that POM can usefully reveal grain and subgrain structures over a large field in aluminum. TEM is most suitable to study dislocation substructure and evolution of subgrains. While TEM microscopy and OIM are capable of resolving individual subgrains, OIM can not reliably distinguish subgrains with small misorientations, particularly in samples with low strain. On the other hand, the OIM technique is very useful in the analysis of many regions surrounded by high, medium, and low angle boundaries (HAB, MAB, LAB). Various misorientation maps were studied using different data processing methods. The analysis revealed that the subgrain size is relatively insensitive to strain. The fraction of low LAB ( < 5°) decreased and HAB (>15°) increased conversely with increasing strain, whereas MAB (5-15°) remained stable. The development of an increasingly bimodal grain boundary misorientation distribution is consistent with the predominance of dynamic recovery (DRV) in the evolution of microstructure, combined with geometrical dynamic recrystallization (gDRX), now called grain-refining DRV.

Jan 1, 2006

By A. A. Abdul-Latif, A. Sahin

"The phosphate deposit, located in the Abu Tartur plateau between the Kharga and the Dakhla Oases in the southern part of the Western Desert of Egypt, is the largest of its kind in the country. The phosphates are found in two horizons referred to as the Lower and Upper Phosphate Horizons within the Late Campanian Sibaiya Formation which belongs to the Nubia Group.This paper presents the results of a geostatistical study on the main phosphorite bed at the base of the Lower Phosphate Horizon which contains almost all the commercial reserves in the area. After semivariogram modeling for the phosphate thickness and accumulation, ordinary block kriging was employed to estimate the values of these variables in blocks of400 m by 400 m dimensions. The kriging results, which are presented in the form of contour maps, can be of considerable use in both future exploration and exploitation of the deposit. The grade-tonnage relationship based on the grade estimates derived from the corresponding thickness and accumulation estimates indicates the existence of 453.9 x 105 tonnes of phosphate above a cut-off grade of 18% P2O5. The mean grade of this tonnage has been estimated to be 25.77% P205"

Jan 1, 1990

By Jean-Luc Collins

"This paper shows how simple reliability concepts such as mean time between failures and mean repair time can be used efficiently to help increase equipment availability and so reduce the economic losses associated with unreliability.More specifically, the paper shows how these simple concepts can be used in maintaining an appropriate balance between fleet failure and repair rates and how they can be used for setting up priority repair rules f or queuing equipment.IntroductionA profitable mining operation must handle large quantities of ore and waste at the lowest possible cost. To achieve this objective, the operation must optimize the productivity of its fleets of equipment by efficient management of the time element. Figure I shows some basic equipment activities in an open pit operation while Figure 2 shows a tree diagram describing some time elements of these activities.It should be noted that the only time a piece of equipment can generate a profit is when it can be found in the operating status. In order to maximize this time element, the sum of the other time elements must be minimized because the total time is always fixed.This paper shows the application of simple techniques capable of reducing the waiting time for repair (maintenance delay) by using simple reliability concepts."

Jan 1, 1988

By A. Gourlie

"This paper describes the performance properties of a new 95 ksi minimum yield strength, oil well casing grade designed specifically to resist hydrogen sulphide stress corrosion cracking, SSCc. The new grade, Soo-95SS, demonstrates NACE Tensile threshold values greater than 90% specified minimum yield strength, SMYS, and NACE Bent Beam values in excess of 12.7 x 1()4 psi. The new Soo-9588 grade also exhibits superior collapse and notch toughness values. IntroductionIn recent years, a trend toward casing grade specialization has resulted in the introduction of numerous proprietary grades designed specifically for particular production environments, In response, Algoma Steel has developed, as part of a "" grade for service"" philosophy, two new 95 ksi minimum yield grades. The two grades are Soo-95, High Collapse (HC), and Sour Service (SS). This paper describes the development of Soo-95 Sour Service.Four main objectives were established:1. Definition of the steelmaking and continuous cast processing practices2. Determination of the acceptable maximum and minimum levels for all chemical elements3. Definition of special processing requirements4. Definition of the physical characteristics and ranges of the product properties.This paper provides a description of the experimental approach, followed by a presentation and discussion of the trial results . Finally, a number of conclusions are given."

Jan 1, 1988

By Bo R. Arvidson

"New permanent magnetic alloys have recently opened up possibilities for development of unique mineral separators. These are now making several new applications feasible. In many cases where conventional electromagnetic-induced roll separators have traditionally been used, the new permanent magnetic roll separators may reduce both over-all capital costs and operation costs.The development of the next generation of extremely powerful permanent magnets, i.e. neodymium-iron alloys, is progressing rapidly and will affect the roll separator as well as another type of magnetic separator. Permanent Magnet Roll SeparatorDesign and FeaturesDiscs of permanent magnets interleaved with soft iron discs constitute the basic magnetic roll design (Fig. I). By enveloping the magnetic roll with a thin abrasive resistant belt (Fig. 2), even highly magnetic particles are removed.The first prototype roll utilizing the new magnets was shown to have approximately equal strength as induced magnetic roll (IMR) separators. Since the initial test roll, the new separator, called the PERMROLL® , has been made twice as strong with regard to magnetic force, that is, the magnetic flux density is determined to exceed 1.7 tesla (17 kilogauss), while the magnetic field gradient is more than twice the gradient than can be practically achieved with IMR."

Jan 1, 1985

By Allan J. Guse

The primary limiting factor for hoisting capacity from great depths is the self-weight of the typical steel wire ropes used for mine hoisting. Steel wire ropes possess properties making them very suitable for mine hoisting including high strength and durability, but have the negative characteristic of being relatively heavy in comparison with their strength. Also, as hoisting depths increase, the service life of steel wire ropes decreases due to the higher stresses and physical effects on the ropes. The significantly higher strength-to-weight ratio of synthetic ropes compared with steel ropes offers the primary advantage of hoisting a larger payload with a similar size rope and hoisting plant. The beneficial properties of synthetic ropes could be used to improve the overall economics of deep underground mining both for new deep shaft projects and for existing mining operations expanding to deeper orebodies. A research and development program has been initiated to evaluate the suitability of a fully synthetic rope for the mine hoisting application, including rope discard methodology and NDT testing. The three phases/projects are: 1) proof of concept with focus on coilability under load (successfully completed in 2012); 2) high speed and load durability optimization & NDT Development; and 3) in-situ mine trial.

May 1, 2013

By C. A. Petch

Abstract - The High Lake polymetallic deposit is located in the northern Slave province, 40 km south of Coronation Gulf, Nunavut. The main zone, the AB zone, hosts an estimated resource of 3.56 Mt grading 5.0% copper, 1.1% zinc, 0.06% lead, 1.7 g/t gold, and 18.2 g/t silver. Archean felsic metavolcanic and metavolcaniclastic rocks are the dominant rock type and are associated with lesser mafic metavolcanic and carbonate-rich metasedimentary rocks. The sequence strikes north-northeast, dips steeply to the west, and is truncated to the west by a large granodioritic intrusion. The mineralization at the AB zone is comprised of massive and stringer chalcopyrite-sphalerite-pyrrhotitepyrite± galena. At the core of the mineralized zone, intensely chlorite-altered rocks are locally metamorphosed to form distinctive zones of anthophyllite-magnetite-cordierite-altered rock. Peripheral to the mineralized core, alteration consists of sericitization, silicification, and weaker chloritization. Primary morphology and facing direction of the zone are difficult to interpret in part due to poor primary metal zonation of the deposit. However, the irregular shape of the mineralized zone and the erratic zones of zinc enrichment at the fringes are consistent with the interpretation that the zone was formed by the replacement of a porous volcaniclastic pile.

Jan 1, 2004

By Chris J. Pritchard

Pumpable, two-component resins for anchoring rock bolts provides significant advantages over traditional cartridge resin and cement grout systems where fast and easily adaptable support is required for difficult ground conditions. Cartridge resin anchoring with rock bolts is often ineffective in oversized, fractured and washed-out holes. Cement grouting of cable bolts is frequently plagued with QA and QC issues related to the grouting process. Installation of cable bolts with resin injection techniques is routinely completed in cycle allowing blasting immediately after cable bolting. Xstrata Nickel has evaluated the Minova Resin Injection System since 2007. The Nickel Rim Mine and partner Minova have tested and validated the Resin Injection process for bolting procedures including Hollow Fiberglass Bolts, Rebar, Modified Cone Bolts and Cable Bolts. The resin injection process is adaptable to most bolting processes and equipment. Currently, Nickel Rim Mine use 2 resin injection products with different set times to grout deep cable bolts and development support in highly variable ground conditions. The product predictability and adaptability in application along with a high crew acceptance continues to make this support process part of an adaptable ground support system. Product consistency and quality significantly reduce the quality control concerns for ground support in highly variable ground conditions.

May 1, 2011

By R. Pot

"IntroductionTHE PURPOSE of this paper is to discuss briefly the main logging and testing devices presently at our disposal, to point out some of their limitations, and to suggest possible improvements of the techniques.Some of the more important devices .are those that are used in:(1) Coring(2) Formation testing(3) Electric well logging(4) Radioactive well logging(5) Measuring of bottom hole pressures(6) Sampling of reservoir fluidsThe first four of these procedures are concerned with the well while it is in the process of drilling. The last two are carried out as soon as possible after a well has been brought into production and .at intervals during its life. My remarks will be concerned mostly with certain aspects of formation testing. The reservoir engineer is dependent on the information derived from these operations in order to obtain a clear picture of the conditions in a reservoir and to enable him to assess and forecast its future behaviour.Since any calculation is no better than the data on which it is based, not enough emphasis can be placed on the necessity for the testing and logging equipment to be of the highest quality and for the analysis of the results obtained to be thorough."

Jan 1, 1952

By Stanley Davidson

"This description of the structural geology of the Beattie mine has been condensed from a more comprehensive paper published previously (4).The property is in western Quebec, a short distance east of the Ontario boundary on the extension of the so-called Porcupine belt into Quebec.According to the geological surveys of the Dominion and Provincial Governments the regional structure in the vicinity of the mine is an easterly pitching, overturned syncline with several thousand feet of Timiskaming sediments in the centre surrounded by Keewatin volcanics (1, 2, 3).The mine lies on the north limb of the syncline, and the Keewatin series in this locality is, with few exceptions, overturned, dipping steeply north and facing south.The mineralization is closely related in space, and possibly genetically, to a body of syenite porphyry intruded into the Keewatin series along the north limb of the syncline. No ore has been found very far from the syenite or related lath-porphyry dykes, and the largest orebodies are composite, consisting of bleached and brecciated volcanics ( primarily tuffs) adjacent to altered syenite porphyry, both silicified and mineralized with very fine pyrite and arsenopyrite. In addition there are important ore shoots following a fracture zone within the syenite."

Jan 1, 1954

By H. C. Cooke

"This paper has reference in a general way to the region extending from the north shore of lake Buron to the northern limit of the elliptical-shaped area generally known as the Sudbury Basin, and more especially to the district lying south of the Basin (Fig. 3). Attention is concentrated mainly on the structure of the district and, as space does not permit of much geological description, it is assumed that the reader has some knowledge of the general geology. The accompanying table outlines the sequence of the rock formations according to the most recent available information; for further details the interested reader may consult the publications of the various authors mentioned in the paper.STRUCTURE OF THE SEDIMENTARY ROCKS SOUTH OF THE SUDBURY IRRUPTIVEThe rocks south of the Sudbury irruptive, excluding certain intrusives, are, in order from north to south:(1) A band of basic lavas.(2) A band of well-bedded greywackes and quartzites, long termed the McKim greywacke.(3) The Copper Cliff formation, with McKim greywacke' both to the north and south.(4) The Ramsay Lake conglomerate.(5) A thick quartzite formation.All these rocks strike approximately east-northeast, dip steeply south, and generally face south, though there are local exceptions."

Jan 1, 1954

By Yasuo Iizuka

We have had studied CO oxidation on unsupported Au powder (mean particle size, ca.100nm) manufactured by evaporating ultra high purity gold metal (>99.99%) in inert gas and reported that it showed some activity after oxidizing pretreatment in O2 at 423 K?453 K. However, recent XPS analysis of the Au powder revealed that it contains much amount of impurity metals such as Ag and In at levels which far exceed those expected from the impurity level of raw gold metal in the bulk. Several samples of Au powder containing different amount of impurity metals were prepared to examine whether the activity depends upon the existence of surface impurity or not. Activity measurements were performed at 273 K after undergoing the powder under various pretreatment conditions. Although the activity of Au powder varied to some extent according to the pretreatment condition, it is strongly correlated to the surface concentration of Ag. Such dependence was not found for In, indicating that the activity of unsupported Au powder is mainly due to the existence of Ag in the surface layer. The activity attributable to ?particle size effect? was not recognized for Au powder with a mean particle size larger than 80 nm.

Oct 1, 2003