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By A M. Lechner, S Arnold, M J. Gillespie, P D. Erskine, D R. Mulligan, A T. Fletcher, A Gordon

Mine ecological monitoring schemes are often conducted only to address compliance and in some cases do not have the sufficient statistical power or understanding of ecological systems to assess, quantitatively, the meeting of rehabilitation targets or mine impacts. Monitoring schemes for rehabilitation commonly rely on analogue sites or premining baselines (reference sites) to assess whether rehabilitation sites are ecologically similar and thus successfully rehabilitated. In the case of monitoring for mine impacts, if the impacted sites diverge from reference data, the site is considered to be impacted. Fundamental to any monitoring scheme is testing the sampling design to ensure that it can detect these differences if they are present through adequate sample sizes (ie statistical power). However, a good understanding of the ecological system is required to ensure that differences detected are ecologically significant. Modelling ecosystem properties can provide a quantitative understanding of how ecosystems change over time and space, in response to natural environmental variations and thus aid in determining significant ecological differences. Furthermore, modelling methods can be used to predict future ecosystem states. Within the ecological literature, guidelines for robust statistical monitoring designs and modelling methods exist but are not routinely being used in the mining industry. This paper uses simple examples to discuss: problems with current compliance monitoring methods; importance of robust statistical techniques; and how modelling can assist rehabilitation assessment and guide monitoring schemes. The aim of this paper is to describe general monitoring and modelling methods that could be potentially used for mine site monitoring and closure assessment. These methods are often considered by mining companies as an extra expense that provide little practical benefit, and the domain of academia; however, engaging these methods may be more cost-effective in the long-run than conducting untargeted monitoring schemes that give no confidence to regulators on whether rehabilitation criteria have been met. Furthermore, monitoring programs in mining contexts provide a good opportunity to better understand long-term ecological patterns and test the application of more rigorous modelling approaches as the life of many mines tends to be greater than ten years.CITATION:Lechner, A M, Arnold, S, Fletcher, A T, Gordon, A, Erskine, P D, Gillespie, M J and Mulligan, D R, 2012. Embracing modern ecological methods - Monitoring and modelling for mine closure, not compliance, in Proceedings Life-of-Mine 2012 , pp 25-32 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 10, 2012

By R. R. Klimpel

Over the last six years, several new commercial families of sulfide mineral collectors have been developed. This paper summarizes some plant data and use experiences gained with each of these product families. The first is a series of products (F-series) based on a chelation mechanism of attachment. The second of these families is a series of products (S-series) based on an electrochemically controlled mechanism of attachment. The major advantage of the F-series collectors is the very high metal recovery capability in complex ores involving Au, Pt, Zn, Ni, and mixed Cu minerals. The major advantages of the S-series collectors are the very high pyrite rejection capability along with reduced lime requirements in Cu/Mo plants.

Jan 1, 1995

By J. Kevin Cotchen

The results of "submerged arc" electric furnace processing of a variety of materials is discussed with respect to the process and products, including the characteristics of the products (e.g. TCLP or Toxicity Characteristics Leaching Procedure). The materials melted include slags and wastes containing various metal oxides including copper, tin, lead, zinc, chrome, nickel and other associated elements. The findings of these tests are compared to those reported in the literature for other operations treating similar "wastes".

Jan 1, 1992

By Oliver Hall

WITH the friendly consent both of the Institution of Mining and Metallurgy, for whom this paper was written, and of the author, we had the pleasure of publishing Mr. Oliver Hall's paper on Mining at Noranda in our issue of last March and of having Mr. Hall present it at the Montreal Meeting. In the following pages we now report the discussion elicited by the paper at a meeting of the Institution in London on March 18th. The report is taken from the April, 1937, issue of the Bulletin of the Institution, to whom we again tender our thanks. THE PRESIDENT (MR. ROBERT ANNAN) said that this paper was, by arrangement with the Institution and the author, also being published by the Canadian Institute of Mining and Metallurgy for approximately simultaneous discussion. He was sorry that Mr. Oliver Hall could not be present to introduce it in person, for he was sure that the author would have had many more details to give about this most interesting mine. The paper contained a very useful account of mining operations, and personally he had been pleased to see the tri-dimensional projections of the orebody in Figs. 3 and S. It was a good illustration o the value of that method in presenting the form of an orebody such as this. While he had no desire to go into technical details, he wished to call attention to a remark in Mr. Hall's introduction, in dealing with the history of the mine and the principles on which it was run. The author had given an account of the early difficulties in solving geological problems, and later of the economic difficulties of seeing this mine through a period of intense depression in metal prices. He stated that it was clear that, to maintain income, tonnage must be increased, and, to maintain profits, costs must be decreased. It would be observed that there was no question of increasing the grade of ore. Then the author went on to say: 'Having set the house in order in the years of adversity, the higher price for gold is being used to mine to still lower limits and lengthen the life of the enterprise and the welfare of those dependent on it'.

Jan 1, 1937

By J. H. Starkey

SAGDesignTM Testing for grinding mill design was introduced commercially in 2004. Up to January 2008, 18 projects have been completed and 99 samples have been tested using this method. Two papers have been published describing the patented test procedure and one of these shows how the results compare with other grinding test methods. This paper will briefly discuss the theory on which this technology is based, and explain the procedures used to develop the calibration equation. Case studies are also included to demonstrate the effectiveness of the test work being done. These case studies show how the SAGDesign test is being used today: to design new grinding circuits for commercial full scale use; to calculate throughput in existing mills for production planning; and to accurately define grinding mill requirements at the scoping, pre-feasibility or feasibility study stage of project development, in order to economically identify the size and cost of the grinding mills that will be needed for the project. This is important because if the full rec-ommended SAGDesign testing program is done at an early stage in the project, the definitive cost for a guaranteed throughput, grinding mill design (by Outotec if their mills are purchased) is available. New grinding mill design for final engineering will be represented by the test work done on the Climax Molybdenum Project for Phelps Dodge (now FMI) in Colorado, USA. The SAG mill and ball mill for Climax are now in fabrication with project start up in late 2009. Next, the sizing of grinding mills at the scoping, pre-feasibility or feasibility study stage of mine development will be represented by a large metal mining property in Russia. Finally, calculation of the throughput for existing mills will be represented by work done at a base metal mine, in eastern Canada. Test work for designing SAG mills is now done in four laboratories at the time this paper was written. One in the USA at Dawson Metallurgical Laboratories, Inc. in Salt Lake City, two in Russia at the TOMS Research and Design Institute and at the Irgiredmet Research Institute, both in Irkutsk, and a fourth mill has been installed in Australia at AMMTEC Limited?s lab in Perth. A fifth SAGDesign test mill for radioactive ores has been built by Starkey & Associates, specifically for testing uranium ores and can be moved to any licensed lab in the world on a project basis.

Jan 1, 2014

By W. K. Gummer

"THE LOCATION of Canada's present aluminum industry is determined by availability of hydroelectric power, and ready access to ocean transport facilities. The chief raw material for the production of the metal is imported by ship over several thousand miles of water. In times of freedom of shipping and uncontested movement this provides the industry with its cheapest method of operation. However, during the early part of the last decade the general conditions of ocean and rail transportation were such that interest in the treatment of materials other than bauxite was greatly stimulated. This was the case not only in Canada, of course, but in most other countries.Canada has no deposits of bauxite and much research was carried out on other aluminous materials, chiefly silicates, in an effort to develop more or less economic and feasible methods of treatment. In the United States, this research was considerably more extensive. Some projects were early shown to be of little or no value, whereas others, including the widely publicized lime-sinter and soda-lime-sinter methods, became important. In North America, however, apart from the application of the sinter method to the hitherto waste-product (red mud) of the normal Bayer plant operation, none of these processes contributed appreciably to the production of aluminum during the war. In certain European countries, on the other hand, largely because of their situation with regard to bauxite deposits, they had a more general application, and Germany, for example, produced alumina from clay, ashes, and slag by at least four methods."

Jan 1, 1952

By P. A. Mingione

AEROPHINE® 3418A is a unique sulfide mineral promoter produced by Cyanamid, based on phosphine (PH3) chemistry. It has proven effective as a collector for the sulfide minerals of copper and particularly lead (galena), as well as for secondary gold and silver values. AEROPHINE 3418A has widest application as a Cu and/or Pb collector for complex ores of Cu-Zn and Pb-Zn, which frequently have significant quantities of associated precious metal values. Advantages shown in the use of AEROPHINE 3418A are improved selectivities against Zn-and Fe-sulfides, increased precious metals recoveries, reduced total collector consumptions for Cu and/or Pb flotation, and increased flotation kinetics leading to higher recoveries of these values. Operating plant, pilot plant and laboratory test data from treat-ing different ores are presented, demonstrating the advantages in use and preferred application of AEROPHINE 3418A.

Jan 1, 1991

By D Finn, D Kentwell

Experience has shown that the E-Type multiple indicator kriging (MIK) estimation technique often works well for resource estimation in stockwork mineralisation that contains a mixture of high and low-grade mineralisation types that are difficult or impossible to separate spatially. E-Type MIK, like ordinary kriging (OK) is a smoothing estimator and where data is sparse can result in estimates of grade tonnage curves that do not reflect the true block variability at selective mining unit (SMU) scale. The rank and replace (RR) estimation methodology is designed to reproduce both local block accuracy and true block variability at SMU scale and has shown good results when used with highly skewed unimodal diffusive style mineralisation. This paper examines the use of RR with mosaic style mineralisation typically found in stockworks via a case study using real data from Newcrest’s Telfer West Dome deposit. Resource level estimation results for ordinary kriging (OK), E-Type MIK and RR are compared to close spaced grade control models as the reference reality.Results show that stationarity requirements and declustering can severely impact on the usefulness of the rank and replace technique and that it should only be used where trends are not too strong and data are relatively uniformly spaced. This does not rule out its application to stockwork or mosaic style deposits. However, in this case, the presence of trends and different data densities requires the non-stationary domain to be further broken down into sub domains for the RR technique to be effective.CITATION:Kentwell, D and Finn, D, 2017. Testing new estimation techniques – rank and replace: a stockwork case study, in Proceedings Tenth International Mining Geology Conference 2017, pp 365–374 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 20, 2017

By R. Thorpe, M. Dosbaba, A. Kopriva, A. Niiranen, J. Ruokanen

"Automated Mineralogy (AM) is an important diagnostic tool in flotation plants as it adds ore and particle mineralogical properties to traditional mass and chemical data. AM is used in project development, for future ore studies and for diagnosing concentrator operations. With the exception of operations who own central laboratory or on-site systems, the use of AM is often limited to the analysis of a comparatively small set of samples. Metrix Plant Technologies has partnered with TESCAN to integrate TIMA AM technology into the implementation of Performance Assessment Campaigns (PAC). Routine daily composite samples from the mill are analysed mineralogically on a size-by-size basis over several weeks. All the relevant metallurgical, process control and mineralogical data is combined into a single large database for mass balancing and interactive examination. This paper describes the implementation and results of a PAC at the Agnico Eagle Kittilä gold mine in Finland. Although challenging, the addition of mineralogical data as dependent variables in multivariate analysis leads to a much deeper understanding of the root cause effect of events driving the flotation performance. INTRODUCTION TO STUDY The Kittilä mine, owned by Agnico Eagle, is Europe’s largest primary gold mine, with annual production of approximately 180,000 Oz. The operation is located in Lapland in northern Finland, and is currently expected to operate until 2035. The location of the operation is shown in Figure 1. Historically, the mine was an open pit, although in recent years ore is sourced solely from underground operations. The processing plant features crushing and grinding, followed by carbon flotation and sulphide flotation. Carbon concentrate is a waste stream, and sulphide concentrate reports to pressure oxidation (autoclave) and CIL circuits for gold extraction. The final flowsheet is shown in Figure 2. Following commissioning in late 2008, the operation achieved commercial production on May 1st 2009. Gold recovery in flotation gradually increased to a 92-96% range at a throughput of ~3500-4000 tonnes per day. In late 2014, the operation commissioned a plant expansion to ~5000 tonnes per day. Following a commissioning period, the operation stabilised with recoveries in a 90-94% range, which over any given period was determined to be ~2% lower with statistical significance. The trends from start-up of gold recovery in flotation and throughput are shown as follows in Figure 3. In early 2016, Agnico Eagle Kittilä mine, along with Agnico Eagle Technical Services (AETS) partnered with Metrix Plant Technologies and TESCAN, to perform a Performance Assessment Campaign (PAC) at Kittilä, involving automated mineralogy on five key streams at Kittilä on 40 days selected from a 50 day period between February 15th and April 4th 2016, when plant operations were stable. In addition to the mineralogical data, metallurgical and operational data were pooled into a single, powerful database to explore opportunities for the operation to improve recovery in a sustained manner, ideally to the levels pre-expansion."

Jan 1, 2017

By P. M. Shibley

"IntroductionMine drainage, surface. drainage and process liquors are the principal mine and mill effluents. The quantity and quality of these flows varies according to mineralogy, type and scale of mining, the process, tailing disposal, local ground conditions and climate.Typical contaminants remaining after solids sedimentation are colloidal or semi-colloidal particles, acids, alkalis, metals in solution, cyanides and thiosalts. Environmental regulations and guidelines have been issued in detail by the appropriate government agencies and will not be reviewed here. Revisions and additions are being made as our comprehension and abilities increase. Some contaminants of consequence have not been specifically regulated as practical treatment technology has not been identified. Thiosalts fall into that category as do the derivatives of the first stage of cyanide oxidation - cyanates.Most mining activities have present or foreseeable water treatment requirements. Because process economics can be adversely skewed by the environmental factor, the acknowledged objective of every operation must be to identify and anticipate those requirements.The evaluation and selection of water treatment techniques for mine-mill applications is complicated by the fact that most mine-mill effluents are high volume, dilute and chemically complex systems. Treatment processes applicable to most contaminants are: chemical or biological oxidation; neutralization and/or precipitation; liquid/solids separation. Other processes such as ion exchange, electro-deposition, foam fractionation, freeze crystallization and reverse osmosis offer the possibility of selective removal or concentration of contaminents. The latter tediniques, representing a slightly higher level of technology, are less suited to the large, low value flows usually encountered in the mine environment."

Jan 1, 1989

By L. R. Wilkinson, W. J. Howarth, G. J. Wenk

Over a period of three years, a cooperative program in Australia has resulted in the development of radioisotope immersion probes for the on-stream analysis of mineral slurries. Two basic probe types are now available on a commercial basis - fluorescence and absorption probes - and within each type there are a number of variations so that optimum sensitivities can be obtained for elements with atomic number greater than titanium (22), thus covering most metals of interest to modern metallurgy.

Jan 1, 1973

By S. K. Kawatra, H. J. Haselhuhn

"Thickening is used during two primary mineral processing operations: water removal and desliming. During water removal, the pulp density is increased through the injection of flocculants. These flocs settle and create a dense pulp while clarified water is removed through the overflow. During desliming, fine particles are removed through the overflow. Desliming can also be used as a mineral separation process known as selective flocculation-dispersion, where valuable minerals are flocculated and gangue minerals remain dispersed and exit through the overflow.There are many ways to analyze thickener performance on a laboratory scale, but these analyses often do not correlate well with full-scale performance. Some pilot-scale systems have been designed using a semicontinuous approach, but the amount of material required to perform their tests can make semicontinuous pilot thickeners impractical for most applications. This paper focuses on the design and optimization of a continuous pilot-scale deslime thickener that requires minimal material to operate. The design, optimization strategy, and an example study of reagent selection are demonstrated. IntroductionMany laboratory methods have been employed to size and optimize thickener performance. The most common of these include the Coe and Clevenger method and methods derived from the Kynch theory of sedimentation. The Coe and Clevenger method was developed in 1916 and was proven for slurries that do not require flocculation to settle. This method proposed that the settling rate of the pulp is only a function of the solids concentration. It is executed by creating slurries of several different concentrations of solids and performing bench-scale settling tests in graduated cylinders. For each concentration, a thickener unit area can be determined using the following equation (Coe and Clevenger, 1916; Laros, Slottee and Baczek, 2002):"

Jan 1, 2017

By J. van Huyssteen, M. Cantor

Newmont Ghana Gold Limited's Ahafo Operation has matured from its project ramp up stage into steady state operations after three years of operation. Management focus has shifted from addressing construction and commissioning problems to optimization and improvement. This focus change has coincided with the introduction by Newmont of a Continuous Improvement (CI) program across the company which provided a project management methodology that can be used in the execution of smaller scale projects. This paper focuses on the application of CI principles at the Ahafo Plant through the discussion of several case studies that demonstrate how these principles are applied.

Jan 1, 2011

By I Lourel

In evaluating the installation of an in-pit crushing and conveying (IPCC) system for any mine, a number of options are available for each of the dig side, transport and dump side operations. Some of them are moreappropriate than others; given the pit arrangement, the material being handled and the rates at which it needs to be moved. This paper seeks to document the options that might be employed, and to rank them in terms of their applicability at any mine and their practicality overall, with a view to nominating those that would be most suitable for further study.

Jan 1, 2009

By G. R. Waters

"The technology behind industrial applications such as Hydrometallurgy continues to evolve, as do the corresponding regulations and specifications that ensure the safety of workers and the environment. Valves make up key aspects of this technology, and often represent the single point of failure for entire operations. More often than not, the valves being used in Hydrometallurgy applications are known as Severe Service Valves (SSVs) due to their ability to withstand the extreme conditions. Most experts agree that SSVs are identified by applications, and that these applications are challenging to the valve’s ability to provide a minimum acceptable level of performance over a minimum acceptable duration. The Manufacturers Standardization Society (MSS) of the Valve and Fittings Industry has designated Ross Waters, President of CGIS, as Lead to the Task Force put in place to determine the minimum requirements a valve needs to be able to perform to when faced with extreme conditions, whether from pressure, temperature, toxicity, solids, or usage. This paper serves to determine what the minimum requirements are for SSVs in Hydrometallurgy applications. It will draw on five decades of industry experience from one of Canada’s leading valve experts.INTRODUCTION Severe Service Valves Severe Service Valves (SSVs) mean different things to different people. Until today, defining SSVs had little if any global agreement or recognition. That is about to change as the Manufacturers Standardization Society (MSS) has accepted an application to produce a Standard Practice so defining them. This paper provides information about the selection of SSVs in all industries but focusses on metallurgical processes and applications and offers examples to illustrate the successful and unsuccessful use of these valves. All of this with the purpose of raising the awareness of the industry on all sides, from the suppliers and manufacturers, specifiers and to the users and owners of them. It also supplies tools to understand where and why to separate SSVs from general purpose or commodity valves (GPVs). SSVs are often identified by applications, and these applications are challenging to the valve’s ability to survive. Within these applications the elements that make the service severe are being analyzed, quantified and qualified. From this, we expect to offer objective and repeatable definitions and guidance to improve the experience of SSVs, reduce unnecessary costs, provide longer service life and process runs, improve safety and reduce environmental issues."

Jan 1, 2017

Carbon sequestration in planted forests provides an immediately available, low cost option to address the greenhouse impacts of coal mining and coal utilisation in a carbon constrained world. In addition, planted forests also offer the opportunity to address other environmental issues, particularly salinity and loss of biodiversity. Given salinity is characteristically associated with agriculture in the 500 to 700 mm rainfall belt, then where such forests can also produce commercial timber products, they offer the additional opportunity to establish new, diversified rural employment in both timber growing and processing. In the majority of Australian catchments affected by salinity, where rainfall is generally less than the 700 mm limit to conventional forestry, and where groundwater reserves are often saline, the objective of achieving economically viable forestry production presents a significant challenge. In 1996, Saltgrow commenced a collaborative breeding program to combine the salt and stress tolerance of E camaldulensis, with the growth rate, stem form and wood properties of the commercial species, E grandis and E globules. This program aimed to produce trees with the potential for commercial rehabilitation of saline landscapes. Results covering a range of site conditions from SaltgrowÆs network of over 100 trials around Australia are presented. The opportunity for commercial plantations integrated with agriculture in low to medium rainfall areas to address salinity and sustainability will be discussed. In addition, the significant potential for partnerships between land-rich, cash-poor farmers, catchment management authorities seeking to invest in public good projects that enhance environmental sustainability, and major carbon producing industries with either mandated or voluntary requirements to curtail net emissions will also be discussed.

Jan 1, 2005

Over the last 15 years working in the mining, construction and extractive industries, one of the areas that has always concerned and at the same time drawn the author to it is the application of drilling and blasting in the underground development mining and civil construction tunnelling fields. In that time, the author has come across many drives and tunnels that are larger than design or badly damaged in the perimeter or both. When the question is asked as to why this is the case, the reply is generally æthatÆs the way it is and always has beenÆ. Sometimes it is blamed on bad ground, bad drilling, bad explosives, bad initiation or just plain bad. Most operators build a dilution factor into development and tunneling costs as an acceptance of overbreak and similarly pattern bolt everything to overcome excessive perimeter damage. This paper will attempt to unravel some of the mysteries behind perimeter drilling and blasting in underground drives and tunnels and discuss methods to reduce overbreak and therefore reduce costly dilution and to minimise perimeter damage which in turn will allow more cost-effective ground support. It should not be assumed that better drilling and blasting alone would automatically allow an operation to reduce ground support. The operator must still æreadÆ the ground and its characteristics in order to ensure sufficient ground support is placed to allow the operation to progress safely. This paper will not go into the intricacies of bolting, meshing, shotcreting, concreting and other ground support, but it will use indicative costs for the primary areas of drilling, explosives, excavation and labor to show the magnitude of cost-efficiencies which can be obtained through improved drilling and blasting applications. Drill and blast remains the most flexible and cost-effective method of underground excavation as long as it is applied safely and effectively.

Jan 1, 1999

By A Marta

Geomembrane (GMB) liners are being used more frequently for the storage or capping of mine waste due to stricter regulatory requirements relating to environmental protection. The longevity of any liner system will be a function of environmental conditions, design (including materials selection), construction and condition monitoring during operations or closure. Based on experience and case studies, this paper presents a review, from design to handover, of some of the smaller and often overlooked details that can have significant impacts on the performance of the GMB and the project overall.The topics covered will include approaches to selecting and testing GMBs to ensure they are suitable. Design considerations to aid installation and quality assurance during construction. Understanding action leakage rates and the consequences of leakage when it creates whales. Construction quality control and assurance procedures, including a brief discussion on non-destructive liner integrity testing. CITATION:Marta, A, 2018. Geomembranes – from design to handover and some of the lessons learnt, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 190–207 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By J. A. Sweet

The issues facing graduate training in the mineral processing industry are not too different today from those that prompted the initiation of the Anglo American Platinum Graduate Development Programme (AGDP) in 2002. Graduate metallurgists in South Africa enter the industry from different undergraduate programmes at various tertiary institutions, and so the knowledge and skills of the young graduates varies. Further, the geographical expansion of the industry combined with the downsizing of business units means that there are fewer opportunities for young graduates to be mentored through their first few years on site. Anglo American Platinum chose to address these issues by implementing an intensive, structured graduate training programme for all their new metallurgical graduates, known as the AGDP. The first two years of experience of the AGDP, from the viewpoints of both graduates and lecturers, were presented to the mineral processing community at the IMPC in Turkey in 2006 (Sweet et al, 2006). From the beginning, the programme was structured in a modular fashion to include a basic technical ?toolbox? including statistics, the scientific method and sampling protocols, while the mineral processing content comprised advanced learning in comminution, classification and flotation (later extended to include hydrometallurgy). Technical communication ? both written and verbal ? was included from the start. The programme was focussed very strongly on site work (?learning by doing?), with a major integrated site campaign conducted and analysed by each cohort. In 2012 the AGDP will accept its ninth cohort into the programme. This paper describes how Anglo American Platinum and the University of Cape Town have developed and adapted the programme over the last few years, in response to the challenges of the global recession, skills retention, and the changing operational needs of the company. The programme, which was drawn up to accommodate around 15 concentrator-only graduates, now accommodates 35-40 concentrator, smelter and refinery graduates annually. The programme has also been modified to facilitate new graduates spending most of their first year on the operations. The benefits of the programme for Anglo American Platinum have been tangible, and will be discussed in the paper. Keywords: graduate training, technology transfer

Sep 1, 2012

By G. Belardi

This paper presents the preliminary results of a research programme conducted to assess the feasibility of a flotation technique in the remediation of soils severely affected by heavy metal contamination. The use of flotation in soil remediation is a recent practice. The main difficulties are given by the variety and peculiarity of the heavy metal containing species, and also by the grain size. Most of the studies reported in the literature concern the use of conventional collectors, such as xanthates, after a preliminary chemical modification of the metal bearing species through sulphidization. On the basis of the minera-petrographic characterization and of speciation, some classes of reagents have been selected, capable of acting both on metal-bearing species and all metallic cations to be separated. The design of the synthetic molecules has been based on the coordinative properties of the metallic centres and functionalized in order to act as collectors for a wide range of metals independently on their surrounding atoms. In laboratory experiments a sample of stream sediment has been utilized, whose contamination is caused by the runoff from Sardinia mine waste dumps and overflow from the settling ponds. The material showed contamination mainly from Zn, Pb and Cu and to a lesser extent from Cr, Ni, Cd, and Sb associated in mixed particles of Fe and Mn. Flotation tests on a laboratory scale have been performed on grain sizes less than 355 µm in laboratory cell Minerais & Metaux. The effects of the structure of collectors (functional group, chain configuration) as well as of the principal flotation parameters (such as pH, concentration of reagent) on the grade and recovery of heavy metals in the concentrate and in the tailings (remediated soil) have been investigated. The results of the laboratory tests substantially confirm the theoretical premises, and the most effecive reagents found belong to the classes ATP, MBT, MBO, fat acids and phosphates.

Jan 1, 2014