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By D. M. Muir

The mineralogy of residues formed during the pressure acid leaching of arid region nickel laterite ore varies according to the salinity of the process water, alkali cation additives and the overall acid loading. In fresh water, hematite is the main iron-bearing leach residue component, together with amorphous silica and hydronium or sodium alunite/jarosite [(H3O,Na)(Fe,Al)3(SO4)2(OH)6]. As the process water salinity increases, or as NH4+ or K salts are added, alunite/jarosite is the kinetically favoured iron-bearing phase accompanied by an increase in acid consumption. The alunite/jarosite appears as two XRD distinct phases with different Fe:Al molar ratios. In weakly saline water, iron-rich alunite/jarosite slowly transforms to hematite and an aluminium-rich alunite/jarosite together with the release of acid. The addition of potassium salts forms a more stable alunite/jarosite whilst the addition of ammonium salts leads to greater transformation of alunite/jarosite at 250°C. Weakly saline process water gives enhanced nickel recoveries, whilst strongly saline process water gives lower nickel recoveries but higher soluble iron because of chloro-complexation. SEM and microprobe analysis shows very little nickel is associated with the alunite/jarosite and hematite phases. Nickel losses to the residues are attributed to adsorption on amorphous silica and to a lesser extent on alunite/jarosite.

Jan 1, 2006

Korea has about 68 hundreds million tons of limestone's reserves. Still, high-Ca2+ limestone containing more than 52% calcium oxide makes up for about 12% only; hence the need for securing and effectively developing limestone. The best solution is to manufacture precipitated calcium carbonate (PCC). The synthesis of PCC using high-Ca2+ limestone has several advantages including the efficient development of resources and easing the import dependence on PCC. The first step is the selection of suitable limestone for the synthesis of PCC. In this study, formation age was decided as the primary key point, with its effect on calcination, hydration, and synthesis of aragonite investigated. Results showed that the yield of aragonite increased when newer limestone was used. On the other hand, neither the activity and bulk density of quicklime nor the particle size of aragonite was affected by the formation age, although special values were registered following each formation age. Moreover, the bulk density of quicklime and particle size of aragonite tended to increase with decreasing activity. This result is different from that of the other experiment. Therefore, a suitable method for measuring the activity of quicklime for use in the manufacture of PCC must be established.

Jan 1, 2006

By S. B. Kang

Magnesium has poor ductility at temperatures lower than 225°C and, as a result, Mg alloy sheets are produced via fairly complex thermomechanical processes consisting of numerous sequential steps of hot (warm) rolling with low reduction and intermediate recrystallization annealing operations. In context of the present study, a simple technology for the fabrication of magnesium sheets by hot (warm) rolling was applied to various magnesium alloys. The misch metal addition in those AZ alloys was done to evaluate the deformation behavior. Tensile tests were carried out for those AZ alloys after applying different heat treatments. The precipitation of ß phase (Mg17Al12 phase) induced different microstructures with various cooling method from solution treatment temperature, and also with various annealing treatment temperatures.

Jan 1, 2006

By N. Sauret-Szczepanski, G. Patry, S. Gauthier, G. Potvin, C. Munger

Adsorption/thermal desorption with sorbent cartridges and analytical method using gas chromatography coupled to mass spectrometry (GC/MS) was developed for the determination of tetrafluoromethane (CF4) and hexafluoroethane (C2F6) emitted from primary aluminum smelters. A customized cartridge was built like a packed column with a stainless steel tube filled with a specific resin. The optimization of adsorption and desorption parameters was carried out to support the PFC sampling for all aluminum production technologies. The proposed method showed good linearity for concentrations ranging from 10 to 500 ppbv for CF4 and from 5 to 500 ppbv for C2F6 with correlation coefficients above 0.999. In certain conditions, the detection limits of the analytical method reached 0.3 ppbv for CF4 and 0.15 ppbv for C2F6- Using this methodology, a field campaign was carried out using a sequential sampler allowing the simultaneous sampling of PFC with cartridges and sampling bags. The results showed no significant difference (t-test) between the two sampling technologies and no breakthrough was observed from the cartridges .

Jan 1, 2006

By Garth Howlett

In 1998 the Matanuska-Susitna Borough formed the new port district at Point MacKenzie, known as Port MacKenzie, located directly across the Knik Arm from Anchorage. In 1991 PND Engineers Inc. (PND), working with the Matanuska-Susitna Borough manager and port director, envisioned a fill structure at Port MacKenzie with a 500-foot-long Open Cell? sheet-pile bulkhead face extending to EL -20 feet Mean Lower Low Water (MLLW) at the face. Now under operation the fill created 5.5 acres of tideland property using local materials for fill. The fill is protected from 2- to-3 foot-thick ice pans and 9 feet per second (fps) tidal currents by an envelope of armor rock. Construction required working in water with 30 to 40 feet of tidal variation. Construction required placement of frozen fill in water depths possibly exceeding 50 feet, creating real concerns about soil consolidation and long-term maintenance issues. A plan was prepared to consolidate the soils using Vibracompaction. Soil Density and consolidation were monitored during the work. In 2003 the port district and NPI, a wood chip export company, formalized an agreement to construct a deep water port facility at Port MacKenzie for cape-class bulk carriers. PND provided planning, studies, geotechnical investigation, design documents and construction inspection for a 500-foot-long trestle with a platform dockhead and dolphins providing 1,100 feet of dock face in EL -70 MLLW as shown in Figure 1. Design included installation of large-diameter spin-fin piles driven on a 2V:1H batter. Also included was a 300-ton tension test of smaller spin-fin piles.

Jan 1, 2006

By L. A. Cornish, R. Süss, M. Sephton, N. B. Maledi, J. H. Potgieter, L. Chown

The gas turbine industry is faced with a challenge to improve the performance of engines, while simultaneously adhering to stringent environmental legislation. One way of addressing the problem is by further increasing the recipient working temperatures. Unfortunately, the use of nickel based superalloys (NBSAs) in the gas turbine industry has reached its limitations. Although coatings can be used for small increases, and air cooling is also incorporated by design, attention is towards developing stronger metallurgical materials having higher melting points, with acceptable creep and corrosion resistance. A series of ternary and quaternary Platinum-based superalloys were developed. Platinum was selected because of its higher melting points compared to nickel, similar fcc structure and better corrosion properties. Mechanical characterisation studies of Platinum-based superalloys alloys, which included oxidation, creep and hardness, demonstrated reasonable results, outperforming an oxide dispersed strengthening (ODS) Fe-based superalloy (PM2000) and a nickel based superalloy (MAR-M200). During any materials development where high temperatures are concerned, high strength is the primary property of interest. However, during the development of gas turbines, component life and reliability, which are influenced by temperature, need to be taken into consideration, and therefore creep as well as corrosion (both temperature dependant properties), are important. These properties become significant with increasing temperatures. With increasing demand for higher temperatures, it is becoming increasingly important to include hot corrosion properties of the alloy during the material selection process. A short description on hot corrosion and its degradation mechanisms are given in this paper. Coatings are currently dominating as the best practical solution to address temperature increases. This paper looks at benefits and shortcomings of coatings over Pt-based superalloys as candidates for applications under extreme conditions. Key words: Hot corrosion, Pt-based superalloys, Ni-based superalloys, Coatings

Jan 1, 2006

By Florian Kongoli

The so-called "fayalite" slag, despite problems associated with it, is the most widely used slag in copper smelting processes. Thirty years ago, in order to overcomes some drawbacks of this slag a new "calcium ferrite" slag was proposed especially for continuous copper converting. Since both slags have strong and weak points depending on the field of their application about 8 years ago another new "ferrous calcium silicate" slag was proposed that is expected to solve the drawbacks of each slag. This new slag is defined as mainly consisting of FeOx, CaO and SiO2 as its main components but it can practically have several combinations of these constituents. In order to determine the best area of this slag for possible industrial application the quantification of phase relations is an important subject. In this paper the work carried out by the authors in quantifying through an original physical model the phase relations, liquidus surface, liquidus regions, behavior of solid phases and the effect of minor components is reviewed. Several special compositions of this slag have been identified and discussed for possible applications in the industrial practice.

Jan 1, 2006

Mercapto organic compound SDMP was used as a depressant for separation of copper activated marmatite from pyrrhotite in the presence of butyl xanthate. Flotation results show that SDMP has strong depressing effect on pyrrhotite recovery in the absence and presence of copper ion, but has promotional effect on marmatite recovery when added together with copper ion. The flotation test of mineral mixtures shows that copper-activated marmatite could be separated efficiently from pyrrhotite using SDMP as depressant. Infrared adsorption spectra demonstrate that SDMP has a strong adsorption on pyrrhotite surface through its functional groups such as ?SH, -S03.

Jan 1, 2006

Mother Nature controls, technical professionals model and miners decide. Decisions to explore, mine and mill. Mine decisions, mine design, planning and scheduling are subject to the quality of models û geological models, geotechnical models, resource models, density models. The closer these models are to reality, the more accurate the predicted outcome. So why is it we delegate the modelling tasks to the most junior and least experienced people? If we insist on this, we need to support them û to provide them with æexperience acceleratorsÆ. Technical mentoring is the most effective way to provide the right information at the right time. When this information (read skills) is supplied at the right time we can inject experience into the quality of our modelling and into our decision- making processes. The objective of this paper is to share those behaviours and manners that foster relationships and create frameworks for skills and experience transfer. Central to this is an understanding of how adults learn, an understanding of the basic rules of mentoring etiquette, and the three keys to building meaningful mentoring relationships. An understanding of adult learning processes and styles provides a structure within which a mentor can understand the learnerÆs perspective. Understanding the world from the learnerÆs point is critical to selecting the right language to engage, teach and transfer skills. Basic rules of mentoring etiquette like timeliness, respect and trust need to be brought into the consciousness so they can be agreed on and monitored to prevent conflicts in cultural and generational norms between the mentor and the learner.Meaningful relationships hinge on the three behaviours: truly listening, rather than just hearing; understanding the technical issues within the WIIFM (whatÆs in it for me?) question; and facilitative behaviour. Stronger and more meaningful technical mentoring relationships within our industry will bridge the generational gap and ensure we can capture and capitalise on the wealth of grey hair experience and develop an informed group of young decision-makers.

Jan 1, 2006

By D van der Merwe

Tracers of known densities are used world wide in coal processing plants to evaluate plant performance. Tracers are added to the feed stream and are counted after being recovered from the product and discard streams to determine partition curves. The need to recover the tracers can be eliminated by adding radio frequency identification tags to the tracers. Readers mounted on the product and discard streams record the passing RF tracers and produce the partition curve instantly. Tests were performed with three different shaped tracers at different collieries on cyclones ranging from 510mm to 800mm in diameter. Sink and float analyses of coal samples were used to compare conventional partition curves to partition curves obtained by using RF tracers. The average amount of tracers recorded was 78% of tracers in the feed. The results indicate that the stone shaped tracers represent the results from the sink-float analyses the best. The results suggest that RF tracers can be used to evaluate cyclone circuits in the coal industry and will make it possible to evaluate a coal circuit?s efficiency without stopping a plant and waiting for laboratory analyses. Keywords Coal tracers, partition curve, radio frequency tracer, RFID

Jan 1, 2006

By Mark R. Svinkin

Regulations are needed to keep construction vibrations in tolerable limits. The existing regulations were developed for low-rise residential structures, but they are incorrectly used for different super and underground structures. The existing regulations cannot prevent most of harmful vibration effects on sensitive devices, people and structures from construction and industrial vibration sources. It is important to determine the areas of application of the existing regulations and bring attention to the necessity of measurement of the structural responses for assessment of vibration effects on structures. For multi-story residential, commercial and industrial buildings, the frequency-independent safe limit of 51 mm/s (2 in./s) can be chosen for the peak particle velocity of structural, not ground, vibrations. Specifications for construction operations with dynamic sources have to consider specifics of each construction site. Preventive measures can be used to mitigate harmful vibration effects on various structures and settlements in sand and clay soils.

Jan 1, 2006

By T. Takayama Filho

Votorantim Metais Zinco is a smelting facility which produces SHG zinc, zinc alloys, sulfuric acid, liquid SO2, copper sulfate, cadmium metal and silver concentrate. It is located at Juiz de Fora, Minas Gerais State, Brazil. This facility has been operating since 1980 and its current capacity is 95,000 tonnes of zinc per year, using mostly imported sulfide concentrates.The plant uses the conventional roast-leach electrowinning (RLE) process, in which iron is removed from the circuit as jarosite. The residues generated by the RLE process, which amount to about 200 t/day (dry weight), were until 10 years ago, deposited in tailing ponds having no impervious lining. More recently, jarosite and other wastes have been deposited in a properly built reservoir, but this is reaching its maximum capacity. In order to decommission these disposal operations and to reclaim the sites in an environmentally acceptable manner, Votorantim Metais concluded in 2004 a rehabilitation project for the old tailings pond and prepared detailed plans for managing the current and future disposal of jarosite-bearing residues. This paper describes the procedure for removing iron from the hydrometallurgical circuit and discusses the past and current status of the residue disposal sites, as well as the future challenges related to the environmentally acceptable handling of iron residues.

Jan 1, 2006

By Paul Hughes

This paper describes a focus of work presently being conducted at the Rock Mechanics Research Group at the University of British Columbia. The underhand method under consolidated fill ensures a high recovery under an engineered back that is comprised of cemented rock fill and/or cemented paste fill. This method of mining has been employed successfully in mines throughout North America as a method of mitigating exposure to the operator having to work under a seismically active ?back?. This paper reviews design methodology in the placement and analysis of sill mats with reference to site observation coupled with on going numerical and analytically derived solutions.

Jan 1, 2006

By Mark Bauckman

Discussion Topics • Market Needs • Technology Developments & Best Practices • Industry & Government Developments • Future Possibilities & Your Role

Jan 1, 2006

This presentation is a 20 minute snippet of my professional career, and my progression in the mining industry, from a lazy uni student to an up-and-coming blast engineer in the middle of a mining boom.My name is Daniel Hepburn and I am a blasting engineer for Orica Mining Services. I graduated from Royal Melbourne Institute of Technology (RMIT), in Melbourne in 2003. I completed both of my final year projects with Orica Quarry Services and was offered an assistant shotfiring job, which I accepted and worked for eight months. Having missed the cut-off date for the Orica graduate program, I planned to work with Quarry Services until the following year where I hoped my marks and the experiences I had gained would secure a graduate position. I didnÆt have to wait long, as in August of that year, I was offered (and I accepted) a graduate position in Perth as a technical services engineer for Orica Mining Services. The Orica graduate program is based over two years, and consists of real roles from day one; however, there is also opportunity to fast track the program for high performers. There is a structured rotation, from site to site, interstate or even international if you are so inclined. This includes the backpacker program, which allows graduates to experience the Orica culture in countries of their choice. There are also opportunities to try cross-functional roles in the different Market segments within Orica. I was lucky in that I knew what I wanted to do and where I wanted to work, so I stayed in Perth for my entire graduate program. I was also lucky enough to be fast tracked and finished my graduate program in 15 months. At the end of 2005 I accepted a position as an open cut blasting engineer based in Perth and even in such a short period of time I have already completed a number of major accomplishments. Some of these accomplishments are described below. This paper is available as a PowerPoint presentation only.

Jan 1, 2006

By C. G. Anderson

As the global demand for copper and gold steadily increases and the need for environmentally sound processing also grows, successful hydrometallurgical treatment of enargite (Cu3AsS4) concentrates has come to the forefront. This type of concentrate contains considerable arsenic so that successful arsenic fixation, for example as scorodite, is of the essence. This paper outlines the successful application of low temperature and low pressure nitrogen species catalyzed (NSC) hydrometallurgical pressure oxidation of enargite concentrates. The successful stabilization of the arsenic as an iron arsenate compound is discussed. Also, the use of experimental design software is highlighted as a process application and optimization tool.

Jan 1, 2006

Forty years ago Dr Pierre M Gy, a metallurgist, introduced variography as applied to monitoring a process. Consequently, his followers used the variogram to elaborate meaningful process control charts, especially since 1993. The name æChronostatisticsÆ was suggested several times by Gy as a logical name for this new science. The intent was to draw a parallel between the variogram identifying the variability components affecting a process parameter as a function of time, and the variogram used in geostatistics identifying the variability components of a given mineral content as a function of space. Heterogeneity problems encountered have indeed strong similarities. However, there is a fundamental difference. The variogram used in geostatistics is often stationary within a given type of mineralisation. While investigating a dynamic process through Chronostatistics, there is no such thing as a stationary variogram. Still, the evolving variogram provides essential information about subtle, often overlooked process difficulties. Chronostatistics is especially useful for management to take advantage of existing data that are often a forgotten source of valuable information to pinpoint recurring structural problems. The superiority of Chronostatistics over conventional statistical process control approaches is that it links observations to the inherent heterogeneity of materials under investigation, therefore to the sampling theory. Chronostatistics is like opening a new world to the metallurgist, making the process variability speak in a more comprehensive and in-depth way. Several case studies are presented to demonstrate the potency of this new science. For each of them, observations lead to solutions for continuous process improvement, therefore attractive economic opportunities. The philosophy is this: if a control chart shows a process is out of control, it must also suggest logical and pragmatic directions for solutions. The intent of this presentation is to vastly expand on these valuable, almost forgotten ideas.

Jan 1, 2006

By Anjali Talekar

Low temperature heat capacities of pentaerythritol [PE: C(CH2OH)4], pentaglycerine [PG: (CH3)C(CH2OH)3], and 2-amino-2-methyl-1,3-propanediol [AMPL: (NH2)(CH3)C(CH2OH)2]have been determined by adiabatic calorimetry from 3 K to 300 K. To the best of our knowledge, this is the first reported heat capacity measurement below 280 K for PE and AMPL. The Debye temperatures for these organic crystals have also been determined and compared with other alcohol derivatives of neopentane.

Jan 1, 2006

By W Roy

When it comes to plan implementation and securing success in organisations in the 21st century, if there was such a thing as the secret to success it would be effective communication. Commoditisation brings financial, operational and cultural advantages to organisations that use effective communication. Effective communication tools turn æpeople problemsÆ into system control solutions, removing personality clashes that hide procedural malfunctions. By introducing communications frameworks available in the market place today, and case studies of their use, this paper provides insights into the successes available to organisations courageous enough to redefine their communications for the 21st century.

Jan 1, 2006

Salaries for mining professionals have gone up substantially in the last two years across most vocations and there has never been a better time to enter the industry, in terms of career opportunities and salary packages. With so many offers on the table and companies outbidding each other to attract the best talent, many new professionals are being lured in by the big money, sometimes at the expense of a satisfying career and a sustainable lifestyle. What should we consider when accepting a new position? What are our values, and how do these drive our decision making? This paper examines our core values as people and makes some observations about what it takes to really succeed in the mining industry.

Jan 1, 2006