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By Ramiro Escudero G.

Since the introduction of column flotation almost forty years ago the column technology has grown into several non-mineral applications such as among others the effluent treatment, soils recovery and de-inking of recycled paper. Recent studies have demonstrated that particular characteristics of the dispersion (bubble size, gas holdup, bubble surface area flux) are needed for a given flotation column duty. In this work, two kind of spargers were tested (i.e., internal and external) using a 4 inch column lab in a two phase system. Results show that the external sparger provides a dispersion with characteristics that include those produced by the two internal spargers.

Jan 1, 2003

By D J. Williams, E M. Rykaart

Soil cover systems are routinely used to reduce acid rock drainage (ARD) from mine waste rock dumps and tailings impoundments. A technology for the analysis, design, instrumentation and monitoring of barrier-type (oxygen limiting) and store/release-type covers has rapidly developed and the number of covers under construction has grown extensively during the past ten years. Mine operators are currently investing in this relatively new technology with the expectation that these covers will reduce long-term liability with respect to acid generation, drainage and treatment costs. While the design life for cover systems may extend into hundreds of years, we have less than ten years of construction experience and proven performance. Some cover designs appear to be functioning well; however, the performance of many more is now being called into question. The paper presented herein evaluates the integrity of cover systems from a global perspective. Soil cover systems for the control of ARD are being constructed at mine sites located within high rainfall equatorial regions, deserts ranging from low to high latitude, humid temperate regions, and cold-continental climates. While the technology for analysis and design of soil cover systems is well developed, factors that compromise the performance of cover systems (in addition to the paramount issue of climate) relate to material selection and availability, cost and construction practices. Long-term performance is also strongly affected by physical stability (ie erosion), volume change (ie cracking, desiccation, settlement and freeze/thaw cycling), vegetation, soil evolution and ecological stability. This paper provides a review of the application of soil cover systems for the control of ARD. Cases where cover systems have been constructed with both success and failure are illustrated. General criteria and recommendations for cover selection, design, construction, and maintenance are provided.

Jan 1, 2003

By S. Fiore, M. C. Zanetti, C. Clerici

The processes and fluxes of a cast iron foundry plant located in the North of Italy were analyzed in order to determine the amount and kind of wastes produced from the different activities. The main fractions are the molding sands, furnace muds and powders coming from the dust abatement plant, the exhaust lime, the furnace refractory, the metallic shotting and the sludges and powders coming from the dust abatement plant of molding lines for a total production equal to 800 t/d. All wastes were sampled and particle-size and chemically characterized to evaluate the best recycling or reuse solutions. Wastes were sieved and divided in three categories according to the particle-size dimensions: below 0.1 mm, between 0.1 and 0.6 mm and above 0.6 mm. The fraction above 0.6 mm dimension underwent magnetic separation to recover and quantify the potentially available iron fraction. The fraction between 0.1 mm and 0.6 mm was chemically characterized in order to understand if it could be fed to the sand regeneration plant. The below 0.1 mm fraction was characterized to evaluate the following recycling and reuse solutions: additive for molding sands and/or raw material for the concrete industry.

Jan 1, 2003

By R C. Cox

The Brukunga pyrite mine was operated from 1955 to 1972 to supply feedstock for sulfuric acid production in the South Australian fertilizer industry. Iron sulfide ore, mined by Nairne Pyrite Ltd, was finely crushed and concentrated onsite with the concentrates being sent by road and rail to Port Adelaide for roasting. Waste rock was dumped at two locations on the western side of Dawesley Creek and the tailings pumped to a valley-fill storage facility on the eastern side. Production of 1.5 Mt concentrate resulted in 3.5 Mt tailings and 8 Mt waste rock. The site has been administered by the South Australian Government since August 1977 and a lime treatment plant has been operated on the site since September 1980. Environmental issues arising from these operations included: diversion of Dawesley Creek to accommodate the waste rock dumps; dumping of low-grade sulfidic ore in waste rock dumps at the angle of repose immediately adjacent to Dawesley Creek; exposed fresh sulfide mineralisation in the quarry floor; tailings storage facility dam wall constructed by upstream up-lift using tailings and waste rock; an acid water pond sited on the tailings; and pollution of natural drainage. As a result, the minesite rapidly became a source of acid drainage and potential contaminants (sulfate, Al, Fe, Mn, Cd, Zn, and Ni). Various Government bodies have been responsible for considerable effort and expenditure in reducing the flow of acid seepage and contaminants into Dawesley Creek. Presently an estimated 60 per cent of seepage from the waste rock dumps, tailings storage facility and quarry is collected and neutralised prior to discharge into the creek. Tailings have been covered with waste rock, biosolids, neutralisation sludge and soil and planted with grasses, shrubs and trees to reduce rainfall infiltration. Monitoring of water flows, water quality and riparian ecosystems is on-going. Consultants have been engaged to develop cost-effective remediation techniques and a five-member Brukunga Mine Site Remediation Board was appointed to oversee remediation of the site and liaise with the community. Construction has commenced on the diversion of Dawesley Creek, and plans are being developed for the relocation of waste rock back to the quarry benches and upgrading of the neutralisation plant. The paper examines operations, environmental monitoring, remediation, research and community involvement with respect to current best practice.

Jan 1, 2003

By Heinrich Hutchison, Thomas von Moltke, Roelof F. Sandenbergh, Katarina P. Cerovic

In the leaching of gold in aqueous cyanide solutions the rate of gold leaching may be decreased by the passivation of the gold, that may however be prevented or reversed in the presence of lead species in solution. In the present study potentiostatic, potentiodyanamic and XPS (X-ray photoelectron spectroscopy) analysis were used to further clarify the action of lead ions on the anodic activity of gold in alkaline cyanide solutions. It was found that lead increased the gold dissolution rate as it deposited on the gold surface at potentials more positive than its reversible Nernst potential for bulk metal deposition, i.e. by underpotential deposition mechanism, but that it decreased gold activity if present as bulk plated lead on the gold.

Jan 1, 2003

By Guillermo A. Vidal

With the introduction of monitoring technologies, process computers and Web services on Industrial Facilities the need for electrolytic processes automation has been set. Recently designed facilities have substantially improved plant layouts, automated cathode processing and copper harvesting. Despite these advancements only limited progress has been accomplished on the electric current distribution of the process. Lately a number of proposals focused on preventing short circuits and balancing cathode currents have emerged. Among these are the AZSA intercell, the Outokumpu double contact, and the Optibar InterCell Plus. Although these intercell bars are clearly superior to the conventional bar, little or conflicting data is available about their merits relative to each other. Consequently, selection of the best intercell bar for most applications is accompanied by uncertainty, which can lead to less than optimum results. A critical evaluation of the performance of the aforementioned bars on the basis of the application is provided, thereby giving the framework and guidelines for the selection of the best bar for each application.

Jan 1, 2003

By Harri J. Lehto, Marja I. Oja

Empirical models used for predicting the performance of screens on the basis of capacity, cut size, water split and grade efficiency curves were evaluated. This paper reports experimental results obtained with single-deck Derrick screens. The performance of the screen was tested with limestone in a separate screen set-up, in a pilot plant and in industrial scale test runs. The results of pilot plant experiments showed that the measured water split was higher than the measured bypass. This is an indication to that water flow does not entrain the same proportion of all fine particles present in the feed which is advantageous for screening. The experimental design for the industrial test runs was made on the basis of the pilot plant tests. Suitability of the existing models has been checked and accuracy compared. The tests showed that best grade efficiency model was the Rosin-Rammler model. An empirical model for the evaluation of the model parameters as a function of pulp density of the feed and the load of the screen is suggested.

Jan 1, 2003

Transport Canada (Federal Government) constructed the Halifax International Airport (HIA) near Halifax, Nova Scotia, Canada in the late-1950s. Site location criteria were primarily; direct access to the city and a raised flat topography. Unfortunately, the site chosen was located on shallow Meguma group pyritic slate bedrock. In 1982, during the construction of an airport taxiway, it became very apparent that acidic run-off from excavated bedrock at the site was having a negative impact on adjacent aquatic habitat. The ensuing 20 years involved many efforts to rectify the acidic drainage problem with mixed results. Some of the techniques which have been implemented at HIA to address the acid rock drainage (ARD) issue include: dry covers, wet covers, wetlands, electrochemical treatment, open limestone channels, limestone gravel polishing beds, agricultural limestone application, and two hydrated lime [Ca(OH)2] addition treatment plants, the first producing low density sludge and the new one that creates high-density sludge. Based on over 20 years of water quality monitoring data it is apparent that only certain acid drainage mitigation methods have been effective at HIA. In 2000 when the Halifax International Airport Authority (the Authority) took control of the operation and management of the airport, including the ARD issue, it was decided to construct a modern, highdensity sludge, hydrated lime treatment system. This new $CAN 7 million system is now in operation and is achieving compliance with water quality guidelines. Due to high operating cost, a review of methods to optimise the system is being carried out. The HIA ARD problem, though minor by comparison to most mine sites, has provided unique challenges and may provide valuable insights into this urgent environmental and financial issue.

Jan 1, 2003

By Karl J. C. Harries

"12.1. NO DEPRECIATION/GAAPAll calculations and computations relating to the Royalty shall be carried out in accordance with generally accepted accounting principles consistently applied to the extent that such principles are not inconsistent with the provisions of this Schedule and the agreement attached hereto, it being specifically agreed that nothing herein contained shall permit, or be construed to permit, the Operator to deduct any amount for depletion, depreciation, amortization or any deduction that represents a non-cash outlay.Comment: In cases like net profit royalties where recoupment of prior expenditures is permitted, care should be taken to avoid any implication that depreciation may also be taken. It is only logical and equitable that Property Owners should not be permitted an apparent ability to “double dip” with respect to deductions. A provision like this example should accomplish the task. It will be noted that the example specifically contemplates that the negotiated arrangements will prevail over any requirements of GAAP. Accordingly, if the parties agree to an unusual formula for recoupment, it will not be set aside to accommodate GAAP requirements. Under GAAP, revenues and expenditures are accounted for on an accrual basis. In addition, it specifically prohibits the taking of non-cash deductions, which is in keeping with the concept of recoupment.Although in some ways the example states the obvious and could be considered redundant, its presence, especially in provisions contemplating recoupment, makes it clear to the financial people that there may well be some variations from normal practices dictated by GAAP, while at the same time confirming the availability of GAAP to fill any voids.The accounting profession often makes the caveat that application of GAAP is an “art”, not a “science”. GAAP do not provide a cure-all and can create problems that will have to be addressed. For example, GAAP contemplate that asset costs are to be reduced by investment tax credits, which can cause a problem for a payor with more than one mine."

Jan 1, 2003

By John Ralston, Stephen Grano, Yongjun Peng, Daniel Fornasiero

"A specially designed mill which allowed the control of pH throughout grinding was used to study the effect of grinding conditions on galena flotation and galena separation from pyrite. The changes occurring on the mineral surface during grinding were investigated by EDTA extraction and ToF-SIMS measurements.Galena flotation and galena separation from pyrite were strongly dependent on the type and amount of oxidation species produced on galena and pyrite surfaces under different grinding conditions. Iron oxidation species depressed both galena and pyrite flotation, whilst lead oxidation species activated pyrite flotation but had little effect on galena flotation. Optimum galena flotation and galena selectivity against pyrite were achieved by selecting grinding conditions that enabled lead and iron oxidation production to be controlled.Grinding conditions had a large effect on the flotation of the galena particles of different sizes. Flotation of fine galena particles (-10 µm) was depressed by iron oxidation species derived from the grinding media. Chromium grinding medium decreased the production of iron oxidation species and therefore increased the flotation of fine galena particles."

Jan 1, 2003

By Anatoly F. Usov, Vyacheslav A. Tsukerman

"The Russian scientists have developed a new energy saving method for an efficient destruction of the sturdy and hard materials (rocks, ores, frozen soils, concrete blocks ets.) - the Electric Pulse Discharge method of materials destruction (EPD). The detailed researches of a broad circle of problems connected to development EPD-disintegration of materials of a various nature and area of use are executed. The electrical and power characteristics of process, physical fundamentals of selectivity of a breakdown and destruction are investigated, the means of electric pulse splitting and refinements of materials are developed, the technological efficiency of disintegration of industrial minerals estimated.One of the most important characteristics of the EPD-disintegration of ores is the high selectivity of destruction, which provides a large ratio of useful minerals' grains opening, and at the same time, it destroy them less. This ensures in the subsequent stages of beneficiation of ores considerable increase of the extraction and improving the quality of concentrates.The technological tests of various industrial minerals have shown a possibility the EPD-disintegration, as a process that provides the best efficiency of disclosure of useful minerals in all types of ores. Technological and economic efficiency of the method of ore beneficiation is the highest for difficult beneficiated ores with rather low extraction by existing methods. The increase of extraction in this case can reach several percents. As a rule, at a EPD-disintegration the disclosure of mineral grains happens in earlier stages of material comminution than at a mechanical comminution, and with less damage of products. This promotes a simplifying the process of ore preparation and for reducing the power consumption."

Jan 1, 2003

By Bryn Harris

Much has been written over the past twenty years on the removal and chemical stabilization of arsenic from metallurgical process solutions. This paper reviews again the latest developments in this field, and concludes as before that the high-iron arsenical ferrihydrites, together with the high temperature arsenic minerals, scorodite and Type II, remain as the best and most viable vehicles for industrial control and disposal. However, a cautionary note is introduced, in that chemical environments cannot be considered in isolation, and that cogniscence has to be taken of microbiological activity in determining the disposal method. Data are also presented on a survey of industrial practice, which shows that arsenical ferrihydrite is by far the most widely-practiced and accepted method used worldwide. Finally, the disaster in Bangladesh is briefly discussed with reference to lessons that the metallurgical community might learn from this.

Jan 1, 2003

By Vladimir Grujic, Milorad Grujic, Ivan Djurkovic, William Riggs

"In this paper, we have studied efficiency of different chemical structures of frothers on copper ore Majdanpek. The goal was to find out the best suitable chemical structure, which allows good bubble formation, size and interaction, forces on mineral surface. The particle size distribution was between 10 and 100 µm. Our research was oriented on three groups of frothers: alcohols, poly glycol ethers and poly glycols.We also used different collectors based on similar or less similar alcohol group in chemical structure as in frothers, expecting higher stability of air bubble in contact with copper minerals. Minimal potential energy was determinate in the hydrodynamic conditions for different particle sizes. It was founded that it is proportional to air bubble volume on 0.88° and contra proportional to the kinematics viscosity of pulp.Analyzing the results, we find out that poly glycols decreased surface tension the most. Also, it increased amount of coarser particles to the top of pulp. This group is less sensitive to pH value compared to the others too.From the class of frothers with higher efficiency in flotation process, we pointed OrePrep X-75 and X-133 as frothers with expressive frothing characteristic in the alkaline and low alkaline circuits. Special suitability of those frothers for floating copper minerals makes their hetero polar molecules with more than one hydrocarbon radicals connected to one polar group. However, those froters have no nether high or low solubility and are non-ionization. Those froters indicate some small collecting characteristics too. In dispersion systems, those two frothers make two types of bubbles: smaller di < 1.2 mm; V = 0.0008 cm3 and middle di < 16 mm; V = 2.2 cm3 (di – Bubble diameter, V – Bubble volume). Transportation speed of air bubbles it is possible to calculate based on equation: ?s = 27.5 * di 1.4 cm/s. Distribution of free surfaces for chalcopyrite is average 80% in the class –74µm +10µm and 20% in the class -10µm. If we get all class sizes, we find that recovery (R) depends from the time by equation:"

Jan 1, 2003

By Jose Bengoa

Low metal prices and environmental restrictions are always a challenge for copper smelters operation and its productivity. Thus, in order to reduce production costs and control gas emissions, improvements of the Teniente Converter (CT) operation were made at 110 Smelter Plant of Southern Peru Copper Co., 110, Peru, and the main objective was to increase its capacity for smelting copper concentrates without affecting normal operation. The present work corresponds to a recent study conducted during the normal industrial operation of the Teniente Converter in this plant and, it shows the effect of increasing air oxygen enrichment from 28 to 34% on its productivity. The results show an increasing of concentrate smelting rate from 800 to 1370 tpd and hence a notorious improving in copper production, and practically no effect on the refractory consumption. The increment of the concentrate throughput, increases also the SO2 concentration and the sulfuric acid production, showing the effort done by this operation in order to accomplish the environmental Peruvian regulation.

Jan 1, 2003

By P Church

What is the best method of splitting a sample from a reverse circulation drill rig? How important is it to obtain a correctly split sample? What is the impact of an incorrectly split sample? These are just a few of many questions asked daily in the mining industry with regard to sampling. Modern sampling theory is well described in the literature in texts and is taught in short courses throughout the world, however little has been published on the relative performance of sample splitting devices used in the field. This paper compares the performance of the Jones tiered riffle splitter with a cone splitter manufactured by SGS Metal Craft in Western Australia. The testwork was carried out at AnglogoldÆs Sunrise Dam Gold Mine, 55 km south of Laverton in Western Australia. Mineralisation at Sunrise Dam is hosted in a structurally complex framework of shear zones with dips that range from steep (70¦) to shallow (25¦). The deposit is characterised by significant amounts of coarse gold, which presents a challenge in sampling, analysis and grade estimation. The three major areas where sampling errors can occur are in drilling, sampling, sample preparation and analysis. Sampling errors attributable to drilling and sample preparation often far outweigh the errors made at other stages in the process, however historically most effort to identify sampling errors has concentrated on the laboratory and analytical procedures. Splitter design and cleanliness can have a large impact on sample collection and preparation. Splitter performance was tested with respect to sample weights, particle size distribution, and gold grade consistency. The aim was to determine if each particle has an equal probability of being sampled, the resulting sample has integrity, and if any segregation problems occurred. The cone splitter was found to provide the best split in terms of particle size distribution, with no apparent size bias. Duplicate samples had more comparable masses than those provided by the riffle splitter. Most importantly, the cone splitter gave less grade variability between duplicate samples than the riffle splitter. Testwork also confirmed that, like the riffle splitter, the cone splitter must be oriented vertically and the design of the rig or cone splitter trailer should accommodate this requirement.

Jan 1, 2003

By R. Hurman Eric

The dew-point technique of activity measurements take advantage of the volatility of a component in solution. The pressure of the volatile component over a sample is determined from observations of the temperature at which condensation of the vapor occurs. The method is applicable best when the vapor pressure of the components would differ by about two to three orders of magnitude. Experimentally, this is a closed system involving the use of evacuated and sealed transparent quartz sample probes. Furthermore reliable vapor pressure data of the volatile component is essential along with a specialized high temperature furnace capable of giving reproducible results. In this context, the vertical Dew-Point Furnace (DPF) was designed and built after elaborate trails until enough proficiency was gained for reproducible results. Over the years the DPF was modified and improved. The DPF developed was versatile and could easily be used for activity measurements in the isopiestic mode (another method of measuring activities of a volatile component in a solution). The necessary ancillary systems; namely evacuation-flushing-evacuation followed by sealing of quartz sample probes under vacuum were also perfected over the years. As and when necessary the dew-point technique was supplemented by classical equilibration-quenching method employed on the sealed quartz sample probes to reveal necessary phase equilibrium information. The following were studied utilizing the above technique: (i) Activities in CU2S-PbS and FeS-PbS binaries and CU2S-FeS- PbS ternary at 1200°C; (ii) Activities in Cu2S-SnS and FeS-SnS binaries and Cu2S-FeS-SnS ternary at I200°C; (iii) Phase equilibria and thermodynamic in Cu-Pb-S, Fe-Pb-S, Fe-Sn-S, Cu-Sn-S and Ag-Sn-S systems. Most recently the following systems have been tackled: (i) Phase equilibria and thermodynamics in the Ag-Pb-S and Sn-Pb-S systems; and (ii) Activities in Ag2S-FeS-CuzS-PbS quaternary at 1200°C.

Jan 1, 2003

By Lawrence Devon Smith, Keith Spence, William Roscoe

"In March 2003 the CIM Council adopted and approved the document “Standards and Guidelines for Valuation of Mineral Properties” as developed by the Special Committee of the Canadian Institute of Mining, Metallurgy and Petroleum on Valuation of Mineral Properties (CIMVal). The document is referred to as the CIMVal Standards and Guidelines. The document evolved from a specific recommendation by The Mining Standards Task Force (MSTF) of the Toronto Stock Exchange and the Ontario Securities Commission in its Final Report (January 1999) that the CIM form a committee of valuation practitioners to review and advise on approaches to valuation of Mineral Properties. The CIMVal Standards and Guidelines are organized into two parts: •,Standards which are general rules in the Valuation of Mineral Properties. The use of the Standards is mandatory if the Valuation Report is stated to follow CIMVal (although not mandatory in the sense of having regulatory authority). Definitions are given at the beginning of the Standards. •,Guidelines which elaborate on the Standards and, while not mandatory, provide guidance and best practices which are highly recommended to be followed in the Valuation of Mineral Properties.CIMVal specifies requirements for the Qualified Valuator who has the responsibility for choosing the appropriate approaches and methods for the valuation of mineral properties. With regard to the specifics of the application and practice of valuation approaches and methods, CIMVal directs the Qualified Valuator to the large body of published papers, published valuations, presentations and court judgments to guide his or her choice. This is also the approach taken by VALMIN (Australia) and SAMVAL (South Africa). To facilitate the dissemination of industry practice, the CIMVal Committee organized a “Valuation Day” at the CIM Annual General Meeting in Toronto (Mining Millennium 2000), on March 8, 2000. Industry experts presented papers on valuation of Mineral Properties which were subsequently published in a proceedings volume and individually ad technical papers in the CIM Bulletin. The Management and Economics Society of CIM has continued to identify and publish papers on valuation in the CIM Bulletin and Magazine. The present document gathers in one place the CIMVal Standards and Guidelines, the papers from the 2000 Valuation Day, and a number of subsequent papers that illustrate industry practice for the valuation of mineral properties."

Jan 1, 2003

By H J. Ross, R K. Beatson, T J, W R. Fright

Traditional method of explicitly defining three-dimensional (3D) ore-waste and geological boundaries relies heavily on a time-consuming process of manual digitisation. This method of modelling can be best described as surface modelling, as complex surface geometry is built up by digitising points that lie on the surface. With the advent of fast 3D interpolation methods, however, construction of geological surfaces using volume functions is now a practical alternative to explicit modelling of surfaces. Unlike explicit modelling, surfaces contained in volume functions are not explicitly defined or digitised. Instead the existence of surfaces in the volume function is implicit, thus the process of modelling surfaces from volume function is called æimplicit modellingÆ. Based on recent advances in fast scattered data interpolation methods, implicit modelling first defines a continuous three-dimensional function that describes the grade or rock distribution. This volumetric function is interrogated for a grade value, or a geological surface, thus allowing the extraction of the 3D object to be automated and eliminating the need to manually digitise surfaces. Since the function is continuous throughout space and does not depend on a mesh or grid for its definition, the extracted geological or grade wireframes can be constructed at any desired resolution in the specific volume of interest. The volume modelling method can work on scattered drillhole data of any data density, including processing combined information from dense grade control data as well as sparse resource drilling. It offers distinct advantages over surface modelling, including: being able to wireframe geological objects that may take days to digitise in tens of minutes; substantial improvement in modelling accuracy; and the ability to generate conditional models rapidly allowing mining risks inherent in geological modelling to be examined.

Jan 1, 2003

By Herman D. Mendoza

A rapid recovery/recycling process was introduced utilizing the surface-chemical properties of finely dispersed mercury and alumina (Al2O3) fibers in aqueous environment. The conventional method of amalgamation or .ball milling. involves the mixing of a substantial amount of mercury to collect free gold during the grinding stage. In effect, a portion of the mercury is transformed into minute droplets that readily float and disperse in the amalgamation effluent. The fine droplets of mercury in the dispersion readily attached onto the positively charged macroscopic alumina fibers (i.e. = pH 9.8) at conditions pH 3 to 10. When an effluent from settling procedure after an amalgamation-grinding stage is passed through a column-bed packed with alumina fibers, maximum collection of negatively charged finely dispersed mercury occurred at pH 3 to 6. The collection/attachment efficiency was 99.5%. The collected droplets of mercury, which are left in the column-bed of alumina fibers, were subsequently rinsed with alkaline solution at pH 10 to 11.5. At these conditions, both mercury and alumina fibers carry negative surface potentials and resulted in the partial detachment of mercury from the alumina fibers. The detachment efficiency was only 30-35%. The attachment/detachment mechanisms in this study were analyzed using the DLVO theory.

Jan 1, 2003

By Atsushi Shibayama, Toyohisa Fujita, Wan-Tai Yen, Ke-jun Liu

"In this investigation, a sponge gold sample (99.92% pure) has been leached with ammonium thiosulfate solution. The effects of CuSO4, (NH4)2S2O3, (NH4)2SO4, NH4OH and retention time on the gold leaching % (extraction %) and thiosulfate oxidation % (consumption %) have been studied. The copper ion acts as a catalyst in gold dissolution. On the other hand, it also accelerates oxidation of thiosulfate (consumption). It was found in this study that the best gold extraction condition was obtained at 43.2 ks with 0.8 - 1.0x103 mol/m3 (NH4)2S2O3, 30 mol/m3 CuSO4, 2.0 - 3.0x103 mol/m3 NH4OH, 0.4 - 0.5x103 mol/m3 (NH4)2SO4, pH 10±0.2 and 150 rpm. The thiosulfate oxidation was about 15% of the initial concentration.For gold recovery from the pregnant solution, the trioctylmethyl ammonium chloride (TOMAC) was used in this investigation as an extractant to extract gold from thiosulfate solution without pH and other adjustments. The effects of gold concentration, pH, ammonia, thiosulfate and cupric ionic concentrations, extractant and diluent concentrations and retention time on the gold recovery were investigated. It was found that 180 mol/m3 extractant diluted with n-octant at O/A ratio of 1:1 could extracted the 100% of gold in 0.6 ks from the thiosulfate solution at the optimal leaching conditions. The 100% gold stripping could be achieved with 10% thiourea solution."

Jan 1, 2003