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By Phil R. Ames, Anil K. Ray, Murali M. Gadde, John A. Rusnak

"Many factors can be responsible for coal mine roof falls including, mining geometry, stress conditions and local geology. In the Illinois Basin coal mines, roof instability is commonly attributed to the low strength of the immediate roof, which is also moisture sensitive. Recently, in order to understand the mechanisms of roof instability, numerical modeling has often been the preferred ground control analysis tool. Since roof materials can exhibit significant spatial variability, such modeling results may not represent every section of the mine. At the same time, it is not feasible to carry out numerical modeling for the full range of geological and mining conditions possible at a mine. Operationally, it is more convenient and highly practical to have a simple map that depicts the expected roof conditions, determined through either complex numerical models or simple empirical analysis throughout the reserve area. In this paper, a case history is presented that shows how a combination of simple empirical analyses of geologic data and past ground control experiences at a mine can be synthesized into a roof stability map, which can then be used to forecast future ground conditions. The usefulness of such a roof stability map will be examined in terms of the predicted and actual ground conditions encountered over a period of more than a year after the map was created.INTRODUCTIONA roof fall, which can result in fatalities and lost work time, is considered to be one of the most severe ground control hazards in underground coal mines. In general, there are many factors responsible for roof falls, including mining geometry, stress conditions and local geology. In the Illinois Basin, roof falls are commonly attributed to the weak nature of immediate roof rocks, and some superficial falls may be initiated due to moisture sensitivity. Some unstable areas also occur when the immediate roof is highly laminated.Numerical modeling is a useful tool used to understand the mechanism of a roof fall by incorporating site-specific parameters. In the past, numerical modeling has been used to explain the mechanism of roof falls as well as simulate· roof falls and cutter behavior, but such work had been strictly site-specific (Gadde and Peng, 2005; Ray, 2009). Because of the restrictions imposed by the input parameters, numerical modeling results cannot represent the entire mine. In the real world, mining conditions vary from place to place, and even in a single panel, modeling results valid at one site may not apply at another nearby site. At the same time, due to the lack of input data pertaining to rock characteristics and in-situ stress variations, it is not practical to carry out numerical modeling for each local area of the entire mine site. In addition to these difficulties, mine operators prefer simple tools to understand the ground conditions at their mine sites. One simple and commonsense based tool is the roof stability map. A stability map not only synthesizes the geologic and stress analysis data empirically, but it can also be used to predict future ground control issues at that mine. Because of this practical appeal, stability maps are more likely to gain mine operators' acceptance and be used in their planning operations. In this paper, a case study is presented on the development of a 'Roof Stability Map' that was principally used for roof fall prediction for a mine in the Illinois Basin."

Jan 1, 2010

By Laurent Cohen

Since the 1970s, Solvent Extraction (SX) in hydrometallurgical processes has been a key enabling technology in the production of high-purity metals. Examples include copper, rare earth oxides, uranium, cobalt and nickel. Notwithstanding incremental improvements in extractant formulations, few breakthroughs can be recounted in this industry outside of the initial amine-, oxime- or phosphine-based reagent chemistries. However, the advent of lithium-ion batteries and their stringent requirements for critical materials (lithium, cobalt and nickel) offer new challenges and opportunities for SX. Solvay recently introduced a new extractant for lithium, CYANEX® 936, and developed unique modeling software capabilities in cobalt/nickel separation using CYANEX® 272, zinc SX using DEHPA® and rare earth separations using CYANEX® 572. This paper discusses trends in SX and provides insight on processing of critical materials essential to energy sources. It also summarizes the technical and economic benefits based on extractant selection and advances in modeling.

By Filippos Patsiogiannis

Laboratory size (5 kg) aluminum killed low carbon steel melts were desulfurized with synthetic fluxes in zirconia crucibles. The sulfur, oxygen, aluminum, silicon, and manganese contents in the melt were determined as a function of refining time and temperature. With a good argon shield and synthetic flux cover, melt reoxidation was not observed. Sulfur removal followed first order reaction kinetics. The effectiveness of calcia saturated calcium-aluminate (12CaO.7Al2O3) based fluxes in desulfurizing the steel melts was evaluated. The effects of initial sulfur level of the melt, weight of the flux (slag), and additions of tellurium, fluorspar, and barium oxide to the melt on the kinetics of desulfurization were also studied.

Jan 1, 1993

The Savage River open cut magnetite mine is located in rugged terrain in densely rain forested northwest Tasmania. The mine and concentrating plant are both in the Savage River valley. Pickand Mather Incorporated (PMI) operated Savage River as an open cut magnetite mine between 1966 and 1996. Acid rock drainage (ARD) was first noted in the last ten years of the operation, leading to elevated concentrations of heavy metals downstream of the mine. When operations ceased in 1996, PMI returned the mine to the Tasmanian Government along with a remediation fund of $11.4 million. At that time, the assessed cost of remediation was in excess of $120 million. As a result of the ongoing ARD contamination and to facilitate both a new operation and effective remediation, Goldamere Pty Ltd negotiated an agreement with the Tasmanian Government in 1996, which resulted in the Goldamere Act and the Goldamere Agreement. The agreement has allowed Australian Bulk Minerals (ABM) to remediate the Savage River mine in conjunction with the Tasmanian Government while re-invigorating a previously closed mine by providing ABM with an indemnity against past pollution. ABM can configure its mine and waste planning activities to maximise remediation benefits without fear of future litigation for past mistakes. The effect to date has been the development of a long-term strategy to remediate the Savage River and short-term remediation works such as water management, which provide benefits to the ecosystem. After five years, the Savage River is no longer significantly impacted by ARD for 30 kilometres downstream and trout are now reported within the reaches of the mining lease. The arrangements between ABM and the Tasmanian Government are an example of a genuine WIN WIN situation where co-operative environmental management of the site results in significant improvements and where the æregulatorÆ and the æminerÆ are working together to achieve mutually beneficial goals. The end result is a significant benefit to Tasmania.

Jan 1, 2003

By T. Panhorst

Evaluation of through-deck blasthole sample reliability at the Lone Tree gold mine revealed a non-systematic bias in the sampling system. Ore is primarily hosted within the Powerline fault zone. Clay gouge, present in the fault zone and typically enriched in gold content, forms agglomerates during blasthole drilling leading to a segregation error during sampling. Replicated samples split from blasthole cuttings piles show through-deck samples to be either significantly enriched or depleted by 1.5 standard deviations or more from the mean gold content of their respective cuttings pile quality of through-deck samples correlates strongly with quantity of clay present.

Jan 1, 1999

By T. A. Gray

The environmental liabilities of coal waste disposal sites can have a major impact on a mining project's economic viability. Developing a waste disposal site is no longer simply an exercise in completing paperwork to obtain a permit, with the proliferation of environmental regulations in recent years, managing disposal sites now requires design creativity, short term and long term planning and detailed monitoring to maximize the benefits to the mining company. Operating costs and future capital costs for expansion of existing sites, new site development and regulatory compliance should be reviewed periodically and considered in the overall management plan. This paper discusses various management methods that are being employed in the industry to improve waste disposal operations both environmentally and profitably.

Jan 1, 1994

By B. W. Steele

"Dofasco began operations in 1912 as a steel foundry located in Hamilton, Ontario. Today, Dofasco is a fully integrated mill that manufactures hot rolled, cold rolled, galvanized and tinplate steels. Customers include the automotive, construction, tubular, manufacturing, appliance, packaging and steel ser-vice centre industries. Raw steel production and purchased semi-finished steel processed in1994 was 3.5 million net tonnes. Dofasco employs 7300 people at its Hamilton facility.Environmental management at Dofasco is guided by its environment policy and associated commitments. This paper discusses Dofasco’s responsibility for its products as it relates to these commitments. Dofasco is com-mitted to:n the principles of sustainable development that require that activities be conducted in a manner that provides for the present without compromising the ability of future generations to meet their needs. These principles will be integrated into product design, manufacturing and business planning;n managing renewable and non-renewable resources through the responsible application of reduce, reuse, and recycle principles;n minimizing any potential impact of its operations and products on the environment, employees, customers and the community;n continuous improvement of the effectiveness and integrity of our environmental management systems;n developing understanding among all employees about their responsibilities, and assigning the necessary authority; andn meeting the standards set by relevant legislation and international agreements through participation with governments and the diligent application of economically feasible and scientifically sound methods and technologies."

Jan 1, 1996

By I. Silin, H. Wotruba, J. Huben, A. Ognyanova

"With increasing shortage of raw materials, the beneficiation of ultra-fine ores will play a larger role in the near future. Many established process technologies do not yield satisfactory separation results for ultra-fine materials. Without selectivity, high-grade concentrates cannot be produced. The material at hand is a taconite which had to be ground to d(90) = 25 µm to guarantee liberation of the iron oxides. The comminution was done by High Pressure Grinding Roll (HPGR) and resulted in smooth surfaces and clear grain boundaries. This is an indication of selective grinding and mineral liberation. Further processing steps included selective desliming, magnetic separation as well as reverse flotation. INTRODUCTION During the last centuries, the processing of iron ores became increasingly important. The coarse-grained, so-called lump ores that are ready for direct usage in blast furnaces without further processing are becoming gradually less abundant. The processing of ultra-fine-grained ores, which in addition require a complex ore beneficiation due to the composition of the material, will progressively gain relevance with increasing resource shortages in the future (Arvidson, 2013). The term “ultra-fine” does not hold a precise definition in mineral processing. In this paper, “ultra-fine-grained” ores are defined by the required grind size for full liberation smaller than 20 µm. Many established mineral processing technologies do not yield satisfactory separation results for ultra-fine materials. Thus, they are limited in their application to produce high-grade concentrates suitable for sintering and pelletizing for direct reduction processes. The production of a high-grade iron concentrate (over 68% Fe) with low silica content (under 2.5% SiO2) is possible from both magnetite and hematite containing ore. In addition to the mineral processing technologies (magnetic and gravity separation, flotation), technologies for the liberation of fine-grained iron ores need to be developed and improved. In contrast to the conventional wet grinding circuit by means of tumbling mills, several future trends in dry and wet grinding and regrinding are already in use. These include technologies such as vibration mills (Palla®Mill), stirred media mills (Vertimill®), vertical roller mills (Loesche) and high-pressure grinding rolls (HPGR) (Jankovic, 2015). This study preliminary investigated the mineral processing of a low-grade, ultra-fine-grained, complex iron ore in a laboratory scale after dry grinding by HPGR to 90% < 25 µm without consideration of the grinding, milling, energy and classification cost."

Jan 1, 2018

By B. G. Kelley

The MIDREX® Direct Reduction Process was developed during the 1960s by the Midland-Ross Corporation, which had pioneered shaft furnace technology and stoichiometric gas reforming for use in processing minerals. In 1969, the first MIDREX® Direct Reduction Plant was built in Portland, OR. Since then, 49 additional modules have been sold in 18 countries. For the last ten years, over 60 percent of the world&apos;s direct reduced iron has been produced in MIDREX Plants. During the quarter century since commercialization, many technical improvements have been made, including larger shaft furnaces, in-situ reforming, greater heat recovery, improved catalysts, and hot briquetting. Midrex continues to enhance the technology in the areas of economy-of-scale, energy efficiency, alternate fuels, and raw material flexibility.

Jan 1, 1998

By Achilles J. B. Dutra, Carlos M. Juarez

"The use of thiourea as a gold leaching reagent has been extensively studied by many researchers, and it has proved to be promising for some cases as refractory ores. Otherwise, the recovery of gold from these solutions did not receive so much attention. In this paper the electrowinning of gold in acidic thiourea solutions was studied by voltarnmetry and chronopotentiometry. An adsorption step was detected prior to Au(I) reduction and the diffusion coefficients at 25°C for Au-TU complex and FD were found to be 1.00 x 10.5 cm2 S-I and 1.98 x 10-5 cm2 S-I respectively. At -0.350 V (SCE) a passivation probably due to TU adsorption was observed. For higher overpotentials hydrogen evolution was the main reaction.IntroductionThe use of acidic thiourea solutions for the extraction of gold and silver has shown to be a promising alternative to the traditional process of cyanidation, specially for certain refractory ores (1-3) and electronic scrap (4). In some cases, the industrial scale was reached (1,5). The thiourea leaching of precious metals presents advantages over cyanidation, as faster kinetics, lower toxicity and lower sensibility to base metals; however the costs due to high thiourea consumption impairs its use.The majority of the publications on thiourea processing of gold is on leaching. Many are review papers (5-7). Recently, the adsorption and desorption of the gold-thiourea complex on activated carbon and ion exchange resins have been studied (8-11).Little research has been done on the electrowinning of gold from acidic thiourea solutions, most of it has been carried on the seventies and beginning of the eighties in the former USSR (12-17) and concerned the eletrolytic extraction of gold in tridimensional cathode cells.The present paper concerns the cathodic behavior of the gold-thiourea complex in the presence of formamidine disulfide in order to provide information on the electrowinning of gold from solutions obtained directly from leaching or from an elution process."

Jan 1, 1997

By Iwueze Anaekperechi Rose

The International Labor Organization has declared mandatory adequate provision of safe workplace and safety for all workers in all occupations including the mining sector. Early scientists like Agricola (1559) who studied the health of Miners, found that there are peculiar health problems associated to their work and working environment. This unsafe working condition was one of the major factors that resulted to the Industrial revolution in England and eventually led to the establishment of regulations and laws guiding operations in all workplaces and workers in England and all over the world. Recent studies by Heinrich suggested chains of events of safety issues in the mining sector. Occupational injuries, accidents and ill health have huge social and economic implications on workers, their families and communities. Top mining top issues are respiratory diseases, noise, explosives, ventilation, fire, and explosion. However, one of the principal mechanisms for achieving Occupational Health and Safety (OHS) goals and mapping the future is government regulations of employers. In Nigeria, the situation is not different; mining operations are equally hazardous and have far reaching implications. In 1995 the Ministry for Solid Minerals was established to focus on the development of other categories of mineral products ranging from gold, coal, uranium, and tantalum deposited across the country. Prior to this an Act of Parliament Act Cap 121 of 1946, was in place to regulate amongst other contents mining safety. This was subsequently reviewed following the incidence of Lead poisoning resulting from small scale miners processing gold ore highly contaminated with lead in Zamfara state (northern Nigeria). Hundreds of children died as a result of exposure to lead poisoning, it was clear that the regulations were not sufficient (details to be discussed). However, advances have been achieved in mining engineering since then. A review team was constituted to provide a more stringent law to regulate mining operations in Nigeria. The strategies for mapping the future of OHS in mining engineering will employ amongst others setting and adopting ISO/ILO standards and enforcement; providing technical assistance; and establishing sustainable developmental structures as surveillance and compensation. The management systems approach was also developed as a result of cases of accidents. The accepted international standards guidelines and requirements will be proposed. Furthermore in mapping the future for Mining Engineering, it is suggested that most countries have their own management strategies and legislation to improve safety of workers through greater consistency and efficiency of OHS programs. Some American researchers came up with the Safety Engineering Model. The Australian Mining Council of mineral and petroleum resources after the Catastrophic Maura Disaster developed the National Mine and Safety Framework. In Canada, after the Hillcrest mine disaster in 1914, Allan shaft coal mine catastrophe in 1918, Westray mine explosion in 1992 and other disasters, Occupational Health and Safety Act R.R.O 1990 was sufficiently developed to provide adequate safety conditions and standards. In Nigeria after the disastrous Zamfara lead poisoning, which claimed the lives of hundreds of children due to exposure and lack of appropriate safety measures, stringent measures were developed by the federal ministry of Justice to address and regulate mining process in Nigeria.

Aug 1, 2013

By William Gregg

Recent environmental and workplace safety legislation has Imposed more stringent limits on the amount and type of particulate emitted Into the air. In the past, the mass of particles contained In a volume of air was the governing criteria. Now the size and precise chemical nature of the particulate must be known and controlled In addition to it&apos;s ?mass. Processors of metallic materials have to implement stricter control practices and more efficient control equipment to meet the new regulations. Pulse-Jet dust collector systems are being used to control particulate emissions from various process gas streams. Pulse-jets :are also being used for maintaining a healthy environment In the workplace. this paper will discuss the impact of these regulations, the control techniques used to comply with such regulations, and the equipment needed for compliance.

Jan 1, 1992

By C P. Gravenor

In 1953, a deposit of sedimentary oolitic iron ore was discovered in the Clear Hills area of northwestern Alberta. Since that time, detailed drilling has outlined reserves in excess of 200 million tons of ore grading 30 to 35 per cent iron. Attempts to physically beneficiate the ore to meet blast furnace or direct reduction feed specifications have been, in general, unsuccessful. In 1960, Premier Steel Mills Limited and the Research Council of Alberta jointly sponsored a pilot-plant test at the R-N Corporation at Birmingham, Alabama. About 5,000 tons of ore were treated, and briquettes containing 90 per cent Fe were produced, with 83 per cent recovery. At the same time that the R-N tests were being made, the Research Council initiated a program to produce high-purity powders by chemical methods. Several purification techniques were investigated; hydrochloric acid dissolution of reduced ore was finally adopted. Briefly, the steps involved in this acid process are as follow

Jan 1, 1964

By Liyuan Chai, Qin Liu, Bing Peng, Jia Wang, Qiang Zhang

"Electrolytic Manganese Residue (EMR) was used as the main material to prepare cementing material activator for the utilization of the residue from electrolytic manganese dioxide (EMD) or electrolytic metallic manganese (EMM) production. The effects of chemical activation, thermal activation and mechanical activation on retarding activity and excitation activity of EMR were investigated according to the setting time and activity index of EMR-slag cementing material. The results showed that the EMR exhibited good activating performance after being ball-milled for 18 min and then treated for 1-2 hours at temperature range of 350-450 ?. The optimal properties of cementing material activator were achieved at the weight percent ratio 30 : 3 : 5 of EMR/Ca(OH)2/cement clinker.IntroductionMany hazardous industrial solid wastes such as blast furnace slag, fly ash, steelmaking slag, chromic slag and electrolytic manganese residue [1] are generated n China and their amounts increases every year. The accumulation of the solid wastes during past years is very huge and they could be hardly recycled effectively as a sustainable resource. 2.35 billion tons of industrial solid wastes have been produced up to now [2]. It is estimated that they would exceed 3.3 billion tons by the end of 2015 [3]. On the other hand, the quick development of Chinese infrastructural construction needs more cementing materials. The production of traditional building materials consumes lots of natural resource such as clay and limestone and discharges at least 1 ton CO2 and other pollutants per ton clinker [4]. Therefore, it is necessary to develop new types of cementing materials instead of clinker [5,6]."

Jan 1, 2012

By Clifford S. Gibson

A year ago a paper (1) was presented at the Annual Western Meeting of the Institute regarding silicosis in Ontario mines. It described the whole problem as we see it and discussed the means of prevention. The work and aims of the Technical Silicosis Research Committee of the Ontario Mining Association, and of the Committee&apos;s field engineer, were fully described also and it is suggested that reference be made to this paper in order to have a better understanding of the observations which are presented now. These observations enlarge upon parts of the dust control measures already discussed and tell of general progress in the past year. They concern fifty properties, the majority of the operating mines, which vary in size from the hopeful prospect to established producers yielding 11,000 tons of ore daily. Most of these are gold mines; a few copper-nickel. The ores range from heavy sulphides to siliceous materials and they are mined by many methods from varying types of deposits. The majority of the latter are steeply dipping and all are found in Precambrian host-rocks. Up to the present, die greatest depth to which mining has penetrated is 6,400 feet.

Jan 1, 1939

By John Erikson, Alan J. Lutenegger, Nicholas Williams

"In order to evaluate the level of disturbance produced in clays during installation, a series of single-helix and multi-helix anchors were installed at a test site consisting of a stiff overconsolidated clay crust overlying softer near normally consolidated clay. Field vane tests were then conducted over the top of the helical plates at various depths to determine the undrained shear strength after installation and were compared with undrained shear strength measured in adjacent undisturbed ground. The tests represent the first time that the degree of installation disturbance has been evaluated directly and show that even with perfect installation practice the clay is disturbed as a result of rotation of the helices during installation. The results show that the soil is not completely remolded but that the strength is below the peak undrained strength of the adjacent undisturbed ground. Measurement of the installation torque and the rate of advance are used to define an “Installation Disturbance Factor” which may help to evaluate the quality of the installation by the Contractor and degree of soil disturbance. INTRODUCTIONAn important consideration in the design of Helical Anchors is the degree of disturbance to the soil during installation. This may be especially important for saturated fine-grained soils where the disturbance from installation may produce a reduction of the undrained shear strength. Even though this was recognized as early as 1950 by Skempton, soil disturbance is often ignored by engineers using current design procedures. Field investigations were performed to obtain both directs and indirect evaluation of the degree of disturbance produced by the installation of single-helix and multi-helix anchors in clay and the influence of disturbance on behavior. The investigations involved measurement of torque and advance during installation, load tests performed to determine load-displacement behavior and ultimate capacity and field vane tests performed over the helical anchors to evaluate changes in undrained shear strength as compared to adjacent undisturbed ground. The characteristics of the site and details of the installation are presented. Results of the field vane tests are shown for a number of helical anchor installations and results of load tests are presented. The results indicate that a reduction should be made to the undisturbed undrained shear strength for design and that the reduction may be related to the Sensitivity of the clay and quality of installation."

Jan 1, 2017

By Louis A. Panek

The practice of roof bolting, now recognized as an effective method of support, is based largely on rule of thumb. Among the various applications of bolting, the support of stratified mine roof is by far the most common. The general principles relating to this type of reinforcement are presented in two companion reports; the first describes the function of the bolts, the bolting pattern, and the behavior of bolted roof (1), 2/ and the second describes the design of the models and the theory of the experimental method (2). This report presents a rational method for designing systems of vertical bolts to reinforce horizontally bedded mine roof, developed from model tests. The structure treated herein may be described as follows: The immediate roof, consisting of beds of like material and equal thickness with no bond between them, is reinforced by vertical bolts installed in straight lines across the opening; the case of suspension is excluded because the bolts are assumed not to extend above the immediate roof. The assumption is made that the behavior of the lowest bed approximates that of a rectangular plate clamped along two opposite sides (the ribs). These specifications represent approximately the roof conditions encountered in mining bedded deposits of all kinds - coal, potash, iron ore, etc. Thus, for the design of a roof-bolting system a quantitative solution to the following problem is required: For a roof composed of beds of given thickness and physical properties, how does the support depend upon the length, spacing, and tightness of the bolts?

Jan 1, 1956

By Peter Johnson, David Barber, Lachlan Henderson

"Within underground portions of metro rail networks the traditional approach to a design fire has been to assume a worst credible railcar fire and develop ventilation and egress measures for life safety. This approach is being challenged as a rail network approach to design fires becomes a more practical and realistic approach. The network approach is based on utilizing an in-depth hazard analysis, to understand ignition and fire load sources in tunnels, above and below the floor of the railcar and within stations, and then utilizing a quantitative risk assessment to determine sets of fire scenarios. The process allows small, medium and large fires to be considered, with the consequences also being quantified. The selection of design fires has a significant influence on fire protection measures within a metro network and hence, is a major cost input. The rail network approach provides more robust decisions on fires, based on the hazards present. INTRODUCTION A fire within a rail car or one that occurs as part of a rail system can threaten the lives of users, maintenance staff and emergency services personnel. Fires in metro systems are rare events but can have severe consequences. As a result, any analysis of a potential fire must be thorough and rigorous and address not only regular accidents and small fires, but also very low probability, high consequence scenarios. The fire safety design process for a tunnel and station must start with the design engineers, contractor and operators making a number of key decisions related to fire protection measures, which may have significant cost considerations. One of the key aspects that influences the required fire protection is the design fire and the design fire scenarios, which is a key input for analysis. This paper provides an overview of the author’s experience in designing fire protection measures for rail networks in Europe, Australia and NZ, where a risk based framework is used to develop design fires and scenarios for the whole rail system – trains, stations and tunnels. This system wide approach is innovative, challenges the norms, but provides significantly more informed outcomes. The range of design fires will include small fires that may halt the network, larger fires for smoke hazard system design and significant post-flashover fires to assess the structural response."

Jan 1, 2016

By Ronald Erdmann

Today the BOF filter dusts and sludges are mainly dumped due to their zinc contents. By typically ranging from 2 to 5 % they prevent the filter dusts and sludges from beeing recycled via the blast furnace route. Based on the different discharge kinetics of Iron and zinc during the main blowing period In a bottom stirred BOF a simple and efficient system for recovery allow zinc fractions has been developed. The obtained material Is suitable for recycling without nsc of shell formation In the blast furnace. Different subsequent development steps have been performed. By starling with a very simple lime dependent model the sludge from the BOF off gas cleaning system was collected in two different sludge channel systems. This model based an the fact that most of the scrap based zinc Is discharged from the melt within the first eight to ten minutes of the BOF process. To Improve the system a spectroscope zinc sensor was Installed at the hot section of the off gas cleaning system to get more reliable informations on the actual zinc concentation of the BOF dust. By use of the system up to 50 % of the BOF sludge can be recycled.

Jan 1, 1995

By M. Saba

In cyanide leaching procedure, achieving an acceptable efficiency for silver and gold is very time-consuming, thus, enough studies have not been performed for optimization and modeling of this process. The kinetics of cyanide leaching includes two steps: first step comprises a sharp slope while the other has a slight increasing trend. In the present study, in order to reduce the time and cost, the cyanide leaching process of a sulfide silver/gold ore was optimized in the first period. The applied parameters and their ranges are: temperature 20-40 (°C); time 1-8 (hrs); cyanide concentration 1-2 (mole cyanide / mole Cu); the percentage of solid to liquid 1-2 (%) and pH 10-12. For design of experiments fractional factorial 2(5-1) was used. Also four center points were applied to increase the accuracy of the model. In addition, by analysis of variance (ANOVA) the most effective parameters were identified and the optimized condition was determined. A regression model was proposed to describe the effects of independent variables and their interacting role on silver recovery. Results showed that the model was linear for silver and nonlinear for gold. In the gold recovery process, the two important parameters are time and pH with the former being more effective. Due to the existence of cyanide ions in the medium, temperature and cyanide concentration have less influence in the gold recovery process. Solid to liquid ratio, in addition, comprises a slight negative impact on the procedure. This emphasizes the different kinetics of silver/ gold cyanide leaching. Finally, using the optimum condition the amount of silver and gold obtained were 61% and 67% in 8 hours, respectively. While in general conditions, the results were 37% and 54% in 24 hours, respectively. Keywords: cyanide leaching, refractory gold/silver ore, modeling, optimization

Sep 1, 2012