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By G. Ferrara

During several years of operation in Europe, South Africa and other countries, the Tri-Flo has demonstrated to represent a substantial improvement of the dense medium dynamic separation systems. The reasons are: (1) high sharpness separation due to the multistage system and the application of new concepts in designing the regeneration circuit and controlling the medium rheology; (2) the possibility of performing two cuts at different densities using a since separation device and a single regeneration circuit. The paper discusses in detail the above mentioned points, with particular reference to the multistage technology, based on the circuit analysis theory, and to the control of the medium rheology based on recent work in the modelling, and simulation of the rheological behavior of dense suspensions.

Jan 1, 1993

By S. J. Gerdemann

The U.S. Bureau of Mines is studying the kinetics of wet oxidation of sphalerite concen- trate (ZnS) as a possible process for a gravity-pressurized reactor (GPR). At tempera- tures in excess of 200' C, a sphalerite water slurry will react with 0, to form zinc sul- fate (ZnSO,). However, the pressure required to keep the water from boiling at these temperatures has kept this reaction from becoming a viable continuous process. The GPR can easily obtain the high pressures required for this reaction. The reaction rate is complicated by the solubility of 0, in water and the further oxidation of ZnSO, to insoluble zinc oxysulfate (Zn4(OH),S04.4H20). The effects of pressure, temperature, and particle size on the rate of reaction were investigated. Reaction rate was found to be limited by the amount of oxygen in solution. However, at 250" C and 1500 psia, over 90 pct of the zinc was solubilized in less than an hour. The conditions for maxi- mizing the Zn++ in solution, while minimizing oxysulfate formation, are discussed.

Jan 1, 1993

By L. W. Beckstead

In a conventional zinc refinery plant, zinc concentrates were roasted at 950°C. The calcine was ground and leached in a series of leaching vessels using sulfuric acid. The pH in the first leaching vessel was maintained at 2.5, while the pH of the solution exiting the last vessel was about 5.4. The leached residue typically contained (in percent) 0.1 Ag, 0.2 As, 0.7 Cd, 2 Cu, 15 Fe, 10 Pb, and 15 Zn, and it was classified as hazardous material according to the EP-toxicity test. In order to make the residue non-hazardous, and to recover most of the metal values from the residue, a brine leach process was developed. The process consisted of leaching the zinc leach residue in CaCI, brine solution at pH 2 for 1 hour at 90°C. Silver extraction was about 95 percent, while lead, copper, cadmium, zinc, and iron extractions were about 80, 50, 50, 30, and less than 0.5 percent, respectively. More extreme conditions of acidity could have been used in the leaching stage to increase zinc dissolution, but iron dissolution would have significantly increased which would have complicated subsequent recovery steps. The leached and washed residue passed the EP-toxicity leach test and could be disposed as non-hazardous. Silver, copper, and lead in the leach solution were recovered by zinc cementation, while zinc and cadmium were recovered by sulfide precipitation. The resulting solution can be recycled in the process after magnesium precipitation.

Jan 1, 1993

By Jin Kim, Jerry C. Tien

Water is still the most economical and popular means of controlling dust underground. It is a process that captures dust by bringing water droplets into intimate contact with coal particles. Wetting agents, also known as surfactants, can be added to greatly facilitate such a process since they tend to reduce the interfacial tension between the coal particles (usually hydrophobic) and the liquid. The surfactants used in the study were first chosen on the basis of their HLB (Hydrophile-Lipophile Balance) value, and later tested in order to select the right type and amount of surfactants to give the best performance. Both static and dynamic tests were later conducted using different types of surfactants to examine their respective wetting effectiveness on coal particles. Experimental results show close correlation with the theoretically calculated collection efficiency that is based on a horizontal tunnel and a solid-cone water spray.

Jan 1, 1993

By C. L. McKenzie

American Girl Mine is located in the Cargo Muchacho Mountains in the southeastern Imperial Valley of Southern California. Production from the current open pit mine and heap leach recovery system began in early 1989. Previous mining and gold recovery took place commencing in 1987 at the Padre Madre site, situated adjacent to the American Girl site to the southwest. In mid-1990, a 790-tonne-per-day underground gold mine and mill went into production. Approximately 6,500 troy ounces of gold per month are recovered from the combined open pit underground mine operation. Copper in the form of Azurite [Cu3(CO3)2(OH)2] and Malachite [Cu2CO3(OH)2] are abundant in the mined ores (Henshaw, 1942). The high solubility of these minerals in caustic cyanide solutions has a negative impact on carbon adsorption and electrowin processes. This paper presents the results of monitoring programs, process chemistry, and control changes introduced at American Girl Mine to abate production complications in the refinery and measures taken to minimize solution gold losses in the adsorption circuit(s).

Jan 1, 1993

By L. Xu, A. Vazirnegad, R. Bhaskar

"Respirable dust samples are collected by the U.S. Mine Safety and Health Administration (MSHA) and mine operators as part of the requirements of the Federal Coal Mine Health and Safety Act of 1969. About 1.85 million respirable dust samples collected by MSHA were analyzed for the period 197/ to 1990 f or the states of Alabama, Colorado, Illinois, Kentucky, Ohio, Pennsylvania, Utah, Virginia, and West Virginia. Trends in coal dust exposure of continuous miner operators, helpers, and roof bolters were analyzed. The reported production in each of the nine states was analyzed. The relationship between average dust exposure and coal production was evaluated. In addition, the differences between mine operator and MSHA inspector collected data were examined for each state. The average exposure levels for the three occupations - miner operator, miner helper, and roof bolter were also compared.The data indicate that the dust exposure levels have significantly dropped over the last twenty years, while at the same time production has increased, attesting to the ability of the U.S. mining industry to adapt successfully to the stringent dust control regulations. In terms of coal production, it appears that some states, such as Utah, Illinois, and Kentucky, were able to increase their production significantly relative to others, such as Pennsylvania and Virginia. The relationship between dust concentration and coal production is, at best, tenuous. 11 implies that existing dust control technology has assisted several mine operators to meet dust standards, while, at the same time, enabling mines to produce more coal than before. Comparison of data collected by MSHA and mine operators indicate that MSHA inspectors recorded higher dust levels and lower shift production relative to mine operators."

Jan 1, 1993

By M. Z. Rashad, H. A. El-Sageer

The intersections of numerous joint sets at the surface of tunnels of the Abu-Tartour project in Egypt create blocks of irregular shape and size in the rock mass. Although most of these blocks are unable to move into the free space of the tunnel, a few key blocks are capable of such movement. In addition, as soon as they move, some restrained blocks will be liberated. The aim of this work is to find the removable key blocks of the walls, floor, roof and corners of a portion of the tunnel under jointed surface rocks and then determine the best tunnel direction.

Jan 1, 1993

By A. Rios

ENAMl's Paipote Smelter commenced operations in 1951. At present, it processes 230,000 tonnes/year of green feed in a conventional smelter, which comprises one reverberatory furnace, two Hoboken, one Peirce-Smith converters and one rotary anode furnace. The feed is composed of 83% copper concentrate and 17% metallic copper precipitates, which results in a feed average grade of 32% of copper content. The final products are 75,000 tonnes/year of copper anodes and 48,000 tonnes/year of sulphuric acid. At present, the plant is undergoing a modernization to expand the smelter capacity to 300,000 tonnes/year of green feed and increase the sulphuric acid production to 100,000 tonnes/year. This will be achieved with the installation of an El Teniente Converter and an expansion in the acid plant. The work began in November 1991 and is scheduled to be in operaton by March 1993. The paper provides an overview of the modernization plans and results achieved to-date.

Jan 1, 1993

By Wayne C. Stewart

Freezing of high pressure air lines and pneumatic equipment has been a recurring problem in the Thompson Smelter. The particular severity during the winter of 1989-90 resulted in costly process disruptions and repairs. A process improvement team with representatives from operations, engineering and both maintenance supervision and the shop floor was established to develop solutions. Their mandate included process evaluation, design, equipment and in-plant commissioning. In 1990, upon recommendation of the team, we installed three Refrigerant/Desiccant air dryers with a total capacity of 20,000 S.C.F.M. to service the Smelter. This paper discusses processes and process improvements associated with this installation.

Jan 1, 1993

By D. W. Mitchell

Planning today for what hopefully will never happen is one of the surest ways to decrease the chance of it happening. As Napoleon proved and Ian Mitroff wrote, "The heat and stress of battle is the worst time to make decisions of strategic importance." Mitroff also wrote, "The value of a plan is not that it will ever perfectly match reality, but going through the process of planning speeds the process of recovery. It allows the organization to emotionally work through the worst before it actually happens." This paper concentrates on things miners must consider; on the need for plans to be like a belt conveyor strong enough to carry the load, flexible enough to stretch a little; on the criticality of throwing away fax machines and telephones, and having certain officials at the scene rather than back in head-quarters; on the training of fire brigades and mine-rescue teams; on having company-controlled chromatographs; on having people who can look at trends rather than numbers. Some of the things in this paper might anger some readers; for that, I can only ask them to consider first the problem not their position.

Jan 1, 1993

By Frank E. Chase

Retreat mining is one of the most hazardous operations conducted underground. One of the keys to miner safety and an efficient recovery of the reserves is to design adequately sized production pillars to prevent pillar squeezes, excessive pillar spalling, severe floor heave, roof falls, and pillar bumps. Currently, few pillar design approaches are available which consider the abutment pressures generated by the gob. The Bureau of Mines is developing a method called Analysis of Retreat Mining Pillar Stability (ARMPS) to aid in the design of retreating sections. Back analysis of 42 case studies indicates that ARMPS can be helpful in predicting stability during retreat mining operations.

Jan 1, 1993

By Larry A. Haas

The U.S. Bureau of Mines, in cooperation with Cleveland-Cliffs, Inc. (Hibbing, MN), investigated ways of enhancing the quality (compressive strength, after-tumble and reducibility) of domestic acid and fluxed magnetite pellets by modifying the oxygen content during the preheat and induration periods of the firing operation . Oxidation of magnetite was best accomplished when sufficient oxygen and time were available before the peak induration temperature was reached. The rate of magnetite oxidation increased directly with the gas oxygen content during the preheat period at 7000 C and above. With 30 pct ( or more) O2 and a preheat rate of 2000 C/min, most of the magnetite was oxidized during the preheat period. With laboratory tube and mini-pot furnace tests, oxygen enrichment during the preheat period improved the pellet properties more in the simulated grate-kiln tests than in the simulated straight-grate tests. The longer induration period with the grate-kiln test resulted in more sintering of the residual magnetite and its reaction with the silicon compounds. When flux was present in the pellets, calcium silicates and calcium and magnesium ferrites were formed. More calcium ferrite was formed when the magnetite was oxidized early and less iron was present in the fayalitic calcium silicate slag.

Jan 1, 1993

By M. Bai

The influence of mining on the hydro-geomechanical environment is greatly constrained by alternating mining geometries. The limiting magnitudes of surface subsidence and groundwater flow over the mining area, as a result of geometry changes, can be reasonably predicted through a coupled finite-element model introduced in this paper. Verification of the model has been tested using real and conceptual case studies which reveal that changes in strata conductivities are strongly related to the strata deformation induced by mining. The greatest modification of hydraulic conductivities occurs within the caving or severely fractured zones. The study indicates that narrowing the panel face width will substantially reduce both the intensity and extent of mining damage to the overlying strata, limit surface subsidence and constrain the change in hydraulic conductivity to a reduced scale and smaller extent, particularly as mining depth increases.

Jan 1, 1993

By Hans von Michaelis

There has been a renaissance in gold and silver extraction and recovery that has taken place over the last fifteen years, since the price of gold was freed from the $3510~ level. Despite major advances in such areas as carbon adsorption processes for gold recovery, refractory gold ore treatment, crushing and grinding, process control, etc., there still remain several gold and silver mineral processing frontiers. Frontiers related to environmental management present significant challenges especially in the USA. More than ever it is appropriate to optimize total economics by adopting a "systems approach" that integrates mining, mineral processing and environmental management.

Jan 1, 1993

By Sehic O. A

Geology can be the root of evil or a source of bliss; there is a choice; to ignore geology is at a mine's peril.Risk can be minimised and profitability maximised by the application of a detailed understanding of geology, alteration, structure, mineralogy, chemistry, fabric and texture.Geology is dynamic, not static.The impact of geology is pervasive.The integration of ore quality control with grade control is one strategy for improving the utilisation of both the mineable reserves and existing plant and equipment. Grade maintenance is but one constraint on the problem of how best to blend the ore. Other ore characteristics such as mineralogy, hardness for grinding, and pulp fluidity or density for slurry size classification can be included to explore alternative blending Strategies.

Jan 1, 1993

By C. Patrick

Longwall face-to-face transfers can cost over $100 per minute in lost production potential and $100,000 for personnel and supplies. Such high cost makes extensive planning and control of the transfer process a critical necessity for the economic feasibility of longwall operations. This paper reports operations research techniques used for the analysis and modeling of longwall face-to-face transfers. Transfer data has been collected from companies who operate over 30% of the total U.S. longwall faces. Comprehensive sequence networks of existing longwall transfers were developed; simulation models of transfers under varying conditions were generated; and, the economics of general transfers and time-cost tradeoffs in the transfer procedure were investigated.

Jan 1, 1993

By J. R. Palmes

Three coal samples, selected out of eight with well characterized surface properties, were used in flocculation tests and synthetic mixture of coal and silica was used in the selective flocculation experiments. Coal wettability and flocculant type were found to have a strong effect on the flocculation results.

Jan 1, 1993

By D. L. Schweyer, W. A. Munson, R. H. Hanewald

Discussed is the INMETCO processing of electric arc furnace (EAF) baghouse dusts from the specialty-steel and low-alloy industries. In addition, the INMETCO process has been modified to recover nickel, chromium and iron from many other waste materials including: •pickling solutions or filter cakes, •spent nickel and chromium plating baths, •carbon refractories from pickling tanks, and •superalloy wastes including baghouse bags. INMETCO is the only North American company presently capable of recycling nickel-cadmium batteries by high-temperature metals recovery. This process and the details of INMETCO's best demonstrated available technology (BDAT) test program are discussed.

Jan 1, 1993

By A. E. Petersen

The United States Bureau of Mines conducted research on high-intensity magnetic separation methods for upgrading tantalum concentrates from Alabama. Process flow sheets were studied to maximize tin removal and minimize tantalum loss. Using laboratory-scale equipment, concentrates were produced which contained over 65% combined Ta2O5-Nb2O5. Up to 78% of the tin was recovered as a byproduct, containing about 70% SnO2. Only 1 to 5% of the tantalum reported with the tin byproduct. The producer subsequently incorporated high-intensity magnetic separation into its process flow sheet to provide concentrates for the National Defense Stockpile.

Jan 1, 1993

By Siwiec A

The laboratory investigations which are necessary to evaluate the mineral processing effectiveness usually include density separation of narrow size fraction of the feed and one of the products. In each size - density fractions the content of valuable mineral has to be determined. These data and yield in each size - density fraction can be specified by a matrix of partition coefficients. They are counterparts of recoveries. These coefficients can be compared with the mean recoveries at each density or size fraction or the total recovery, to determine which density - size fractions are processed in the best or worst way. The basic categories are: vector of metal content l _i 1711, 7t2, òòò, ltM I ò vector of particle size distribution x = I d1, d2, ..., dN I ò matrix of partition coefficients P11, P12, Pi N P _ P21, P22, ..., P2 N PM1 PM2..., PMN These three conceptions allow one to determine all the basic metallurgical parameters of a mineral processing unit. Losses of valuable mineral are connected with: ò mineralogical composition of the ore (types of minerals, their properties, dissemination, crystallochemical affinity, type and properties of gangue minerals), ò applied technology and technical equipment (beneficiation as a stochastic process, processing methods, process control, intergrowth liberation, water quality). Examples of application of the analytical method proposed are given for zinc - lead and coal processing plants.

Jan 1, 1993