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By H. J. McQueen

Mineral and energy resource consumption were continuously reduced by process improvements as chemical understanding was developed and applied. During the past two centuries, technological improvements increased human productivity that was accompanied by social advances and labour saving products; however, these sometimes proliferated to endanger sustainability, e.g., automobiles. In the steel industry, precisely controlled rolling of HSLA steels required little extra mineral consumption but reduced weight and heat-treating energy. Continuous casting of slabs reduced scrap compared to ingots and energy for the homogenizing soaking pit. Al alloy extrusions were improved by retaining the strengthening in the near-surface substructure, of high strength textures and of press quenching that is suitable for direct age hardening. Continuous bar casting of Al-0.65Fe, coupled with rod rolling and followed by wire drawing with only a final recovery anneal, yielded electrical wiring for households to replace less plentiful Cu and later for light-weighting use in autos and aircraft Looking backwards, the 1970 decade saw the first oil crisis and inspired Ottawa to undertake a campaign to develop an energy strategy that would decrease dependence on imported fuels. One significant undertaking under Energy Mines and Resources was the organization of industrial energy conservation, managed by each industry association,that collected detailed current statistics and set the goals for a 2-year campaign. The metal producing industries, as compared by E.C.N. Perryman to about 7.2 exajoules (EJ) for the nation, consumed about 0.8 EJ, being about one third of all heavy industries. While manufacturing consumed 30.2% of total energy, it created 87.3% of total national dollar value. Within the industrial envelope, smelting and refining utilized 28% (0.67 EJ, mining beneficiation 6.7%, 0.16 EJ); there was a significant contribution to exports: 80% of iron ore and 70% of aluminium in 1973. A general concern was that decreases in ore grade would lead to a rise in energy expenditures countering benefits from processing efficiency.

Jan 1, 2012

By H J. J Boshoff

Mine closure planning integrated into life-of-mine (LOM) planning during the operational phase consists of many subcategories. One of these subcategories that needs to be fully integrated into the LOM planning is that of water management planning. Issues arise when mine water management infrastructure, which is required post-mine closure, is only considered closer to the end of LOM. Once the mine is closed monitoring is focused on water quality as an indicator of closure performance, hence inadequate upfront post-mining water management planning or integration into operations will result in environmental harm. The lack of considering post-mining water management is not uncommon in LOM planning. Poor mine site water management and planning are a wide reaching problem for the mining industry. Numerous active mines have been issued with environmental notices and penalties for contaminated water discharge; including issues with abandoned mines now being cared for by governments all over the world.Mitigating sources of water contamination caused by existing and closed mine sites that are leaching pollutants might be impractical, due to inaccessibility to the contaminants or final landform topography. The opportunity to consider and introduce post-closure required mine water management infrastructure is lost once the waste facilities are constructed. Mitigating contamination is made more problematic with mines located in remote areas, serviced by dedicated roads, water supply, electrical supply, etc. It is expected that these services will be decommissioned or drastically reduced, once closure is reached making remedial work much harder. Inadequate planning, to ensure access and easily maintainable water management infrastructure, could lead to erosion and contamination going unnoticed. There are numerous examples of poor mine water management practices in Africa, Asia, Australia, South and North America. In the United States more than 23 000 km of streams are affected by pollution sourced from some 50 000 abandoned or mature mine sites (DeGraff, 2007).CITATION:Boshoff, H J J, ?2014. Inadequate water management planning resulting in long-term closure liabilities, in Proceedings Life-of-Mine 2014 , pp 233–246 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 16, 2014

By Nicholas Kyriazi

A joint effort by the U.S. Bureau of Mines and the U.S. Mine Safety and Health Administration (MSHA) was undertaken to determine how well self-contained self-rescuers (SCSR's), deployed in accordance with Federal regulations (30 CFR 75.1714), survived the underground environment with regard to both impact damage and aging. This report presents findings regarding laboratory-tested SCSR's from 1982 through 1990. The SCSR's were tested on human subjects and on a breathing and metabolic simulator (BMS). These results indicate that most of the apparatus, if they pass their inspection criteria, perform as expected except for units with manufacturing defects or design deficiencies. However, when the apparatus are carried in and out of the mine daily and stored at the working section, they may suffer abuse. Physical signs of abuse, unless extremely obvious, are frequently not detected by the miners or mine operators. This poses a potential danger to a user in an emergency. Recommendations include improved training in inspection procedures.

Jan 1, 2010

"The Archaean komatiite-associated nickel sulphide deposits at Kambalda, Western Australia, exhibit a number of stratigraphic features that are indicative of a strong volcanic control on ore localization, including (1) a restriction to specific basal cumulate metakomatiite host units, (2) confinement within distinctive synvolcanic embayments in the footwall and (3) variations in the internal structure and composition of overlying and adjacent barren metakomatiite flow's and the distribution of interflow metasediments with proximity to the ore zones.The high magnesium content of the host units (up to 45% MgO volatile-free) in comparison with that of aphyric or spinifex- textured lavas (16-32% MgO) has been considered previously to indicate either magmas/lavas rich in intratelluric olivine or selective accumulation of olivine phenocrysts. The marked linear trend of the oreshoots, basal host units, footwall embayments and the volcanic stratigraphic relationships have been used as evidence for local linear feeding fissures. Rare relict igneous olivine in some host units is, however, demonstrably not intratelluric, and there is no direct or indirect evidence of a proximal eruptive site (e.g. footwall feeders, pyroclastic breccias, ultramafic intrusives) at Kambalda such as at some other deposits of this type. Kambalda is interpreted as a distal rather than proximal volcanic environment.Emplacement of the komatiite sequence at Kambalda was probably controlled by the locations of a few specific eruptive sites relative to regional topographic gradients and influenced by the topography of the pre-existing volcanic surface. Olivine enrichment in the basal host units occurred by in-situ fractionation and cumulus crystallization of olivine during longitudinal lava flow within linear lava conduits, possibly centralized on depressions between non-overlapping footwall basalt flows. The distinctive stratigraphic relationships are attributed to localization of lava conduits along the volcanic pitchline, flanked by more slowly moving parts of the flows. There are analogies with the physical volcanology of Modern basaltic and Proterozoic komatiitic lava flows.A corollary of this model is that the lava conduits thermally eroded and assimilated sulphidic sediments, contributing additional sulphur to sulphur-saturated komatiites or possibly inducing sulphide separation in originally sulphur-undersaturated komatiites. The latter would account for the restriction of ores to linear cumulate komatiite host units (thermally active lava conduits) and the locally mutually exclusive, but stratigraphically equivalent, relationship between the ores and sulphidic metasediments at Kambalda."

Jan 1, 1984

By M. Tiedtke, T. Crary, P. MacPhail, M. Ounpuu

"The SGS carbon-in-pulp (CIP) / carbon-in-leach (CIL) model was used to evaluate and optimize the carbon circuit at Alamos Gold’s Young-Davidson Mine. Plants samples (pulp and carbon) were tested in a series of small scale batch experiments to determine rates of gold leaching and adsorption on carbon from a combined flotation concentrate/tailing product. The testwork data, along with existing plant data were then used to model the performance of the existing CIL plant and optimize the circuit to improve performance and overall recovery. The primary purpose of the modelling exercise was to determine the most cost effective way to lower solution losses at the plant. The modelling was also used to learn how the various parameters in the CIL circuit affect solution losses and the gold inventory tied up on the carbon. This resulted in recommendations for minor changes in the CIL flowsheet, which were successfully implemented in the plant. The approach, results and plant changes are presented.INTRODUCTION This paper presents the details from testwork conducted on samples from Alamos Gold’s Young- Davidson gold mine which is located near the town of Matachewan, approximately 60 km west of Kirkland Lake in Northern Ontario, within the southwestern part of the Abitibi Greenstone Belt. The objective of the test program (completed by SGS Canada in 2013) was to investigate and model the combined flotation concentrate / tailing carbon-in-leach (CIL) circuit and suggest ways to improve gold recovery. The metallurgical test program included mineralogy, rheology, and carbon modelling testwork. Plant information was provided during the test program and used in the optimization process. Upon completion of the testwork, plant changes were recommended and implemented at site (October 2014). Plant results from 2014 to 2017 confirmed the modelling results."

Jan 1, 2018

By Gary P. Sames

This U.S. Bureau of Mines study was conducted in eastern Kentucky drift mines as part of an ongoing research program to characterize the outcrop barrier zone. "Hillseams" were identified as the dominant geologic cause of roof instability unique to the outcrop barrier zone, with many roof fall injuries and fatalities attributed to them. Hillseam is the eastern Kentucky miners term for weather-enlarged tension joints that occur in shallow mine overburden where surface slopes are steep. Hillseams are most conspicuous within 200 ft laterally of a coalbed outcrop and under 300 ft or less of overburden. Hillseams form by stress relief, and therefore tend to parallel topographic contours and ridges. They can intersect at various angles, especially under the nose of a ridge, and create massive blocks or wedges of roof prone to failure. Examples of hillseams are described in both outcrop and in coal mine roof to establish their geologic character and contribution to roof failure.

Jan 1, 1989

By J. C. Johnson

The problem of estimating pillar capacity in coal mines has motivated development of a variety of empirical equations. Most of these equations have arisen from experience and a very limited set of measurements that have, necessarily, been focused on particular regions or coal fields. Their applicability is often limited to a specific range of pillar sizes. This is of particular concern in the design of large gateroad pillars and small barrier pillars between panels. The result has been a variety of equations and equation coefficients that can calculate load estimates to size pillars. Inclusion of these equations in more sophisticated loading models, such as boundary element methods (e.g. LaModel and MULSIM) has been hampered by absence of a function that describes specific variation of coal strength within the pillar. A singular exception, to our knowledge, is a function corresponding to the Bieniawski pillar strength equation. Because of this, it is the only coal strength criteria inherently available in most boundary element models. This paper presents a general method for deriving local coal strength, as a function of distance from the pillar rib, for an arbitrary pillar strength equation. Integration of this function provides the strength of pillar regions, or cells, needed for boundary element models. The method is demonstrated for the Bieniawski, Maleki and Holland-Gaddy equations. The Maleki and Holland-Gaddy equations contrast strongly with Bieniawski as strengths are extrapolated to large pillars and barriers. This development provides a tool for incorporating any of the proposed empirical equations into a boundary element model, thereby allowing the analyst to choose the most appropriate equation for a particular region, coal seam and/or pillar size.

Feb 23, 2014

By J. A. Organiscak

Two types of airflow splitting methods for improving longwall dust control were investigated by NIOSH's Pittsburgh Research Laboratory. These methods included a translucent mesh barrier and a staged spray barrier system to confine the shearer-generated dust to the coal extraction side of the long wall face while maintaining a cleaner split of airflow on the opposing worker walkway side of the longwall face. The translucent mesh barrier was shown to provide notable dust control effectiveness up to 60 m downstream of the shearer in both the laboratory experiments and a long wall field evaluation, provided the mesh barrier remains relatively parallel to the airflow. The staged spray barrier system showed marginal dust control effectiveness in the laboratory and subsequently was not field tested.

Jan 1, 1999

By M. P. Tixier

Abstract In a review of the application of electrical logging in Canada, examples are .given of long and short distance correlations by means of the electrical logs. The use of MicroLogging for the determination of permeable and porous formations is explained. The question of log analysis for the quantitative determination of fluid saturation and porosity is .discussed. An example is provided to illustrate the significance of the resistivity gradient. The advantages of the new method of the Laterolog are shown, chiefly for the case of wells filled with high-salinity mud. Introduction Electrical logging techniques developed rapidly in Canada at the time an intensive drilling activity started for the exploitation of the Devonian series in Alberta, namely, at the beginning of 1947. The conventional service was soon thereafter supplemented with the latest technica1 improvements. Canada has been among the first regions to take advantage of MicroLogging*, which has proved a most powerful .tool for the investigation of permeable and porous formations; also, the more recent development known as the Laterolog has ?been introduced in Canada. The Laterolog provides a better determination of .the formations, particularly in the case of salty mud where the conventional logging is greatly handicapped. The various methods of electrical logging are now commonly known in oil industry and have been described in numerous publications ( 1) ( 2) (3).

Jan 1, 1951

By H. D. Pallister

A review of? reports and literature on the pyrite deposits at Pyriton, Ala., indicated that a large tonnage of pyrite, some of which contained a small amount of copper, had been mined and shipped to fertilizer plants throughout the South. The information contained in this literature tended to demonstrate that the ore occurred in separate lenses of greater or less extent and of varying thickness and richness in pyrite as well as in copper. The outcrop being parallel with the Atlantic Coastline Railroad and just south of it makes the deposits readily accessible for shipment. Slopes could be sunk as they were in the past in the ore body if it were of sufficient grade and thickness, and the ore could be hoisted up the slope and milled close to the slope mouth with an ample supply of water from Talladega Creek, which follows the outcrop closely.

Jan 1, 1949

By H. C. Gunning

In spite of the fact that mining has been more or less active in the northern part of Vancouver island since the late 'nineties', there seems to be a remarkable lack of information regarding the nature and development of the region. Recently the operations at the Old Sport mine of the Coast Copper Company, Limited, and spectacular copper discoveries in the vicinity of Nimpkish lake, have directed the attention of the mining fraternity to the district. The writer spent the summer of 1929 making a reconnaissance examination of the general geology and mining properties of the area between Quatsino sound and Nimpkish lake, and he feels that a short paper describing the nature and mining possibilities of the region should be of interest at this time. A more detailed account of the ?geology and of the mining properties will be published in the forth- coming Summary Report of the Geological Survey. A short paper dealing with the Nimpkish Lake district was presented at the Annual Meeting of the British Columbia Division, held recently in Vancouver.

Jan 1, 1930

By Larry A. Cramer

"Three primary drivers are setting the trend for base and precious metal processing . they are: continued low real base metal prices, environmental concerns, and continued high prices for PGM.s. Low base metal prices are increasing the search for economies of scale and company consolidation as well as the development of some hydrometallurgical technologies. Environmental concerns are pushing for continued reductions in SO2 emissions and hydrometallurgical technologies. The high prices for PGM.s are driving major expansions and a focus on minerals processing recoveries and, to a lesser extent, reductions in the refining metal lockup.In nickel, HPAL operations on laterites have failed economically but Inco is still pursuing some alternatives. BHP-Billiton and others are developing bioleaching alternatives for nickel laterites and sulphides.Copper continues to be dominated by the hydrometallurgical and pyrometallurgical debate; new hydrometallurgical developments are being tested at several sites whilst the pyrometallurgists continue to make competitive cost and environmental improvements.Gold processing developments are dominated by the use of improved gravity recovery equipment and by the development of thiosulphate as a more environmentally acceptable lixiviant.PGM processing trends are the use of fine grinding technologies, higher power input flotation cells, and new pyrometallurgical technologies. Hydrometallurgical options for some applications are being sought.OVERVIEW The metals industry has remained under price pressure for some time; low and decreasing real prices for most metals have become an expected scenario. Occasional price spikes give some relief but invariably bring expansions and new entrants into an already oversupplied commodity market, thus leading to the continued price pressure. Technical innovation, economies of scale, and improved work systems are continually sought, so as to improve the competitive position of each individual company in such a climate; however, these developments add to the downward price pressure. In such a situation the application of scarce funds to research and development is a difficult task. Excess funding is not available in tight economic times and yet the main route to higher profits is clearly the application of technical developments to lower the cost of producing a metal commodity. Many technical centers have closed as a cost saving exercise and some have coalesced to obtain economies of scale. The Australian based AMIRA research organisation has grown to serve the R&D part of the market well in Australia and in South Africa by acting as the catalyst to form research partnerships between a number of industry players and as an administrator to direct the funding of research projects towards the various applicable research institutions. AMIRA has developed closer ties to Camiro (Canadian Mining Research Organisation) through the appointment of Camiro.s metallurgical processing research director as AMIRA.s North American based director. AMIRA is continuing discussions with MIRO (Minerals Industry Research Organisation) in regard to a merger, with a report outlining the merger proposal expected in March of 2003. Company focused research centers continue to be effective at Anglo American Research Labs, Teck-Cominco Research, Falconbridge Research center, Inco Research and some others."

Jan 1, 2003

By Brahm Prakash, R. Schuhmann

Chemical conditions for flotation and nonflotation of quartz with oleic acid as collector and barium, calcium, aluminum, iron, and tin as activators were studied using a simple vacuum-flotation technique in glass-stoppered graduates. The detailed study of barium activation led to an interpretation based on ideal Langmuirian chemisorption.

Jan 1, 1950

By G. G. Oberfell

THOUGH the largest volume use of natural gas has been, is. and in all probability will continue to be as a fuel for domestic and industrial heating, it has various market outlets, both as a fuel and as a raw material for the chemical industry. Natural gas is a preferred type of fuel where ease of control, fuel uniformity, and freedom from ash are of primary importance. Other industrially important uses are as a source of carbon black and as a fuel in various low-cost heating operations. Many other uses are of varying importance and new potential uses are continually being uncovered, some being of economic importance to the gas indus¬try as a whole, but most of them involve such small volumes of gas that they are only of passing interest. Since various products extracted from natural gas and recovered as by-products from petroleum refining, such as liquefied petroleum gas and fuel oil, are being utilized in many industrial and domestic heating applications, some consideration will have to be given such materials in order to present a reasonably complete story of the importance of natural gas. Some of these materials may prove to be transient competitors and will not be available when more profitable uses are found for them. Meanwhile, however, the potential volumes of such materials available, the current volumes being marketed, and the nature of the utilization are considered as constituting an essential part of the over-all fuel picture.

Jan 1, 1946

By J. Robert Van Peli

IT was a strange but highly fruitful marriage-that union of hardy explorers, seeking the rich treasures of copper in the Lake Superior wilderness, with Boston's aristocracy of brains, capital, and enterprise. This historic wedlock, which has continued happily to the present day, was the means by which the wealth of Lake Superior's copper was won for the use and benefit of an expanding America. One branch of this family tree, the western branch, begins with prehistoric Indian miners, embraces the early French explorers of the Upper Lakes, and finally includes the British and American pioneers who reduced the vague rumors of copper to known fact and actually began the mining of copper in the wilderness. The other branch, the New England line, begins

Jan 1, 1948

By Margreth Tadie, Chalwe Chibwe

Physicochemical properties of copper electrolytes are a strong fundamental consideration in electrodeposition processes during electro-purification and recovery of copper. Their influence extends to mass transfer as well as energy consumption during the electrodeposition process. In this study, the influence of electrolyte composition on electrolyte physicochemical properties was investigated to review the existing literature data. This review of data is considered necessary as more and more electrowinning models are being developed for process prediction and optimisation and a need of such data is required for accurate prediction of physicochemical properties. The major components of importance to the formation of smooth high-quality and high-purity copper cathodes at optimum current efficiency are considered the species in solution. These include Cu ions, Fe ions (major impurity), H2SO4, and a smoothing agent additive. A 5-factor, 2- and 3-level experimental design was employed to determine the effect of copper (35 and 45 g/l), sulphuric acid (160 and 180 g/l), iron (1, 3, and 6 g/l), polyacrylamide additive (2, 5, and 10 mg/ l), and temperature (45 and 55 °C) on electrolyte density, conductivity, and the diffusion coefficient in synthetic copper electrowinning electrolytes. The major species in a copper electrowinning electrolyte are found to be the most relevant for prediction of physicochemical properties. These results indicate that relatively simple empirical models are sufficient for modelling of the electrolyte domain in electrowinning, without the need for the generation of vast amounts of complex experimental data.

Feb 1, 2021

By MAURICE ALTMAYER

M Y DUTIES, as a member of the Department of Franco-American War Cooperation of the French High Commission were to study the copper and brass industries of America from the mining of the various non-ferrous metals to the semi-finished, or finished materials. In the pursuit of these studies, it was my privilege to visit a number of industries and organizations in different parts of the country. I first visited most of the Eastern copper refineries that were supplying the Allies with vast amounts of metal. These works are producing their material by the multiple or the series process, although the first method predominates. But, regardless of the process employed all the plants attain an exceptionally high standard of quality in their production. One of the points that particularly attracted attention was the manner in which improvements could be traced from the older worlds to the more recent ones. The impression was that, thanks to a spirit of broad-minded cooperation between the principals of the companies and frequent exchanges of views between members of the staffs, all persons interested benefitted by the experience thus gained, to the advantage of the community at large.

Jan 1, 1920

By B Davis, A H. Benzer, A N. Mainza, C M. Evertsson, L M. Tavares, M M. Hilden, M S. Powell, C Rule, G Asbj÷rnsson

The Mogalakwena North Concentrator of Anglo Platinum Operations was built with the capability to allow for future projected expansion. Several research groups, currently working with Anglo American on collaborative research over a range of projects, were brought in to review the existing operation, with a view to releasing some specific bottlenecks and providing specialist design input to the potential plant expansion.Based on a thorough review of the high pressure grinding rolls (HPGR) and crushing circuit, a wide range of de-bottlenecking opportunities were identified. This was followed by a series of surveys to provide performance measurements and to model the circuit in detail. From this effort a full simulation of the plant has been developed, including updated models of the HPGR, crusher, bins and screens. These models have been implemented in the researchersÆ Model Development Kit (MDK) version of JKSimMet, and in a prototype dynamic simulator based on the Matlab Simulink software.The observations, measurements and simulations have provided guidance and quantified the benefits of some proposed circuit modifications. Based on these findings a number of upgrades are being planned, with the aim of ensuring full utilisation of the installed equipment. The circuit demonstrates a potential expansion of over 30 per cent through minor improvements, and a 70 per cent increase in capacity with the addition of some strategic equipment.The HPGR-crushing upgrade project demonstrates the potential benefits of nurturing disparate Research groups into a strong inter-disciplinary technical team capable of supporting operational needs while developing future technology.CITATION:Powell, M S, Hilden, M M, Evertsson, C M, Asbj÷rnsson, G, Benzer, A H, Mainza, A N, Tavares, L M Davis, B, Plint, N and Rule, C, 2012. Optimisation opportunities for high pressure grinding rolls circuits, in Proceedings 11th AusIMM Mill OperatorsÆ Conference, pp 81-94 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Oct 29, 2012

By AIME AIME

The following abstract of the minutes of the final Adjourned Annual Business Meeting, held Nov. 12, 1912, in the office of the Institute, 29 West 39th Street, New York City, is here presented for the information of the membership at large. On the announcement by the Secretary that there was a quorum present, President James F. Kemp called the meeting to order. The minutes of the Adjourned Annual Business Meeting of Oct. 7, 1912, were read and approved. (Sec p. xi,Bulletin No. 71, November). Prof. Jos. W. Richards, in behalf of the Special Committee of the Board of Directors and the Council (Messrs. Richards, Kirchhoff, and Rand), withdrew the two proposed amendments to the Constitution offered by the said Committee at the Adjourned Annual Business Meeting of Oct. 7, 1912. (See Bulletin. No. 70, October, 1912, p. vi., and Circular Announcement No. 8, Oct. 15, 1912, p. 15.) Professor Richards presented a syllabus of the proposed amendments to the Constitution and By-Laws prepared by the Special Committee. Several members present discussed various sections of the proposed Constitution, and the Committee advised that the suggestions would he duly considered before submitting the final document, which would be duly presented and sent to the membership at large at least 30 days before the next Annual Business Meeting, Feb. 18, 1913. Professor Richards presented a resolution, seconded by Mr. Kirchhoff, making a change in the present Certificate of Incorporation, so that it would conform to the proposed changes in the Constitution and By-Laws; said resolution was unanimously adopted. Professor Richards presented another amendment to the Constitution, which had been purposely omitted from the printed list, but had been requested by many members, namely, the creation of a " Class of Fellows." This question was freely discussed at the Cleveland meeting (see Bulletin No. 71, November, 1912, p. 1348), and in view of the diversity of opinion it was-decided to present it in separate form for separate action of the membership at large at the Annual Business Meeting, Feb. 18, 1913. In answer to question, the President announced that the proposed amendments to the Constitution and By-Laws presented by Messrs. Corning and Stone at the Adjourned Annual Business Meeting, Oct. 7, 1912, and published in Circular Announcement No. 8, Oct. 15, 1912, were still on record. Professor Richards presented a syllabus of the proposed amendments to the By-Laws, and several sections were discused by members present, but no action of record was taken. Mr. Charles F. Rand read a letter from Mr. L. K. Armstrong, Sec-retary of the Spokane Local Section of the Institute, referring to the proposed amendments to the Constitution, and he announced that many of Mr. Armstrong's suggestions were, in one form or another, already incorporated in the proposed amendments submitted by the Special Committee. A special vote of thanks was passed to Dr. Albert R. Ledoux for the valuable assistance rendered by him to the Special Committee in the preparation of the proposed amendments to the Constitution and By-Laws.

Dec 1, 1912

By J. Petersen, A. E. Lewis, J. Chivavava

Rare earth elements (REEs) have special properties that prompted their extensive use in high-tech applications. The demand for REE has, therefore, increased over the past years, resulting in the supply risk of the materials. Extraction from non-conventional low-grade ores, like easy-to-mine ion adsorption clays (IACs), by hydrometallurgical methods is being explored to supplement the supply of REEs. The extraction of REEs from low tenor IAC leach solutions requires enrichment using cost-effective methods such as precipitation. Therefore, the aim of this study was to understand the recovery of REEs from IAC leach solutions using various reagents for precipitation. In the first part of the study, recoveries of REEs from IAC leach solutions through direct precipitation using H2C2O4 and NH4HCO3, as well as antisolvent crystallization using C2H5OH, were predicted via thermodynamic modelling using OLI Stream Analyzer. Verification experiments were then conducted through the use of an agitated reactor. Simulation results showed that high yields of REEs were possible using each of the reagents, but large quantities of C2H5OH were required. Experimental results confirmed the high yields predicted from simulations. Precipitation with H2C2O4 was found to selectively recover REEs while rejecting Al. However, utilization of NH4HCO3 and C2H5OH resulted in the co-precipitation of Al. Furthermore, the yield of Y from antisolvent crystallization was significantly lower than the theoretical value. The product recovered from antisolvent crystallization consisted of well faceted, large crystalline particles, which filtered faster than the fine, amorphous REE carbonates recovered using NH4HCO3. REE oxalates were crystalline, larger than the REE carbonates and, overall, showed the highest filtration rate.

Dec 11, 2024