Search Documents

By Heyer T, Wasmuth H-D

The concentrator plant of Fahrica Mine, that started production in 1977, was using nine Jones wet high intensity magnetic separators (WHIMS) of the standard type DP 317 with a 1.5 mm gap width for the production of pelletfeed concentrate. These WHIMS units were operating in parallel with a feed rate of 110 t per hour, with about 47 per cent Fe in the feed, and with a maximum of only 0.8 per cent magnetite. The field strength was about 1.2 Tesla. From 1986, the mine has adapted its production facilities to mine and concentrate larger amounts of lowgrade itabintes to maximise the use of the available iron ore reserves. An increase of up to three per cent magnetite in the magnetic separator feed, resulted in a reduction of capacity. This was due to partial clogging of the separation boxes at high field intensities, which were required for the recovery of the very fine hematite. Even by lowering the feed rate and the field intensity the problem could not be resolved. After extensive testwork in a pilot plant, with a Jones separator model DI' 90, the commercial WHIMS plant was modified into a two stage process using the existing nine Jones separators. The gap of the first stage with four machines was increased to a width of 3.5 mm, corresponding to a maximum field intensity of 0.7 Tesla. This first 'medium intensity scalping stage' is followed by a second 'real' high intensity WHIMS step with five machines operating at the original settings with 1.5 mm gap width and 1.0 Testa maximum field intensity. Feed rates of up to 320 tons per hour in the first and up to 240 tons per hour in the second stage could be achieved. The design concept of the concentrator at Fabrica mine is described using the old and new flowsheets. Details of the pilot plant testwork as well as actual performance data of the new plant section are presented.

Jan 1, 1993

By K Li, C Zhang, i, J Oh, S Saydam, H L. Ram

Rock surface roughness plays an important role in excavation engineering projects and applications related to surface support structures, such as shotcrete and thin-sprayed liner (TSL). The morphology of the substrate affects the mechanical behaviour at the interface significantly. Therefore, it is necessary to quantify the roughness to investigate the relationship between roughness and mechanical properties. The joint roughness coefficient (JRC) proposed by Barton and Choubey (1977) is widely used in practice. It initially estimated the roughness by comparing it to 10 standard profiles visually. However, this method has lots of limitations, it is not only subjective but also a two-dimensional parameter with a small lab scale (Beer, 2002). The subsequent research on JRC, from visual comparison with Barton’s standard profiles to measuring the roughness with a profilometer (Weissbach, 1978; Alameda-Hernández et al, 2014). Then, 2D profiles or 3D surfaces by different technologies with higher resolution and accuracy, such as 3D laser or optical scanners (Fardin, 2004; Jiang, 2020, 2021). These 3D scanners are expensive and only suitable for laboratory scales. LiDAR scanners (Lato, 2009; Aubertin, 2022) have been applied in industrial size, but it is difficult to achieve a millimetre-level accuracy, which is mostly used to detect the thickness of shotcrete in practice. Thus, finding a cost-effective surface roughness measurement method with high accuracy is necessary. Photogrammetry is another method to digitalise the roughness of the surface. Similar to 3D scanners, photogrammetry also generates the point cloud of the objective surface and then reconstructs the 3D model of the objects. 3D reconstruction technology is a trendy technology in recent years. The structure from motion (SfM) algorithm (Westoby, 2012) to rebuild the 3D model with a flexible workflow, aligning photos, building dense point cloud, mesh and texture, which has been proved that can rebuild an accurate model in variable fields.

Nov 29, 2022

By Vynne J. F

Drill monitors for rotary blasthole drills have been available to the mining industry since the 1970s. The early monitors were pen strip chart recorders that were developed for the oil drilling industry and adapted to mining. They recorded drilling parameters such as depth, pull-down pressure, torque, RPM, and hailing air pressure. While these recorders could generate a large volume of paper, the amount of useful data was minimal. The data was not summarised and required an engineer to interpret the chart traces. Being a mechanical recorder, the devices were also susceptible to frequent failures. Modem electronics, and the development of the personal computer and its associated software have radically changed the type of instrumentation that is now available for blasthole drills. Perhaps more important is what can be done with the data. The PC allows the logged data to be analysed, summarised, and a variety of reports to be generated. The reports can be customised to meet the specific requirements of the mine and reduce the amount of time that is required to interpret the data. There is also an increased awareness in the mining industry of the importance of production drills. Blasthole drills have typically been the piece of production equipment that received the least amount of attention in a surface mine. Management focussed on the trucks and shovels or draglines. This situation is changing, and therefore the benefits that can be derived from monitoring drill performance are being recognised. Potential economic benefits of installing drill monitors have been documented in previous papers (Peck and Vynne, 1992). Mines are finding that pay-back periods of less than twelve months and rates of return in excess of 30 per cent are not uncommon. These benefits include the following: 1. Reduced overdrilling; 2. Increased rate of penetration; 3. Helping to locate coal seams; 4. Identification of weak and strong zones; 5. Reduce geophysical logging; 6. Optimising blasts; 7. Improved fragmentation and diggability; 8. Decreased coal dilution; 9. Increased bit life; 10. Reduced maintenance costs; 1 I . Improved accuracy of data and reports.

Jan 1, 1995

The five main ways in which coal is used are1. for electricity generation,2. as a lump fuel for domestic and industrial purposes,3. for gas making,4. for making carbon for chemical and metallurgicalindustry, and5. as a source of coal tar and coal-tar chemicals.In the past about 80 per cent of Victoria's brown coal has been used for power generation and the rest for making a lump fuel, in the form of briquettes. Some of these briquettes have been used for gas making, and a carbon industry based on them has recently been commenced, and could expand rapidly. However the enormous increases expected in power requirements, approximately a doubling every 10 years, will ensure that even if the manufacture of carbon increases dramatically and a large amount of coal is used for other purposes, the brown coal industry will always be dominated by power generation. As new fuels such as natural gas, oil, and nuclear fuel become available at competitive prices these will take their share of the power generation load.Natural gas or oil, or possibly pumped storage hydro, will almost certainly be used for all future peak-load stations, comprising around 40 per cent of the total installed generating capacity, but new base load stations will continue to be designed for brown coal operation until about the mid-1980s, by which time nuclear power stations will become competitive. By this time Victoria will have installed about 6000 MW capacity of brown coal stations, burning around 50 million tons/year of coal, compared with 18 million tons/year at present, with perhaps 15 million tons/year being used for other purposes.This consumption of 65 million tons/year should then remain fairly stable over the life of the power stations installed, well into the 21st century. Brown coal therefore appears to have an assured place in providinga major part of Victoria's fuel requirements, despite the diversification in fuel usage pattern which appears certain to occur with the recent developments in new fuel resources.

Jan 1, 1971

By W A. Ducker, R-H Yoon, M Mao

Froth flotation relies on an attractive force between a particle and a bubble to selectively extract particles from a mixture. The range and magnitude of this attractive force is an area of ongoing investigation. We describe measurements of the effect of dissolved gases on the long-range attractive surface forces between a silica plate and a glass sphere in aqueous octadecyltrimethylammonium chloride (C18TACl) solutions. The measurements follow on the work of Sakamoto et al (2002) who have concluded that long-range interactions occur in air-equilibrated surfactant solutions but not in degassed solutions. In the present work, we have measured attractive forces that have a much larger in magnitude than the expected van der Waals force in solutions that were degassed by the same procedure used by Sakamoto et al (2002). We find that the forces are most attractive at 5 + 10-6 M C18TACl, which is close to the charge compensation point (ccp) of the glass sphere. At this concentration, the attractive force decays exponentially with distance and the decay length is 34 in air-saturated solution, and 38 nm in degassed solutions. In both air-equilibrated and degassed solution, the force is quite sensitive to the concentration of surfactant. The force is also sensitive to the pH. We note that our degassing procedure increases the pH of the solution from about 5.7 to 6.6 (presumably by removal of dissolved CO2). We find that the forces measured in degassed solution can be reproduced by using a solution that was equilibrated in air, then the pH was increased by addition of NaOH. Therefore, we conclude that the main effect of degassing in our experiments is to raise the pH. We show that the range and magnitude of the attractive force decreases in the presence of salt (NaCl). This suggests an electrostatic mechanism for the attraction. Possible mechanisms for the attractive force are examined, including the mechanisms that rely on a patchy coverage of surfactant on the silica surface.

Jan 1, 2005

By M Chiquito, R Castedo, P Segarra, L M. López, J A. Sanchidrián, J Navarro

The aim of this work is to assess the performance of different constructive solutions against explosions on the strength of masonry walls. The solutions tested, namely an external metal mesh, a glass fibre film on the external face of the wall and a basalt fibre film located on the inner face of the wall, have low to medium cost and are originally designed for other purposes, like seismic protection. Four cubic boxes 3 × 3 × 3 m were built using each of the solutions and typical masonry blocks. In the tests, a spherical plastic explosive initiated in the centre was placed at scaled distance of 2.9 m/kg1/3, so that moderate damage would be caused on the wall. In order to assess the performance of the explosive, pressure gauges were placed at the wall and at different distances from the explosion. Additionally, vibrations were monitored with seismographs in the far field and a high-speed camera was used to estimate the shock wave velocity during the tests. The resulting damage has been evaluated on 13 points of the external wall of each box using a rebound hammer. Damage maps have been drawn for each wall based on these measurements and damage has been assessed inside the box considering the fragments mass launched during the test. The use of external metal mess leads to a decrease of 34 per cent on damage of the external wall and 38 per cent reduction of spalling. The use of a film in the inner wall provides a strong reduction on spalling.CITATION:López, L M, Segarra, P, Castedo, R, Sanchidrián, J A, Navarro, J, Santos, A P and Chiquito, M, 2015. Performance of different constructive solutions against explosions in full-scale masonry walls, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 819–824 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By Miller JD, Ye Y

The Air-Sparged Hydrocyclone (ASH) has been developed for the fast and efficient flotation of fine mineral particles in a centrifugal field during the past decade at the University of Utah. Over the years, the air-sparged hydrocyclone unit has shown promising potential for the flotation of copper porphyry ore, low-grade placer gold and auriferous pyrite ores, various industrial minerals, and fine coal cleaning. Many fundamental studies including the X-ray computed tomography (CT) analysis have been carried out in order to understand the multiphase fluid flow phenomena associated with ASH flotation. With data available from these studies, it is now possible to construct more accurate ASH flotation models for different applications in order to analyse the behaviour of the system and to optimise design and operating variables. The ASH flotation model developed in this paper is based on the data given in `Air-Sparged Hydrocyclone/Advanced Froth Flotation Fine Coal Cleaning', Final Report, DOE Contract No DE-AC-88PC88853, submitted by Pennsylvania Electric Company (PENELEC), December 1989. Data from several hundred experiments with the two-inch ASH-2C air-sparged hydrocyclone (capacity 0.1 - 0.3 tph dry coal) are available from the report and have been used for this analysis. In the past, a preliminary model based on limited data had been developed. The current study, however, emphasises the global behaviour of the ASH system by utilising almost all the data from the report for the purpose of scale-up and industrial application. There are two parts in the current modeling and analysis effort for ASH flotation of fine coal. The first part is the modeling/analysis of dimensionless ratio of overflow opening area to underflow opening area, A*, and the dimensionless ratio of air flowrate to slurry flowrate, Q . The second part involves the modelling/analysis of all other variables in the system and an expert system for operation and control is introduced.

Jan 1, 1993

Segregation of granular material is a very common phenomenon. Realised in a forced manner it is a basis of all separation processes in mineral processing, mainly classification and beneficiation. Spontaneous segregation, occurring under dynamic conditions and making possible mutual translocations of grains, is however an undesired phenomenon as a rule. It decreases the degree of blending of the material which in many cases is an important technological feature of the material. It should be noted that the segregation can be treated as the reverse phenomenon to blending. The importance and frequency of spontaneous segregation has caused many rules and technical solutions to be developed aimed at decreasing the possibility of the spontaneous segregation. However, not enough attention has been focused on an quantitative description of the phenomenon of segregation, either to ways of quantitatively evaluating segregation effects or to explanation of the influence of conditions under which the grained material exists on the occurrence of segregation and its degree. The paper presents the following topics: 1. new numerical indicator for evaluation of the segregation degree (and blending) of material contained in an arbitrary determined region is proposed; it is determined relative to the maximum possible degree of segregation of the given material when taking into account its individual properties; values of the indicator can be calculated effectively for an arbitrary material, also for ulticomponent material. 2. there is proposed a way of evaluating the state of segregation (or blending) of material in an arbitrary part of the region mentioned above, based on investigation of the gradient of distribution of the material features; algorithms of analytical procedures and calculations are presented for typical cases met in mineral processing; 3. results of initial experimental studies, both laboratory and industrial, concerning the effect of the chosen factors occurring in transport and storage of the material on its degree of segregation are presented; and 4. conclusions referring to the fundamental and practical significance of the results are also presented.

Jan 1, 1993

The authors have succeeded in providing additional rigour and clarity to the formulation and execution of the dynamic programming algorithm for optimum open pit limit determination. The inclusion of the blocks on the J + 1 column in the search for Pmax, and constraining this search with blocks assigned a value of negative infinity, ensures an optimal solution within the defmed blocks. The effect of the negative infmity blocks is to preclude mining along the diagonal blocks from the first row that they occur in. Figure 1 graphically illustrates the effects of this on the calculation of P. A practical application for constraining mining with negative infmity blocks is the case where the pit outline is defined by lease boundaries and not by the value of blocks to be removed. Any legal, social or physical constraint could be accounted for in the same way.The danger in applying this technique is that the negative infinity blocks will override any other more profitable solutions that may exist. This is in fact what has happened in the example that the authors use. If a further column is added to the left hand side (column -1) and the calculation is carried out again, a more optimal x-section can be found. (If the negative infinity values are removed the same result is obtained.) This gives a pit value of 112 as against the 108 of the authors' optimal pit. This calculation is shown in Figure 2. Lerchs-Grossman optimization is reliable only if there are sufficient columns available to allow "mining" to optimum depth of the ore body and still allow the pit to break out at the surface within the confines of the columns.This author's approach is to create enough columns each side of the lateral limits of the ore to allow the pit to intersect the surface while still within the confines of the block model. Implementing the methods discussed by the authors helps to reduce the number of columns required to achieve this.

Jan 1, 1987

By Wang S

Fragmentation is the basic concern in rock blasting and serves as the main measure of blasting effectiveness. A good estimation of fragment size distribution before blasting is very useful and helpful for selecting the proper equipment for loading, transporting, and crushing rocks. A fragmentation model is presented that is based on a hole by hole analysis and correlates the rock properties, burden, spacing, and explosive column with the blasted volume and fragmentation obtained. The drill bench is divided into three separate areas corresponding to different breakage mechanisms. They are: 1) a main breakage or casting area, 2) a secondary breaking area, and 3) an overbreak area. The boundary of the main breakage area is found from the magnitudes of strains in the stress waves and the tensile strength of the rock. The secondary breaking area is determined by stress wave reflections at discontinuities and interactions between colliding stress waves from adjacent boreholes. The overbreak area is that beyond the main breakage area "where the reflected tensile waves no longer break the rock. This analysis is applied on a hole by hole basis to locate the breaking points. Then connecting the breaking points on each side of a borehole forms the triangle of the main breakage area. This is repeated for the next hole and the remaining area is the secondary breakage area. After the angle and area for each hole are found the Kuz-Ram model is used to predict the fragmentation size distribution for each hole. Then summing up the size distribution for each hole gives the total fragmentation distribution. This analysis has been successfully applied to field tests performed in a limestone bench where the entire spoil pile was screened to determine the fragment size distribution. Knowing the explosive and rock properties the breaking area was found for each hole, the strain and stress values, the breaking point, and angle of breakage (104 degrees). The fragmentation size distribution was then calculated and compared to the field data with excellent agreement.

Jan 1, 1990

Ok Tedi Mining Limited commenced construction in mid-1981 of facilities and infrastructure to mine and process gold ore at Mt Fubilan in Papua ew Guinea. Production ofgold began more or less on schedule in mid-1984 although design capacity is yet to be achieved. Due to geotechnical problems, two important items of infrastructure, hydropower and permanent tailings disposal, are not yet in place. Current low metal prices make it likely that copper facilities will be postponed.The deposit compriscs a leached gold capping overlying copper sulphide porphyry mineralisation containing significant gold and molybdenum. Mining is by open pit methods. The soft leached capping gold ore is ripped and dozed, loaded by hydraulic shovel and trucked to a dump pocket. After passing a large semi-autogenous mill of nominal capacity of I, I00 tonnes per hour, the ore is treated by the carbon-inpulp process, with a gravity circuit to recover coarse gold. The final product is 12 kg dore bullion bars.At present, all tailings are detoxified with hydrogen peroxide; after cycloning, the coarse fraction is stored, and the slime fraction discharged into the river system; expected environmental impact is acceptable. Investigations for a suitable dam site for a permanent tailings system are still underway.Peak 'I. hour power demand for Stage I is 17 MW, presently supplied by a diesel alternator power station and a 2 MW mini hydropower plant.Initial access to the base camp at Tabubil was only by air. Eventually a road was pushed through 134 km from the river port at Kiunga (where port facilities have been constructed) and a further 23 km to Mt Fubilan.Roads are constructed of compacted gravel and crushed limestone generally underlain by geofabric. Eight major steel bridges were built.The town of Tabubil has been established, including housing, airport, shops, offices, schools and all facilities.Environmental studies have been extensive and a detailed monitoring program is maintained. Ok Tedi Mining Limited is making considerable efforts to train Papua New Guineans and to foster local business.

Jan 1, 1985

The Callie Underground Mine is located in the Tanami Desert 560 km Northwest of Alice Springs in the Northern Territory and is currently operated by Newmont Australia Limited with all mining activities carried out by Henry Walker Eltin. Callie was discovered in the region in 1991 with the box cut portal commenced south of the pit in 1995 and underground ore production commenced in 1998, after completion of the profitable Callie Open Pit. Development is currently occurring at depths of over 700 m with the decline currently below the 640 Reduced Level (RL) level (surface RL of 1400) with production haulage from 600 m below the surface. The combination of auto compression, a moderate geothermal gradient of 2¦C/100 m and diesel heat transfer causes the wet bulb temperature of intake air at the bottom of the mine to be typically 5¦C higher than on the surface. Wet Bulb temperatures can be up 5¦C higher again in active areas under secondary ventilation. During the 2002/2003 wet season many activities in the lower levels of the mine were stopped due to miners experiencing adverse heat related symptoms or the temperatures exceeding the Underground Heat Management Procedure stop job criteria of 32¦C wet bulb. To improve the working environment, combat the heat related illness and improve operational efficiency, a temporary 1.8 MW refrigerated cooling plant consisting of three 600 kW modules were installed underground to provide bulk air cooling for the lower levels of the mine during the 2003/2004 wet season. Several studies have been conducted in relation to future ventilation demands at Callie and all came to the conclusion, that some mine cooling will be necessary for Callie to meet the high production and development demands. This paper will describe the ventilation network at the Callie Underground operation focusing on the installation, operation and effectiveness of the temporary underground refrigeration plant.

Jan 1, 2005

By K Baskaran, T McKenzie

Sustainability is becoming increasingly important in the mining and mineral processing industries and must incorporate the associated waste products. Acid mine drainage (AMD) is one such by-product and is one of the most serious environmental problems facing the minerals industry today. The oxidation of sulphidic mine wastes often continues for a substantial period of time after mine closure, resulting in difficult and costly remediation and rehabilitation works. Mining companies are often reluctant to spend increasing amounts of money on waste treatment when the mine life is limited or even finished. Hence a simple, low maintenance and low-cost method of treating AMD is required. Whilst this paper does not address the issue of AMD, it does propose methods for removal of individual species from AMD with potential benefits, including raising AMD pH. A novel concept of using biosolids as a biological adsorbent, or æbiosorbentÆ, of metals from AMD is being investigated at a laboratory/pilot scale level. Biosolids are a by-product resulting from the biological treatment of wastewater, and have been previously shown to adsorb metals from aqueous solutions. This could lead to an environmentally sustainable or ægreenÆ method for treating both AMD discharges and disposing/reusing the biosolids. The result of a laboratory-scale study of the biosorption of Zn(II) is presented in this paper. Physical parameters including reaction kinetics, mixing speed and solution pH were investigated. Solution pH also rose an average of 2 pH units over the 24 hour equilibrium time û a valuable side effect when treating acid mine drainage. The outcome of the study highlights the usefulness of biosolids as a biosorbent for the removal/recovery of metal ions from acid mine drainage. A simple, low-cost treatment technology requiring low maintenance would be beneficial to the mining industry to address some issues relating to AMD and would help integrate environmental and economic considerations into sustainable environmental management.

Jan 1, 2002

By S Ellis, J McMullen, M Habner

A new leaching regime was implemented at Kalgoorlie Consolidated Gold MinesÆ (KCGM) Gidji plant on a cyanide leach of ultra-fine ground sulfide concentrate. High lime concentration and lead nitrate were used to overcome the refractoriness of the fine sulfides (high reactivity of fine sulfides with the presence of gold tellurides). The leach pretreatment stage was shown to be detrimental and was shut down. Lime titration was introduced as part of the process control. It was shown that the leach could be performed at low dissolved oxygen, (ie 3 - 5 ppm) to avoid sulfide oxidation and the associated high cyanide and lime consumption. Plant results showed reduced cyanide consumption (40 per cent) and an accelerated leaching rate, whereby most of the gold was dissolved in 24 hours compared to 72 hours used previously. Similar work was performed at KCGMÆs Fimiston plant, which leached a combined ultra-fine ground sulfide concentrate along with the slimes fraction from hydrocycloning the bulk flotation concentrate. The use of lead nitrate, high lime and carbon-in-leach generated a faster leaching rate and minimised adsorption of gold on fine pyrite particles. The grind, previously controlled with a P80, was replaced by a P98 to give a better operational indication of top size hydrocyclone performance. Before the implementation of the changes, average leach residues for slimes and UFG were respectively 4.0 g/t and 5.5 g/t. With the modifications to the leaching regime, average leach residues were lower by 1.5 - 2.0 g/t. Whilst significant improvements have been demonstrated, further work is progressing at KCGM to further reduce ultra-fine concentrate leach tail grades, and also to improve the understanding of concentrate refractoriness and the factors responsible for differences between laboratory and plant leach results. Estimated profits since the implementation of the new approach are in the range of $A3.5 million per year.

Jan 1, 2005

By Mackenzie W. R, Harding C. G

The Islamic Republic of Mauritania is a large country of over 1 000 000 square kilometres situated on the Atlantic coast of north-west Africa. It is bounded to the north by Western Sahara and Algeria, to the east by Mali, and to the south by Mali and Senegal. With the exception of a narrow strip in the south along the Senegal River valley, the country lies entirely within the Sahara. The north of the country is largely devoid of vegetation, and it is estimated that 90 per cent of the population of 2.1 million people live in the southern quarter of the country. From about the turn of the century, Mauritania was ruled by the French from Dakar in Senegal and, until 1960 when it obtained independence from the French, Mauritania did not have a capital. Today, the capital is Nouakchott, home to an estimated 600 000 Moors of mixed Arab, Berber and African descent. After independence in 1960, disputes over Spanish Sahara to the north led to a military coup in 1978 and it was not until 1991 that a democratic constitution was adopted. The new constitution declares Mauritania to be an `Islamic, African, and Arab Republic.' It provides for an executive president, elected for a six-year term, and for a bicameral legislature, consisting of a national assembly and a senate. The first presidential and legislative elections were held in 1992 under United Nations' supervision. Mauritania's economy is predominantly pastoral, and the country depends heavily on foreign aid. Its principal export industries are iron ore mining (about ten million tonnes per annum from mines near Fderik in the north) and fishing. Mines d'Or d'Akjoujt SA (MORAK), a company in which General Gold Resources NL (GGR) has 42.5 per cent equity, produces over 50 000 ounces of gold per annum, which represents the third largest export industry in the country.

Jan 1, 1996

By K Gottliebsen

Many hydrometallurgical and chemical processes produce large amounts of acid waste. This is illustrated by the copper S/X-E/W process used at the Mount Gordon mine in North Queensland, which produces a tank house bleed in the form of a concentrated sulphuric acid stream. The bleed stream is necessary to remove impurities such as iron that decrease the efficiency of the electrowinning process. However, this bleed stream comes at a high financial cost due to large quantities of make up sulphuric acid required as well as the need to neutralise the bleed stream prior to disposal. The present work describes the approach taken to develop a solvent extraction process for the selective recovery of sulphuric acid from copper tank house bleed liquor. The proposed extraction system was investigated using a branched long chain aliphatic tertiary amine tris(2-ethylhexyl)amine (TEHA) as the extractant, Shellsol 2046 as the diluent and octanol as a modifier. Computer simulations were used to determine the optimum operating conditions for the recovery process. It was found that the process was able to selectively recover up to 90 per cent of the sulphuric acid from the copper electrolyte. This is recovered as a pure aqueous acid stream at a concentration of up to 130 g/L that can be recycled back into the tank house circuit or other areas of the process. The raffinate acid concentration was reduced from 180 g/L to as low as 18 g/L, significantly reducing waste disposal and the environmental impact of the copper process. The equilibrium data and simulation results were also compared with an alternative extractant, CYANEXR 923. Finally the efficiency of the TEHA extraction system was investigated on a pilot-scale in a pulsed perforated plate column. This information was used in order to scale the process for an industrial application. The same methodology applied in this case study could be used to provide innovative and cost-effective solutions to waste streams encountered in other hydrometallurgical or chemical processes.

Jan 1, 2000

IN the ordinary course of treatment of pyritic ores or concentrates, whether for the recovery of copper, tin, gold, or any other contents, the removal of some or all of the sulphur contents is almost invariably the first step. The practice is to roast the ore in a current of air so that the sulphur is oxidized to sulphur dioxide and the metal constituents are changed from sulphides to oxides. If it is feasible to produce sulphuric acid in conjunction with the treatment process, the sulphur can be usefully employed; but if this is not possible, then the sulphur contents not only become a dead loss, but tend to be a nuisance as well in the surrounding neighbourhood.The problem of avoiding this disadvantage and making economic use of the sulphur has had attention from the early days of scientific metallurgy, and in the past few years very special efforts have been made both to drive part of the sulphur as such from pyrites and recover it, and to replace the sulphur in the S02 by carbon, with the production of carbon dioxide and precipitation of the sulphur. So far economic success does not appear to have crowned these efforts. In the case of pyrites, of the two atoms of sulphur which go to make the FeS2, the first is very lightly held. Dissociation is effected by heat alone at a temperature which is given by Peters as 5160 C.Now, sulphur and hydrogen will unite or burn together, with the production of sulphuretted hydrogen. It occurred to the writer that, if hydrogen was passed over pyrites heated to the above temperature, this first atom would be snatched away by the hydrogen, and could possibly be economically recovered.The first step consisted of some simple laboratory experiments. From these it was found that this first atom was readily removed, and that the extraction was practically complete. Further, the reaction took place at a low temperature, a dull red heat being sufficient.

Jan 1, 1923

By E R. Ramanaidou

The presence of clays in channel iron deposits (CID) within the Pilbara region of Western Australia causes problems in the classification and subsequent processing of the iron ore. In particular, the presence of clay adversely affects the processing and ore metallurgical properties by increasing the amount of Si and Al. Iron ore companies are seeking new methods to quickly and objectively detect the type and amount of clay in these deposits. Traditional methods of clay quantification such as X-ray diffraction (XRD) and thermal analysis are time consuming and expensive. Reliance on bulk chemical techniques (eg X-ray fluorescence, (XRF)) to derive normative mineral abundances can give misleading results. For example, the replacement of Fe by Al in the structure of the iron oxide minerals, goethite and haematite, which dominate in CIDs, can be significant. Silicon can also occur in association with these Fe minerals. If not accounted for, chemical techniques may overestimate the normative abundance of clays. In comparison, reflectance spectroscopy in the visible-to-near infrared (VNIR) and short wave infrared (SWIR) wavelength range (eg 400 - 2500 nm) and Fourier transform infrared (FTIR) (6000 - 900 cm-1) analysis are non-destructive techniques that can provide rapid and objective mineralogical information. Both techniques are particularly suited to Al-, Fe- and Mg-OH bearing minerals such as clays. Kaolinite and, to a lesser extent, montmorillonite are the most common clay contaminants that occur in the Pilbara CIDs. Previous applications of VNIR-SWIR spectroscopy have demonstrated the potential of these methods in quantifying the clay mineralogy of CID ore. In this study, variations in the depth of diagnostic spectral adsorption features in the SWIR wavelength range of kaolinite and montmorillonite in standardised mixtures, with known proportions of clay, were well correlated to the abundance of kaolinite and montmorillonite, and to the clay alumina content (ie per cent Al2O3 û clay).

Jan 1, 2007

ON milling plants, where a large number of slime samples are collected each day, considerable work is involved preparing them for the assayer. The usual practice (as the material usually passes a 150-mesh screen) is to place the sample on a 30-mesh screen an 1 brush it through on to a cloth below. The sample on the cloth is mixed and a portion taken out for the assayer. A simple apparatus that would rapidly disintegrate and prepare these slime samples for the assayer was needed. The manufacturers of assayers' supplies appear to have overlooked apparatus for this class of work. To overcome the tedious preparation of slime samples by the above method, the writer devised the apparatus shown in the accompanying drawing (Fig. 1). It will be seen that the apparatus is a combination of a modified household flour sifter and a riffle sampler.The apparatus is made up in two parts, the top half consisting of a screen box carrying the disintegrator, and the bottom half a, riffle divider, the joints between the two being a slip-in fit. A lid is provided for the screen box. The disintegrator consists of an open drum, to which are soldered three rows of spring steel fingers. Each row has a number of steel fingers which, on rotation, press against the semi-circular screen in the screen box, forcing the slime particles through.To operate the apparatus an 8-in. sample tin is placed under each spout of the divider. The sample of slime, which is about 2 lb. in weight and usually in lumps, is placed in the screen box, the cover replaced, and the drum rotated about half-a-dozen times by means of the handle.The disintegrated sample is divided by the rifle divider into two portions, which are found in the tins under the spouts of the apparatus. One of these samples is taken, mixed on a sheet, and sent to the assayer.

Jan 1, 1922

Kumba Iron OreÆs Sishen Mine is one of the worldÆs largest iron ore mining operations situated in the Northern Cape, South Africa. It produces 29 million tonnes of iron ore products per annum using a dense medium separation (DMS) beneficiation process. Kumba is currently commissioning the Sishen Expansion Project (SEP) which will produce a further 13 Mtpa product through a jigging beneficiation process. The products from the Sishen Mine are highly sought after and consumed by domestic and various European and Asian customers. During beneficiation iron ore slimes are generated and discarded as waste material to the slimes dams. A study was initiated in 2005 to investigate processes to beneficiate these slimes to saleable products û prompted by the current high demand for iron ore products and the high grade in the Sishen slimes thickener underflow of approximately 54 per cent Fe. Initial laboratory scale test work indicated that a 66.5 per cent Fe iron ore concentrate could be produced from the Sishen slimes thickener underflow through a process of classification, two stage wet high intensity magnetic separation (WHIMS) and five stage flotation. This process, however, did not produce the desired results during pilot plant testing and numerous alternative process routes were investigated. The process that did achieve the desired product grade of 66.5 per cent Fe at economically feasible product yields consisted of two stage WHIMS using SLON magnetic separators. Results achieved indicate that the thickener underflow slimes can be upgraded from 54 per cent Fe to 66.5 per cent Fe at a product yield of ca. 40 per cent. Product yield could be increased through the further beneficiation of the SLON tails. The Sishen slimes thickener underflow production rate is ca. 3 Mtpa û resulting in a potential concentrate production of ca. 1.2 Mtpa. The slimes concentrate will be fed to a pelletising plant that will produce 66 per cent Fe pellets destined for domestic and or export markets.

Jan 1, 2008