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By M. Tanaka, Y. Sato, H. Narita, S. Alam, T. Ogata

To ensure a stable supply of rare earth elements (REEs), it is highly necessary to establish the corresponding recycling technologies for RE magnets and phosphors in inplant wastes and endoflife products. Solvent extraction using 2ethylhexylphosphonic acid mono2ethylhexyl ester (EHPNA) is often applied in the separation and purification of REEs. In this study, the equilibrium distribution ratios of neodymium and dysprosium between 1 mol/L nitrate solution and the EHPNA in an alkane diluent were measured at 298K. The experimental data were analyzed by correcting the nonideal behavior of the organic phase using the Alstad empirical equation under the assumption that a complex with a molar ratio of 1:6 (REE:extractant monomer) was formed. The model correlated well with the experimental data and the extraction equilibrium constants were obtained. The extractant equilibrium constants obtained by this methodology would be useful in the design of REE recycling processes using solvent extraction.

Jan 1, 2014

By D. S. Conochie

The world is poised for rapid growth in consumption as large, less developed economies acquire greater wealth. It might be expected that there would be a corresponding growth in waste generation, but this might not necessarily be the case. The metallurgical industry has an excellent record of process development which has allowed it to provide a high tonnage supply of low cost, high quality metals. Environmental challenges have been faced and indeed the recycling of scrap iron through the electric arc furnace has made a massive contribution to cleaning up obsolete structures and equipment of past generations. Issues in waste generation and processing still remain, and the expectation for cleaner processing and environmental performance continues to rise. The waste impact of key process developments of the last century and the recent developments in metallurgical waste processing in Canada will be outlined. The potential to use state of the art design tools to produce the next generation of zero waste processes will then be explored.

Jan 1, 2004

By P. Hubert, J. P. Ildefonse, F. Qafssaoui, J. Poirier

Corrosion tests by corrosive alumina-lime slags were carried out on commercial high alumina bricks used in steel ladle linings and model refractories (with different raw materials : bauxite, andalusite, and different microstructures). Using (SEM) scanning electron microscope and (EDS) energy dispersive spectroscopy, microstructures of slag-corroded refractory interfaces were studied in detail. The monomineral and glassy phases, the composition of reaction products and chemical profiles were determined. A thermochemical analysis based on phase equilibrium diagrams has permitted to estimate the proportion and the composition of the high temperature intergranular liquid phase. These data were compared to the experimental microanalysis results. The viscosity of the high temperature liquids were calculated according to Urbain 's model and the relationship between the viscosity and the penetration of liquid phases were discussed. These theorical and experimental results were used to understand the complex phenomena of slag penetration and corrosion of andalusite and bauxite refractories at high temperature and to propose new ways of improvements for the formulation of high alumina refractories.

Jan 1, 2004

By Z. D. Hora

Sedimentary phosphate-bearing rocks are found over a considerable area of so utheastern British Columbia that extends from Fernie east to the Alberta-British Columbia boundary and from the International Boundary northward to the headwatei: s of the Elk River. Phosphatic beds occur at the following four stratigraphic levels: 1. lower part of the Banff-Exshaw sequence of Mississippian age; 2. lshbel Formation of Permian age; 3. base of the Fernie Group of Jurassic age; 4. belemnite bed within the Rock Creek Member of the lower part of the Fernie Group. To date, considerable tonnages of phosphate rock have been proven in the area. However, no commercial production has been initiated because of a relatively low P2O5 grade. Data on assays and thicknesses of the phosphatic beds are in part recalculated from the paper by Telfer (I 933) and in part from assessment reports filed at the British Columbia Ministry of Energy, Mines and Petroleum Resources.

Jan 1, 1984

The uranium ore processed by the McClean Lake Operation is co-mineralized with niccolite, rammelsbergite and gersdorffite (nickel arsenides). During the strong acid leach process, the majority of the reduced arsenic is oxidized and liberated into the lixiviant solution as As+5. Following uranium extraction, the residual raffinate solution, enriched in As+5, reports to the tailings preparation process. In this process, Fe+3 is first added and mixed with raffinate (pH~1) to achieve a Fe+3/Astotal molar ratio of at least 3. This is followed by two stages of neutralization, using slaked lime to achieve a solution pH of 4, and approximately 7.5, respectively. Synchrotron based x-ray absorption techniques (XANES, EXAFS) applied to neutralized raffinate solids and tailings samples collected from the tailings management facility provide evidence that arsenic has been precipitated as a poorly crystalline form of the mineral scorodite (FeAsO4?2H2O).

Aug 1, 2010

By R. A. L. Drew, J. P. Immarigeon, F. Jalilian, M. Jahazi

In the present work TLP bonding of Inconel 617 is investigated. The influence of the main processing parameters i.e. time and thickness of the interlayer were studied with optical and scanning electron microscopy. Boron containing interlayers with two different thicknesses were used and the influence of various holding times from 5 min to 24 hours on the microstructure of the bond region was investigated. The results indicated that, for the testing temperature of 1065°C and holding times above 2 hours with an interlayer of 25.4 microns thick no liquid phase was observed. The same phenomenon occurred only after 6 hours for a 76.2 microns thick interlayer. Precipitate growth started at grain boundaries and continued inside the grains. The composition, size and morphology of the precipitates were studied using electron microprobe analysis. No noticeable changes were observed in the grain size of the base metal with increasing holding times.

Jan 1, 2004

By Q. Dong, S. A. Nightingale

An investigation has been carried out to assess the effects of an applied voltage on the dissolution rate of MgO refractory in a steelmaking like slag. In this study corrosion results obtained from dip tests using a dense direct bonded MgO refractory in a CaO-SiO2-Fe2O3-FeO-MgO slag are presented. These results demonstrate that the application of a voltage across a dense MgO refractory-slag interface can change the rate of refractory dissolution. For the slag composition used and the voltage range tested, it was found that a maximum corrosion rate was obtained at a voltage setting of -0.45V. The results of this investigation have been explained in terms of voltage affects on Marangoni (interfacial tension induced) stirring and its effect on the MgO dissolution reaction that is at least partly controlled by mass transfer in the slag.

Jan 1, 2004

By K. Koyama

As a study to establish a new energy-saving copper recycling process, the copper deposition at a cathode and oxidation of copper(I) at an anode from ammoniacal alkaline solutions containing Cu(I) or Cu(II) were investigated in order to examine the feasibility of electrolysis in this solution.. The current efficiencies were greater than 95% in the current density range of 200 to 1000 A m-2. The current efficiency decreased with the increasing Cu(II) concentration and temperature. In the batch-type electrolysis at the anode, during the initial stage, the current efficiencies were 100%, and the anode potentials ranged from 0 to 0.15V vs. SHE at a current density of 100 A m-2. During the subsequent stage, the current efficiency decreased with time, and the anode potential was around 1.35V vs. SHE where oxygen evolution at the anode surface was observed. As a result, the present electrolytic method can be the core technology in the said copper recycling process.

Jan 1, 2007

By G. Dörsam, M. Spreij, S. J. Van der Wal, A. P. Schmidt

The transfer of hot metal desulphurising from the torpedo cars to the hot metal ladles at the IJmuiden BOS plant no.2 caused a decrease in ladle lining life from 680 to 470 heats. Changing the desulphurising agent CaC2 for CaO during a trial period, for environmental reasons, led to a further decrease in refractory life. Availability of the ladles became critical and the major reasons for the low life were identified. Solving one of them, temperature, quickly resulted in restoration of the original lives. However, re- introduction of the new desulphurising agent on 50% of the heats again resulted in a decrease, this time from 700 to 550 heats. In order to be prepared for the full introduction of the new agent, thorough investigation of worn linings was conducted, revealing the major (chemical) wear mechanisms. With these findings, a new design for the hot metal ladle is proposed.

Jan 1, 2004

By R. W. Thompkins

"PREFACEThis paper will be published in three parts. Part 1, in this issue, will cover the occurrence of uranium, radiation from uranium ores, the uranium series, radioactive theory, radioactive equilibrium and application to the radon series, the working level, the theory of emanation and diffusion, transport by thermal diffusion of radon emanating from porous rocks, and definitions.Part 2, to appear in the October issue, will deal with radiation theory applied to uranium ores, other radon migration factors , fact ors affecting the radon gas release rate, measurement of radon gas emanation rates, the tunnel concept, variation of emanation rate with grade, and estimating radioactivity from grade analysis.The series will conclude with Part 3, in the November issue, which will discuss the techniques for controlling radiation and give some example calculations.1.0. Occurrence of Uranium1.0.1. Uranium is widely distributed in nature. Sedimentary rocks contain less than igneous or metamorphic rock s and as the outer 10 miles of the earth's crust is composed of 95 per cent igneous and 5 per cent sedimentary rock, it has been estimated that about 1.3 x 1014 tons of uranium exist in the earth's crust.1.0.2. It is not surprising, therefore, that radiation has existed naturally in the ear h ever since the beginning of time. It is found in such places as:(1) non-uranium mines;(2) houses not close to or connected to uranium mines;(3) ground-water tables supplying drinking water to large populations.1.0.3. All mines do not necessarily have abnormal radiation in them, but it is possible for many mines to have abnormal levels of radiation. Therefore, all underground mining operations should be tested for radiation."

Jan 1, 1982

By Francis Dakubo, Courtney Young, Avimanyu Das

"Hydrometallurgy of copper ores typically involve acid leaching followed by solvent extraction and electrowinning (SX/EW). EW is the final purification stage in which a voltage is applied across two electrodes causing the copper ions to reduce and deposit on the cathode. Applied voltages are near 2 volts with current densities around 300 amps/m2. In this study, research was undertaken to decrease the energy consumed in the EW process. To do this, various cell designs were constructed and tested in which a membrane was used to separate the cathode and anode compartments with concentrated solution from SX serving as catholyte and raffinate from SX serving as anolyte. Therefore, copper in the concentrated solution would be deposited on the cathode while ferrous in the raffinate would be oxidized to ferric at the anode. Because it is assumed that ferric acid leaching is used, resulting ferric would be recycled to the leaching process. A positive side effect of the envisioned process would be the elimination of oxygen evolution at the anode and thus the prevention of acid-misting. After a cell design was selected, it was used to test a number of variables: flowrate, concentration, temperature, ion-exchange membrane, and applied voltage. Following experiments in which variable ranges were determined, statistical modeling was conducted using STATEASE software. Optimal results indicate the voltage can be decreased to 1.5-1.7 volts with current densities of 300-400 amps/m2. Significant reduction in the energy consumption was accomplished by reducing the applied voltage. Furthermore, current efficiencies and copper production rates was increased by application of the membrane.INTRODUCTIONLeaching of copper ores is achieved using mostly sulfuric acid. The copper pregnant solution is contacted with an organic solvent or resin adsorbent which picks up copper ions as in Equation 1:"

Jan 1, 2016

By Yongfeng Jia, Shaofeng Wang, Danni Zhang

Ferrihydrite is ubiquitous in soils, groundwater and aquatic sediments and is usually classified as "2-line" or "6-line" according to the number of diffuse XRD peaks. It has high surface area and reactivity; therefore, it may serve as a sink for sequestering trace metals, metalloids and organic matters via adsorption and co-precipitation. Although considerable attention was paid to the transformation process of this thermodynamically metastable solid, there are still some controversies on the mechanisms of the formation of goethite or hematite from the ferrihydrite precursor. This work systematically investigated the transformation of 2-line ferrihydrite produced by using different neutralization regent (CaO vs. NaOH) into crystalline products at different pHs (4, 7 and 8), three temperatures (25, 40, 75 °C) and in different media (sulfate vs. nitrate). X-ray diffraction (XRD), Raman, Fourier transform infrared spectroscopy (FTIR) and chemical extraction were employed to characterize the transformed solids as well as the redistribution of Fe between the amorphous and more crystalline phases. The results showed that the transformation product in nitrate media was hematite (major) and goethite (minor), which was independent of pH, temperature or neutralization reagent. In sulfate media, goethite was the dominant solid under slightly acidic conditions (pH 4) with 6-line ferrihydrite as the intermediate product, whereas neutral to slightly alkaline conditions still favor the formation of hematite. Chemical extraction results indicated that there was only ~3 % of amorphous phase detectable after aging at 25 °C for 280 days at slight acidic pH. In contrast,~70 % of the iron remained as an amorphous phase under neutral to slightly alkaline conditions. The results suggested that the pH as well as the reaction media (sulfate ion) plays an important role in the 2-line ferrihydrite transformation process.

Jan 1, 2016

By P. Reyes

The Codelco Chile El Teniente Division Caletones Smelter has an objective to smelt 1,250,000 tonnes per year of copper concentrate. This is a great challenge for the smelter facilities and particularly for the acid plants. The analysis ensuring that there are no obstacles to achieve the production capacity was of great importance. Therefore a series of activities were undertaken as well as studies dedicated to reach the target. This paper presents work focused on a fluid dynamic study, translated in an operation methodology of integrated handling of the smelting and converting gases with the objective to optimize the gas flow and S02 concentration. The optimization should be done employing the current installations, equipment and instrumentation and/or minor modifications. In the first part of the work the condition of the instrumentation involved in the gas handling was checked, improvements determined and the corresponding corrective actions were carried out. The proposed operation method consists of operation of the Cleaning Gas Plant 2 (TC' s gases) and operation of Gas Cleaning Plant 1 (the remaining gas plus the gases from CPS). The implementation of the operation method involves the modification of the valve of the gas into the duct to plant 1 from On to Off to modulate flow. After modification a three days test was carried out. To evaluate the tests, a "Sulphur Capture" indicator was used. During the test the behaviour of the effluent treatment plants was closely examined. No problems or unusual operating conditions were observed. The reduced flow of gas to Gas Cleaning Plant No. 1 permitted the start up of the 2nd test day treating most of the gas received by Gas Cleaning Plant No. 2. The operation was carried out with the limitation not to increase the effluent pond level, which was maintained constant.

Jan 1, 2007

"Line Creek Resources Ltd. produces three million clean tonnes per year of metallurgical and thermal coals for the international market. The mining operation, which is located in the mountains of southeastern British Columbia, produces coal from four pits by conventional truck and shovel methods.The South Pit, which has been in operation since J982, has a benched highwall 490 m in height. Shallow dipping coal seams at the base of the syncline formation will be exposed in the highwall over the next four years of pit life. The first of these seams, which will measure 500 m in final highwall length, was exposed in J994. An auger, powered by a 1250 hp engine capable of cutting 2.2 m diameter holes, was brought on site in J994 and has proven to be a successful means of recovering coal from the J3 m thick seam.This paper covers the background to the selection of an auger mining method to recover highwall reserves together with the geotechnical and methane considerations for this approach.IntroductionLine Creek Resources Ltd., a wholly owned subsidiary of Manalta Coal Ltd., owns and operates the Line Creek mine. The operation which consists of four active pits, a processing plant, and rail loadout is located in the southeastern coal fields of British Columbia. Figure 1 shows the general area.The coal bearing sequence at the mine is preserved on the east and west limbs of a major syncline. Up to twelve mineable coal seams, ranging in thickness from 2 m to 15 m are contained in the formation. Within the pits the seams are stratigraphically consistent and structurally undisturbed, except for small-scale thrust faults that create multiple repeats of the seams."

Jan 1, 1995

By S. M. Bulataovic, D. M. Wyslouzil

"The Martison Lake phosphate-niobium deposit is composed of unconsolidated residuum containing clay and silt-size particles of phosphate, niobium, iron and clay minerals. This paper deals with the laboratory and pilot plant development of the flowsheet and the reagent scheme to treat the Martison Lake ore. The ore, in addition to the complex gangue composition, contained several phosphate minerals including fluorapatite, francolite and florencite. The detailed laboratory and pilot plant evaluation resulted in the development of an effective flowsheet and reagent scheme for the selective flotation of phosphate minerals using a fatty acid circuit, followed by niobium flotation using amine collectors at acid pH. The developed flowsheet included des liming of ore, magnetic separation, and selective P 2 O 5 -Nb 2Os flotation. The main aspects discussed include characterization of the ore, step by step development of flowsheet and evaluation of dfferent modifiers and collectors for P20s and Nb20s flotation.INTRODUCTIONMartison Lake phosphate-niobium ore deposit, located 75 km north of Hearst, Ontario was discovered in the early 70's and has been the subject of extensive technical-economic evaluation in the late 70's and early 80's.The deposit is covered completely by 30 m to 90 m of glacial overburden and is composed entirely of unconso1idated material called residuum, that lies on top of a precambrian age carbonatite intrusive from which the residuum was derived by weathering and natural leaching in situ. The residuum is and irregularly-shaped horizontal lens, 2 km by 3 km in area, and up to 100 m thick, composed mostly of unconsolidated clay and silt-size particles of phosphate, niobium, iron, mica and clay minerals."

Jan 1, 1986

By S. Banisi, A. R. Hasankhoei, Gh. Parsapour, A. R. Ghasemi

At the Gol-E-Gohar mining and industrial Company, a pelletizing plant, which includes two parallel dry closed grinding circuits and a pellet production circuit, produces 600 t/h. Each grinding circuit consists of a burner, a dry ball mill (6 m×13 m) and an air separator. Each ball mill consists of a 2 m-long dryer chamber and an 11 m-long grinding chamber. Iron ore concentrate is fed to the drying chamber to decrease its moisture from 2.5% to below 0.2%. The drying chamber consists of 56 flights in two rows. It was found when the feed moisture content decreased from 1.3 to 3.5%, the throughput decreased by 14% (40 t/h) indicating a low performance of the dryer. In order to improve the efficiency of the drying section, a scale down version of the dryer was constructed in a 1m diameter mill with a transparent end to make image analysis possible. It was found that because of the inappropriate veiling profile in the drying section, most of materials are not subjected to the hot gas tunnel. To overcome this problem, various flights with different geometries were physically tested and also simulated by the KMPCDEM © software. With the aim of arriving at a proper veiling profile which maximizes the particles contact with hot air, a new flight design was obtained and tested. The installation of the rectangular tooth type flights in one of the mills in the plant made the comparison of the old and new designs possible. The evaluation of the designs in a period of three months indicated 15 t/h increase in the throughput in the case of the new flight design.

Jan 1, 2016

By S. D. Tolgyesi

Kidd Creek Background ? Located in Northern Ontario, Canada ? Underground base metal mine ? Operating since 1966 ? Total of 125Mt mined to date (2.43% Cu, 6.60% Zn) ? Current plan at 2.4Mt/Y (6575t/D) Current Practices ? Evaluating stope margins to ensure that value is added ? Scheduling sulphide and Cu stringer ore to limit oxidation in passes ? Scheduling to maintain uniform grades to concentrator ? (SOPs highlight problem stopes on mine plans, and limit blast sizes in those stopes which may contain sulphides prone to oxidation) ? Scheduling high-Pb stopes to avoid spikes to concentrator ? Providing weekly, monthly and long-term forecasts ? Reconciling mine and mill production ? Underground grade and dilution estimates by mine supervision ? Terminate mucking when grade becomes sub-economic ? Laser cavity surveys to provide feedback and improve Designs Cut-off Grades ? Ore value is obtained from copper, zinc and silver ? Ore outlines at 2% copper equivalent used to guide stope planning; sulphide outlines obtained from contacts while copper stringer outlines drawn from block model (kriged) ? Datamine block model and CADD software used to evaluate alternative stope shapes ? Stopes classified as waste, incremental, or full-cost based on margin calculations for each stope ? Incremental ore may be mined if it does not displace fullcost Ore Conclusions ? Grade control remains an important function for optimizing the ore extraction at Kidd ? The scope of the function has changed to a scheduling focus ? A change in grade control practices over time has not led to significant changes in concentrator feed ? The lead and iron sulphide content of the ore display upwards trends and may require more attention in the future ? The key function of field observations has shifted to flagging exceptions and terminate mucking at grade cut-off

May 1, 2003

By Jas. E. Thomson

"The Omega mine is in McVittie township in the Larder Lake area, Ontario. Production at the mine commenced in 1936, and, until the end of 1946, ore milled amounted to 1,558,604 tons, from which 207,074 oz. gold and 28,205 oz. silver, valued at $7,585,470, were recovered. The mine workings extend to a depth of 1,975 feet.GEOLOGYThe geology of the mine has been described in detail by C. P. Jenney (l) and the writer (2). The general geology and structure in the vicinity of the mine is discussed on an earlier page in this volume. The rock formations found in the mine workings are indicated on the accompanying plan and section (Figs. 1and2). They consist of an intermingled, south dipping complex of volcanics, sediments, and secondary talc-chlorite schists and carbonates. The carbonatized rocks, which are often referred to as 'dolomite' in the Larder Lake camp, are siliceous-carbonate replacements in the talc-chlorite schist zones. In places they contain green mica, probably fuchsite, and are cut by a stockwork of quartz veinlets and stringers. A stock of syenitic intrusives lies south of the mine workings.STRUCTUREThe main structural features are indicated in Figs. 1 and 2. The formations and orebodies have a pronounced southerly dip, which flattens with depth. The talc-chlorite schist and 'dolomite' zones are part of the Larder Lake fault or 'break' on which there appears to be very large displacement. Evidence throughout the district would indicate that the south side moved up and, in the case of the Omega mine, the thrust may have been distributed throughout the several intensely sheared zones. This slice faulting could account for the repetition of sediments and volcanics. An alternative possibility would be original interbedding of volcanics and sediments."

Jan 1, 1954

By E. J. Marcotte

"INTRODUCTIONThe Upper Canada Mine is located at Dobie, approximately ten miles east of Kirkland Lake, Ontario.The mill contains Upper Canada's cyanide circuit and Upper Beaver's flotation circuit. The combined capacity is 590 tons per day consisting of 415 t.p.d. of Upper Canada gold ore and 175 t.p.d. of Upper Beaver copper-gold ore.The Upper Beaver ore is trucked five miles to the Upper Canada mine site.Crushing:The crushing circuit consists of primary, secondary and tertiary crushing employing one C .A. C. 15 in. x 24 in. Superior jaw crusher, one 4 ft. x 8 ft. Tyler-Niagara double deck screen, one 3 ft. Symons standard cone crusher and one 3 ft. Symons shorthead cone crusher.The -2 in. product from the jaw crusher is fed to the double deck screen. The+ 5/ 8 in. passes over the top deck to the 3 ft. standard cone crusher; the+ 3/ 16 in. material passes over the lower deck to the shorthead cone crusher. The - 3 / 16 in. material pas sing through the lower deck of screens is the product to the mill.The screens used prior to the installation of rubber screen cloths were: one 4 ft. x 4 ft. section with 3/ 4 in. square openings and one 4 ft. x 4 ft. section with 5/ 8 in. square openings on the top deck; two 4 ft. x 4 ft. sections with openings of 3/16 in. x 4 1/2 in. slot on the lower deck. The fine screens were positioned so that the 4 1/ 2 in. slots were parallel to the flow of feed.The crushing circuit is operated on a three shift per day basis by one operator per shift."

Jan 1, 1968

By D. R. Rice

"The Smoky Valley Common Operation is managed and 50 percent owned by Echo Bay Mine' s Round Mountain Gold Corporation. The other partners with 25 percent each are Homestake Mining Company and Case Pomeroy. The operation in central Nevada includes an open pit, 3-stage open-circuit crushing train and heap leaching on asphalt pads. Presently, about 18,000 tons per day of 0.039 troy ounce gold per ton are transferred to the leach pads, and a similar tonnage of leach residue is transferred to a waste dump. One million tons of ore are being leached at any one time.Gold and silver cyanide are adsorbed from pregnant leach solution on activated coconut shell carbon granules. Pressure stripping desorbs values from loaded carbon to electrowinning solution.Three electrowinning cells are operated in parallel. Each contains six cathodes. Each cathode includes about 40 troy ounces (2.7 pounds) of Number 2 medium coarse steel wool. The wetted area of each cathode is about 24 by 30 inches. Solution flow is 2 to 3 gallons per minute per electrowinning cell. Average current flow is 25 amperes per cathode. The voltage is controlled in the range of 3 to 4 volts to maintain desired amperage.Twice a week two cathodes are pulled from each cell and drained. Each cathode is split into four portions. These are put in a steel pan coated with WD-40 and dried overnight.Each dried cathode portion is put into a paper sack. Each group of four sacks corresponding to a cathode is weighed together. The typical weight ratio of loaded cathode wool to new cathodes is 9 or 10 to 1. To each sack is added 35 troy ounces of silica, 45 troy ounces of anhydrous borax, 35 troy ounces of nitre, and 5 troy ounces of fluorspar. The sacks are taped shut."

Jan 1, 1986