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By K. J. Fair, G. Van Weert, J. E. Schneider

"IntroductionCyanidation is the principal process for extracting gold from ores . Many primary gold ores, however, are partially or totally refractory in the conventional cyanidation process.Considerable success has been achieved with new gold leaching techniques, such as intensive cyanidation, pressure cyanidation, carbon-in-leach cyanidation, etc. These techniques however, do not offer substantial gains in gold extraction from refractory pyrites.The more drastic pretreatment processes such as roasting, chemical oxidation, autoclave oxidation, and bacterial oxidation all utilize oxidation to break down the structures of pyrite and arsenopyrite. This generally renders the gold amenable to cyanidation.Comparative cost studies indicate that the oldest commercial pretreatment method, i.e. high temperature roasting, is currently the least expensive option if the sulphuric acid can be sold. It operates with air at atmospheric pressure and is characterized by fast reaction rates. For an alternative hydrometallurgical con centrate treatment method to be competitive, it too should operate with air at atmospheric pressure and with fast reaction rates. The NITROX process meets these conditions."

Jan 1, 1986

By L Thompson, R C. West, T S. Kho

In 1978, the Outotec direct to blister flash (DBF) smelting process was commercialized with the commissioning of the Glogow 2 smelting facility in Poland. Since then four further DBF facilities have been constructed, two at Olympic Dam, one in Zambia and most recently one at Glogow 1 in Poland. The DBF smelting process differs considerably from conventional smelting process in both chemistry and unit operations, presenting opportunities for flowsheet capital and operating cost savings particularly when the concentrate copper grade is high. WorleyParsons has amassed considerable expertise in the Direct to Blister process and in this paper the process is compared to the modern two stage Double Flash process. The processes are modeled, and the key operating parameters, consumables and production metrics are directly compared. Subsequent flowsheets, key equipment lists and capital costs are also presented for comparison and discussion. The results show the range of concentrates which are most economically treated by the DBF process relative to those best treated in conventional processes along with those concentrates which could be treated by either process. INTRODUCTION The Outotec Direct to Blister (DBF) process was developed and installed at Glogow in 1978 (Czernecki et al., 2006). Currently there are a total of five DBFs built on three sites: Glogow No.2, Olympic Dam No.1, Olympic Dam No.2, KCM Zambia and Glogow No.1, being the most recently constructed. The DBF process was the first flash furnace process to produce blister copper and paved the way for the subsequent development of the flash converter and other continuous converting processes. Today four flash converters are in operation taking the total number of flash furnaces producing blister copper to eight. In all DBF operations it is the unique ore and concentrate composition which made selection of the DBF process the most attractive. In all cases, the concentrate is relatively high in copper but low in iron because chalcopyrite is not the major constituent. When considering smelting options for high copper, low iron concentrates a key question is then often asked, “At what point does it become economic to switch from two stage smelting and converting process to the DBF process?”

Jan 1, 2019

By John C. McKay

"The five papers which follow, under the heading of ""Technology Transfer-Universities to Industry"", were originally presented at the 20th Annual CIM Conference of Metallurgists in Hamilton, Ontario. They are a unique group of papers, unique because each paper is concerned with applied research done wholly or partly in a university environment and then translated into industrial practice.Universities can rightly be regarded as one of our nation's greatest resources-a veritable storehouse of knowledge and expertise. Yet, too often, this resource is overlooked or, at best, sparingly used by Canadian industry. Of course, university-based research cannot supplant industry-based research, nor vice versa; each type of research activity has its proper role in the over-all process of technology development.University-based scientists are best equipped to conceptualize, innovate, determine viability of basic premises and to verify these at the bench or small pilot-plant level. Industry based scientists are best equipped to develop ""bench-scale"" innovations into mature manufacturing practices. Thus, university-based scientists and industry-based scientists do not compete with, but rather complement, each other. Active, relevant university research enhances industrial research provided good communication between the two ""solitudes"" is continually nurtured.Good communication between industry and university is a prime objective of CSIRA/ACRIS (Canadian Steel Industry Research Association /Association Canadienne pour la Recherches dans d'Industrie Siderurgique), The directors of CSIRA/ACRIS foster improved communication by making regular visits to universities, by sponsoring projects and by providing lists to professors of uncharted areas where basic research is needed. More can be done to improve communication between industry and university, and it is the intent of the Association to do more.The five papers sponsored by CSIRA/ACRIS are examples of good communication and healthy cooperation. It is interesting to note when reading these papers that the cooperation arose, in each instance, as a result of different circumstances. However, there is a common thread and it is personal acquaintanceship-the university scientist/professor and the industry investigator/manager knew each other prior to the initiation of the project."

Jan 1, 1982

By David J. Forrester

"CANMET’s research into underground coal mining is primarily conducted at the Cape Breton Coal Research Laboratory (CBCRL), established in 1981 to conduct safety research in underground coal mines. Located close to Canada’s largest underground coal producer, in the Sydney Coalfield of Nova Scotia, CBCRL’s program also includes the two western underground coal operations. CBCRL is a relatively small laboratory with a staff of thirteen — eight professionals and five support staff — with an annual budget of over $1 million. In order to maintain effective research response, flexibility is key and staff are increasingly working in project teams, crossing traditional section ties and also drawing from specialist expertise elsewhere within CANMET.CBCRL’s research activities have had a substantial impact on the Canadian underground coal mining industry, particularly in Cape Breton. CBCRL contributed to Cape Breton Development Corporation’s (CBDC’s) threefold reduction in lost-time accidents in the 1980s. Also, in the last four years alone, CBCRL’s work has enabled CBDC to save over $17 million in improved utilisation of reserves and cost savings. The work embraces the three traditional areas of mine environment, strata mechanics and mining technologies, however the current direction has been strongly influenced by recent external and internal factors. It is timely to review progress and recent directions."

Jan 1, 1996

By J. Oyunaa, P. Munkhbaatar, A. Sarnai

"The molybdenum mining process used at Mongolia Erdenet Company is a selective flotation of molybdenite from the copper porphyry ores in which the extraction of molybdenum comes as a byproduct of the ongoing copper production.The mineralogical composition of molybdenum concentrate is 99.4% molybdenite (MoS2), 0.09% molybdenum oxide (MoO3), 0.52% powellite (CaMoO4) and wulfenite (PbMoO4) and content 47.76– 47.92% molybdenum, 1.5–2.67% copper, 0.04% renium.From compared solvents sodium and carbonate and ammonia are like extracted molybdenum than hydrochloric acid, which contained 96.23–97.72 p.c. of its total amount. Hence to take into consideration abundance, cheap and suitable for analysis and processing the molybdenum concentrate ammonia is choosing as a basic solvent. By direct evaporation of ammonia extract solution, we obtained ammonium ortomolybdate, which contains 73.47% MoO3. INTRODUCTIONMolybdenum occurs in the earth’s crust in an abundance of about 10–14%, mainly as molybdenite, MoS2. Small quantities are also associated with other metals having similar chemical properties. Thus wulfenite (PbMoO4) is found in oxidized parts of sulfidic lead deposits in many regions of the world; powellite [Ca(Mo,W)O4] is a calcium molybdate usually formed from the modification of molybdenite in deposits containing tungsten as scheelite (CaWO4) and tungsten substitutes for molybdenum up to about 10%. Ferrimolybdite (Fe2Mo3O12·8H2O) is the product of oxidation of molybdenite in the presence of iron (III) compounds. Molybdenite is the primary source of molybdenum. Should demand for molybdenum rise so that additional sources become necessary, wulfenite, powellite, and ferrimolybdite may become commercially significant. Molybdenum ore is mined by underground and open-pit methods. A typical primary molybdenum ore body contains 0.05–0.25% Mo, and secondary ore bodies (copper porphyry ores) average 0.3–1.6% Cu and 0.01–0.05% Mo. Flotation remains the preferred and almost exclusive method of upgrading the molybdenite mineral to an industrial-grade molybdenite concentrate containing 90–95% MoS2, the balance being gangue (Habashi, 1997)."

Jan 1, 2016

By J. P. Grau, J. Z. Lu

"Thickeners/clarifiers are widely used in coal preparation plants, potash processing and other mineral processing facilities. Thickeners play a very important role in slurry treatment systems to accomplish solid/liquid separation. The demand for larger plants and the increased thickener handling capacities sometime require thickener diameters as large as 200m. The development and use of high capacity thickeners makes it possible to increase the handling capacity of these thickeners by several to more than 10 times compared to conventional thickeners. Hence, for a given slurry rate, selection of a high capacity thickener will significantly reduce the footprint of the thickener. Much higher handling rate, higher concentration of underflow, clearer overflow and lower capital cost are obvious advantages of high capacity thickeners; however, some process requirements and the concerns of operational cost, especially the flocculant cost of a high capacity thickener operation, keep some engineers selecting conventional thickeners and staying away from the high capacity thickeners. Forty years after the first high capacity thickener was developed, there are still arguments in the selection of conventional thickeners or high capacity thickeners in mineral processing. The arguments will continue unless there is a clear picture of capital cost vs. operational cost for each of the thickener types. The purpose of this paper is to analyze these costs and to provide guidelines for selection of thickeners. INTRODUCTIONThickeners/clarifiers are widely used in various slurry treatment systems. For mining and mineral processing, thickeners are an integral part of the solid/liquid separation system. The feed to the thickeners are processing slurries. The fundamental mechanism for the solids/liquid separation is for the solid particles in the slurry to gravity settle inside the thickener tank. The clear water overflows from the top of the thickener tank and is typically reused in the processing circuit, and the concentrated underflow is discharged to different downstream process systems depending on the application of the thickeners. The general requirements for a thickener operation include high density of underflow and clear overflow. Since thickener operation consists of continuous feeding, overflow and discharge of underflow, the solid particles will gravity settle against an upward flow with its velocity dependent on the feed rate and the underflow discharge rate. Higher feed rates to a given thickener produce higher upward velocities. Underflow discharge is typically relatively small compared to the amount of overflow. The upward flow tends to take particles up to the overflow. Only those particles having a settling velocity greater than the upward flow velocity will possibly settle out. Hence, thickener feed rate has to be controlled so that the required overflow water clarity can be achieved."

Jan 1, 2012

By Ralph W. Edie

"IntroductionTHIS PAPER presents some analyses of diabases from a number of metallogenic provinces in Canada and the United States. It is intended as a contribution to the literature on the genesis of mineral deposits associated with diabase.As it has been in the past, opinion today on the origin of the cobaltnickel- native silver and associated pitchblende type of deposit is sharply divided. Some geologists hold that this type of deposit is in some way genetically related to intrusive diabase; others are of the opinion that the deposits are related to granite. The controversy, like others of a similar nature, probably will not be settled satisfactorily for many years to come, •but in the meantime it is recognized that, with respect to most deposits of the type referred to, altogether too few facts are known for accurate conclusions on genesis to be drawn. To contribute in a small way to factual data on this whole .problem, the writer analyzed diabase from several districts in Canada in which deposits of the aforementioned type occur. For comparative purposes, the copper, cobalt, and nickel content of diabase from Cornwall, Pennsylvania, and of norite from the Sudbury basin of Ontario, was also determined.Insofar as is known, none of the analytical work undertaken had been previously carried out."

Jan 1, 1953

By Toivo Toivanen

The paper begins with a brief history of the nickel industry in Finland, and then deals with the introduction of the flash smelting process. The main part of the paper is devoted to nickel refining, which is studied under four main headings -grinding, leaching, electrolyte precipitation, and nickel electrowinning. Flowsheets are illustrated, and the equipment used is described. Analyses of the material in the various stages, from concentrate to high-grade nickel matte, are also presented. N ICKEL made its appearance in the Finnish mining industry forty years ago, when a nickel deposit was discovered at Petsamo in Lapland. Mond Nickel Co. received the concession for this deposit from the Finnish Government, and the Petsamon Nikkeli Company constructed a mine and a nickel smelter (1), the completion of which was prevented by the 1939 Winter War. The mine and smelter were, however, completed soon afterwards in spite of World War II,

Jan 1, 1964

By Louis Frost

"1N 1951, the Dominion Steel and Coal Corporation, as part of a programme of modernization in their coal mining operations at Sydney Mines and Glace Bay, Nova Scotia, undertook the development of two large cross-measure tunnels, which were to be used for the purpose of raising the coal from the underground workings by conveyor belts direct to wash plants located on the surface.These tunnels were to reach from the surface to central loading points underground located at a depth of 600 and 900 feet, respectively. They were to be driven on a pitching gradient of 11 degrees to the horizontal, and they were to reach a length of 3,600 feet in the Sydney Mines area and 10,000 feet in the Glace Bay area.The longer tunnel, 19 feet in diameter, was driven a distance of 1,500 feet and, for domestic reasons, bas not yet been •completed. The other tunnel, in the Sydney Mines area, 18 feet in diameter, is steel supported and concreted throughout its entire length. This tunnel has been completed and will be in operation at an early date.The development of this particutar tunnel posed an additional problem, as the rock through which it had to pass was considered to be water-bearing. In the sinking of Princess Colliery shafts in 1866, a great deal of water had been encountered, and it had been necessary, while sinking, to line the shaft with cast-iron tubbing through the water-bearing strata. The shaft had to be lined for a depth of 300 feet at the upper end. It was anticipated that we would meet with difficulty in driving the tunnel through this strata."

Jan 1, 1955

By Timo Heikkinen

We have read, with great interest, Mr. Crocker's article on "Recent Trends in Autogenous Grinding," published in the October issue of The Canadian Mining and Metallurgical Bulletin. Referring to our paper, "Two-Stage Autogenous Grinding Investigations at Outokumpu," we can now report that last August we changed to this method at the Keretti concentrator. Prior to the conversion, the Keretti plant (see flow-sheet, Figure 1) had two primary rod mills, 6 ft. in diameter and 12ft. in length, in open circuit, followed by four secondary 9-by 12-ft. pebble grate mills in closed circuit with rake classifiers. Last summer, wl1en the Since August, grinding has been successfully carried out autogenously in two stages, with two mills being employed in the primary stage and four in the secondary. The size of the pebbles in the secondary mills is about the same as earlier -l V: i to 3 inches (Figures 4 and 5). Also, we generally prefer two-stage grinding to single-stage grinding because, in the former,

Jan 1, 1964

By Xiaozhu Chen, Qi Ping, Pu Yuan, Qinyong Ma

"In order to investigate the fractal feature of coalmine deep rock fragments under impact loads, variable cross-section split Hopkinson pressure bar apparatus, 50 mm in diameter, was adopted to conduct impact compressive test for rock specimens from -962m deep coalmine. Various impact pressures, such as 0.3, 0.6, 0.9 and 1.2MPa, were selected to implement different loading rates. Sieving statistical analyses were conducted for rock fragments after being impacted, and the particle size distribution of broken rock in various loading rates were calculated with the fractal method and then the corresponding fractal dimension was obtained. Test results shows that there is a good self-similarity and fractal feature in fragments distribution of deep coalmine sandstone under impact loads. The fractal dimension of fragments is between 1.9 and 2.7. The research also indicates that there is an approximate power relationship between dynamic compressive strength and fractal dimension, and a strength power relationship between fractal dimension and average strain rate. Moreover, there is a linear relationship between fractal dimension and specimen absorbed energy. The rock fractured process can be quantitatively described through fractal dimension, which can reflect the deep rock broken degree and is an ideal index to evaluate the distribution of rock fragments.INTRODUCTIONBroken rock is one of the most basic processes in mining operations, rock fragmentation has always been an important index to evaluate rock breaking effect (Xu & Yu, 1984). Macroscopic fragmentation of rock material is the final results of continuous development, expansion, gathering and cutthrough of internal micro-cracks. This process, developing from microscopic damage to macroscopic fragmentation, is an energy dissipation process and shows fractal characteristics (Xie, 1993). Turcotte (1986) has conducted statistical analyses of fragmentation for different kinds of geological materials under various broken conditions, and arrived at the conclusion that fragmentation distribution is a fractal."

Jan 1, 2015

By D. D. Liu

This paper proposes a charge induction dust measurement method based on detrended fluctuation analysis (DFA) for use in coal mine environments, based upon electrostatic interference, dust properties, wind speed, particle size, moisture content and other factors. In this methods, sequence x(t) is first obtained through a dust concentration sensing probe, and then the cumulative deviation y(t) is calculated, and y(t) is divided into same lengths. Secondly, a first-order linear fit is used for data of each interval, and mean-square deviation filtered DFA was calculated for each interval. Finally, the dust mass concentration of the corresponding time is obtain by supplemented calibration coefficient and fitted the data point which is the mean and square root for all lengths of interval. Simulation and verification experiments showed that the charge induction dust measurement method based on DFA can reduce coal mine electrostatic interference effects with high accuracy. The design has been successfully applied to select areas.

Aug 1, 2013

By G. F. Doggett

In describing accounting methods at Lake Shore Mines, it is the intention of the writer to limit the discussion to the principal features of the system used in securing cost figures and other statistics. The subject can be conveniently treated under the following divisions: (1) Time-keeping and Labour Distribution (2) Supplies: Handling and Distribution (3) Method of Assembling Data for Cost Purposes (4) Details of Operating Costs Time-Keeping and Labour Distribution After a new employee has gone through the routine of being 'hired on', he is assigned an employment number corresponding with the group applying to his occupation. This is for identification purposes in the plant and time office. He is also given an individual serial number, the use of which will be refer-red to later. On entering and leaving the plant, each employee passes through the clock room adjoining the time office, where he registers the time in and out on time recorders, on the clock card (Figure 1) bearing his name and number. It is the duty each morning of the time clerk to extend the hours worked by each employee, as indicated by the clock for the previous day, and at the end of the half-month period the total hours are multiplied by the rate and entered in the space provided for total wages at the bottom of the card.

Jan 1, 1935

By M. B. Mansur, A. S. Guimarães, A. J. M. Santanilla, D. C. R. Espinosa, J. A. S. Tenório, R. A. Pini

The separation of Ni and Co from sulphate medium containing Mn, Mg, Cu and Ca was carried out by solvent extraction. The object of this study was to investigate the synergistic effect using phosphinic acid (Cyanex 272) and carboxylic acid (Versatic 10) and their mixtures in kerosene. The extraction percent of each metal ion was found to increase with increasing pH and extractant concentration. Co was preferentially extracted over Ni under the same extraction conditions. The separation factors of Ni/Co increased with the use of the synergistic systems investigated.

Jan 1, 2014

By P. Ashtari

Influence of Sr and Mn single and combined additions on the modification of the Fe-containing intermetallic compounds and mechanical properties of Fe-rich AA319 aluminum alloys have been investigated, The microstructural features e,g, morphology of the Fe compounds and eutectic Si has been correlated to the mechanical properties, It was demonstrated that modification of the Fe compounds from the platelet ß-Al5FeSi to the Chinese script a-Al8Fe2Si compound improves the UTS and elongation of the alloys by 10.3% and 83.9%, respectively. Moreover, the simultaneous modification of the Fe compounds and eutectic Si increases the UTS and elongation of the alloys by 15,3% and 116,1%, respectively.

Jan 1, 2005

By K. S. Raja, B. McNall, B. Pesic

"High-level radioactive wastes are stored in large underground storage tanks made of low-carbon steel. The wastes consist of concentrated solutions of sodium nitrate (NaNO3) and sodium hydroxide (NaOH), and the radionuclides 137Cs, 99Tc, and 90Sr. The corroding steel microenvironment may produce localized reducing or oxidizing conditions that affect the solubilities of the species such as Tc(VII) and Tc(IV), which in turn modifies the kinetics of corrosion of the storage tank. To understand the influence of technetate ions on the corrosion of steel, electrochemical polarization studies of A 537 steel samples were carried out in 1 M NaNO3 + 0 .05 M S r(NO3)2 + 0.1 M NaOH with and without addition of HReO4 at different temperatures (24 – 85 °C). The concentration of HReO4 was varied from 0.014 – 0.04 M.INTRODUCTIONAqueous processing of spent nuclear materials generates a large amount of high-level radioactive wastes. The wastes are primarily salt solutions of sodium hydroxide and sodium nitrate which also contain fission products such as 137Cs, 99Tc, and 90Sr. Among the high level radioactive fission products, Tc-99 is of great importance because of its high concentration, long half-life (2.1 x 105 years), high solubility in geologic waters as technetate, and rapid diffusivity through the geologic systems. The solubility of technetate ions varies depending on the oxidizing conditions prevailing in the storage containers. High level radioactive wastes are stored in single shell or double shell tanks made of low carbon steels such as ASTM type A15, A516-70 and A537. Most of the available literature on corrosion of steel in simulated radio active waste environments pertains to nitrate induced stress corrosion cracking (Subramanian & Mickalonis, 2005). The corroding steel microenvironment may produce localized reducing or oxidizing conditions that affect the solubilities of the species such as Tc(VII) and Tc(IV). Corrosion of steel and formation of Fe(II) and Fe(III) will affect adsorption and reduction of Tc species. The radioactive species can irreversibly be sorbed on the steel surface by oxidation of Fe(II) to more stable Fe(III) and fixed as less soluble Tc(IV)/Fe(III). The solubility of Tc species is also affected by other factors such as dissolved oxygen, local pH, temperature etc. How the corrosion behavior of steel will be affected in the presence of Tc species is not clearly understood.Cartledge (Cartledge, 1960) demonstrated that passivation of iron can be achieved in the presence of oxygen along with suitable inhibitor ions/molecules of the general formula XO4 n-, such as pertechnetate (TcO4 -). The pertechnetate ion is univalent. Since it is derived from a strong acid, no buffering action can be expected from this ion. The redox potential of the reaction (1) is 0.738 VSHE (Pourbaix, 1974)."

Jan 1, 2012

By Staff

The Tetreault mine, operated by the British Metal Corporation (Canada), Limited, holds a unique position in Canadian mining, being the only steady producer of zinc in Canada east of the Rocky mountains. Its importance in Canadian zinc production may be gauged with some accuracy, since, in 1927, it was responsible for over 13 per cent of the zinc output of the Dominion. In addition, it also made valuable contributions to the production of lead, silver, and gold. Location: Situated in the foothills of the Laurentian mountains, 600 feet above sea level, 20 miles from the St. Lawrence river, and 52 miles due west from the city of Quebec, the property is in the township of Montauban, county Portneuf, Province of Quebec, as shown in Figure I. The municipality of Montauban, immediately adjoining the mine, has a permanent population of 700 people and is six miles by road from Notre Dame station on the main line of the C.N. Rys. between Montreal and Chicoutimi-Notre Dame being n6 miles by rail from Montreal. Connection by 19 miles of dirt-and-gravel road with the Provincial highways' system of Quebec Province, the city of Quebec, which is distant 78 miles, can be reached by automobile in less than three hours, while the distance to Montreal by road is 16o miles .

Jan 1, 1928

By Richard P. Curtin, John M. Goris, Lewis A. Martin

Cable bolt supports are being recognized as an effective ground control system in under-ground coal mines in North America, and their use has increased considerably during the past few years. The U.S. Bureau of Mines personnel are conducting both laboratory and field tests to evaluate the performance of these supports under a variety of conditions and to establish realistic design guidelines. This paper describes efforts to evaluate the capability of cable bolts to resist the high shear forces often present in longwall operations. Shear tests were conducted on pairs of 0.025 m3 (0.88 cu. ft) concrete blocks having joint surfaces ranging from rough to smooth. Tests were conducted on blocks both with and without reinforcement with 15.2 mm (0.6 in.) diameter steel cables. During each shear test, the loads and displacements along the normal and shear axes, as well as loads on the cable, were monitored. Cableloads were determined using strain gauges attached to the outside surfaces of the barrel-and-wedge anchors used for pretensioning the cables. Test results show that a cable bolt placed across a joint more than doubled shear resistance of shear blocks having both smooth and rough joints.

Jan 1, 1996

By M. Abumiya, N. Onodera

Stabilization of arsenic via the precipitation of large-sized scorodite (FeAsO4·2H2O) particles usually involves the use of expensive autoclave systems operated under high temperature and pressure conditions. Alternatively, DOWA developed a novel scorodite synthesis process (DMSP®) wherein the Fe(II) ions in solution containing As(V) ions were oxidized by O2 gas under atmospheric pressure. In this process, crystalline scorodite particles were formed via the formation of a gel-like precursor containing Fe(II). Based on this concept, in this study, we have demonstrated the synthesis of scorodite particles by the addition of Fe(III)-containing solution to the experimental solution containing Fe(II) and As(V) ions, without the O2 gas oxidation process. Ferric sulfate (Fe2(SO4)3) was used as the source of Fe(III) ions. Results indicate the precipitation of scorodite particles, comparable to that of the O2 gas oxidation method.

Jan 1, 2014

By J. Stachulak

In recent years more emphasis has been placed on the control of nitrogen dioxide (NO2) emissions from mining diesel equipment. Worldwide, diesel engine regulations to control emission and protect the environment are also driving the development of the diesel engine technology to reduce oxides of nitrogen NOx (Nitric oxide, NO + NO2). NOx are toxic gases produced in mines during the operation of diesel equipment. Most of the diesel equipment used in underground operations are equipped with Diesel Oxidization Catalysts (DOCs) designed to reduce carbon monoxide (CO) and hydrocarbons (HC). The effects of DOCs on NO2 production from diesel powered equipment is not well understood. DOCs do not alter NOx concentration, but may promote the oxidization of engine exhaust NO to the more toxic NO2, thus increasing the undesirable NO2 exposure of workers in the mine environment. In 2012, the ACGIH reduced the NO2 TLV concentration value from 3 ppm to 0.2 ppm. Vale and CanmetMINING have been involved in several research projects to reduce diesel emissions exposure to workers. One aspect of the current program is to determine the effects of in-use DOCs on NO2 production. Several in-use DOCs taken from mining equipment were selected for testing in the laboratory using ISO 8178-C1 and mine LHD transient test cycles. The paper presents the laboratory test results and effects of DOCs on NO2 production. The results indicate significant reductions in CO concentration, by over 77%, while increases in NO2 varied from 46% to 315% based on the ISO 8178-C1 8-mode steady state test cycle. The mine LHD transient test cycle showed the same pattern, although the magnitude of CO reduction was less. Consequently, it is recommended the use of only those DOCs that have been properly evaluated and shown not to significantly increase NO2 emission in the environment be used on mine equipment.

Aug 1, 2013