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By K. Niboucha, M. Zergoug, S. Brick-Chaouch, H. Houali

"Corrosion is an electrochemical process that causes degradation and deterioration of various steel works (pipelines, drains, cisterns) whether they are buried, immersed, or not. Worldwide, we estimate that corrosion destroys a quarter of the annual production of steel at a rate of 5 tons per second. Several techniques are used to protect against corrosion. Among these processes, Cathodic protection, which is regarded as the best technique to assure the protection of steel, works against this phenomenon. This is achieved either by a system of reactive anodes, or by the technique of impressed current protection or other techniques. Before any installation of cathodic protection, a preliminary study and pre-evaluation of certain parameters must be made. In the present work, we will present an example of dimensioning of an installation of cathodic protection by imposed current of a pipeline using solar energy, where we discuss the following items:•,Evolutions of the potential as well as current along the pipeline and their respective expressions deduced from the laws known as telegraphists;•,Range of protection (potential of protection along the pipeline);•,Influence of the isolation resistance of the coating on the range of protection;•,Effect of the aging of the coating and its influence on the current of protection."

Jan 1, 2005

By S. K. Kawatra, C. A. Hardison, J. Gurtler, T. C. Eisele, K. Lewandowski

Acid soak tests were used to measure the effectiveness of binders in highly acidic conditions to determine their suitability for use in copper heap leaching. Soak tests involved placing the agglomerates on a screen, soaking them in a solution that replicates the pH of the raffinate used in a heap leach, and measuring the quantity of fine particles that passed through the screen. A wide range of binders were evaluated which had potential for functioning in acidic solution. Only a few binders were effective, with the best-performing binders being nonionic polymers designed for dust suppression applications. The most effective binder prevented all but 1.86% of the fines from being released and passing through the screen, while binderless agglomerates allowed as much as 29% of the fines to pass through the screen. The soak test developed for this study provides a useful method for rapidly identifying promising binders at a low cost, and for examining effects such as curing conditions on agglomerate quality.

Jan 1, 2005

By D. Perednis

Fuel cells with thin samaria-doped ceria (SDC) electrolyte films deposited onto an anode support using spray pyrolysis were fabricated. The SDC films were deposited onto porous NiO-YSZ substrates at deposition temperatures between 400°C and 450°C. The influence of process parameters such as deposition temperature, flow rate, type of salt and salt concentration on the quality of the film was studied. A smooth dense film was successfully deposited using the precursor cerium ammonium nitrate and samarium nitrate dissolved in butyl carbitol (33.3 vol.%), 2-methoxy-l-propanol (33.3 vol.%), and ethanol (33.3 vol.%) solvent mixture. A deposition rate of 125 nm/h was achieved.

Jan 1, 2005

By Jan E. Nesset, Phillip J. Mackey, Joo Y. Kim, Giovanni Di Prisco, André R. Laplante

Understanding the appropriate gold recovery to associate with copper recovery when assessing laboratory testing on porphyry deposits is often complicated by several factors including variable and/or complex mineralogy, and the variability contributed by the low Au content of the various flotation products. As a result, gold recovery is often underestimated and the value contributed by the gold to project economics is less than it should be, a problem that could influence overall project viability. Typically, for these types of deposits, the gold recovery is found to be lower than the copper recovery. In this unique project, having the objective of seeking a better understanding of gold recovery relative to copper recovery, mill feed samples from a selection of six operating world-class Cu-Au low-grade deposits were collected along with the mill metallurgical results for the corresponding sample periods. The samples were subjected to laboratory flotation tests, as well as the Laplante gravity recoverable gold (GRG) test, mineralogical assessment and cyanidation leaching. The aim was to better understand the copper and gold recovery relationship, the links between laboratory and plant flotation performance, the influence of mineralogical differences, and the potential for enhancing gold recovery by gravity recovery techniques. A new correlation of copper and gold recoveries based on the results is presented in the paper. The results showed that the link between copper and gold recoveries established in the best laboratory tests were maintained in the plant results, and further, that the potential for improving Au recovery by gravity or flash flotation methods is directly proportional to the amount of gold greater than 75 microns.

Jan 1, 2005

By Helmut Hass, Michael S. Shultz

For many tunneling, deep shaft and deep excavation projects ground freezing is one of the best if not the only technique available to create a watertight and load bearing temporary support system in soft ground conditions. When appropriate attention is given to the details of the ground freezing system design, ground freezing is a very safe method and is economically viable with competing techniques and combinations of techniques. Recent innovative uses of the technique in Europe are highlighted in this paper and compared with current uses in North America.

Jan 1, 2005

We all live in professional silos û comfort zones, where we talk to like-minded people with the same training, experience and view of the world. We note in passing the existence of other disciplines, but they are tolerated rather than embraced. To the geologist, the metallurgist is a mad scientist conjuring gold out of some foul solution about which the less said the better. To the metallurgist, the geologist is a bearded, self-appointed sage who guesses what is under our feet by sniffing the air, and drives a Land Rover badly. As to the view of mining engineers held by both geologists and metallurgists, this is best left to the imagination. And of course we are all confused by the term æmetallurgistÆ. I am called a metallurgist though my skills are in mineral processing not metal processing, but I canÆt be called a mineralogist because that definition is already taken. *Please note that this is available as an extended abstract only*

Jan 1, 2005

By P. Sauriol

This work addresses the design challenges and demonstrates the capabilities of a novel water transfer factor measurement apparatus. Several measurement concepts were screened on the basis of their water transfer factor accuracy using Monte-Carlo generated virtual experiments. The most promising measurement concept was assembled and tested to assess its actual measurement accuracy. For these concept validation experiments, the polymer electrolyte membrane fuel cell was simulated by adjusting the water injection rate to corresponding levels. Combining the anode and cathode measurements, the water transfer factor accuracy was typically better than 0.01. Real-time measurements of the water transfer factor on both anode and cathode sides of a polymer electrolyte membrane fuel cell were achieved. The anode and cathode side measurements were in good agreement with each other; however the anode side measurements were generally more reproducible. A parametric study showed that stream humidification plays an important part in the water transfer across the membrane electrode assembly. Finally the water transfer factor along the channel of a 300cm2 co-current fuel cell was obtained by using a series of six 50cm2 sub cells. The results were in good agreement with predictions from a recently proposed model.

Jan 1, 2005

By V. Vorontsov

Catalysts Mo-Ni-S were prepared by combining MoS2 and NiS in weight ratios 1:1, 1:2, 1:4 and 2:1, each of which was admixed with 5%wt Ag and 5%wt YSZ to increase three-phase boundary surface area of the electrode. For comparison catalysts comprising Co-Mo-S in weight ratio of 1:1 of CoS to MoS2 admixed with 5%wt Ag and YSZ and pre-sulfided NiMoO4 were made. The catalysts were examined for electrochemical oxidation of hydrogen sulfide in solid oxide fuel cells (SOFC) at 850°C temperature. The catalyst prepared from 1:1 (wt. %) NiS:MoS2 demonstrated highest performance. Current density up to 1,330 mA/cm2 and power density up to 300 mW/cm2 were achieved using pure H25 gas, which are the highest among the reported H2S-powered fuel cells ever published in the literature. Anode materials of different NiS:MoS2 ratios have been characterized by means of X-ray diffraction (XRD), simultaneous TG/DSC analysis and Neutron Activation Analysis (NAA). TG/DSC and NAA results show that addition of NiS and Ag increases fuel cell performance due to improved structure/integrity of the anode. It has also been demonstrated that MoS2 is a suitable anode material in H2S-powered SOFC, with high activity towards H25 oxidation and thermally and chemically stable up to 850°C.

Jan 1, 2005

By Christopher J. Oates

Overview ? Mining Codes ? Best Practice ? Mining Standards Guidelines ? Get it right from the start ? External Auditors ? The 5% rule ? MMCRM's - The Key Components ? The MMCRM Report / Certificate ? MMCRM's & Round Robins ? Summary

Jan 1, 2005

CSIRO Minerals, in association with the AJ Parker CRC for Hydrometallurgy, has an active program of hydrometallurgical research in which physical and computational modelling are used to better understand and improve a range of different unit operations. The modelling is based on flow simulation (Computational Fluid Dynamics or CFD), but incorporates other physical and chemical phenomena of importance, such as droplet break-up and coalescence, species transport and reaction. This paper reviews some of the major projects that have been undertaken at CSIRO Minerals and will illustrate the critical importance of hydrodynamics to the performance of unit operations and the improvements that can be made to performance using such modelling techniques. Unit operations that are discussed include solvent-extraction, gravity thickeners, flotation cells, bio-heap leaching and stirred tanks.

Jan 1, 2005

By C Agreda

The Cushion Blasting Technique applied to solve the high risk case history represented by a 10,704 TM rock locate at 120 M from the hydroelectrical plants of 350 KV each, is described, analyzed and discussed. The generation and distribution of 700 KV produced by two hydroelectrical plants must not be interrupted by any reason, because the 26 district of the province of cajatambo, of the Lima department; would not have electrical power. The search of the best alternative and methodology, the drilling and blasting pattern calculations, charge design and loading, connections and initiations of the 50 blasts are described, analyzed and discussed. Finally, the excellent results from a technical, economical, enviromental and safety point of view of the 50 primary blasts are discussed and emphasized.

Jan 1, 2005

By J. Jankovic

Numerous advantages have been recognized for solid oxide fuel cells (SOFCs) operating at temperatures of 500-700°C. However, there are several issues related to low temperature SOFCs, such as high electrolyte resistance and high electrode polarization. One of the routes to enhance the electrode performance, particularly for the cathode, is to use new materials with optimized microstructure. In this work, the plasma-spraying technique, recognized to have several advantages over presently used deposition techniques, was used to deposit cathode materials onto ceramic and stainless steel substrates to obtain highly porous structures. Cathode materials with composition of Lao 6Sr0.4Co02Fe0 8O3 (LSCF) were employed in the powder form. The LSCF was prepared from powder precursors with different pore formers and binder levels, or from already produced, single-phase LSCF. The (La0.8Sr0.2)0.98MnO3 (LSM) cathode material was also processed for comparison purposes. The deposition process was developed to obtain coatings with good bond strength, porosity, film thickness and residual stresses. The phase and microstructure of deposited materials were characterized using XRD and SEM.

Jan 1, 2005

By Sunil S. Basarkar, Dilip M. Dewaikar, Rajesh H. Gajjar

"A load transfer program AXPILE was developed for simulation of the loadmovement characteristics of socketed piles of the Mumbai reg ion. This program used empirical relationships for ultimate shaft resistance at pile-rock interface recommended by Zhang and Einstein (1998). According to their recommendation, ultimate shaft resistance at pile-rock interface is related to the square-root of uniaxial compressive strength of intact socket material by a parameter C, which ranges from 0.4 for smooth sockets to 0.8 for rough sockets. Results of three instrumented pile load tests were compared with the AXPILE generated results. The comparison of analytical and field estimates of the unit shaft resistance confirm the recommendations of Zhang and Einstein (1998) on the unit side shear parameter c,, which was found to be in the range of 0.35 to 0.67.INTRODUCTIONInstrumented pile load tests were carried out on the test piles at the Bandra-Worli sea link project in Mumbai city of western India. High capacity socketed piles were required to take up loads from the superstructure. Hence, in addition to the available toe resistance, an accurate measurement of the shaft resistance in socket portion was desired. The instrumented load tests incorporated Osterbergcell (0-cell) assisted by strain gauge instrumentation to estimate the shaft resistance mobilization in the socket portion.AXPILE load transfer program was developed for load-movement simulation of socketed piles (Basarkar, 2004). The load transfer algorithm based on Coyle and Reese (1966) was incorporated in this program, which used empirical correlations and functions to account for load transfer in piles through shaft and toe resistance.This paper compares the computed unit shaft resistance from the AXPILE program with the measured values recorded from the instrumented pile load test."

Jan 1, 2005

By M. J. Gagnon

The agglomeration of particulate materials is used in many mineral processes to enhance the settling of the fine particles, Depending upon many physical and chemical parameters, the aggregates demonstrate specific density-size distributions, In this study, a fractal model of the agglomeration process is introduced, Based on reliable experimental data and on physical calculation, the model presented helps to envisage the initial formation of the micro-flocs, and to interpret the subsequent interactions between the aggregates in terms of either coagulation or flocculation, Data from different sources, materials and different agglomeration processes are analysed and compared in the light of the proposed model.

Jan 1, 2005

By Hee-suk Yun, Dae-jin Hwang, Jeong-woo Seok, Myoung-mo Kim

"In this paper, the accuracy of the data measured by a newly developed displacement measuring system, DPRMs (Digital Pile Penetration and Rebound Monitoring system) and its applicability as a quality control tool were verified by field measurements of pile penetration and rebound for pile driving performed at 3 construction sites and 1 test site. The DPRMs data were found to be much better than handwork data. A new dynamic formula for pile capacities is proposed uses the results of a pilot dynamic load test and the final pile penetration. The ratios of pile capacities obtained by the new formula to those by the dynamic load test were 94%±7.4% in the contrast with 123±28.3% by the 5S formula and 68±24.0% by Hiley's formula. This result shows the superiority of the new formula. The ratios of the maximum compressive stresses calculated by using DPRMs to those calculated by using PDA (Pile Driving Analyzer) were about 90-110±10%. This result confirms the applicability of DPRMs as an overdriving monitoring tool. Two sets of DPRMs were used to measure the 3-D displacement behavior of a pile head at the test site. The more the pile head moves laterally, the less the final set values were expected because of the loss of driving energy, but this trend was not obvious within the limited data obtained at the test site.INTRODUCTIONPile construction monitoring consists of two parts. In the first part, enough capacity of the pile is secured to stand the design load. In the other part, pile damage during driving is prevented. Although several methods can be applied to achieve the first part, PDA is nearly the only tool for measuring pile stress.Several methods such as a static load test, a dynamic load test, an Osterberg cell, and numerous driving equations can determine the pile capacity. Among them, the static load test and the dynamic load test are most widely used. The static load test is advantageous because it has the highest reliability. The disadvantages are as follows: it is costly and time-consuming. Also, the capacity of the pile under construction cannot be evaluated. The dynamic load test has lower reliability than the static load test, but it is cheaper than the static load test, is reliable enough to determine the pile capacity, can evaluate the capacity of a pile during construction, and can offer information about construction conditions such as the pile integrity and the pi le stress during driving. The dynamic load test takes a relatively short time and is low cost compared with the static load test. However, it is still costly, time-consuming, and unnecessary to apply to all piles in the field as a construction measurement tool. Therefore, driving resistance (blowcounts) is commonly measured to confirm the pile capacity at construction sites."

Jan 1, 2005

Sishen uses a state-of-the-art tracking system to track material from its position in blast blocks through various stockpiles and crushers. Qualities are blended directly to the crusher as opposed to blending from stockpiles. This poses an interesting challenge to the planning department to simulate these conditions. The software used in these simulations are Whittle 4X and Maximiser for long-term planning, Xpac for medium-term planning and Mine Works Planner for short-term planning. Geological models and mine design layouts utilise Surpac. Sishen introduced Xpac a number of years ago; the system has developed and changed over the years. With the Sishen Expansion Project (SEP), which aims to utilise low-grade material, major changes to the planning process have to occur. SEP requires that the mine have two different plants, which utilise two different ROM feeds and have different beneficiation curves. Xpac is used to produce a rolling 18-month plan, which is as close to actual operations as possible. In order to do this, the simulations have to take into account the plants beneficiation curves, stockpile movements, hauling distance and equipment needs. On top of this, the schedule has to continually consider specifications for Fe and the contaminants. Plant yields also have to be kept within a certain bandwidth. Xpac is used to simulate the above parameters, as well as generate the raw data required to produce a mine budget. The paper will also show how the 18-month planning process and subsequent planning processes are measured and aligned. Xpac has proved to be an excellent tool to achieve these goals.

Jan 1, 2005

Following the Moura No 2 Wardens Court of Inquiry and subsequent changes to the Queensland Mining Legislation there is a requirement in Queensland coal mines for: a person with the recognised competencies to be appointed at each underground coal mine to the position Ventilation Officer; and the person is directly responsible for the implementation of the mine ventilation system and for the establishment of effective standards of ventilation for the mine. The Regulations require that an underground mine must have principal hazard management plans that provide for at the least the following: emergency response, gas management, methane drainage, mine ventilation, spontaneous combustion, and strata control. Other than strata control all the plans require the ventilation officer to have roles and responsibilities to develop, control, monitor and undertake actions in relation to these plans.There are also another 34 Regulations that either directly or indirectly requires the Ventilation Officer to take actions.The purpose of this paper is to outline the information that the regulators look for in sealing plans and the actions the regulators will take if the sealing does not go to plan (TARPs being exceeded).

Jan 1, 2005

This paper outlines the role of commissioning in the project cycle, shows how to get organised for commissioning and describes the principal commissioning activities. Emphasis is placed on appointing key commissioning staff early in the project to coordinate the preparations for commissioning and on detailed planning and tracking to ensure that the required commissioning activities are performed satisfactorily. The management of safety during commissioning is reviewed.

Jan 1, 2005

By D McInnes

Rather than look at the problems associated with sampling, this paper deals with the issue of sampling and blending to optimise revenue û predominantly in the mining industry. An example of the use of this methodology in the agriculture industry is also presented. Mining companies, in particular, are experiencing a boom in commodity prices and many believe the industry is in the middle of a æsuper cycleÆ. Production levels are being escalated dramatically to meet the demand coming from China and India. This in turn has further stretched the capacity of our rail and port infrastructure û resulting in significant shipping queues around most Australian commercial ports and increased demurrage costs for the producers. Mining companies are now looking for effective scheduling, planning and blending to maximise production and reduce demurrage charges û given the current infrastructure constraints. Mining companies can no longer use spreadsheets to run their business. This paper further looks at how these outcomes can be met by optimised blending using an integrated supply chain management system such as MineTrak together with effective sampling and analysis.

Jan 1, 2005

By R Moreby

This paper is a demonstration of the techniques developed during an Australian Coal Association Research Program (ACARP) funded research project aimed to develop aids, principally computer based, to assist mine personnel to more efficiently manage significant incidents in coal mines. These aids include software to aid in the location of the incident, electronic information storage and retrieval, online site emergency response manuals and software to aid in decision-making.

Jan 1, 2005