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By E. S. Longfellow, S. H. Katz

Poisonous hydrocyanic acid gas (HCN) is sometimes evolved in dangerous quantities from cyanides used in metallurgical and chemical operations. This gas is much used for fumigating buildings, ships, greenhouses, and such commodities as grain and cotton to destroy rats, mice and insect pests. Wherever cyanide fumes are evolved, thorough ventilation is necessary in order to render the sur- rounding air safe to breathe. Many persons have been killed by entering tanks and fumigated places too soon, and a simple test for this gas would promote safety. In view of the need for an easy method for quantitatively determining HCN in air, the three color reactions used originally for testing HCN in solution tions *** were modified and adapted. The reactions employ (1) picric acid (CH(NO2)3OH) which is yellow but combines with hydrogen cyanide to form a red- purple dye, isopurpuric acid****; (2) phenolphthalin (CH1604), which is a reduc- tian product of the phenolphthalein (CH4) used for acid indicator, this colorless substance is oxidized***** by presence of HCN to pink colored phenolph- thalin; and (3) guaiacum which oxidized from colorless to blue******. Phenolph- thalin and guaiacum require the presence of copper compounds which catalize the color formation by reduction of cupric cyanide. The chemical processes involved *Associate physical organic chemist, Bureau of Mines, Department of the Interior. **Assistant gas chemist, Bureau of Mines, Department of the Interior. 2014 20 *** Kohn-Abrest, E., Notice toxicologique sur les gas: Arnales des Falsifica- tions, vol. 8, 1915, pp. 215-35. (Tested air with picric acid and guaiacum papers). **** Élasiwietz, H., Ueber eine neue Zersetzungsweise der Trinitrophenylsaure: Anal. der Chemie, vol. 110, 1859, pp. 289-303. ***** Weehuizen, F., Phenolphthalin as reagent for HCN: Pharmaceutrisch weekblad, Utrecht, vol. 42, 1905, pp. 271-2. Abstract, Jour. Chem. Soc., vol. 88, part 2, 1905, p. 489. ****** Schonbein, C. F., Ueber den thatigen Zustand der Helfte des in dem Kupfer- oxydenthaltenen Sauerstoffs und ein darauf beruhendes hochst empfindliches Reagens auf die Blausaure und die loslichen Cyanmetalle: Jour. fur. Praktische Chemie, vol. 106, 1869, pp. 263-70.

Jun 1, 1923

By M. A. Belokrys, F. O. Milovich, D. D. Aksenova, V. A. Ignatkina, V. A. Bocharov, A. A. Kayumov

Copper remains one of the most sought-after metals in the industry. Tennantite (Cu12As4S13) and tetrahedrite (Cu12Sb4S13) that occur in pyrite copper, copper-zinc and polymetallic ores are an additional reserve for increasing technological parameters of flotation. Pyrite mass (85% and more) has similar flotation properties to other sulfide minerals, and imperfection of reagent regime is a common problem that occurs during quality copper concentrate processing. Due to tennantite's and chalcopyrite's differences in flotation properties with butyl xanthate at pH > 10, tennantite often reports to the flotation tails. Hight alkalinity of the medium increases the oxidation level of sulfide minerals, thus increasing the concentration of S2O3 2-, SO3 2- SO4 2-. At processing facilities in the Russian Federation, the concentration of thiosulfate ions in pulp is in the range of 0.5 to 1.5 g/l and higher, which leads to a decrease in flotation activity of the tennantite. The effect of butyl xanthate (as standard), thionocarbamate, dithiophosphate and M-TF (a mixture of dithiophosphate and thionocarbamate) on monomineral (tennantite and pyrite) flotation in the presence of sodium thiosulfate was studied. The variable parameters of the "thiosulfate-collector" flotation complex were thiosulfate concentration (100-900); pH (8-12,5). The scientific methods included contact angle for hydration assessment; TEM for surface studies; UV spectroscopy and iodometric titration for solubility control. Comprehensive studies have established a connection between the concentration of thiosulfate ions and tennantite flotation selectivity. Flotation activity of tennantite is higher at pH 8 with a thiosulfate concentration under 300 mg/l. Pyrite remains active with butyl xanthate under the same conditions. TEM images of the surface films of the collectors on pyrite were acquired at pH 8. The MTF provides the biggest difference in adsorption, wettability and flotation activity between tennantite and pyrite at pH 8 and thiosulfate concentration under 300 mg/l, in comparison with butyl xanthate. The results of the research will be applied to improve selective reagent regimes of tennantite minerals flotation. Keywords: Tennantite, pyrite, chalcopyrite, sphalerite, flotation, sulfhydryl collectors, thiosulfate, adsorption, mechanism, reagent regime

Jan 1, 2020

By T. Bhambhani, E. Arinaitwe

Solvay has developed several novel reagent innovations to improve separations in sulfide ore flotation and address major industry challenges. These innovations include: a) carbon management strategies to reduce the deleterious impact of organic carbon on flotation circuits; b) new collectors for heavily tarnished or oxidized Cu-Au ores; and c) a functionalized depressant for minimizing penalty elements in metal concentrates. Owing to their unique chemistries, these innovations exhibit a wide spectrum of rather unique properties that are quite in contrast to the traditionally used reagents. The chemistry, attributes, application, and advantages of these innovations are discussed in this paper based on laboratory, pilot, and plant results and observations for various ores

Jan 1, 2023

By Ron Webber

With the difficult economic challenges currently facing the steel industry, it is essential to perform a complete analysis when determining which rolls to purchase. A properly designed “Total Cost of Ownership” model can result in significant savings. This paper will review the costs associated with rolls in both Hot Strip and Cold Strip Mills. The multitude of factors that must be considered in performing a complete analysis for the roll purchasing process will be discussed. Models for both Hot Strip and Cold Mills will be presented. Examples where traditional analysis can lead to expensive, incorrect decisions will be presented.

Oct 30, 2017

By Sataev IS, Malinovskaja ND, Otrozdenova LA, Knodov NV, Maximov II, Kuznetzou OK

The technology of flotation recovery of silver from the residue of a zinc plant is described. The peculiarity of this technology is a preliminary pulp conditioning in sodium chloride solution in the presence of aluminum metal under high temperature. In this process the silver is converted to the metallic phase and then floated with the usual sulphydryl collectors. A variant using a combined technology is also described, in which before flotation is performed about 50 per cent of silver is leached. The total silver recovery with the combined technology comes up to 90 - 94 per cent.

Jan 1, 1993

By Johannes Münzer

Regeneradores são elementos importantes em uma usina siderúrgica. Eles são os responsáveis pelo aquecimento do ar de sopro aplicado no alto-forno a partir do aproveitamento da energia contida nos gases do processo de produção de ferro gusa. Dessa forma, os regeneradores estão diretamente associados ao processo siderúrgico. Durante do seu ciclo de trabalho, o qual se denomina campanha, problemas podem ocorrer devido a variações operacionais indesejadas, falhas de projeto, entre outros fatores. Num ambiente onde o tempo cessante de um equipamento gera enormes custos, a solução é desenvolver soluções customizadas que minimizem essa interrupção. Cada uma das partes do regenerador tem funções únicas e consequentemente soluções únicas, que visam o reparo no estado da arte com menor custo.

Aug 17, 2017

By Lionel Loïc Limol

Polymeric materials, such as polyurethanes and rubbers, are widely used in the mining industry because of their moderate cost and excellent mechanical properties. Such polymers have been used mainly in transportation (conveyor belt systems and pipes coatings) and screening, for their appreciable abrasion wear resistance. Studies revealed the complex influence of test parameters, such as grit size and applied normal load, on the abrasion wear process for polymers. In this study, the abrasive wear behavior of several polyurethanes and rubbers were investigated at room temperature according to a rotary drum abrasion method (DIN 53516). Wear tests were carried out at 26 cm/s test speed and load value of 5 N and 10 N. Corundum paper grit varying from 60 to 400 mesh were used as an abrasive surface. After each test the mass loss of the pin was recorded and the wear rates were calculated from wear volume. The wear surfaces were investigated by scanning electron microscopy.

Jul 31, 2018

By Breno Totti Maia

Due to operational conditions and locations, BOF suffers variations in important parameters whose effects on the liquid bath are usually neglected. The present paper investigated two aspects: inner BOF pressure and oxygen temperature in the stagnant reservoir. The results have shown that oxygen temperature changes properties like density and velocity but has small influence on jet penetration. The BOF inner pressure has significant influence on jet penetration and creates a new challenge regarding nozzles dimensions considering overexpanding and underexpading jets.

Oct 30, 2017

By Ehsan Alavi, Eren Kusdogan

The City of Toronto’s Coxwell Bypass Tunnel is currently being constructed by North Tunnel Constructors ULC, a joint venture of Jay Dee Canada, C&M McNally Tunnel Constructors and Michels Canada. This project includes construction of approximately 10.5 km of 6.3 meter finished diameter rock tunnel, five 20 meter diameter storage shafts and eleven tunnel connection drop shafts, along with associated deaeration and adit tunnels. This paper describes progress on the project to date and reviews the risk mitigation measures utilized on the project to move the project forward through tough geological conditions during shaft excavation and tunneling phase of the project.

Jun 13, 2023

By Doug Harding

The 3.5 km long Ashbridges Bay Outfall in Toronto, Ontario, Canada was a challenging drive set below Lake Ontario. After a remote machine acceptance due to the global pandemic, an 8 m diameter Single Shield machine launched in March 2021 from an 85 m deep shaft and began its bore in shale with limestone, siltstone and sandstone. During excavation, the TBM and its crew bored a city-wide record of 30 rings in one day, or 47 m of advance. This paper will cover the unique project, from TBM acceptance through to launch, tunneling in difficult conditions, and completion in 2022.

Jun 13, 2023

By Ryan Ward

The Missouri River Intake Screen Structure and Tunnel (MRISST) is one phase of the Red River Valley Water Supply Project (RRVWSP), a vital piece of infrastructure in the state of North Dakota to transport water to drought-laden communities in the eastern half of the state. The scope of work consists of constructing a cofferdam in the Missouri River, mining a 1,600-foot by 74-inch tunnel from a secant pile shaft near the riverbank into a cofferdam, and erecting a 40-foot Y-shaped vertical pipe structure in the cofferdam to support the intake screens. Construction personnel worked in the river through the North Dakota winter to construct the cofferdam and contended with high hydrostatic pressures and raveling sands, gravels, cobbles and boulders while mining the tunnel. Diligent planning and meticulous execution were essential to overcoming the challenges encountered below the Missouri River.

Jun 13, 2023

By Dariusz Kopyci ski, Józef Dorula

The study proves that by introducing the iron powder and disintegrated steel scrap to low-sulphur cast iron still before the inoculation carried out with a conventional graphitising inoculant, the mechanical properties similar to those obtained during the inoculation treatment carried out on cast iron with the recommended high sulphur content are achieved. The said operation increases the number of crystallisation nuclei for dendrites of the primary austenite. In this case, the iron particles act as substrates for the nucleation of primary austenite, due to a similar crystallographic behaviour of the regular face centred cubic lattice The more numerous are the dendrites of primary austenite, the less free space is available in the interdendritic spaces for the formation of graphite eutectic grains, which makes the structure more refined (more eutectic grains) and the mechanical properties higher.

Jan 1, 2016

By Cui Wang, Bing Dai, Haibin Zuo, Jianliang Zhang

The damage mechanism of ductile cast iron cooling stave applied to No.4 blast furnace of Guofeng steel was analyzed through damage investigation in details, the damage causes: hightemperature gas flow erosion, wear of burden, high-temperature ablation, carburizing damage, improper operation on blast furnace, etc. were given out both in macroscopic and microscopic views. It can be obtained from metallographic diagrams that the diameter of graphite nodules increases, the number per unit area reduces, and roundness declines, successively, from cold to hot surface, which are not conducive to stave longevity. In summary, the material for staves manufacture should be better in comprehensive mechanical properties to prolong the service life, thus making blast furnace long campaign.

Jan 1, 2015

By Isadora Almeida Rosa

Aços baixo-carbono com microestruturas ferrítico-bainíticos, bifásico, ou multifásicos têm características apreciáveis para a indústria automobilística, pois, combinam resistência, ductilidade e conformabilidade, permitindo produzir chapas mais finas resultando na redução do peso. Com o intuito de avaliar as características mecânicas e microestruturais obtidas através da variação da temperatura de bobinamento, desenvolveu-se um estudo a partir de um aço baixo carbono com microadição de molibdênio e nióbio, onde se verificou a possibilidade de produzir um aço dual phase na forma de chapas laminadas a quente, em escala industrial. Pode-se verificar que para menores temperaturas de bobinamento, obteve-se melhor desempenho quanto ao aumento da resistência mecânica e garantia de uma alta ductilidade vinculados a um refino expressivo no tamanho de grão da matriz ferrítica em conjunto com uma segunda fase com evidência de ilhas de martensita.

Aug 16, 2017

By Marton A

The Readymix Group have a Quarry Improvement Program - 'Building in Quality (BIQ) which has many parallels to the ICI Explosives' total quality management - 'Quality Improvement Program' (QIP). Both companies have for some time recognised that the 'do it right first time' principle means less wasted effort and materials, that efficiency breeds profitability and so actively promote the quality culture. To install the principles and generate the culture requires considerable commitment and effort from the top down and invariably spreads to the suppliers and sub-contractors. Understanding the component processes involved with the quarry operation, analysis of those processes and gaining a breakdown of the cost of non conformance then allows the astute quarry operator to make the necessary changes to improve the process to realise profits. This paper outlines the steps in such a process and the profitable outcomes of the commitment to continuous improvement at the Nickol Bay Quarry.

Jan 1, 1994

By Theodore B. Counselman

Of all natural resources, iron ore made into steel is the most important both in tonnage and value. The primary reason for the prosperity of the United States in the last century has been its pre-eminence in domestic supplies of iron ore and steel. The depletion of these reserves by two world wars and by the demand for richer blast furnace charges, as well as the constantly growing world- wide demand for steel, has fostered the recent quest for new iron ore mines around the globe. These developments have made a dramatic change in the iron ore picture of the world. It is the purpose here, however, to look briefly at the development of the United States iron ore industry, which has played such an important role in the events leading to the modern day boom in iron ore exploration.

Jan 7, 1965

By John P. Weir

The coal industry is ever changing. This paper discusses some of the problems which must be faced and the projected economic effects. Challenges include a relatively mature technology, a resource base which has deteriorated significantly in some areas, rapidly escalating freight rates, and a constantly changing regulatory environment, wherein reduced sulfur emissions will probably be required.

Jan 1, 1984

By Larry L. Snyder

A compact 4.87 m (16 ft) diameter tunnel boring machine (TBM) is capable of boring a 12.2 m (40 ft) radius curve while gripping horizontally, or vertically, as may be required for the excavation of turnouts. The machine's 5.0 m (16.5 ft) length and a patented machine structure allows steering while boring without causing harmful eccentric loads. An extremely stiff thrust system, rigid front and rear grippers, and the torsional stiffness of a front end electric cutterhead drive combine to create superior machine stability and boring efficiency. A 2.2 m (7.2 ft) diameter prototype, complete with a soft ground shield attachment, was used successfully on a tunnel project in Scotland.

Jan 1, 1989

By Lianhui Jia, Yali Han

"The key technologies of a large rectangular pipe jacking machine with dimensions of 10.12m × 7.27m (width x height) include selection of rectangular cross-section cutting modes, analysis on the strength and stiffness of the rectangular shield, integrated control of electro-hydraulic proportional thrust systems and ground conditioning for excavation are presented in detail in this paper. These key technologies have been successfully applied and verified on site during tunneling, providing a new concept for the building of large rectangular traffic and pedestrian tunnels in urban areas for the future.1 INTRODUCTIONIn the past, underground tunnels were mainly used for drainage, sewage, utilities, metro tunnel, etc. and most of them had circular cross-sections. Recently, as a result of economic development, gradually accelerating urbanization process and diminishing ground space, underground tunnels have already become a new trend for urban underground space utilization. Due to the heavy traffic flow, the demands for rectangular cross-section underground tunnels, such as pedestrian underpass and road tunnel, are increasing gradually.The Rectangular pipe jacking machine (hereinafter referred to as RPJM) was firstly developed in Japan for the construction of metro station, pedestrian underpass, underwater tunnel by-passes, etc. Kazunaki Kawai et al. introduced a RPJM developed and manufactured by KOMATSU in 2002 [1]. Tosikazu Kubota et al. confirmed the rectangular tunnels’ superiority to circular tunnels with regard to larger inner cross-section and lower construction cost in their RPJM construction reports [2]. Compared to circular pipe jacking machines, a RPJM also has the merits of a higher inner tunnel space utilization ratio and is able to excavate in shallow overburden areas. As shown in Figure 1, the effective area of a rectangular tunnel is more than 20% higher than that of an equivalent circular tunnel."

Jan 1, 2016

By Paul C. Schmall, Kevin Clarke, Paul J. Lewis, John M. Stanbury

"The $200M rehabilitation of the more than 100-year-old Gowanus Flushing Tunnel and pumping station located on the Gowanus Canal in Brooklyn, NY required deep excavations in an extremely congested urban environment. The environment posed significant challenges, including: support of excavation for protection of existing structures, excavation through man-made fill while eliminating groundwater inflow due to potentially contaminated groundwater chemistry; discharge and disposal impacts; and potential settlement of surrounding structures. This paper will present the design and construction challenges associated with the construction of a new combined sewer overflow (CSO) chamberwhich included a jet grout bottom seal, to mitigate groundwater inflow during excavation. The foundation for the finished structure also included a unique system incorporating the jet grout bottom seal elements with deep jet grout columns (piles) acting as the foundation system for the final structure. Design and construction challenges included highly variable soil conditions such as man-made fill, obstructions from previous construction, presence of an organic stratum, and conflicts with existing timber foundation piles. The jet grout bottom seal was constructed in loose sands with the deeper jet grout foundation elements extending to bear on a dense sand stratum. Challenges associated with the bottom seal included grid spacing and construction sequencing. Wet in wet sequencing was used to mitigate potential windows in the bottom seal further complicated by shadowing from existing timber foundation piles.Introduction And BackgroundModernization of the Gowanus Tunnel Pumping System required deep excavations in the extremely congested urban environment of Brooklyn, NY. The project location is shown on Fig. 1 and 2. The focus of this paper is to present the design and construction challenges associated with the support of excavation, control of groundwater, and ultimate foundation support for the combined sewer overflow (CSO) bypass chamber extension. The project site was tightly constrained by adjacent, active roadways and underground utilities, as well as residential and industrial structures. Therefore, excavation support was required to limit ground movement and maintain the integrity of the surrounding facilities. Excavation depths to as much as 16 ft below ground level, 8 ft below groundwater, required that seepage and groundwater be controlled so as to minimize pumping and disposal of groundwater and maintain the surrounding groundwater levels to avoid potential settlement of adjacent roadways, utilities, and structures. In addition, the subsurface conditions required that the proposed CSO bypass chamber extension be supported on a deep foundation to avoid differential and total settlements that may be detrimental to the existing and expanded structure. A plan view of the existing CSO bypass chamber and the proposed extension is shown on Fig. 3."

Jan 1, 2016