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By A. Hayatdavoudi, K. G. Sawant, F. Boukadi

"In this work, we found that contact between shale and water results in development of micro fractures. Based on results of experiments on Pierre shale, we conclude that appearance of micro fractures begin with saturation of capillaries, ionic and diffusive transport of water into the shale clays and once capillaries are saturated, the cause of micro fracture propagation is the conversion of ionic activity/exchange to excess pressure that did not exist before fracking. Based on these findings, the spread of micro fractures appear to be a time-dependent phenomenon which has not been addressed in the existing macro/micro fracture models.INTRODUCTIONShale has often been involved as a hazard in drilling operations. This hazard can be defined as “destabilization” of shale. When contacted with water-based drilling fluids, some shales readily swell and sometimes, cause the wellbore to cave-in, slough, wash-out, close, and pack-off, impeding the drilling by sticking the drill-pipe. However, once drilling reaches the desired depth or length, the casing is set, cemented, and perforated, and then actually we wish to initiate fractures and destabilize the shale formation, using hydraulic fracturing.Clays constitute a major portion of minerals in shale. These clays contain a large amount of free energy which is the main factor for “slick” water adsorption/absorption. In fact, the reason for using “surfactants” in hydraulic fracturing fluids is to make the penetration of the fluid into the capillaries much easier, thus water meets with less resistance to enter the small capillaries. Also, the result of high capillary suction pressure is due to small Angstrom size capillaries, smaller pores and presence of ions and hydrateable metal atoms. The free energy is thus, related to all the above mentioned and other affects. Capillary pressure, osmotic pressure and other pressures are responsible for creating the micro-fractures in shale, thus, increasing the network of micro-fractures which leads to more gas production. The objective of this study is to evaluate the pressures of the individual ions which are released by the diffusing “slick” water into shale. These pressures would be added to the above mentioned capillary pressure, osmotic pressure, bacterially-induced pressures, chemically-induced reaction pressure, pressure due to exchangeable ion-transport, pressure due to release of free energy of solvation and eventually to the pore pressure as suggested by Terzaghi’s equation."

Jan 1, 2015

By Mark E. Gershon

A mixed-integer formulation of the mine scheduling problem is discussed and applied for the purpose of optimizing both the mine production sequencing and the mill blending and processing problems simultaneously. Previous attempts at solving these problems separately, although successful, fail to take into account the interrelationships between these problems. Project structure serves as the outline of this paper, which is directed towards a mining engineering audience. Generalized in its organization, this concept is useful for long, intermediate and short range scheduling. Actual applications are mentioned which show that the concept is also applicable to mining a variety of ores.

Jan 1, 1982

By C. E. Jordan

The Bureau of Mines has investigated the fundamentals of fatty acid/fuel oil conditioning for improved flotation selectivity. Both conditioning time and intensity can provide optimum flotation selectivity as well as good recovery. Traditional conditioning seeks to optimize conditioning parameters with subsequent recovery of the hydrophobic mineral. In the fatty acid/fuel oil system many silica gangue particles are also rendered hydrophobic by the flotation collector. Fundamental studies have shown that particle-particle collisions transfer the collector reagents selectively to the mineral surfaces with the highest affinity for the reagent. This mechanism deactivates the gangue particles while increasing the collector reagent loading on the selected mineral. The degree of this transformation is directly related to the number of particle-particle collisions which can be controlled through conditioning time or conditioning mixing intensity.

Jan 1, 1995

By Robert Vidal

The performance of a laboratory-scale cell for the electrolysis of an aqueous chrome alum solution was studied. Electrode potentials, pH, and Eh were recorded. An optimum catholyte pH of about 2.5, consistent with information from the literature was observed. Values exceeding this range resulted in a precipitate formation and are detected by wavering cathode potentials. The role of anodically produced dichromate ions was investigated by chemical analysis. It was found that the steady state concentration of dichromate ions varies inversely with fluid flow from catholyte to anolyte. This concentration was also reduced with the use of precious metal coated titanium anodes.

Jan 1, 1994

By Osvaldo A. Bascur

Most mining and metallurgical plants have developed predictive maintenance policies based on statistical analysis and special techniques, like vibration analysis, oil and lube analysis for critical equipment. Process control strategies have also been installed in several metallurgical sites. These control strategies require instrumentation maintenance from local personnel. The availability of real time and process history to identify the most critical part of the processing system from mechanical integrity is a must for global plant optimization. Specialized performance control monitoring algorithms are required to justify their existence and contribution to the bottom line. Emerging technologies are combining these techniques into a single total plant system. Tools are required to assist in troubleshooting and adapting these process control instruments and strategies. The key is the plant equipment and process control availability and utilization rather than just maintenance.

Jan 1, 1997

By Georgette Smits

The gun-sprayed refractory lining of electrothermal furnaces used for the manufacture of carbon disulphide from liquid sulphur and charcoal at between 800 and l000°C are severely attacked during the process. A mineralogical study of samples of eroded refractory material disclosed that carbon disulphide had penetrated the lining, causing the precipitation of sulphides and carbon, and the decomposition of mullite, a major constituent of the lining, to corundum and amorphous silica. Calcium, iron, titanium, and chromium are undesirable cations in a refractory that is used in furnaces for the production of carbon disulphide, since they react readily with this substance. A series of tests, in which samples were exposed to different amounts of carbon disulphide for various residence times and at different temperatures, was carried out with eight types of aluminosilicate-based castable and brick refractory materials, to compare their resistance to attack by carbon disulphide. Mineralogical investigation of the test cores showed that castable refractory materials are unsuitable for this type of process because of the presence of calcium aluminates and other impurities in the cement. Of all the refractories that were tested, a mullite brick of low porosity, containing a minimum amount of impurities, appeared to be the most suitable for use in this type of operation.

Jan 1, 1989

By B. Dubreuil, J. -M. Lalancette, D. Lemieux

A gold bearing pyrite concentrate was treated at the pilot scale for the extraction of gold. Mineralogical analysis of the concentrates identified gold to be mainly present in the form of a solid solution in pyrite. Gold distribution resulted in a poor extraction yield of 55 % by direct cyanidation. A piloting campaign including an oxidative pre-treatment by roasting in a fluid bed was followed by treatment with halogens for gold extraction and has led to a gold extraction yield of 94%. Sulphur removal during the oxidation was very efficient at >99.5% and gold extraction by the halogens was completed within a 1 hour contact time. The piloting was performed on a 300 kg sample and used a diluted solution of hypohalites as the oxidizing agent for gold extraction. Sulphuric acid was injected in the reactor during the halogens treatment to lower pH to 2. The diluted solution of hypohalites (1-3%) was generated by electrolysis during the piloting campaign in a diaphragm-less electrolysis cell. The extracted gold was recovered via adsorption over silica and the gold depleted brine was treated for impurities removal. This brine was recycled for further gold extraction. With the recycling of water and brine, the regeneration of hypohalites and with a barren solid that is inert and stable, the Nichromet Extraction technology is a green process where the protection of the environment does not preclude profitability.

Jan 1, 2014

By Robert J. Coutts, Dan A. Payne

"The Broadmeadow mine is a punch longwall mine owned and operated by BHP Billiton Mitsubishi Alliance (BMA) in the Bowen Basin of Queensland, Australia. In 1999, an exploratory adit was driven as part of the feasibility study for the establishment of the mine. Subsequent development of the mine in 2004 started some distance away from the initial test adit. Ten years later, the trial adit would be used as the headgate of the 5'h longwall panel. However, multiple roof falls had occurred in a heavily jointed area over a distance of 1, 000 ft (300 m) during the past 10 years. Due to the immediate coal roof, low stress environment and time, some of these falls had progressed to 38 ft (11.5 m) above the mining floor. As a result of the extensive work involved and safety implications of trying to recover the roof falls conventionally, a strategy was developed to fill these roof falls with a cement based product from the surface, down boreholes, and redrive the roadways through the consolidated roof fall material. This paper describes the process of rehabilitating these roadways, the results when the roadway was redriven and the headgate performance as the longwall mined through the area.INTRODUCTIONBMA operates 7 open cut and 2 underground mines in the Bowen Basin of Queensland, Australia producing over 50 mt per year of high quality coking coal. As a result, BMA has established over 150 miles (250 km) of open cut highwall.Broadmeadow Mine is a punch longwall mine located 22 miles (35 km) north of Moranbah in Queensland, Australia on the western limb of the Bowen Basin Coal Measures (Figure 1). Broadmeadow Mine commenced development in 2004 and began longwall operations in 2005. Broadmeadow is currently completing the fifth longwall panel and produces over 4 Mt per year of high quality coking coal. Mining is undertaken in the Goonyella Middle Seam, which is 21 to 25 ft (6.5 to 7.5 m) thick in the current mining area.The mine layout required the use of an old exploratory gateroad as the headgate of its 5th longwall. This gateroad had experienced numerous large roof falls and required extensive rehabilitation."

Jan 1, 2010

By G. Goodall, R. Jabbar, S. Muinonen, A. Cummings

"Glencore’s Sudbury Integrated Nickel Operations in Falconbridge, Ontario, has been in operation since 1930. Many new technologies and practices, now common in the industry, have been implemented at the site and contribute significantly to the industry’s understanding. Since the last update on the Smelter operation published at the NiCo 2005 conference, the Converter Aisle has undergone significant changes in the operation of vessels. The Aisle continues to consist of 4 Peirce-Smith converters, but the Slag-Make Converter, and the Slag Cleaning Vessel have been re-tooled or re-built as Hybrid Vessels (HV), each generating matte for the two Finishing Converters and clean slag for disposal. The complicated scheduling and the overall benefits to the Smelter are reviewed here as part of the on-going tradition of industry support.INTRODUCTION The Glencore Nickel Sudbury Smelter operates a Roast Reduction Smelting (RRS) flow sheet with a specialized Converter Aisle operation that maximizes metal recovery to Bessemer matte. The main process equipment consists of a pair of Fluid Bed Roasters, a submerged-arc Electric Furnace and four Peirce-Smith converting type vessels (Figure 1). In the RRS flow sheet, concentrate is roasted with air to remove sulphur as SO2. Calcine from the Roasters is mixed with petroleum coke upon addition to the six-in-line rectangular Electric Furnace. The coke back reduces the metallic oxides, producing a matte and a discard slag.Gases from the Roasters are sent to a single pass absorption Acid Plant where the SO2 is converted to acid. Under the previous operating targets, approximately 70–75% of the sulphur in the incoming concentrate was fixed as acid with the balance going to the Electric Furnace in calcine for Bessemer matte production. Off-gases from the Electric Furnace and Converters are combined in a balloon flue, treated for particulates in electrostatic precipitators and discharged to the Smelter stack without any SO2 fixation."

Jan 1, 2017

By X. L. Wang

Hydrothermal method was applied in the preparation of calcium sulfate whiskers in airtight re-actor using gypsum as primary materials. The optimum conditions of preparation are as follows: pH value 9.8~10.1, concentration 5%, material size 18.1µm, which were determined by the analysis of the diameter of CaSO4 whiskers through SEM. On these conditions a product of ultrafine CaSO4 whiskers with diameter of 0.19µm and aspect ratio of 98 is obtained. Ultrafine CaSO4 whiskers with different concentrations, modified by titanate NDZ-401, were added into polypropylene as intensifier and composites of Ultrafine CaSO4 whiskers/ polypropylene were prepared by melting-extruding method. Mechanical performance of the composites was tested and surface morphology of the composites was observed by SEM. The results indicated that impact notched izod of the composites was enhanced by 49.5% compared with pure polypropylene when 10.0% Ultrafine CaSO4 whiskers were added into polypropylene and toughening effect was very remarkable. Dispersion behaviour and interface phenomenon of Ultrafine CaSO4 whiskers in polypropylene matrix were investigated by SEM. The results indicated that Dispersion performance of Ultrafine CaSO4 whiskers modified by titanate NDZ-401 in polypropylene matrix is good, which improved mechanical performance of composites to some extent.

Jan 1, 2014

By Gus Van Weert

Hydrometallurgical oxidation of sulphides is capital and energy intensive, with autoclave and bio-technology competing for lowest overall cost status. The use of surface aerators instead of stirred tank reactors could provide lower costs for bio-oxidation of concentrates. With this in mind, the Delft Inclined Plate reactor was designed with inclined plates above a settler shaped reactor to continuously return slurry from the lowest point in the settler to the surface of the liquid. The multiplate superstructure overcomes the scale-up restriction of the standard circular surface aeration patterns. DIP aerator energy and volume requirements for oxygen transfer from air will be presented in terms of kg O2/kWh and kg O2/m3/h transferred as a function of wt % sand in the slurry and compared to stirred tank performance. Scale up from the 4 m3 pilot unit will be discussed.

Jan 1, 1996

By Rainer Antretter

"THE CHALLENGE The 14km long, Arlbergtunnel, closed for public traffic during summer 2015, receiving a comprehensive and substantial renovation from 2015 to 2017. The main works discussed here, carried out during 2015, comprise 37 drill and blast SEM/NATM emergency escape tunnels from road level to the ventilation duct plenum have to be constructed as well as eight additional lay-by niches and three transformer tunnels. This presentation comprises the construction ventilation design, designed according to national regulations, suitable for 150 employees working 24/7 simultaneously at more than 40 single working sites lined up along the tunnel. The ventilation-system chosen was utilising two existing shafts for intake/discharge and a cross passage to surface, to handle a total fan power of 1.600kW. DESCRIPTION OF RENOVATION WORKS Linking Tyrol and Vorarlberg, two Federal States of Austria, the Arlbergtunnel is a single tube two-way road tunnel with vent duct plenum, constructed in the mid-1970s. According to latest EU legislation, additional escape exits have become obligatory. The existing seven cross passage links to the adjacent Arlberg Railway Tunnel, with average spacing of about 1.500m constructed in 2007, an additional upgrade to shorter escape spaces of approx. 400m was now required to comply with the updated legislation. Additional transformer tunnels, lay-by niches and small niches for emergency maintenance use, cleaning and other purposes, as well as a the installation of a new fire main in the invert, coupled with the simultaneous replacement of virtually the entire power and signaling cables, generated several dozen small and large single sites distributed along the 14km of tunnel.Purpose of the 37 walkable emergency escape tunnels is to reach the “upper deck” of the Arlbergtunnel, the vent duct plenum. These have an 180deg curve in plan, inclined at 10% and approx. 60m (65yd) long tunnels, excavated using drill and blast method starting from road level and working upwards to the level of an “intermediate soffit”, the vent duct plenum in the crown of the tunnel. The vent duct plenum is separated into a fresh air part and an exhaust air part, shown in Figure 1. The escape tunnels end with a pressure door in the fresh air section of the ventilation duct plenum. From there illuminated signs show the shortest escape route to the safe area between the road tunnel and the railway tunnel, as shown in Figure 2."

Jan 1, 2016

By Lizelle Glaner

An investigation was carried out by Mintek to investigate the influence of additions of gold to ?Fecraloy?, alloys based on Fe-Cr-Al. The aim was to try and improve the oxidation resistance of the ?Fecraloy? alloys at elevated temperatures over extended periods of time. The ?Fecraloy? alloys are very oxidation resistant alloys already employed in industry as substrates for metallic catalysts in auto-catalyst systems for high performance cars. Since their life and durability is limited by the slow, but steady, oxidation of the substrates, any change in the growth or stability of the oxides could be an improvement.

Oct 1, 2003

By R. Havens, B. K. Shilber

"INTRODUCTION In the course of the investigation of the occurrence of manganese deposits in the western United States, ore-dressing tests were made on three samples procured by Bureau of Mines engineers from two properties in southeastern Juah County, Utah, each of which is known by the name Black Jack. To avoid confusion, the tests will be described under the names of the owners Kendall-Duvall and the Empire Mines.None of the samples were amenable to ore dressing for the production of high-grade manganese sinter.Ores from the Kendall-Duvall deposit represent an interesting metallurgical phase of low-grade manganese occurrence, as the occurrence of manganese as silicate (braunite) automatically governs the extent to which they can be beneficiated by mechanical methods of treatment. As less than 50 percent of the total manganese was recoverable by complex methods of treatment in a 40- percent-manganese sinter, attempts were made to recover most of the manganese in a low-calcite, intermediate-grade product that might be acceptable for subsequent metallurgical treatment. By selective flotation of calcite and manganese, up to 68 percent recoveries were obtained in plus 20-percent manganese products..No encouragement can be given for successful ore-dressing of Empire ores as represented by samples received for testing, as no products were obtained that would meet minimum marketing specifications. Empire ore contained only 1 percent lime and might be high enough in grade (19 percent manganese) for direct hydrometallurgical treatment."

Nov 1, 1947

By David A. Orava, Richard C. Swider

"The technical knowledge and practical experience accumulated by industry and others in abating acid mine drainage (AMD) is being proactively applied at every phase of the mine life cycle. This paper traces the mine life cycle from exploration to post closure monitoring and maintenance, and reviews AMD abatement measures that have become an integral component of exploration and mining activities.Attention is increasingly being given to evaluating AMD potential as part of exploration work, and studies related to project feasibility and design. Mining, mineral processing, and waste management options are selected taking into consideration their suitability to inhibit AMD. These inhibition measures are typically committed to in closure plans submit-ted at the permitting stage. Mines are operated and decommissioned, often progressively, as planned and in accordance with environ-mental protection policies."

Jan 1, 1996

By E. T. W. Bailey

A HISTOR Y of the development and application of instruments, from the simplest U gauge to a modern indicating recording controller, would contain many interesting accounts of difficulties experienced and over-come. Important as is the history of development to any branch of science, this phase will, of necessity, have to be omitted from this paper and remarks confined to the results from the use of instruments in their present form. The steel industry bas, in the past decade, become increasingly instrument minded. More than ever, economy and adherence to doser specifications are demanded, and any tool that will aid in attaining these objectives by intelligent application and use finds a ready acceptance. The open-hearth furnace bas offered a field for instruments which is different from almost any other and one in which even a small percentage saved in operating costs may represent a considerable sum. Nevertheless, this department of the steel industry has been more cautions than most others in accepting the benefits which automatic control bas given on many other types of industrial furnaces, and one is puzzled why open hearths have not more generally benefited by the application of controlling instruments. The furnace operator bas to adjust the same three main valves that control fuel, combustion air, and stack draft as on most other furnaces, with the additional regulation of reversing the furnace. He is just as aware of the importance of proper draft control and correct air volume to burn most economically the applied fuel as any good boiler-plant engineer. What, then, are the special conditions that pertain to the open-hearth furnace?

Jan 1, 1939

By A. G. Starliper

Laboratory studies were made to produce whiskers of tungsten over a wide range of operating temperatures. Hydrogen reduction of tungsten hexachloride in a vacuum furnace at temperatures from 2,7000 to 3,3000 C yielded a small quantity of tungsten whiskers, provided a low degree of supersaturation was maintained. Direct measurements of 3,000,000 to 4,000,000 psi were obtained for the ultimate tensile strengths of individual whiskers averaging 3 to 4 microns in diameter with average aspect ratios of 1,000. This compares with strengths of 300,000 to 400,000 psi for 13-micron-diameter commercial filaments.

Jan 1, 1968

By Jerzy A. Mielczarski

The separation of albites from quartz by flotation applying the conventional HF-methods is no longer acceptable from an environmental and health point of view. Therefore, the search for a new reagent scheme without using HF depressor for separation of albite from quartz is under consideration. The flotation behaviour of ore mineral components depends on the produced hydrophobic or hydrophilic surface coverage (chemical functionalization). Currently we have excellent possibility of monitoring surface composition and structure at molecular and atomic levels at surfaces of natural minerals contacted with aqueous solutions of collectors, activators, depressants which is vitally important for the understanding of the surface chemistry that govern selective and efficient flotation. Detailed surface characterization of minerals before and after their exposition to different solution conditions was performed by the most modern spectroscopic techniques such as developed by us the infrared external reflection technique combined with spectral simulation and X-ray photoelectron spectroscopy (XPS). It is possible to monitor surface reactions which facilitate the separation process and those which bring disadvantage to selective flotation. At first we found that a small amount of ?mineral impurity? presented in natural ore could play important role in selective hydrophobization process. It was found that the pH of solution (parameter possible to control) and natural mineral impurities present in mineral samples (parameter related to ore origin) play a very important role in the separation process. Another important parameter is interaction between minerals, quartz and albite, present in aqueous solution. The limitation of flotation separation resulting from chemistry will be discussed. Moreover, the most promising scheme for separation of albites from quartz will be examined.

Jan 1, 2014

By D. Emadi

The ASTM B108 Mould and a Modified Mould were used to cast test bars under a variety of conditions: mould and pouring temperatures, mould coating and tilt. Mechanical properties were determined in the as-cast and heat-treated conditions. The ASTM Mould is less sensitive to casting variables. Enlarging the gating system and adding additional gates to the ASTM mould can improve properties in the tilt position. The reproducibility of properties in as-cast and T6 heat treated bars was investigated.

Jan 1, 2004

By Ralf M. Kleine

THE property of Consolidated 1 Discovery Yellowknife Mines Limited, (Figure I) is situated in the Northwest Territories, approximately 50 air miles north of the town of Yellowknife. The mine is reached by a shaft which extends from surface to a depth of 4,000 feet, with working levels established at 1 50-foot intervals. Stopping operations are carried on throughout a vertical range of 2,000 feet, with both shrinkage and cut and fill methods being used, depending on the ground conditions. Production started in 1950 and milling is done in a 1 65-ton per day cyanide plant. During ten months of the year, the property is serviced entirely by air, utilizing charter aircraft from Yellowknife. A 4,000-foot runway near the mine was constructed from mill tailings. This strip is adequate to receive Bristol freighter planes carrying heavy loads. Other servicing is done by Otter aircraft, equipped with skis or wheels for winter and with pontoons for summer operations.

Jan 1, 1962