Search Documents

By L. Diels

About 45% of the contaminated sites are dealing with heavy metal problems. Metals are spread in the environment by mining activities, surface treatment and non ferrous processing. As heavy metals can not be degraded, removal or immobilization (leading to bioavailability reduction) are the only risk reducing measures that exist. The currently best available technique for remediation of heavy metal contaminated groundwater is to pump the contaminated water and to treat it in a wastewater treatment plant installed on the surface. Next to this often used, but expensive, pump and treat technologies, heavy metals can be immobilized by inducing sulfate reducing bacteria (SRB) to transform the sulfates, that are very often present in the same groundwater (due to the metal mining or processing activities), into sulfides. These sulfides will precipitate the metals as insoluble metal sulfides. At the moment several studies have demonstrated the feasibility of this In Situ Bioprecipitation Process (ISBP) for the removal of heavy metals from ground-water as well at lab scale (batch and column tests) as at field scale. However, some questions arise concerning the continuation of the process, the efficiency and the sustainability of the precipitates. The presented study will try to answer these questions. The study is based on more than 10 different studies, all done by the same authors, on different groundwaters and aquifer samples. The presentation will give an overview of the guidelines necessary for a correct and successful bioprecipitation process with stable metal sulfide precipitates. An important question in the ISBP is related to the sustainability of the heavy metal precipitates. It could be observed that the interruption in the carbon source delivery also stopped the in situ bioprecipitation process. Depending on the metal also some release from the precipitate could be observed. It was shown that release can occur with Co and Ni. Aquifers, on which the metals precipitated during the ISBP, were treated in a sequential extraction process under an-aerobic and aerobic conditions. It could be shown that especially under the anaerobic conditions the Zn and Cd precipitates changed from the leachable and the exchangeable fraction to the organic or Fe-Mn fraction (i.e. from the unstable to the stable fraction). The same could be observed for Co and Ni but still some fraction was present under a more available form. On the other hand it could be shown that large differences were observed concerning the heavy metal speciation on the aquifer in function of the used carbon source during the ISBP. The molasses treated systems showed a much more available heavy metal fraction on the aquifer compared to the lactate or HRC® treated groundwater. The different speciation forms based on the use of different carbon sources will be discussed in detail. It will pay attention to the influence of the carbon source, the efficiency of the induction of the bioprecipitation process, the influence on the competence between sulfate reducers and methanogenic bacteria and the influence of low pH on the ISBP. It seems that acetate, which is also a degradation product of fermentation of some carbon sources, can inhibit some sulfate reducers. Also the relation between slow release compounds and immediately available compounds will be explained. Finally a pilot study will be presented showing the problems that can be encountered during this process. Focus will be put on the induction of the process, the keeping on of the process and the follow up of the process by the installation of in situ mesocosm socks. These results will allow the correct implementation of the ISBP with an eye on longevity and sustainability of the process and present the ISBP as a much more sustainable alternative to the pump and treat technology as measure for heavy metals contaminated groundwaters.

Jan 1, 2006

By R. F. Baxter, C. M. Read, R. I. McCulloch

"Globalization of the aluminium industry continues to increase the pace of change and the intensity of competition, while simultaneously, society demands better products, cleaner technologies and sustainable industries. Bechtel, a global engineering, construction and project management company, is not immune to either the opportunities or the challenges created by globalization. However, and not withstanding the challenges, for aluminium industry ""players"" with a true global perspective, globalization presents very real opportunities that may be leveraged to deliver value creating goods and services. The following paper will focus on the exploitation of one of the opportunities created by globalization in the Knowledge Management domain - the application of high level tools and methodologies to improve global delivery of greenfield and brownfield aluminium smelter construction projects. Specific examples will be presented of value driven solutions that were delivered at the early stages of project engineering."

Jan 1, 2006

By D. Schreuder

Conditions in the South African market relating to atmospheric emission control has changed dramatically over the last 10 years. Companies have become more responsible, environmentally aware, and have to comply to more stringent environmental limits set by legislation. This paper describes briefly the current best available atmospheric pollution abatement technologies relating to particulates, acid gases, NOx, acid mists, aerosols, mercury, dioxins and furans. Mention is also made as to the best practices for product work-up and waste product disposal.

Jan 1, 2006

This paper presents the development of a knowledge based integrated decision support system (E.X.I.S) for the extractive industries to provide information concerning the environmental impact of extractive operations on land quality, surface and ground waters, and the best solutions for the rehabilitation/revegetation of the waste disposal areas to the relevant target groups (extractive industries, regional authorities, national authorities, research institutes, public). GIS was integrated with the decision-making models for the rehabilitation and revegetation of mine spoil. The system design involves several steps including site selection ? mine type identification ? waste identification ? selection of rehabilitation (revegetation or other methods). The knowledge based model consists of two integral parts: the model base, in which the input data are processed and classified using special fuzzy algorithms and criteria and the knowledge model, which hosts the various decision algorithms concerning evaluation of vegetation covers, selection of trees and plant species, selection of rehabilitation and revegetation schemes and also economic analysis for each option. The system input will include parameters on site characteristics (climate, topography, geology, hydrology etc), waste type and properties (physical-geotechnical and geochemical data) as well as environmental parameters of the existing waste disposal area. Based on the values of the above parameters and the characteristics of the rehabilitation technologies developed worldwide, the system, using IF-THEN rules will define a list of appropriate techniques for the rehabilitation of the examined waste. Then, the model will involve the application of multi-criteria analysis (MCA), i.e. a structured system for ranking alternatives and making selections and decisions. Each technique shall be judged based on its behavior into four fields, i.e. financial, social, technical and environmental criteria. In turn these fields will be analyzed into a lower level of evaluation criteria.

Jan 1, 2006

By John W. Lund

The Geo-Heat Center has been investigating the utilization of waste silica from the Cerro Prieto geothermal field for several years. The main objectives of the research were to com-bine silica with various additives to (1) form bricks for low cost housing, and (2) to produce a suitable road surfacing material. The various additives that were tested included hydrated lime, portland cement, plastic fibers, asphalt cement and emulsified asphalt. The silica-cement combination produced the strongest bricks and had the best weather resistance, whereas, the silica-lime combination produced the bricks with the lowest thermal conductivity and specific gravity density. The addition of plastic fibers to the silica-lime mixture improved both strength and weather resistance. The combination of asphalt and silica is not suitable as a road surfacing material, however, silica-cement appears promising.

Jan 1, 2006

By C. Vasilescu

Phytotechnologies use plants to remediate various media impacted with different types of contaminants. These technologies can be implemented either in situ or ex situ. The affected media in which phytotechnologies can be applied include soil, sediments, groundwater and surface water. They are best applied at sites with shallow contamination of organic, nutrient, or metal pollutants that are amenable to one of five treatment options: phytoextraction, phytotrans-formation, rhizosphere, bioremediation, phyto-stabilization or rhizofiltration. Phytoremediation can be used along or, in some cases, in place of mechanical cleanup methods. Phytoremediation can be used to clean up metals, pesticides, solvents, explosives, crude oil, polycyclic aromatic hydrocarbons and landfill leachates.

Jan 1, 2006

During the hydrometallurgical processing of the major base metals Cu, Zn, Ni and Co, the presence of iron is normally a serious complication, and iron separation from the pay metals usually constitutes one of the main challenges for the metallurgist. There are many instances, however, where the presence of iron is beneficial, or is even required. Two cases are presented where iron is required during the processing of base metals. The first example deals with the use of ferric sulphate to oxidize sulphides, more particularly copper and zinc sulphides, under atmospheric conditions. The results presented confirm that ferric ion leaching is efficient, particularly when the oxidant is regenerated during the process. The second case is the use of iron to solubilise refractory cobalt oxide minerals; examples, including pilot plant results, are presented for various ores from Africa and Central America. In both cases, this paper reviews the basic concepts involved and provides details of their application.

Jan 1, 2006

By Mark Bauckman

Discussion Topics • Market Needs • Technology Developments & Best Practices • Industry & Government Developments • Future Possibilities & Your Role

Jan 1, 2006

By Tom Watts

Bulk Security Best Practices

Jan 1, 2006

By T. Rahimzadeh, C. W. Trueman, S. Farzaneh, S. V. Hoa, I. Abdalla

This paper presents the shielding effectiveness (SE) of woven continuous carbon/epoxy composite materials. The theoretical and physical concepts behind the experimental results are demonstrated in details. The influence of frequency, the overlapping angle between overlapped layers and the number of overlapped layers upon the EMI shielding of composite sheets are discussed. In this work, in particular, the epoxy layers are considered as dielectric apertures of the conducting carbon fiber slab for the interpretation of the experimental results. The experimental results, using ASTM standard D4935-89, indicate that the SE can reach values greater than 90 dB above 500 MHz.

Jan 1, 2006

By M. Rafati

In this investigation, the effects of T4 and T6 heat treatments of AZ91 magnesium cast alloy have been studied. The effects of different microstructural details such as morphology, size and distribution of precipitates and their influence on fracture mechanisms were investigated by optical and scanning electron microscopy. The mechanical strength of the alloy after T6 treatment was found to increase in comparison to the T4 treatment, due to the formation of discontinuous precipitates in the grain boundaries. Precipitation in this alloy occurs in two ways: continuous precipitation, which nucleates and grows inside the grains, and discontinuous precipitation, which forms at the grain boundaries. During ageing, the length of the continuous precipitates increases, and, hence, interprecipitate distance decreases. The formation of discontinuous precipitates causes initiation and propagation of cracks at and the weakening of the grain boundaries. This is the principal reason for the reduction of the ultimate tensile strength in T6 heat treatment in comparison to the T4 condition.

Jan 1, 2006

By X. Cao, M. Xiao, M. Jahazi

Magnesium alloys have low hardness, wear, erosion and corrosion resistance. The repair of service-damaged aerospace components made of magnesium alloys is an attractive solution in terms of time and cost saving. The feasibility of applying laser beam technology to repair ZE41A-T5 magnesium alloy sand castings in the machined surface conditions was studied using a continuous wave 4 kW Nd:YAG laser system. The influence of process parameters such as laser power, cladding speed, wire feed rate and defocusing distance on the shape, size and area of single cladding beads is discussed using a process optimization software. Sound single clad beads with good geometric characteristics were obtained using strictly controlled laser process parameters. The overall results indicate that laser surface cladding using filler wire has the potential for repairing aerospace components made of cast magnesium alloys.

Jan 1, 2006

By R. M. Kear

Strategic and tactical planning are both required in the mining industry but have completely different objectives and require different environments. If these are not fully understood, then the best value for a mining operation may not be realized. This paper examines the differences in these approaches and how they interface in the mining environment. The objectives, content, skills required and the implied management issues for these two components are examined with the hope that this will assist management and the planning teams in defining their respective roles and expectations. The opinions are those of the author based on his experience on several mining operations and projects.

Jan 1, 2006

By L. S. Almeida, U. A. Courbassier, C. T. Guimãaraes, M. N. Souza, V. L. Silva, H. P. Dias, G. A. Bicalho, B. S. Rocha, P. N. Rodrigues, A. Carnevale

During primary aluminum production the anode changing is a very important task. So improvements on it will be essential to avoid disturbance and have a better operational control. After anode changing a good current distribution will be guaranteed using a cavity cleaner and precise anode setting. Albras switching a manually anode setting to an automatic one solved the setting problems. In this paper it will be shown some pot line results and the improvements on workers ergonomic and safety conditions. The device was developed in a partnership between Albras and Pesto.

Jan 1, 2006

By F. H. Samuel, H. Tahiri, S. Valtierra, H. W. Doty, A. M. Samuel

L'affinage des grains dans les alliages d'aluminium consiste à augmenter le nombre de sites de cristallisation de la phase a-Al afin d'obtenir une structure fine. Les alliages mères de type Al-Ti-B sont largement utilisés comme raffineurs des grains. Cette étude a pour but d'établir des mécanismes convenables d'affinage des grains dans l'alliage A356 en utilisant cinq alliages mères et deux températures de coulée (750°C et 950°C). Les résultats montrent que la phase a-Al prend une forme selon l'alliage mère ajoute; les échantillons coules a haute température montrent une taille de grain plus grosse; les températures de germination et de croissance augmentent avec I' augmentation du Ti ou du B et la taille des grains diminue. L'alliage mère Al-4%B montre une puissance remarquable en comparaison d'autres alliages mères. Pour cet alliage mère, le titane résiduel dans l'alliage A356 réagit avec le bore pour former TiB2 qui, par la suite, agit comme un germe actif pour la phase a-Al.

Jan 1, 2006

By M Field

Kimberlite pipes, as opposed to dykes, sill and secondary deposits, are the primary target for diamond exploration companies because they have simple geometries and can contain large volumes of potentially diamond-bearing ore. Once discovered, important decisions have to be made regarding the sampling of these geological entities to establish the total volume of ore present, and to define the internal geology, which can be complex in nature and controls the distribution of diamond grade. It is essential that as part of this process the uncertainty in constructed geological models are assessed. In this paper the Orapa AK1 kimberlite pipe in Botswana is used as a case study to explore a potential methodology for defining this uncertainty. The uncertainty of the rock volumes of different types can be characterised by a geostatistical approach. Geostatistical simulations, based upon a plausible representation of the geological bodies, provide different possible images of the orebody that can be considered as different realities. By testing different borehole layouts and drilling the orebody virtually on the computer, many different, but equi-probable realisations of the pipes can be produced. It is then possible to estimate the rocksÆ volumes and compare them with the actual ones. A statistical analysis of the relationship between estimation error and the number of boreholes can then be used to optimise the next sampling campaign. The rock volumes are obtained from a two-step simulation process. Firstly, the pipe geometry is simulated by means of introducing variations around the geological block model, by an original method called centre point simulation (CPS), which has been developed for this purpose. Secondly, the internal geology is then simulated within the pipe. The methodology for simulating the internal geological zones has to be adapted to the level of information and to the geological structure itself. The upper portion at Orapa AK1 is filled with sedimentary crater facies. Here plurigaussian simulation techniques can be applied that are adapted to the simulation of sedimentary facies. The central zones of the pipe are typically subvertically-oriented massive volcaniclastic deposits and breccias and the lower regions comprise a complex root zone. CPS is appropriate for these zones.

Jan 1, 2006

By M. Aljarrah

The phase equilibria in the Mg-Al-Ca system was investigated experimentally by differential scanning calorimetry (DSC) and X-ray diffraction (XRD) techniques similarly the Mg-Al-Sr system has been studied using DSC and XRD as well as scanning electron microscopy/energy dispersive spectrometer (SEM/EDS) and quantitative electron probe micro-analysis (EPMA). A new ternary solid solution MgxAl4,xSr was confirmed in Mg-Al-Sr system, which is a substitutional solid solution of Mg atoms in Al4Sr. Maximum solubilities of 21.3 at.% Al in Mg17Sr2 and 11.4 at.% Al in Mg were observed. It was also noticed that Mg38Sr9 dissolved 12.5 at.% Al. In the Mg-Al-Ca ternary system, one of the invariant transformations predicted by thermodynamic modeling was verified experimentally and found to occur at 512°C with composition close to 10.8 at.% Ca, 79.5 at.% Mg and 9.7 at.% Al. A ternary solid solution (Mg,Al)2Ca was confirmed where large solid solubility of Al in Mg2Ca was observed.

Jan 1, 2006

This paper is for mine managers. It is about maintenance of mining equipment. This is an extremely broad subject so this paper is given with the caveat that it necessarily contains generalisations, not true in all cases, but broadly correct. The job of mine managers is to be good at making money from the excavation and preliminary treatment of mineral. To do this well, they need to understand the cost and value drivers in the business. This includes understanding the drivers associated with maintenance. Maintenance is often identified as a problem at mine sites. It is frequently listed as the cause of production shortfalls when reporting. The state of maintenance within mining as an industry is generally among the lower end of the range, when compared to manufacturing, petrochemicals, etc. Why is this? Experience and review of many audits and evaluations of maintenance has shown that some patterns are consistent with good performance and some consistent with poor performance. These often centre around the time horizon of the management team and are associated with knowing the sensitivity of the business to certain maintenance drivers and the mechanisms of maintenance and their results. To summarise, some common misunderstandings can be listed as statements that are obvious and extrapolations from those, which are not necessarily correct. For example: High availability of equipment is necessary for production. Incorrect extrapolation:focus on availability will produce high production. Design is often the greatest factor in determining the reliability of a mining machine. Incorrect extrapolation: the newest and biggest machines generally have the lowest cost operations. Operation has an enormous impact on machine productivity and reliability. Incorrect extrapolation: the fastest operators are generally the best from a productive point of view. Some maintenance improves the performance and reliability of machines. Incorrect extrapolation: more maintenance will give you more reliability. Some maintenance depends on disassembly and reassembly of components. Incorrect extrapolation: assembly is basically the reverse process of disassembly. Maintenance improvement in the mining industry in the last 15 years has focused largely on planning and systems improvement. Incorrect extrapolation: most of the problems in maintenance can be traced to a lack of planning. Actions based on flawed extrapolations will steer a business suboptimally. It is therefore important that the mine manager understands these issues so that the improvement effort can be directed to the greatest benefit.

Jan 1, 2006

The desire for minimising impacts of mining activities on the environment, and in particular, water resources; is usually tempered by the costs and practicalities of implementing æbest practiceÆ measures. This paper briefly discusses the theoretical and practical options for water management for typical mines and quarries in a range of environments to assess if adverse impacts can be completely eliminated or at least be perceived as doing so. The regulatory requirements for water resources management are usually an essential part of mine planning and operations that can be a primary focus for all stakeholders. As such they can distract attention from implementing best practice in water management for the benefit of the environment and the community for altruistic reasons that have a long-term benefit for the mining industry as a whole. Cost-effective options for supply, demand and quality management of water that comply with basic regulatory requirements are readily available. Making a mine æinvisibleÆ in a practical sense, in terms of impacts on water resources would require eliminating potentially contaminated discharges, minimising demand, maximising reuse and recycling and putting back a healthy proportion of the clean water that is taken out of the natural environment for use in mine operations. This may sound simple enough and there are many well-known standard approaches that are usually applied. But which are the most effective, and who benefits? New approaches to water management are becoming more affordable and can benefit the bottom line as well as the environment, but can they make a mine ædisappearÆ? The perception of whether a mine is æinvisibleÆ in terms of its impacts on water resources is as important as the actions taken to try to achieve such an objective. The viewpoints and thresholds of perceptions of the different stakeholders are therefore relevant to how ævisibleÆ mining activities become.

Jan 1, 2006

By F. Chiesa

The permanent mould process, which is a favoured process for producing premium quality aluminium casting, is rarely used to produce magnesium alloy parts. This may be attributed different factors such as: the reservation with which the automotive industry considers using magnesium in structural castings; also the relative hot shortness of most magnesium alloys when compared to aluminium A356/357 is another factor. A third reason stems from the fact that the "heat content" of magnesium is much less than that of aluminium, resulting in the difficulty, for a relatively slow process such as permanent mould (versus pressure die casting), to reach a mould dynamic equilibrium temperature sufficiently high to avoid premature freezing and misruns. The present work will address this problem by carrying out controlled cycling of a laboratory mould, poured with aluminium and magnesium alloys. The influence of insulation of the mould and artificial electric heating on the run-in mould temperature will be determined experimentally. A thermal model will be sought for these thermal devices that will allow to predict the thermal behaviour of moulds of different geometry before a single casting is poured. The model will be tested on an industrial casting in a workshop environment.

Jan 1, 2006