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By Martín Reyes

Iron concentration by ion flotation techniques, from sulfate solutions in presence of zinc was studied in a laboratory flotation column by continuous mode using a synthesized sand shell plate sparger, an anionic collector, promoters, and surfactant propylenglicol 400. Effects of experimental parameters, such as the concentration of reagent: potassium amyl xanthate and dithiophosphate, superficial gas velocity, and superficial liquid velocity were studied in terms of the recovery and enrichment of Fe (III). The results show that the iron elimination from the solution in the presence and absence of zinc (II) are of 59 % and 72 % respectively. The flotation efficiencies decrease with an increase of the concentration of xanthate and air flow rate. The best recovery was achieved, at Jg 0.1 cm/s, Jl 0.72 cm/s and a mixture of xanthate and dithiophosphate as promoter. It was also demonstrated that it is possible to selectively separate and concentrate iron (III) from solutions containing zinc. The behavior of iron ion flotation in a flotation column is reported in this research as a gas hold up, superficial gas velocity, bubble size and superficial bubbles area flux function. The results show that the extraction of aqueous ions of metal iron by ion flotation is strongly affected by: [C], Jg (cm/s), eg (%), Db (mm), Jl (cm/s), y Sb (s-1).

Jan 1, 2009

By Yan Yuan

Stable Nitroxyl polymers, such as poly (2,2,6,6-tetramenthyl-1-piperidinyloxy-4-yl methacrylate) (PTMA), are known to be effective as cathode active materials for lithium rechargeable betteries.The nitroxide radicals displayed a reversible and very rapid redox performances.We present a new synthesized method to get PTMA powder, then a doctor-blading method was used to prepare the PTMA composite electrodes, enabling successful production of homogeneous electrodes. It was characterized through FT-IR and SEM methods.The organic radical battery consists of lithium metal anode and PTMA cathode with an active material content of 65wt%.The best performance is achieved with a thin cathode that shows nearly 100% utilization of the active material (111mAh/g) at 0.1C.Through the electrochemical tests, it was found that there was a stable plateau at 3.5V while discharging. Besides, the cycling stability and rate capability were measured in detail. Although they showed a certain quantity of irreversible capacity on the first cycle, the capacity stabilized after the second cycle.

Jan 1, 2009

By C. M. F. Vieira

Crushed fired brick waste, known as grog, screened at two different particle size, 840 (20 mesh) and 180 µm (80 mesh), was used in mixtures with clayey body to make typical red ceramics for bricks. The effect of the grog addition up to 20 wt.% on the properties of bricks fired at 700oC was evaluated. The results indicated that both the particle size and the amount of grog addition changed the fired properties of the clayey body. Additions above 5 wt.% of grog, with a coarser particle size, decreased the mechanical strength of both the dry body and the fired ceramic pieces. By contrast, grog with a finer particle size may be used up to 10% wt. without deteriorate the properties and corresponding microstructure of the clayey body.

Jan 1, 2009

By Li Qian

Mechanisms of bio-dephosphorization from iron ore was investigated in this Paper. The results show that there are two bio-dephosphorization ways from iron ore, the one is that Acidithiobacillus ferrooxidans directly derive phosphorus from the ore, the other is phosphorus is able to be leached acid produced during metabolizing of Acidithiobacillus ferrooxidans, and the latter is more important than the other. Adding suitable pyrite can enhance the bio- dephosphorization process through providing nourishment and producing acid directly due to S 3oxidized or indirectly due to Fe3 as oxidant. The potential varies in the range of 0.434~0.498V and pH is in the range of 2.5 ~ 1.25 during bio-leaching process. It can be founded that, according 2+to the E-pH graph of Fe-H2O system, Fe wouldn?t be oxidized under sterile system in this potential and pH ranges. It can be obviously concluded that the Acidithiobacillus ferrooxidans are 2+able to reduce the potential for the oxidization of Fe and make the oxidization occur in the above pH and potential zone, so the bio-leaching process can proceed. the investigation of E-pH graph of P-H2O system show that H3PO4 can exist steadily.

Jan 1, 2009

By Daguang Lu

The section of sintering and BF (blast furnace) is very important in iron-making process. In practice, the scheduling is so extensive that three faults unfavorable to continuous product will be easier to happen. This paper introduces the integration Petri Net and GA (genetic algorithm) as suitable tools for simulation and optimization of scheduling to section of sintering- BF under a certain hot iron or-der. The situation of the iron plant Chongqing Iron and Steel Company is researched in approach above mentioned. By analysis, the conclusion is drawn that scheduling with optimized values can maintain continuity of key operations , can satisfy order of hot iron in maximal degree and can keep the best stability of key storages.

Jan 1, 2009

By Christian Wögerer

For material or process development as well as for quality checking of materials, thermal diffusivity measurement may be the tool of choice in many applications. Especially if diffusivity is measured locally resolved, a lot of information can be read out of such a ?diffusivity image?. This paper explains the method to measure coplanar specimen like plates and lists some interpretations of diffusivity images, like inhomogeneity of sintered materials, structural voids or inclusions. Diffusivity is a material property, describing transportation of heat in solids in spatial and temporal terms. With thermo cameras it is possible, to measure diffusivity of larger areas simultaneously. The result is an area of diffusivity values that may be plotted or displayed like an image. Locations with lower diffusivity values could be caused by the presents of structural differences in the material, by decomposition of the material components or by inclusions of other material like air.

Jan 1, 2009

By Xie Hao

According to its raw materials orthogonal test scheme is designed and a large number of systemic experiments were carried out in order to study the sintering characteristics of three types of fine ores in Kunming Iron&Steel Co.Ltd(KISC). The effects of carbon mixture ratio and basicity on sintering time, agglomeration ratio, physical properties and utilize coefficient were researched via single factor analysis and range analysis. The experimental results show the best mixture ratio of each fine ore. Analysis found that the influence of the carbon mixture ratio is more significant than which of the basicity on the sintering process except agglomeration ratio of foreign ore.

Jan 1, 2009

By Thomas Niehoff, Dave Stoffel

"Energy in the form of natural gas, oil and electricity is expensive and will continue to be a rare resource in the future. Recycling of metals, instead of primary production, is a logical and crucial step towards energy conservation. Energy consumption can be impacted by using advanced combustion systems for metals recycling. Air-fuel combustion has been the conventional method to melt and recycle metals. Global competitive pressures, “greenhouse” gas emissions, and high energy prices force melt shop operations to optimize energy usage and reduce overall operating costs. Oxy-fuel combustion and process technology can be applied to metal recycling operations to meet these objectives. Linde has converted several hundred furnaces from air-fuel to oxy-fuel technology and has extensive experience in optimizing the use of oxygen in furnaces. Additionally, Linde has the process knowledge necessary to avoid costly start-up issues that can accompany the transition to oxy-fuel technology. This paper will describe the benefits and potential issues for conversion to oxy-fuel.IntroductionThe furnace combustion system is the heart of a fossil fuel fired melting process and must be properly matched to the furnace to work as one cohesive unit. Furnaces vary widely in size, shape and features. Rotary furnaces are barrel-shaped and can be designed for tilting or nontilting operation. In a rotary furnace, the products of combustion create a single or double pass through the furnace prior to exiting. Reverberatory furnaces are box-shaped and can also be designed for tilting or non-tilting operation. Reverberatory furnaces are constructed of single or multiple chambers, with or without metal bath movement, and designed for continuous or batch processing. Different furnaces are used for different feedstock materials and products.Furnace combustion systems also vary in many ways. Combustion systems can be of air-fuel or oxy-fuel based technologies, or a combination of the two, resulting in an air-oxy-fuel system. Each of these types of systems has different combustion characteristics which can produce very different results. Here we will describe specific differences in melting processes and their associated energy requirements."

Jan 1, 2009

By P Christen, D R. Ashley, G R. Power

The Ernest Henry Mine is currently a copper-gold open pit operation situated in north-west Queensland, Australia. It is owned and operated by Xstrata Copper with a current throughput of 11 million tonnes per annum; however, open pit operations are scheduled to cease in late 2011. The deposit dips at approximately 45¦ and extends for at least another 400 vertical metres below the final 530 m deep pit design. Resource drilling from 2002 until mid 2008 has enabled an Indicated Mineral Resource to be established to 1000 m below surface. Scoping and prefeasibility studies (PFS) have been completed toward determining if this resource is suitable for underground mining and a feasibility study is currently progressing with a sublevel caving (SLC) concept. This paper briefly describes the process by which the SLC method was selected, conclusions regarding the non-selected methods, and then discusses the optimisation process used to derive the mining plan. The key optimisation parameters include the production drive spacing, level spacing, draw strategy, cut-off grade and production rate. Key risks will then be assessed and economic sensitivities studied. Final sensitivities will use Monte Carlo simulations to improve the transparency of the projectÆs risk profile. The feasibility study (FS) began in March 2008 and this paper describes the main optimisation steps at the time of writing and outlines the plan for study completion through to March 2009.

Jan 1, 2009

By H Benzer, N A. Aydogan

It is well known that the high pressure grinding rolls (HPGR) can only be operated efficiently under choke feeding conditions in which a material bed is built up between the rollers to ensure interparticle breakage. By increasing the fines amount in the material bed up to a specific level with the recycling load, a uniform material bed is created and higher pressure gradient along the roller width is obtained which results in compact flakes including more fines. Extensive test work has been carried out with an industrial HPGR unit grinding cement clinker in a cement plant in Turkey. During the test work the recycling load of the circuit was changed to achieve different ratios to the fresh feed rate in order to identify the effect of the recycling load on the circuit performance. Six different tests were performed with the circuit at steady state. For each test, samples were collected from HPGR fresh feed and discharge, and total feed, then the particle size distributions of the samples were determined and mass balances around the circuit were calculated. The conclusion was that the reduction ratio of the HPGR increased with increase in recycling load. The flake densities showed the same trend with more compacted flakes being produced for higher recycling loads.

Jan 1, 2009

By Sergey Shabala

Green leaf tissues convert solar energy into the energy of chemical bonds of sugar molecules during the process of photosynthesis. The efficiency of this conversion can be much higher than efficiency of any of the currently known silicon-based solar panels. Importantly, vast amounts of CO2 are assimilated during this process. The efficiency of photosynthesis is critically dependent on the availability of a large number of nutrients, among which metal cations such as K, Ca, Mg, Cu, Zn, Fe, Mn, and Ni play a key role. In this paper I summarize basic requirements and major functions for each of these essential nutrients in plant photosynthesis, both at the whole-plant and molecular level. I will talk about how these requirements may be affected by the global climate trends and discuss the prospects of creating artificial photosynthetic “bioreactors” for efficient energy conversion and CO2 assimilation.

Jan 1, 2009

By I. Hilerio

Chromium Nitride (CrN) thin films were deposited on AISI steel 316 substrates by means of the reactive magnetron sputtering method. CrN films were produced under two different conditions. In the first one, the substrate was heated by a DC source. For the second coating a negative substrate bias voltage was applied. X ray diffraction, quantitative energy dispersion and scanning electron microscope were employed to characterize the two different phases, their chemical composition as well as their microstructure. In addition, a microhardness test was carried out. The results show that a better phase formation of CrN thin films was achieved when a heating source was present (first case). Both coatings presented homogeneous surface. Their compositions show differences even when the gases flowing are the same in composition. Regarding to the hardness test results, there can be found a higher value when using a heating source.

Jan 1, 2009

By Jewel Gomes

Green rust is an important intermediate in oxidative transformation of Fe(II) phase. This unstable compound contains a mixture of ferrous and ferric hydroxides that belong to a family of minerals known as layered double hydroxides (LDH). Its general formula is [FeII(6-x) FeIIIx (OH)12]x+[Ax/n-*yH2O] x-, where A is an n-valent anion mainly Cl-, CO3-2 and SO4-2, and in which either the bivalent or the trivalent iron can be replaced for other trivalent or bivalent metal ions. It was first identified as corrosion product, later in soils as a product of interactions between microbes and metals in soils. Due to its high reactivity, it is used in the reduction of organic and inorganic compounds, As removal, and the treatment of acid mine drainage. In this paper, we described the method of electrochemical generation of green rust, its characterization by XRD, SEM and FT-IR, and its implications to electrocoagulation.

Jan 1, 2009

This paper sets out to consider a specific type of corrosion protection system, which is referred to as a Duplex Coating system. The dictionary describes a duplex system as consisting of two elements or a “twofold” composition. The duplex system described in this presentation is such a two-part corrosion protection coating, viz, hot dip galvanizing as the firm base or primer, followed by a top paint system designed to combat severe corrosive environmental conditions encountered in nature. In principle, the duplex system is a cost effective and balanced, designed coating that is suited to the environmental conditions and service life requirements.

Jan 1, 2009

By P A. Tilyard

There have been enormous changes in mineral processing in the past four decades. For example grinding mill power has increased by an order of magnitude, regrinding is done to -10 microns and flotation machines are 100 times bigger. Operating staff have unprecedented opportunities for online monitoring and performance control of mineral processing plants. Sophisticated instruments can provide a plethora of data characterising the mineralogy and surfaces of particles. Digital computers allow complex calculations on huge amounts of data including modelling and simulation of machine and plant performance. However, all these changes have not necessarily lead to better metallurgical results. An analogy can be drawn with the thoroughbred racing industry in Australia. Significant advances in scientific knowledge in animal genetics, physiology, biomechanics and nutrition applied to the business have resulted in only a two per cent reduction in winning times for the Melbourne Cup and Caulfield Cup since the 1920s. A critical look at some mineral processing metrics suggests similar failures to improve performance despite putting in more resources. In fact certain parameters such as operating times and plant start-up performance are considered to have remained static or even deteriorated. There has been an emphasis on 'process' at the expense of 'outcomes'. The industry's strength has been in finding technical (or 'hardware') solutions while its weakness has been at the people end of the business in maximising and consolidating the gains from the technologies. Some trends in plant design over these years have exacerbated the apparent deskilling of operating and technical staff. Despite unparalleled options for communications, some staff are embarrassingly uninformed about technical developments in their fields. The 'boom and bust' cycles of the industry, together with trends in tertiary education and the effects of fly-in, fly-out (FIFO) operations, raise serious questions about the sustainability of human capital in the mineral processing sector. This paper by two experienced mineral processing engineers, with contributions from other senior practitioners, reviews these trends. While there may be an element of 'the older we are, the better we were', it is an attempt to identify the issues and propose solutions.

Jan 1, 2009

Many young mining engineers do not consider consulting as a possible job, believing that many years of working on-site is required to achieve practical experience, develop expertise and acquire industry contacts. However, mining consultancies employ engineers with varying levels of experience, including part-time university students, graduates and engineers who are relatively new to the industry. This paper outlines the role of a young engineer in a large mining consultancy and the benefits to both the consultancy and the client of having a mix of consultants with a diverse range of experience. From the authorÆs perspective, the work experience, lifestyle and rewards of mine consulting are compared to site based work, including a discussion on whether consulting is able to offer the professional development that a young engineer needs.

Jan 1, 2009

Since the days of Adam Smith and Milton Friedman the discussion of corporate citizenship and sustainability has been flooded with multiple contradictions, with proponents of sustainability saying that it is a crucial cog in the business strategy, while those against, maintain that æthe business of business is businessÆ and therefore sustainability issues are just add-ons. Sustainability arises from a deeply held vision by corporate leaders that businesses can and should play a role beyond just making money. Businesses should embrace the understanding that everything that a company does has an impact both internally and externally (communities, employees and customers), and the natural environment. This paper highlights the approach that led to a view that there is a contradiction between profitability, sustainability and community development, and we provide a further argument to the contrary. This argument is based on a comprehensive literature review of over three decades by various scholars linking corporate social performance and corporate financial performance. Driefontein Gold MineÆs approach is that of linking the community development, natural environmental and employee well-being initiatives and projects to the mineÆs business strategy. The paper further highlights the coordination and implementation mechanism of sustainability at the mine where the accountability lies with the head of the mine operations. A two pronged approach is employed where there is an internal dialogue on sustainability between the various departments coordinated by the sustainable development department and an external tri-sector partnership with local government, interested and affected parties and the mine. These approaches are closely linked to the contributions towards the mineÆs financial bottom line.

Jan 1, 2009

People in economically developed societies demonstrate inherent human care for Earth and want to stop pollution. Yet efforts to clean Earth seem bogged in confusion from wildly contradictory and alarmist predictions of æclimate crisisÆ. Supposed experts openly disagree yet weÆre told thereÆs universal agreement humans are causing æthe end of life as we know itÆ. The turmoil combines with peopleÆs feelings of fear, guilt, anger, hopelessness and even resignation and apathy to trigger æclimate alarmÆ. The paper enables people to rediscover clarity, hope and support for Earth by understanding how climate alarm and confusion were created and how they actually increase pollution. Many people seem to think global warming is as serious as pollution and worry that questioning alarm will enable pollution. Yet theyÆre different. We need be even more concerned about climate alarm because history shows repeatedly that when buried by ignorance and panic real problems grow overwhelming. Environmental credibility is endangered by confused politicians and sensationalist media. When weÆre willing to re-evaluate what weÆve been told we replace fear and confusion with facts and freedom to identify opportunities. Combining this with practical understanding of human behaviour and leadership enables opportunities to be identified and action taken. The paper shows how confident, informed leadership leads and supports higher productivity and effective care for the natural environment.

Jan 1, 2009

By J OÆDriscoll, R Butler, L Winter

The iron ore mining district of Labrador West and adjacent Quebec is Canada's largest iron ore producer with almost 50 years of production. The area is currently experiencing a period of renewed activity not seen in decades that includes new mine development, mine expansion and exploration for new iron ore resources. All of the past and present production and exploration programs in the district are centred on the Lower Proterozoic Superior-type iron formations of the Knob Lake Group, located within the Grenville tectonic province of the Canadian Shield. The Knob Lake Group is a continental margin sedimentary sequence which was deformed and subjected to greenschist to upper amphibolite facies metamorphism during the Grenville orogeny. Regional deformation and metamorphism plays a key role in making the iron formation of the Knob Lake Group economic. The distribution of orebodies in the district is controlled by superimposed F1/F2 synclines which causes thickening of the iron formation through repetition. Ore mineralogy consists of specular haematite, magnetite and locally martite with quartz as the major gangue mineral. Regional metamorphism has caused an increase in grain size of the ore minerals making it more amenable to concentrating and pelletising. Altius has been active in Labrador West since 2003 and is now the second largest licence holder in the district with several iron ore exploration projects. The Kamistiatusset project is located in the heart of the region's transportation, power and mining infrastructure. The property has seen limited previous exploration, but covers several significant iron ore prospects. Work by Altius includes a helicopter-borne magnetic survey, ground magnetic and gravity surveys, geological mapping, sampling and 6000 m of diamond core drilling all of which confirm both a favourable geologic setting and ore mineralogy.

Jan 1, 2009

In view of the increasing environmental regulations that have been promulgated all over the world in the last 30 years, non-ferrous smelters and refineries have learnt and adapted to treat effectively metals'-containing process waste streams that need to be bled from the plant. However, anions such as sulfates, chlorides and fluorides-presently not a major problem ?are coming under increasing scrutiny and need to be addressed in the near future. The current paper reviews options for waste water treatment with reference to: a) types of waste streams processed b) process chemistry c) discharge options d) recovery and reuse of water and e) solids disposal. Methods to obtain zero liquid discharge ?a possible solution to eliminate discharge of above anions and residual heavy metals- are discussed with case studies. The long term goal of any non-ferrous smelter plant should be to have a zero liquid discharge philosophy-an approach that would become an epitome of water reuse and conservation.

Jan 1, 2009