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The addition of a thallous salt to the cyanide leach of a calcined pyritic concentrate causes a marked increase in the"rate of extraction of gold. This probably is due to the activation of passive gold by.th,e. thallous ions'.''Lea'd, bismuth, and mercury salts, which should produce ' a, similai effect, fail to do so. It is postulated that'this latter result, together with'the reprecipitation of silver at low cyanide levels, is due to the presence of soluble sulphide. The use of thallous salts to reduce leaching time is discussed briefly.

Jan 1, 1964

By M Zhu, J Safarian

Understanding the slag composition-structure-property relationship remains challenging due to the amorphous nature of slag melts and the difficulty of high-temperature experimental investigations. Since the CaO-Al2O3-SiO2 slag system is maybe the most important slag system for various hightemperature metallurgical process, the present research employed high-throughput molecular dynamics (MD) simulations on the entire composition region of the CaO-Al2O3-SiO2 slag system to determine physical properties like molar volume, density and diffusivity, structural properties such as distribution of different oxygen types for each simulated slag melt. The obtained slag properties result from the simulations displayed good consistency with experimental data, underscoring the reliability of the MD simulation as a novel tool to predict reasonable slag properties and to study slag behaviour from atomistic insight. The simulated results demonstrate a near-linear relationship between molar volume changes and composition, highlighting the predominant role of oxygen atoms, which is attributed to the significantly larger size of oxygen compared to other cations in the slag melts. This disparity in size leads to oxygen ions occupying most of the space in slags, thereby playing a major role in determining the overall molar volume. The simulation results of slag density revealed a decreasing trend with increased SiO2 content and identified a local minimum at constant SiO2 when Al2O3 content increases, also consistent with established slag density models. Furthermore, the simulated oxygen self-diffusion coefficients reveal a strong composition-structureproperty relationship, where an increase in CaO content enhances slag diffusivity, while a minimum in diffusivity is observed near a CaO/Al2O3 ratio of unity. The diffusivity minimum also corresponding to the local viscosity maxima, indicating effective simulation of charge compensation effects and dynamic characteristics of slag melts. The simulated distribution of oxygen types in slag — bridging oxygen (BOs), non-bridging oxygen (NBOs), free oxygen (FOs) and tricluster oxygen (TOs) — reveals a composition-dependent pattern: BOs peak near CaO/Al2O3 = 1, NBOs and FOs are abundant in CaO-rich areas with NBOs peaking near the Ca3SiO5 composition, FOs in the CaO corner, and TOs predominantly in the Al2O3 corner, highlighting the complex interplay of network formers and modifiers for the charge compensation effects on the slag’s structural properties. The successful application of MD simulations in this study paves the way for a powerful approach to explore the complex relationships in multicomponent slag systems and bridges the gap between mathematics modelling and experimental observations in high-temperature metallurgical processes.

Aug 21, 2024

Computational models are very useful for studying many of the physical mechanisms which can cause sample bias. Within such models we can predict the trajectories of all individual particles and thereby make observations which are not possible for physical systems. Physical mechanisms highlighted include congestion at the cutter aperture, particles bouncing over the cutter aperture, air drag on fine particles, waves of material being bulldozed off the belt by the upstream side of the body of square cutters, and particles being thrown by the leading edges of cross-belt cutter blades. Having identified relevant physical mechanisms for an existing cutter, we can estimate the extent to which they are likely to result in unequal representation of portions of a stream of material and thereby estimate the maximum likely sample bias.

Mar 1, 2010

By G M. Hoffmann

Utilisation of lower grade (Jigging technology has progressed to a point where SishenÆs 50 to 60 per cent Fe run of mine (ROM) material, once considered as waste, can be beneficiated to produce a saleable 64 per cent Fe product. This has been confirmed through appropriate beneficiation testwork. Consequently, Sishen can now produce saleable product from material not currently included in the resource definition, significantly increasing the resource base of the mine and ensuring higher resource utilisation. Mine planning utilised the geological models to produce detailed planning schedules, reflecting the current and SEP plants separately, optimised to comply with product specifications of both the current and SEP plants and to confirm the viability of the low-grade resources identified as SEP feed material. The SEP product specifications have been derived by optimally matching iron ore market requirements with the revised resource base. A 64.0 per cent Fe lump product and a 63.5 per cent Fe fine product are the optimal SEP products. The SEP plant will be able to produce 10 Mtpa at an average yield of 60 per cent and a lump to fine ratio of 62:38. The plant consists of five major sections: namely crushing, material preparation, beneficiation, final product handling and quality control services. Maximum integration with the current Sishen plant was considered. Kumba currently has an agreement with Transnet to rail up to 23.5 Mtpa through the Sishen Saldanha iron ore export channel (IOEC). Transnet and Sishen Iron Ore Company have signed a Definitive Agreement that deals with the expansion of IOECÆs capacity, which increases KumbaÆs entitlement from 23.5 Mtpa to 35.0 Mtpa. The detailed enviro-legal impact assessments for the SEP indicated that the project has low enviro-legal risk as a result of it being a brownfields project incorporated into the current Sishen operations.

Jan 1, 2005

The performance of the Australian Mining Industry over the past 10 years using key indicators of production, revenue, aftertax return investment, together with key cost elements, market changes and ore reserves is briefly reviewed. The elements of competitiveness are discussed forthe industry and the effects of Government charges and policies relating to existing operations are outlined. There is a demonstrated need for improvements in competitiveness in direct and indirect costs and for improved access to resources for the mining industry to continue to grow and add to Australia's economic growth.

Jan 1, 1987

Response of a mineral to anionic and cationic flotation reagentsvaries with the nature of the mineral and the particle size. A ruleis deduced for the selection of the correct type of reagent, which leads to a simple method of testing ores to determine the possibility of separating the constituents by flotation.

Jan 1, 1963

By L M. Zhang, T H. Xu, J Zhao

Blasting is one of the most commonly used strategies for excavation in civil and mining engineering. Yet blasting can also bring along such undesirable effects as ground vibrations and soil disturbance. Numerical analysis is a powerful tool for estimating the effects of blasting and improving blasting design. In this research, a constitutive model for sand is proposed for the numerical analysis of blast-induced ground motions and wave propagation in soil mass. In the model, three model surfaces, ie the critical surface, the dilatancy surface and the bounding surface, are defined following the bounding surface hypoplasticity framework. The strain rate is included explicitly into the model formulations so that the proposed model is valid under high strain rate loadings caused by blast-induced vibrations. The performance of the proposed model is validated by the simulation of drained triaxial compression tests conducted on a crushed coral sand under different strain rates.CITATION:Xu, T H, Zhang, L M and Zhao, J, 2014. A bounding surface model for sand subjected to blast-induced vibrations, in Proceedings AusRock 2014: Third Australasian Ground Control in Mining Conference , pp 201–206 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 5, 2014

The Taupo Volcanic Zone in New Zealand and the Philippine Mobile Belt in the Philippines are characterized by active subduction, active volcanism and high seismicity. The main factors affecting characteristics of geothermal systems in both countries are: tectonic setting, source magmas, maturity of the systems, and depth to the degassing magma body. Within New Zealand, geothermal systems are grouped into arc- and rift-type. Fluids in arc-type systems contain high amounts of volatiles (40%) and higher Cl contents (3,000-10,000 mg/kg). Maximum temperatures are also higher, reaching up to >400¦C. Arc-type alteration assemblages in New Zealand and the Philippines are similar. Because Philippine geothermal systems are less mature, have higher temperatures and steeper geochemical gradients than New Zealand ones, advanced argillization is more widespread occurring down to depths of 2000 m. Mineral phases are more varied due to the active input of magmatic waters and the formation of vapor conditions at depth, forming P04-, B-, Li-, Ce-, F-, and Cl-bearing minerals at high temperatures. In the Philippines, high temperature magmatic-hydrothermal to contact metamorphic assemblages containing biotite, amphiboles and pyroxenes are relatively common, but rare in New Zealand.

Jan 1, 1995

By Parks T. C

A low-grade disseminated nickel sulphide serpentinite ore from W.A. had a relatively high permeability after drying. Various techniques indicated that the permeability resided within a fine network of fibrous vein- lets and especially within coarse cracks along which the sulphides lay. The ore minerals were therefore open to selective extraction by chemical leaching. A IM ammonia-7.8 wt.o "ammonium carbonate" solution, oxygenated at 1 bar oxygen pressure and about 23¦C, released nickel, copper and cobalt from the sulphides, leaving a permeable residue of goethite, while calcium, magnesium and iron concentrations remained negligible in the leachant. The nickel and copper was electrodeposited directly from the pregnant liquor in a deposit which included 16.5 wt.% sulphur. Enhanced copper/ nickel ratios early in the extraction suggested that valleriite (not amenable to flotation) was leached preferentially. Th$ controlling influence of the pore structure was demonstrated by the dependence of leaching rates on the size of the ore particles used, and on the measured porosity of different ore samples. A 2mm size was probably the optimum for exposing sulphides to the leachant. Leaching was accelerated by increasing the temperature and oxygen pressure.

Jan 1, 1974

By Y-B Kang, W-Y Cha, Y-M Cho

Molten slag used in the secondary refining process (RH process) for the production of Ultra-Low C (ULC) steel is typically composed of CaO-Al2O3-MgOsat.-FetO with minor constituents. FetO in the RH slag is the main source of reoxidation of the molten ULC steel in the ladle by 2Al + 3(FetO) = (Al2O3) + 3Fe, thereby serving as the source of the alumina inclusions. On the other hand, FetO also enhances the fluidity of the slag, thereby increasing inclusion absorption capacity. Optimum slag chemistry design is therefore required to produce clear ULC steel. The reoxidation kinetics was investigated in the present study by employing high-temperature experiments and developing the reaction rate model. Initial compositions of slag ((% CaO)0/(% Al2O3)0 and (% FetO)0)) and reaction temperature were varied and change of [% Al] in the molten steel was measured. The rate-controlling step was analysed. It was found that the rate-controlling step in some cases changed during the reoxidation: from a mass transport of Al in the molten steel to a mixed transport including Al2O3 in the molten slag. The experimental data validated the reaction rate model based on the elucidated reaction mechanism and FactSage thermodynamic database. The model suggested that high (% CaO)0/(% Al2O3)0 suppresses the reoxidation only when (% FetO)0 is low (5 or lower in the present study).

Jun 19, 2024

By Howes PM

In the iron and steelmaking processes, dusts are generated and treated by wet dedust- ing methods to form slurries which are high in iron content, but also contain certain impuri- ties. For many years these slurries have been processed and the wet cake, which is produced, has been dumped because of the high zinc and alkali chloride contents. Sintering is an appropriate process for recycling of these materials, provided the deleterious impurities can be kept under control. Zinc is a deleterious element in blast furnaces because it promotes the formation of accretions on the upper walls of the furnace. This results in irregular furnace performance. Alkali chlorides effect the emissions from the sinter plant waste gas due to the high resis- tivity of these components, resulting in decreased efficiency of the electrostatic precipitator. Experimental work indicated a concentra- tion of zinc in the -11 pmt particle size frac- tion. A cyclone plant was installed producing a "coarse" usable product and a "fine" waste Product.

Jan 1, 1984

I WISH to express to the members of the Institute my sincere appreciation of the distinction which they have conferred upon me by again making me their president. It also gives me great pleasure to once more welcome the Institute to Mount Lyell.Since your last visit certain improvements in plant have been made, which I trust you will have found interesting, and which show that, though located in a remote corner of the world, we are abreast of the times.The opportunities which a recent lengthy trip to America has given me to observe the degree of interest which our local smelting practice continues to arouse in metallurgical circles make it seem appropriate that I should take advantage of your visit to lay before you some detailed information on the more practical features of pyrite smelting, particularly as carried out at Mount Lyell. There are only a few places in the world where the method is now being practised in approximate purity-only about half...

Jan 1, 1915

By H Zhang, S Li, J Song, Z Lv

In this paper, a method for extracting and refining metallic molybdenum using low-temperature ZnCl2- NaCl-KCl molten salt was proposed. The electrochemical behaviour of molybdenum ions in ZnCl2- NaCl-KCl molten salt was investigated in detail, and pure metallic molybdenum was collected on the cathode. The reduction and diffusion processes of Mo(V) ions in ZnCl2-NaCl-KCl molten salt were determined through a series of electrochemical methods. The diffusion coefficients and nucleation modes of Mo(V) ions were also studied, and electrolysis was conducted for a prolonged period at a constant current density. The results indicated that the electrode reduction of Mo(V) ions in ZnCl2- NaCl-KCl molten salt proceeds through a three-step reaction: Mo(V) → Mo(IV) → Mo(III) → Mo at 250°C. The Mo(V) → Mo(IV) reaction was reversible and diffusion-controlled, with a Mo(V) diffusion coefficient of 6.02 × 10-6 cm2 s-1. Additionally, the nucleation mode of Mo(V) ions was instantaneous nucleation. The products electro-deposited were confirmed of metallic molybdenum with a particle size of less than 1 μm.

Aug 21, 2024

By H Han, d S. Hapugoda, L Lu

With the recent rapid development of Chinese steel industry, the world iron ore resources of good quality are depleting rapidly. As a result, iron ore deposits of lower quality have been or are being developed to meet the market demand and are becoming increasingly important to iron and steel companies. As concentrates have advantages of high Fe grade and less harmful impurities, they are ideal sweeteners to maintain sinter grade and quality when high proportions of low-grade ores are used in the sinter blends. However, due to their fine nature, addition of concentrates will inevitably increase the proportion of adhering fines and reduced the proportion of nucleus particles of the sinter blends, which can adversely affect the green bed permeability and sintering productivity. In the present study, lab scale sintering tests were carried out under the conditions similar to the sintering process to examine the effect of concentrates on the high temperature sintering characteristics of sinter blends and the structure and strength of the resultant sinter analogues.

Sep 18, 2023

By Bigu J, Grenier M. G, Knight G

Particulate control is a major concern in underground mining and the subject of continuing research world wide. In Canada the federal government's Mining Research Laboratory at EIIiot Lake, Ontario, has been using two aerosol counters to aid its investigations. Specific studies with the units include: a) evaluating total and elemental size efficiencies of dust filtration units: b) characterizing the dust particulate cloud from different mining operations: and c) determining dust transportation characteristics.

Jan 1, 1988

By Collins M. J, Ozberk E

A major advantage of the Sherritt Zinc Pressure Leach Process is the conversion of sulphide sulphur in zinc concentrate to elemental sulphur during pressure leaching. Elemental sulphur can be recovered as a marketable byproduct by flotation of the leach residue, and melting and filtration of the sulphur flotation concentrate. The behaviour and deportment of sulphur during pressure leaching, flotation, and melting and filtration are discussed in this paper using data obtained from the treatment of a wide variety of zinc concentrates in the laboratory miniplant at the Sherritt Research Centre. The quality of the elemental sulphur byproduct and a process for purifying the sulphur are also Presented.

Jan 1, 1993

By Mahoney BK

The development of simulation models to reflect accurately the operations of a port and its associated transportation systems can be an expensive and time consuming process. However the complexity of such operations leaves little choice for other than simulation techniques since analytical methods are rarely appropriate. The development of suitable software has now reached the stage that these techniques can be used with confidence. Types of simulation models and their requirements are discussed together with the results from some recent applications to the planning and management of bulk terminals.

Jan 1, 1983

By Aiming Z, Shenyi S, Xialei W

Zhangmatun Iron Mine is situated in the suburbs of Jinan city. Shandong, China. Because of surface environmental constraints, no suitable site can he selected to dispose of mill waste. The full mill tailings must be disposed of underground. This paper deals with the work conducted at Zhangmatun mine to develop a total tailings backfill system, taking advantage of a double- shaft blade mixer and an activating agitator to prepare backfill. Cement and ground slag are added to tailings for strength development. Two scopes have been filled and the pillars have been effectively mined out during the field trial. The application of innovative total tailings backfill technology is a new concept at the mine. Detailed planning has achieved a close integration of mining, milling and backfilling. Full mill tailings, with or without rock, are disposed of underground in a continuous process to fill, totally and systematically, the cavities formed by mining.

Jan 1, 1998

By M Ogle

"Booster fans are relatively rare in Australian coal mines. However, as mines become progressivelydeeper it is likely that such fans will be increasingly adopted as a method to sustain or improve the ventilation of underground workings. The reasons why booster fans may be an att ractive alternative include: increased cost of sinking additional ventilation shafts with greater seam depths; environmental objections to shaft sinking projects; and increasing urbanisation and surface constraints limiting availability of potential ventilation shaft sites. As Tahmoor Colliery movedinto its northern lease the ventilation constraints became the limiting factor on production. Thelimitations of the old workings meant that the existing ventilation system would be inadequateto sustain the required production. Extensive ventilation modelling was carried out to evaluatevarious potential solutions and the recommended option was the installation of a booster fanor fans, to gain underground access to an already approved shaft site in the northern lease.Proposals were sought from recognised fan manufacturers and various alternative arrangements were tendered. Ultimately the choice was between one large centrifugal fan and a set (three or four) of smaller æauxiliary-likeÆ fans in parallel. The successful tender was for a single centrifugal, an arrangement very similar to the booster fans that have been operating eff ectively at Westcliff Colliery for a number of years. This paper describes the current ventilation network, evaluation of the ventilation options, the fan selection process, and the project status to date."

Jun 1, 2012

Towards Improved Hydrocyclone Models - Contributions from Computational Fluid Dynamics

Sep 13, 2010