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By GRANT COLLIGAN, BROCK O’KELLEY, Corby Anderson

With the world’s ever-growing push to expand technological capabilities, the need for specialized materials including rare earth elements has exploded. One source of rare earths found in the United States is bastnaesite, a rare-earth-bearing fluorocarbonate, mined at the Mountain Pass Mine in California. To increase production, it has been essential to optimize existing processes and create new ones to capture current reserves. This paper presents the results of a research program conducted to expand the understanding of the bastnaesite leaching system. With the help of prior knowledge and thermodynamic calculations, a novel single-stage hydrochloric acid leach system was created to optimize the extraction of rare earths from bastnaesite. Historically, this extraction has entailed the use of a two-stage leach system involving a high-temperature hydrochloric acid leach followed by a caustic crack. We ran a series of single-stage leach experiments by reacting locked-cycle flotation concentrate with hydrochloric acid to test common leaching parameters. The results of these single-stage tests showed significantly higher rare-earth recoveries than the reported recoveries of the historic two-stage caustic crack processes, all while decreasing the number and amount of reagents needed.

Feb 1, 2023

By A. T. GRIFFIS, R. J. GRIFFIS

A large magnesite-talc body is locared in Delora Township, 11 km sourh-southeasr of Timmins, Onrario. The deposit occurs in part of an Archean greensrone belt dominated by volcanic and sedimenrary rocks and large bodies of ultramafic intrusions. The magnesite-talc zane is abour 1800 m long, has a maximum width of 300 m and has been drilled ro 120 m below surface. Chemical analyses of rhe main carbonate zane average 20 ro 28% soluble MgO (magnesia), 5 ro 6% rota/ iron oxide and less rhan 0.1 % CaO (lime). Mineralogically, the zane consists of approximately 54% magnesite, 28% rate, /5% quartz and 3% hematire. Perrographic srudies suggest that rhe various assemblages of magnesite, rate, quartz and serpentine were derived from a parenr serpenrinire (after dunire). An early carbonitization stage, which produced a high-magnesite, low-talc assemblage, preceded a farer decarbonitizarion stage, which formed rhe main magnesite-talc assemblage. Despite a favourably low calcium oxide content of rhe magnesite-talc rock, considerable iron in the magnesire /at rice has limited the quality of the beneficiared product: rhe besr flotation concentrate to dare yields 92 to 94% dead-burned MgO. Experimen- I L t r i i c:~:.•-4- -------- ? -_;> ,•----1---- ta/ work continues on finding a process whereby high-purity magnesia can be produced on a commercial scale.

Jan 1, 1984

By H. W. McQuaid

IT IS usually assumed that chemical specifications are sufficient for steel to be used for case carburizing, and if the steel analyzes within the ordinary limits specified for steel for this purpose, no difficulty traceable to the steel used should be encountered in obtaining satisfactory results in the case carburizing and hardening. Much work has been done to determine the effect of various alloying elements on the rate of carbon penetration, etc. but, to our knowledge, little if anything has been published in regard to the effect of the quality of the steel on the final results in the hardening of case-carburized steel parts. The writers believe that the structure of the case both before and after quenching is greatly affected by the actual condition of the steel itself as made, and that for good results in the case-carburizing and hardening departments, the steel should be of the best possible quality as regards non-metallic impurities. It is the purpose of this paper to prove that the presence of excess dissolved oxides in the steel, as made in the melting furnace, affects permanently the results obtained in carburizing and hardening and that it is possible that the presence of dissolved oxide can result in total unfitness of low-carbon steel for, case hardening purposes. When races and rolls for roller bearings are made from a low-carbon steel, case carburized and hardened, it is of primary importance that the results of this treatment be of the highest quality. It is necessary, therefore, that in the case-carburizing work each detail be rigorously checked to avoid any defects which would cause the loss of much time and material. The case carburizing with which this paper deals was done in under-fired oil furnaces. The temperature of each furnace is controlled by means of a platinum platinum-rhodium thermocouple, in connection with a potentiometer indicator and potentiometer recorder. The temperature of each furnace is registered every 15 min. by an operator, who is continually checked by the automatic recorders.

Jan 2, 1922

Incidental to the progress of a geological survey of the Kalgoorlie goldfield during 1927 - 1928 a number of specimens of telluride minerals were obtained, chiefly with the help of Mr F G Brinsden, general manager of the South Kalgoorlie mine, and Mr Ernest Williams, general manager of the Boulder Perseverance mine. This collection was supplemented by a number of small specimens, including the rare copper telluride, which were collected and preserved from the Kalgoorlie mine by Mr A E Paton, and also by a few miscellaneous specimens from the collection of MrS F C Cook, of the Palace Hotel, Kalgoorlie.An extensive knowledge of the rare tellurium-bearing minerals was compiled during the last century from occurrences in Transylvania and Colorado. The recognition of different species has been based on chemical analyses and crystallographic measurements. In a few species there has been an absence of crystalline form, and these, together with the discoveries in this century of rickardite and 'weissite', muthmannite and empressite, have depended chiefly on the chemical analysis for identification. On the other hand, the crystalline form of nagyagite and stiitzite has been described in detail, while their precise chemical formulae were doubtfully defined.The announcement of the occurrence of tellurides at Kalgoorlie by A G Holroyd in the Kalgoorlie Mine on 29 May 1896, followed by their discovery in comparative abundance, stimulated the further study of these minerals. In this locality there is a general absence of well-formed crystals, and the knowledge gained has been confined to the record and description of previously known, but exceedingly rare, species.No new species has been recorded, but the intimate association of various species resulted in early description of two supposedly new species, kalgoorlite and coolgardite. These have been discredited since the investigation by L J Spencer in 1903, based on a collection of specimens donated to the British Museum.Spencer's list of species at Kalgoorlie comprises calaverite, sylvanite (or krennnerite), petzite, coloradoite, 'and altaite, and does not include hessite, previously mentioned by Krusch. In 1912 melonite and a copper telluride were added by J A Thomson and the presence of hessite confirmed. In 1912 there also appeared a full and detailed account by E S Simpson on behalf of the WA Geological Survey, which embraced his earlier notes on the tellurides, and which represents the state of our knowledge of the Kalgoorlie minerals, practically as far as can be attained without the use of the reflecting microscope.The position has been stationary for about 18 years, and it was thought. that the best use to which the present collection of tellurides could be devoted was an attempt by mineragraphic methods to study the mineral relationships, not only of the tellurides among themselves, but also to gold and other associated minerals. The precise mineral content and relationships become a factor of added importance with the development of flotation methods of treatment at Kalgoorlie.Moreover, the study would supplement the description of the ore deposits of the Boulder Belt that has recently been published.

Jan 1, 1994

By H.E. Brauer

Among the zinc base alloys used for casting in metal moulds, pnrticularly die casting, those alloys containing aluminum usually together with copper, are probably the most widely used. The reason lies in their desirable mechanical properties and the fluidity and absence of hot shortncss which facilitate ca,sting. Objection to the use of these alloys may be raised on account of the rather frequent instances of failure of a type variously described as disintegration, exfoliation and intererystalline corrosion. In all cases which have come to our kno~vlcdge where the conditionsof service were known, failure has occurred upon cxposurc to moisture and heat varying from a hot moist atmosphere to lligh pressure steam. RIoreover, the alloys described in all such roses contain impurities or alloying metals which the present authors have found to have enormous accelerating effects on intererystalline oxid:~t'ion in zinc-aluminurn alloys. Thus Williams1 experimented with an alloy containing a large percentage of tin exposed in Cuba. Baucr2 reports failure of a boiler plug containing over 1 per cent. of impurities, doubtless lead for the must part, and Rawdon's3 examinations were madc on an alloy containing 0.1 per cent. lead also exyosctl to thc Tropics. No thorough investigation of the nature and cause of this type of failure has been made heretofore, so far as the authors are aware, although Rawdon correctly classified it as internal oxidation. We have, therefore, carried out this investigation in order to det'ermine the exact nature of this phenonienon and the effect of other metals present as impurities or intentional additions in accelerating or retarding it. In the appendix we include a considerable amount of data which may be valuable in selecting an alloy combining good physical properties with high resistance to oxidation. At the time this work was undertaken the best available equilibrium *Investigator, Metal Section, Research Division, The New Jersey Zinc Company. 'H. W. Williams—Jour. Am. Inst. of AIet,als, Vol. 11, p. 221 (1917). 2o. Bauer—ZeiL, fiir i'vletall Kunde, Vol. 12, .No. 7, pp. 129-31 (1920). 3H. S. Rawdon—Trans. Am. Elcctrochcmic.al Society (1921).

Jan 1, 1923

By P. C. Lightfoot, J. M. Duke, A. J. Naldrett

"The segregation of magmatic sulphides from mafic and ultramafic silicate magmas, in many circumstances, leaves the magma with a lower-than-normal Ni/MgO ratio, which is characteristic of both lavas erupted from the magma chamber and olivine crystallizing within it. Two end members of the segregation process are discussed; i) batch segregation and ii) fractional segregation.In the former, the critical factor is the magma/sulphide ratio. Computer modelling suggests that where this ratio has been less than 1000, the magma will be recognizable as anomalously low in Ni, due to sulphide segregation, and thus a good target for exploration. In fractional segregation, the critical factors are the proportion of sulphide to silicate being segregated and the degree of fractionation.Samples believed to represent the liquid portion of komatiitic lava f lows from a series of unmineralized sequences in the Abitibi greenstone belt, Canada. Belingwe belt, Zimbabwe, and Barberton Mountainland, South Africa coincide with the sulphide-free fractionation model. They are in marked contrast to samples from the ore-bearing districts of Kambalda and Scotia. Western Australia in which distinct Ni depletion, corresponding to fractionation of olivine plus sulphide in a ratio of between 100 and 200:1 is recognizable. Ni-depleted olivines also mark the sulphide-bearing Dumont intrusion of the Abitibi belt.The Moxie intrusion of northern Maine has distinctly Nidepleted olivines, as does the nearby and petrologically related Katahdin body. In both of these intrusions, the composition of the olivine allows reasonable predictions to be made of the Ni tenors of sulphide showings within them. At Katahdin, the Ni depletion is so widespread that little hope is help out for the presence of economic concentrations of sulphide. At Moxie. the olivine compositions suggest that the best chance of economic sulphides lies in the southern lobe of the intrusion.Ni-depleted olivines also characterize certain rock units within intrusions of the Insizwa complex, Transkei, Southern Africa. Many millions of tonnes of Ni have apparently been removed by sulphides from these rock units, many more than are contained within the single mineralized occurrence so far identified at Waterfall Gorge."

Jan 1, 1984

By H. E. Brauer

Among the zinc base alloys used for casting in metal moulds, pnrticularly die casting, those alloys containing aluminum usually together with copper, are probably the most widely used. The reason lies in their desirable mechanical properties and the fluidity and absence of hot shortncss which facilitate ca,sting. Objection to the use of these alloys may be raised on account of the rather frequent instances of failure of a type variously described as disintegration, exfoliation and intererystalline corrosion. In all cases which have come to our kno~vlcdge where the conditionsof service were known, failure has occurred upon cxposurc to moisture and heat varying from a hot moist atmosphere to lligh pressure steam. RIoreover, the alloys described in all such roses contain impurities or alloying metals which the present authors have found to have enormous accelerating effects on intererystalline oxid:~t'ion in zinc-aluminurn alloys. Thus Williams1 experimented with an alloy containing a large percentage of tin exposed in Cuba. Baucr2 reports failure of a boiler plug containing over 1 per cent. of impurities, doubtless lead for the must part, and Rawdon's3 examinations were madc on an alloy containing 0.1 per cent. lead also exyosctl to thc Tropics. No thorough investigation of the nature and cause of this type of failure has been made heretofore, so far as the authors are aware, although Rawdon correctly classified it as internal oxidation. We have, therefore, carried out this investigation in order to det'ermine the exact nature of this phenonienon and the effect of other metals present as impurities or intentional additions in accelerating or retarding it. In the appendix we include a considerable amount of data which may be valuable in selecting an alloy combining good physical properties with high resistance to oxidation. At the time this work was undertaken the best available equilibrium *Investigator, Metal Section, Research Division, The New Jersey Zinc Company. 'H. W. Williams—Jour. Am. Inst. of AIet,als, Vol. 11, p. 221 (1917). 2o. Bauer—ZeiL, fiir i'vletall Kunde, Vol. 12, .No. 7, pp. 129-31 (1920). 3H. S. Rawdon—Trans. Am. Elcctrochcmic.al Society (1921).

Jan 1, 1923

By Claudia Gasparrini

"The ore microscope and electron microprobe, two common instruments for academic research, have not been used to full advantage in the Canadian mining industry, perhaps because they are not readily available to most mining companies.The present paper gives a description of the two instruments and of the manner in which, when used together, they contribute to the identification and description of mineralogical and metallurgical samples, and reviews the applications, to . date, in the mineral industry.The metallurgical applications can assist in determining the best separation technique for a particular metal or other economically important element, can provide explanations for poor recovery and/or liberation, can be used to determine theoptimum concentrate grade and can indicate environmental problems that may arise from the extraction process.In certain cases, the use of the two instruments may assist in the evaluation of new mineral deposits and in the determination of the origin of mineralization.IntroductionThe ore microscope and electron microprobe, two widely used instruments in universities and other research institutions, have not been exploited to their full potential by the Canadian mining industry.High-magnification, high-resolution ore microscopes, owned by most Canadian universities and government mining branches, are not widely used by mining organizations. The situation is very much the same with the microprobe. The geology departments of several major Canadian universities have easy access to this instrument. Fifteen of them, to the author's knowledge, own one and a few have already acquired or are planning on acquiring a second and later model. The mining branches of the Canadian Government have similar easy access to microprobes, as at least four of these instruments are available to them in Ottawa alone. The mining companies, on the other hand, except for the few larger ones which have their own research laboratories, have not been able to take advantage of electron microprobes in the past.This failure to exploit good ore microscopes and electron microprobes has been mainly due to a lack of expertise in the use of the two instruments for the study of metallurgical problems related to ore mineralogy. Government institutions providing research and test work to the industry are few in number, and are not always equipped with these instruments or are not geologically-oriented. Information provided on a consulting basis by universities and by government mining branches is normally limited, and frequently is not oriented to the needs of the mining company."

Jan 1, 1980

By William Gleason

"What will the mine of the future look like? Will it resemble the current operations that supply the world with the products it needs to function, or will it be something totally different? How will the demands from the communities that are most affected by mining operations shape the mine of the future? How will technology and innovation be used to help miners reach deposits that are getting harder to access, and what are the dangers of this new world? Who will work at the mine of the future, and what will that work look like?These are questions that do not yet have definitive answers, but they are questions that need to be asked for the mining industry to move into a future that is as filled with uncertainty and challenge as it is with promise and opportunity.On Feb. 16, the 2015 SME Annual Conference and Expo and the 117th CMA National Western Mining Association conference began with a keynote address, "The mine of the future: Forecasting opportunities and challenges for the global mining industry." Panelists from five sectors of the mining industry participated in the session, which was followed by the conference and expo, that in large part, were also trying to answer the question of what the mine of the future will look like.In coming months, Mining Engineering will continue the discussions and answer some of the questions submitted by members of the 2,000-person audience during the keynote address in a monthly feature called, "Predicting the Mine of the Future," and in Thought Leaders Podcasts with the panelists and other industry experts."

Jan 1, 2014

By R. A. Meyer

A table that greatly simplifies determination of metastable transitions in mass spectra has been prepared. All the mathematically possible metastable transitions of any compound whose molecular weight lies between 26 and 150 can be determined from the table without calculation. The method of utilizing the table is described, using selected peaks from the spectrum of normal butane for illustration. In the mass spectrometer, ions are formed in the isatron and accelerated through a series of slits. Most of these ions reach the collector without further change, but a few dissociate in transit to form new ions. These ions appear in the mass spectrum at neither the mass--to-charge ratio (m/e) of the original ion nor that of the new ion. A formula that relates the appearance of these new ions to the ion from which they were formed is: [ ]

Jan 1, 1957

By Melvin A. Jennings

Ion-exchange technology for precious metals recovery is at a turning point. Some very exciting technology has been developed in the past five years which should lead to commercialization of the process. Ion-exchange will allow not only for the recovery of gold and silver, but also will allow for the recovery of cyanide form plant tailings. This process may soon be competitive with Merrill-Crowe for silver and once this occurs, it will become the process of choice.

Jan 1, 1991

By T van Niel, M Trefry, B Baker, I Rea, A Hawdon, D McJannet, D Boadle, R Fandrich, A Littleboy

Many open cut mines extend to depths well below the natural water table level with constant dewatering required to maintain operations. When mining activities cease the groundwater starts to fill the void and pit lakes form. The resultant pit lake is directly connected to the surrounding water table and understanding the hydrological and chemical evolution of these lakes is important for minimising environmental impacts. In Western Australia alone there are currently 1800 mine voids and more than 150 mines operating below the water table (Johnson and Wright, 2003). In conjunction with BHP Billiton Iron Ore, CSIRO has been undertaking research to measure and model rates of evaporation from pit lakes in the Pilbara region of Western Australia. Extreme high temperatures and low humidity ensures that this region experiences the highest evaporation rates in Australia.CITATION:McJannet, D, Hawdon, A, Boadle, D, Baker, B, van Neil, T, Littleboy, A, Trefry, M, Rea, I and Fandrich, R, 2016. Measurements and modelling of evaporation from abandoned mine pit lakes, in Proceedings Life-of-Mine 2016 Conference, pp 106–109 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jun 28, 2016

By F. E. Kottlowski

Widespread high-calcium limestones in New Mexico region are low -in magnesium, but some units include shale interbeds deleterious for sulfur removal usage. Thick limestones in Mississippian Escabrosa, Lake Valley, and Leadville, Pennsylvanian Madera and Hermosa, Pennsylvanian-Permian Horquilla, Permian Hueco and Capitan, Cretaceous U-Bar, and some Cenozoic travertines are high-calcium units. Significant outcrops are in mountains of southwestern, south-central, central, southeastern and north-central New Mexico, southeastern Arizona, southwestern Colorado, and northwestern Chihuahua. Coal-fired powerplants are mainly in northwestern New Mexico and eastern Arizona, thus transport is mainly by railroad.

Jan 1, 1994

By William Gleason

"Ed Rapp is among those who believe in the saying that necessity is the mother of all invention. Rapp is the president of Caterpillar’s mining group. As such, he is tasked with leading the world’s largest mining equipment maker, and its customers, through this time of lower commodity prices, while also positioning his company to be prepared for better days that lie ahead.The decade-long mining boom fueled by growth in emerging markets and demand for commodities that led to record prices for some metals paused in 2008 with the global financial crisis. However, according to Rapp, thanks to stimulus packages around the world, and in particular the stimulus from China that was focused on infrastructure, the mining sector recovered fairly quickly, and from 2010 to 2012, mining was strong.And then the stimulus stopped. Credit dried up and global growth began to slow down and, in the three years since, commodity prices have declined by an average of 60 percent. Caterpillar expanded during the boom, acquiring Bucyrus, and investing billions into the mining sector. It has felt the pinch of the slowdown as much as any mining company in the world. These pages, and those of other mining publications as well as mainstream media, have been filled with stories of doom and gloom about the industry. But Rapp, while acknowledging that the difficult times have been painful, also said Caterpillar sees opportunity in the slow down and reaffirmed his company’s commitment to the mining industry as absolute."

Jan 1, 2014

By J. Rajek

The novel multi-component, multi-particle, multi-phase precipitation model developed recently is used to predict the precipitation kinetics in complex 9-12% Cr steels investigated within the European COST 522 project. These steels are used for tubes, pipes, casings and rotors in USC (ultra super critical) steam power plants for the 21st century. In the computer simulations, the evolution of the precipitate microstructure is monitored over the entire production heat treatment starting with the casting process, including austenizing, several annealing treatments and in-service conditions. The main interest lies on the concurrent growth and coarsening interaction of different types of precipitates. Keywords: Precipitation kinetics, heat treatment, power plant steels, simulation

Jan 1, 2003

By WM. G. Heeley

This paper will describe the experience gained and explain the deductions made from the phenomenon of the great squeeze which occurred at Brule Mines. The first indication of the commencement of the squeeze was the breaking of posts on the high-side rib of the slope. At first we thought this was due to a lateral pressure only, and we renewed the broken posts with new ones, the result being that the new posts also were soon broken. A noticeable bending and breaking of the collars occurred, with a corresponding reduction in the height of the haulage slope. These symptoms were also evident on the counter above the slope, indicating that the trouble was of an exceptional nature. In the meantime, we had concentrated a large force of repair men, renewing broken timbers and brushing the roof and floor, but in spite of all our efforts we could not overtake the damage being done. Our next problem was to find the cause of this trouble. We were in a new basin of coal (No. 2) which had only been opened a few months, as we had worked the previous four years in another basin (No. 3) where no such trouble as this had ever been encountered. Naturally our first thought concerned the adequacy of the size of the pillars. We had worked in the No. 3 south basin for the previous four years. without any such experience, with 60-feet pillars between slope and counters; whereas we had established 100-foot pillars in the No. 2 south basin between the slopes and counters with an 80-foot pillar between counter and first line of cross-cuts, and 100-foot pillars between the breasts.

Jan 1, 1924

By David S. Cronan

The traditional method of deep sea manganese nodule exploration is to conduct grid survey and sampling on successively finer scales until a suitable deposit has been delineated. Clearly this is both time consuming and ultimately self-defeating if large areas of the ocean floor are to be explored on a human timescale. A conceptual deductive approach would be preferable if one could be found, as it would aim to outline areas of potentially economic nodules on the basis of easily measurable oceanographic parameters. An attempt to achieve this aim in the Central Pacific is outlined below. Nodule Distribution in the Central Pacific Ocean Maps of ore grade nodules in the Central Pacific show that they are confined to two zones trending roughly east-west which are well separated in the eastern Pacific but which tend to converge towards 170-180ºW. They follow the isolines of intermediate biological productivity in the surface waters, strongly suggestive of a biological control on their distribution. Within these zones the nodules preferentially occupy basin areas. Thus they are found in the Penrhyn Basin, Tokelau Basin, Central Pacific Basin, Clarion Clipperton Zone and Tiki Basin. Nodules in all these areas have features in common and are thought to have obtained their distinctive composition by similar processes.

Jan 1, 2003

Jan 1, 1882

By Steve Dillingham

The origin of the written blasting log or shot report can likely be traced back to the earliest annals of blasting and record keeping. These records were, for the most part, a way of checking inventory, production progress, or billing, and not necessarily designed with the intention of being used as a legal document in a court of law. As our litigious society has evolved to include far reaching regulatory requirements, however, the blasting log has developed to support and aid in the defense of the common blaster from blasting lawsuits by providing a comprehensive written report of his or her actions.

Jan 1, 2002

By N. J. Rarmrez, C. Perez, J. D. Calderon, L. Lopez

"Among the thermal characterization of any material, one of the variables to know is the coefficient of thermal conductivity because this value can tell how much heat passes through the material and if the material could be used as an isolator. In order to determine this parameter is required some kind of special equipment and controlled conditions which implies high costs in the development of tests. The present paper proposes a design of a low cost measurement system in order to determine this coefficient with the lower possible error. This equipment was thought for companies or labs where they do not have the economic resources or the infrastructure (environmental controlled labs, heat flux transducers, human resources with specialized knowledge) to do this kind of tests.The system is based on ASTM C 518 - 04 [l] and integrated by two plates (one that contains a thermal resistance and which temperature is controlled by a closed loop controller and the other one with a route of water flow). The thermal resistance is actuated by a relay and a supervisor system checks the total time the relay is on in order to determine the effective power applied to the system. The contact faces of the plates contain a group of temperature sensors connected to a data acquisition system that process and record the temperature in each measurement point.With the power applied to the system, the measurement of temperatures and a process of calibration is possible to determine the coefficient of thermal conductivity. IntroductionWithin the thermal characterization of a material of known variables is the coefficient of heat transfer, since this value can know the amount of heat the material is capable of transferring or isolating. To determine this ratio requires specialized equipment and controlled conditions, which implies high costs in the development of a test. This article proposes a design of a low cost machine to allow closer this coefficient with the least possible error. This equipment was done thinking about companies that do not have the infrastructure (laboratories, controlled environment, heat flux sensors, human resources expertise) and financial resources to conduct these tests."

Jan 1, 2011