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By Emilia Visileanu, Eftalea Carpus

"Ecological economic policy shall be understood as the sum of political, economical and environmental measurements aimed at the entire economy dematerialization and the dematerialization shall be ""imposed"" since the designing stage of goods and services"". European textile and clothing industry with a long leading tradition in terms of innovation, fashion and creativity, continues to be one of Europe's major industrial sectors. Textile industry affects the environment by high consumption of water, energy and chemicals, as well as by the large amount of waste it generates as a result of using a large number of chemicals and technological processes.Textile waste prevention, reduction and ecological exploitation require the implementation of new management and education tools.Introduction“Europe must learn from the experience of global economic and financial crisis ""- this was the conclusion of the European Commission that has elaborated a ten-year strategy designed to reinvigorate the economy and make possible a growth which is ""intelligent, sustainable and favorable to inclusion"", by a better coordination of national and European policies.Adapting infrastructure and logistics that encourage the marketing of ""sustainable"", ""fair traded"" and ""green"" products as well as other special „green” products will facilitate the movement towards dematerialization and eco-efficiency among producers."

Jan 1, 2012

By H. J. McQueen

Mineral and energy resource consumption were continuously reduced by process improvements as chemical understanding was developed and applied. During the past two centuries, technological improvements increased human productivity that was accompanied by social advances and labour saving products; however, these sometimes proliferated to endanger sustainability, e.g., automobiles. In the steel industry, precisely controlled rolling of HSLA steels required little extra mineral consumption but reduced weight and heat-treating energy. Continuous casting of slabs reduced scrap compared to ingots and energy for the homogenizing soaking pit. Al alloy extrusions were improved by retaining the strengthening in the near-surface substructure, of high strength textures and of press quenching that is suitable for direct age hardening. Continuous bar casting of Al-0.65Fe, coupled with rod rolling and followed by wire drawing with only a final recovery anneal, yielded electrical wiring for households to replace less plentiful Cu and later for light-weighting use in autos and aircraft Looking backwards, the 1970 decade saw the first oil crisis and inspired Ottawa to undertake a campaign to develop an energy strategy that would decrease dependence on imported fuels. One significant undertaking under Energy Mines and Resources was the organization of industrial energy conservation, managed by each industry association,that collected detailed current statistics and set the goals for a 2-year campaign. The metal producing industries, as compared by E.C.N. Perryman to about 7.2 exajoules (EJ) for the nation, consumed about 0.8 EJ, being about one third of all heavy industries. While manufacturing consumed 30.2% of total energy, it created 87.3% of total national dollar value. Within the industrial envelope, smelting and refining utilized 28% (0.67 EJ, mining beneficiation 6.7%, 0.16 EJ); there was a significant contribution to exports: 80% of iron ore and 70% of aluminium in 1973. A general concern was that decreases in ore grade would lead to a rise in energy expenditures countering benefits from processing efficiency.

Jan 1, 2012

By John Cory, Ran Tamir

Blasting data analytics are being increasing used to increase mining productivity, reduce mining costs, maximize high margin aggregate products, and to reduce fines. Three examples will be illustrated using simple models to maximize the percentage of blasted rock within established dimensions and reduce fines-one from video fragmentation distribution information, the second from sieved crusher fragmentation data, and the third from plant production data. In addition, the use of sieved crusher results to determine blasting related fines and the use of mine productivity data to maximize aggregate sizes when pattern (burden and spacing) areas are changed will be illustrated

Jan 1, 2012

By Jan E. Nesset, James A. Finch, Wei Zhang

"Bubbles are unquestionably the heart of the flotation process. Their size and combined surface area are largely what drive the recovery process. This suggests that plant engineers should be aware of where their plants are operating with respect to what is achievable for these key parameters. The paper presents a model of how the key operating variables of frother type and concentration, gas rate, altitude (above sea level) and viscosity affect the Sauter mean bubble size (D32) and bubble surface area flux (Sb). The results are compared to a set of plant measurements that demonstrate the benchmarking capability of the approach. A case study is used to link hydrodynamic change to improved metallurgical performance.INTRODUCTION At the beginning of the 20th Century the early practitioners of flotation were aware of the importance of understanding bubble behaviour (Rickard, 1916) but measurement of individual bubble and gas behaviour in the industrial environment was not possible due to a lack of adequate sensors. This situation was not rectified until three quarters of a century later with the advent of industrially-robust sensors developed, notably, at the University of Queensland’s Julius Kruttschnitt Mineral Research Centre (JKMRC) (Schwarz & Alexander, 2006) and McGill University (Gomez & Finch, 2002). What emerged was not the chaotic environment perhaps expected, but defined relationships between gas rate, gas holdup, bubble size and the total surface area of bubbles. These relationships could be defined by mathematical expressions and predicted from an understanding of the key process variables (Gorain, Franzidis & Manlapig, 1997; 1999) (Hernandez-Aguilar, Gomez & Finch, 2002) (Gomez, Cortes-Lopez & Finch, 2003) (Nesset, Gomez & Finch, 2007). The early JKMRC work focused on a large pilot cell (3 m3) installed in plant environments, while the McGill work was initiated on flotation columns (Finch & Dobby, 1990) (Xu, Finch & Uribe-Sales, 1991) and later adapted to industrial mechanical cells (Cooper, Scott, Dahlke, Finch & Gomez, 2004) (Dahlke, Gomez & Finch, 2005) (Nesset, Gomez, Finch, Hernandez-Aguilar & Difeo, 2005). Yianatos of Santa Maria University (Chile), a graduate of the McGill research team, carried the work to industrial settings in South and Central America (Yianatos, Bergh, Condori & Aguilera, 2001). The methods of gas dispersion measurement are now well accepted and most major research centres and flotation cell manufacturers have adopted the technology (Pyecha, Sim, Lacouture, Hope & Stradling, 2006) (Yañez et al., 2009) (Collins, Schwarz & Alexander, 2009)."

Jan 1, 2012

By G. J. Simandl

"Since the 1980s, China has become the predominant producer of REEs. Recently, it introduced REE export quotas and this started a world-scale REE exploration rush. REE resources are concentrated in carbonatite-related deposits, peralkaline igneous rocks, pegmatites, REE ± P veins, ion adsorption clays, placers, and some deep ocean sediments. REEs could also be derived as a by-product of phosphate fertilizer, U processing, Ti-Zr-bearing placers, and exploitation of Olympic Dam-type sub-type of IOCG deposits. The ideal REE development target would be located in a politically stable jurisdiction such as Canada. REE grade and tonnage, mineralogy, and permissive metallurgy are some of the key technical factors that could be used to screen projects. INTRODUCTIONAccording to the International Union of Pure and Applied Chemistry (IUPAC), the term “rare earth elements” (REEs) encompasses yttrium (Y), scandium (Sc), and the lanthanide series: lanthanum (La), cerium (Ce), praseodymium (Pr), neodymium (Nd), promethium (Pm), samarium (Sm), europium (Eu), gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), ytterbium (Yb), and lutetium (Lu). This definition is used throughout this paper.REEs are subdivided into light (LREE) and heavy (HREE) categories. LREEs include, Sc, La, Ce, Pr, Nd, Sm, Eu, and Gd and HREE include Tb, Dy, Ho, Er, Tm, Yb, Lu, and Y. Promethium (Pm) does not occur in nature. Concentrations of individual LREEs in the upper crust of the Earth are comparable to those of base metals. Even the least abundant REE (Lu) is about 200 times more abundant than gold.The production of REEs, reported in the form of oxides (REOs), for 2011 is estimated at 140 000 t (Figure 1a). Although high technology industries can substitute several REEs with other materials, these substitutes are typically more expensive or less effective than the REEs they replace. A number of countries, including the United States, consider several REEs essential for national security, their economy, and a general reduction in green house gas emissions. The forecasted demand for individual LREOs is much higher than that of HREOs (Figure 2). Dy, Eu, Tb, Nd, and Y are essential for the US economy and subject to predicted supply disruptions (U.S. Department of Energy, 2010)."

Jan 1, 2012

By A. Taylor, M. Blanchette, J. Doucet

"A Z1600 Jameson Cell Test Rig was rented for test work at Vale’s Clarabelle Mill operation. This paper discusses the evolution of renting the unit for test purposes to owning the unit and operating it as a revenue generating process component. The paper focuses on three aspects of the Z1600 project; the initial rental and installation, the test work performed in the cleaning circuit, and the business factors which led to the unit being permanently incorporated into the copper circuit.INTRODUCTION Clarabelle Mill is located in Sudbury Ontario (approximately 350 km north of Toronto) on the southwest rim of the Sudbury basin a meteoric impact crater that is 62 km long and 30 km wide. The result of the meteoric impact was concentrated nickel (Ni), copper (Cu) and platinum group metal (PGM) ore bodies in the outer perimeter of the basin; described in more detail by Hanley (1957). Vale currently has seven operating mines in the Sudbury basin, from which nine distinct ore types are mined. Ores are also received from two QuadraFNX mines. Clarabelle Mill processes all of these ores for the Ontario Operations of Vale. The mill, commissioned in 1971, was originally built as one of four mills operated by then Inco Limited. Between the late 70’s and the early 90’s process changes were made to consolidate the Sudbury Operations milling processes into a single operating mill, Clarabelle Mill. In 1990, the SAG mill was installed resulting in peak mill throughput of 11.9 million short tons per annum (Mstpa), with typical throughputs of ~10 Mstpa. Mill average feed grades were 1.4% Cu and 1.2% Ni. During the resources boom, plans were developed to increase the mill capacity at Clarabelle Mill in stages to a final capacity of 13.5 Mstpa. The project known as the Clarabelle Mill Expansion and Recovery Project (CMERP) included expansion and reconfiguration of the grinding and flotation circuits. The first stage was a planned increase in grinding capacity with the reallocation of existing mills, the existing flotation capacity would be required to treat higher throughput until the new flotation circuit was constructed."

Jan 1, 2012

By Lijuan Li, Xin Xia, Junjun Huang, Qijie Zhai, Xiang Jiang

"Some experiments with different temperatures (1173, 1223, and l273K) and different annealing times (3, 4, 5, 6min) were carried out on cold-rolled plate of Fe-36Ni invar alloy. The microstructure and the mechanical properties were observed and tested respectively, and the fracture morphology was observed by SEM. The results show that with increasing of the temperature and the annealing time, the austenite grains gradually grow up accompanied by a small amount of annealing twin crystals, meanwhile, its plasticity and toughness are improved, and it is typical ductile fracture under the condition of tensile failure. After annealed at l223K, the invar alloy has better comprehensive properties than that at the other annealing temperatures, and the grains size is more uniform. Furthermore, when the annealing time is 4min, the invar alloy has the best comprehensive properties.IntroductionAs we known, most metals and alloys expand with increasing temperature. More than one hundred years ago (in 1897), Guillaume observed that Fe-Ni alloy with face-centered cubic (fcc) crystal structure, consisting of36%Ni, showing a very small thermal expansion coefficient below the ferro-to-paramagnetic transition, the thermal expansion coefficient around room temperature( <2 X 1O-6K-1 compared to most metallic materials which have a thermal expansion coefficient of 10-20 X 1O-6K-1) [1,2]. Since then, the subject has attracted many researchers, and various alloys with low thermal expansion coefficients have been developed. These alloys, generally known as ""invar alloys"", are in demand where dimensional changes due to variation in temperature must be minimized and where high stability is required [3, 4]."

Jan 1, 2012

By K. M. Murphy, M. B. Wittrup

ABSTRACT The Saskatchewan Ministry of Environment recognizes the importance of environmental protection as an important contributor to Saskatchewan’s economy, with the environmental performance of industry closely monitored. Unfortunately, environmental regulation is often accompanied by significant process that does not always add value to environmental protection activities. The Saskatchewan Ministry of Environment has embarked on a visionary restructuring of its regulatory framework from conventional command and control regulation to a results-based regulatory framework. This new regulatory framework will provide for establishing clear environmental protection and resource management objectives; streamlining the environmental acts and regulations; developing an environmental code of practice; relying on qualified persons; enhancing compliance and enforcement tools; eliminating of many permits; and developing greater certainty in environmental assessment decisions. Results-based regulation promises to deliver enhanced environmental protection with less process. The uranium industry in Saskatchewan will be used as an example of the potential effects of results-based regulation.

Jan 1, 2012

By J. Mothomogolo

Mining projects are capital-intensive and are also characterized by high technical and economic risks. These factors pose challenges to mining entrepreneurs when they seek to raise seed capital for mining start-ups. There are limited sources of mining investment funds in South Africa and each has shortcomings due to one reason or another. Another impediment is South Africa?s status as a developing economy, in which the standards of living ? which in turn influences the savings culture ? the limited GDPs and budget, the socio-political environment, and banking, mining, treasury and other regulations, determine the size of investments, particularly in mining ventures. The proposed funding mechanism was developed with the aim of filling the gaps identified in existing funding mechanisms that were developed by the government with the introduction of the Minerals and Petroleum Resources Development Act (MPRDA), 2002. The shortcomings identified were presented to the study participants as questions to obtain views that were used to define innovative ways of raising mining start-up capital. Most participants in the study supported the derived hypotheses and proposals, and these were used to refine the proposed mechanism for mining investment in South Africa. The proposed funding framework is aimed at encouraging interaction between mining entrepreneurs, government, and the investors to align goals and expectations when undertaking a mining investment.

Jan 1, 2012

By Enrique Munaretti, Vitor Rosenhaim, Jair Carlos Koppe, Joao Francisco Feijo

The B3 mine is a multiple coal seam strip mining in operation in Rio Grande do Sul, the southernmost state in Brazil. A traditional truck & excavator operation is used to remove the overburden and selectively mine coal seams, ranging in thickness from 30 cm (1 ft) to 2.5 m (8.2 ft). Blasting is required in order to excavate part of the sedimentary rock overburden where the rock is too hard for mechanical excavation, and to mine the coal seams, selectively.

Jan 1, 2012

By J. E. Nesset

"I had been requested earlier this year by MetSoc, our sister society of CIM, to contribute a chapter on technical developments in Canadian mineral processing over the past 50 years to their 50th Anniversary volume. Accepting the challenge of assembling such a chapter seemed at first a reasonably straightforward task, until one realises that the list of contributions by Canadians to mineral processing over this period has been more than just significant. It turns out to have been an extraordinarily fertile time for innovation and impact for Canadian-based technology. The list is necessarily a subjective one, however I had no trouble identifying twenty technology developments that are clearly outstanding, and there are undoubtedly others. As much as possible, I approached the individuals themselves who played key roles in each technology and asked that they tell the “story”. Without exception, all who were invited accepted eagerly and delivered more than I had hoped for. The technologies have been grouped into those that are truly Canadian innovations, such as the Knelson gravity concentrator and the McGill gas dispersion sensors in flotation, and technologies where Canadians and Canada played a very significant role in their success and implementation, such as AG/SAG grinding and ion-beam surface analysis. Also included are what may be termed technology transfer initiatives and institutions that have risen to a world class level, such as SGS Lakefield and the Canadian Mineral Processors Society of CIM. The challenge is now for the coming generation to continue this record of innovation and contribution to the industry, and that includes the (mostly) Canadian mining and metallurgical companies who have taken the longer term view and supported many of these initiatives, through their critical early years, with both financing and project sites for these ideas. Let us hope that the current trend of mining company globalization will not dampen their enthusiasm to participate. This plenary presentation will highlight many of these technologies, the individuals behind them, and their significance to the mineral processing industry."

Jan 1, 2012

By J. Talja

"Non-ferrous metal concentrates contain typically 7 – 12% water when received at the smelter. Removal of this water prior to smelting is always economically feasible because unnecessary heating of vapour (from 100 °C to 1200 °C) in the smelting furnace can thus be eliminated. This results in major reduction in CO2 emission and direct annual savings of several millions of dollars due to improved energy efficiency. Next step to further improve the energy efficiency, to gain substantial savings and simultaneously cut emissions is to select modern technology for the drying process. Consequently, all CO2 emission will be completely eliminated (from 40,000 tpy down to 0 tpy), NOx emission will be negligible, and the SO2 emission will be reduced by over 99 %. Switching of conventional direct heated drying technology to modern indirect steam drying brings, in addition to dramatic emission reduction, additional savings due to further improved energy efficiency. Direct energy savings count for 900 – 1300 MJ/t H2O, which depending on the concentrate feed rate and its moisture load can be worth several millions of dollars every year. Additional savings in operational expenses related to drying and gas cleaning may be worth a few million dollars more. Sustainability is a key issue today, and major savings together with significant emission reduction are readily available by proper technology selection for concentrate drying. INTRODUCTIONSustainability is a decisive principle in any process industry accompanied with emissions and high amount of energy. This is of significant importance in metal processing, including concentrate drying, where minimum impact on the environment, people and community are targeted, and all this with minimum cost, effort and resources. Therefore, special attention is paid to high energy efficiency, low energy consumption with preferable utilization of waste energy, safety issues, availability, level of maintenance, cost of maintenance, and emissions among other things.Non-ferrous metal concentrates can be dried using various techniques. Conventional drying based on direct heating, and use of fossil fuels for drying energy has almost entirely been replaced by steam drying. It is based on indirect heating and it has become the most dominant drying technology for copper concentrates during the last decade with over 90% of the market share of all new dryer installations. Among the steam dryers the Kumera Steam Dryer is the most pre-dominant technology with some 70% of all new dryer installations world-wide."

Jan 1, 2012

By W. Gabryk

A large new underground platinum mining project required that all different mining options were investigated during an option study before proceeding to the prefeasibility stage of the project. The capital project team identified 21 different options requiring investigation. These options considered 10 different access methods and 4 different mining methods. Each of the 21 options required a mine design, a valid production schedule, and the associated economics in order to facilitate a comparison on project Net Present Value (NPV) and other metrics. The project sponsors required this work to be completed in 3 months and therefore the project team decided to adopt an object-oriented modelling approach as implemented by Cyest Corporation. This would allow all 21 options to be valuated within the tight time frame due to the generation and re-use of templates. Standard objects were configured into templates containing the mine layout, design, and scheduling logic. These templates could then be assembled into a model to represent the option being investigated. The adoption of rules-based design and production scheduling then allowed for the rapid generation of a valid production schedule for each option with different iterations of varying production ramp-up and mining efficiency assumptions. The activity-based operating costs, labour, and capital were also linked to the standard templates such as a half level or barrel, which were then replicated to represent the overall mine structure for each option under consideration. Using this approach for each option, a full production schedule was produced per mining activity, the operating costs were calculated using activity-based costing, an infrastructure capital expenditure estimate was determined, the development capital requirements costed, and an overall NPV determined. This options study was completed in an unprecedented 10 weeks and a recommendation was put through to the Business to take three of the options to the next study phase.

Jan 1, 2012

"Ore deposits containing rare earth elements normally contain small amounts of the radioactive elements thorium (Th) and/or uranium (U). These are the naturally-occurring isotopes U238, U235, and Th232 (and associated decay-series daughter products) that are ubiquitous in nature, and that contribute a small percentage of the natural background radiation exposure encountered by humans. The presence of these radioactive materials in the ore deposit creates potential hazards to human health and the environment that must be dealt with properly in the mining, processing, and refining of the ores, as well as management of waste streams and residues. This paper presents an overview of the environmental and safety issues associated with U and Th, with particular emphasis on rare earth mining, processing, and refining projects; the regulatory approaches followed to ensure that rare earth deposits are developed, operated, closed, and decommissioned safely; and the development of information during the project predevelopment work and permitting processes that feed into the design, operation, and closure of tailings impoundments and milling/separation/refining facilities. Case studies will be presented subject to the availability of relevant public information. INTRODUCTIONNearly all ore deposits containing economically-recoverable rare earth minerals also contain small amounts of the radioactive isotopes for the elements thorium (Th) and/or uranium (U) and their associated radioactive decay products. Therefore, the handling and management of these materials in mining and mineral processing operations must be performed so that workers and the environment are protected from harm from Th and/or U (and their radioactive decay products), just as they must be protected from any other potentially harmful constituents present in the ore or introduced in processing. Examples of these might include ores with high sulfide content, which may pose a risk of acid rock drainage, or chemicals used in ore processing and metals production.The purpose of this paper is to present information on how rare earth mining and processing projects with ores containing Th and/or U can be developed, operated, and decommissioned safely according to applicable regulations intended to protect worker health & safety and the environment.It should be noted that some countries are considering developing Th as a feedstock for producing nuclear energy, which could have some effect on future development of rare earth ore deposits. To avoid confusion, that issue is not discussed in this paper."

Jan 1, 2012

By C. S. R. Rondestvedt

In February 2010, Teck?s newest Concentrator at Mina Carmen de Andacollo (CDA), Andacollo, Chile was commissioned. The Concentrator is a single line configuration, comprising of one 36 ft diameter x 20 ft long SAG mill driven by an 18,000 hp gearless drive. The SAG mill feeds two ball mills each 25 ft in diameter x 40.5 ft long, each driven by a total of 19,000 hp through dual pinion drives. A series of four phases will be reviewed from operational readiness, mechanical completion, commissioning, and ramp-up. Also, now after 6 months of operation, this paper will review the significant steps taken during ramp-up enabling the announcement of commercial production, in October 2010.

Jan 1, 2012

By Mohamed Ourriban, Stéphanie Somot, Éric Proulx, Jean-Sébastien Marois, Marjolaine Drouin, Paul Blatter, Ahmed Bouajila, Claude Gagnon

"The mining industry has to face increasing restrictions concerning the use of fresh water in Québec and throughout the world. Increasing recirculated water usage could lead to a better control of the quality and the quantity of water supplied to the mineral processing units. Furthermore, it could reduce the volume of waste water to be managed and treated before its release to the environment. However, process water may have a negative impact on mineral processing operations, thereby limiting the incentive for sustainable development initiatives. As a first step into selecting and testing remediation strategies, one of which being blending local waters, a mapping of process water quality (inorganic and organic fractions) allowed to locate zones in an industrial case study where fresh water is introduced into the circuit and to detect dissolution and precipitation zones. A complementary hydro-geochemical modeling study on water blends was also performed showing encouraging results towards the objectives of the project.INTRODUCTION The industry has to face increasing restrictions on the use of fresh water in Québec (Quebec Government, 2009) and throughout the world (Brown, 2003; UNESCO, 2006). The cost for the use of fresh water and for water management is highly variable and case-dependent (from 0.2 to up to 7 million dollars/year according to available private estimations, excluding the capital expenditure). It may be, or may become, significant for any plant; thus, risk assessment is of concern here. Using recirculated water could lead to a better control of the quality and the quantity of water supplied to the mineral processing units. Furthermore, it could reduce the volume of waste water to be managed and treated before its release to the environment. However, process water may have some positive and negative impacts on mineral processing operations (Janssen, 2003; Johnson, 2003; Rao and Finch, 1989). Negative impacts could limit the incentive for sustainable development initiatives. Water management strategies at mineral processing sites are supported both by a strategic plan and a water management plan. The strategic plan includes legal aspects, investment costs, potential benefits and various risk levels (Corder and Moran, 2006; Côte et al, 2006; Evans et al., 2006; MacIntosh and Merritt, 2003; McLellan et al., 2008; Merritt and MacIntosh, 2006; Robinson and Keddie, 2006; van Beers et al., 2007a; van Beers et al., 2007b; van Berkel, 2007). In practice, the strategic plan evaluates technical possibilities and costs of various scenarios, such as for example: bringing fresh water to the plant or recirculating waters, or using blends of both. Two important factors to consider in order to enhance the future production efficiency and to minimise risks are: the durability and the stability of the resource, both from quality and quantity points of view."

Jan 1, 2012

By D. Gagnon, B. Dubreuil, J. -M. Lalancette, D. Lemieux

"The pilot scale extraction of gold with a brine of sodium chloride and bromide at 30 ºC, in an atmosphere of halogens at atmospheric pressure, leads to gold chloride with 95% gold recovery. The use of dilute hypohalites (1 – 3%) instead of free halogens, which is strong enough to oxidize hypobromite into bromine, simplifies the recycling of halogens by electrolysis. With the recycling of water and brine, the regeneration of hypohalites and with a barren solid that is inert and stable. The Nichromet Extraction technology is a green process where the protection of the environment does not preclude profitability.INTRODUCTIONThe use of chlorides for the extraction of gold predates the discovery of chlorine by Scheele in 1774. In the Plattner chlorination process (Christy, 1888) sodium chloride and copper salt were used to promote gold recovery by amalgamation with variable results. The introduction of the cyanide technology in 1889 has led to a general use of this method for gold recovery. In the last decades, a return to chlorine in extractive processes has been noted (Ferron, Fleming, O’Kane and Dreisinger, 2002), mostly because of environmental pressure for non-cyanide technologies.This paper describes a closed circuit proprietary approach (Lalancette, 2009) developed and piloted by Nichromet Extraction Inc. for the extraction of precious metals with recycled mixed halogens; chlorine and bromine from hypohalites. DESCRIPTION OF THE PROCESSThe attack of gold by halogens can vary significantly. The rate of reaction is substantially higher with bromine (Br2) than with chlorine (Cl2), by a factor of more than five, although the oxidation potential of Cl2 is higher than Br2, as shown in Equation 1a and Equation 1b (Latimer, 1952)."

Jan 1, 2012

By Alex Luyima, Jaan Kers, Lifeng Zhang

"The pyrolysis of PWBs was investigated by a TG-DTA-MS furnace at 300–1173 K. The kinetics and the control of emitted gas during the pyrolysis of PWBs with and without chemical additives were studied. Moreover, the possibility of controlling the amount of toxic exhaust gases like HBr, C6H6, Br2, Cl2, HCl gas and recovering beneficial gaseous fuels like CH4 and H2 from pyrolysis process is discussed. The MS data for each PWB sample were examined as a function of temperature and particular m/z values could be associated with the mass loss steps in the TG data. The degradation of the organic material was characterized by m/z = 2, 16, 18, 28, 36, 44, 71, 78, 81, and 160. Fe2O3 was the best inhibitor of toxic HBr and C6H6 when compared to Al2O3, CaO Y-zeolite and ZSM-5. Moreover, it had no significant effect on the valuable H2 and CH4 gas evolution. This selective inhibition of toxic gases while maintaining the valuable ones make Fe2O3 the best candidate among the investigated additives in controlling gas emissions from PWB pyrolysis process.IntroductionThe electronic and electric industry is one of the world’s largest and fastest growing manufacturing sectors. As a consequence of this growth, electrical and electronic waste (e-waste), such as computers, washing machines, printers, mobile phones, television sets, stereos, radios, etc., is generated in large quantities around the world. Printed wiring boards (PWBs) are a common component of many electronic and electric systems.[1]. The rapid development and expansion of the electronics industry over the past several decades have led to a dramatic increase in the production of PWBs and a corresponding increase in the amount of waste generated from both production and disposal. The environmental impacts of the treatment and recycling of PWBs waste have become a major concern [1-2]. PWBs are particularly problematic to recycle because of the heterogeneous mix of organic material, metals, and glass fiber [1]."

Jan 1, 2012

By R. T. Jones

"Technical publications in the field of mining and metallurgy have existed for a long time. Recent developments in electronic publishing on websites make it possible to disseminate information more widely and cost effectively than before. Professional societies have an opportunity to serve their members and their industry by publishing high-quality peer-reviewed papers on their websites as well as in printed form. Older publications can be scanned, and optical character recognition can be used to provide searchable text. Various business models exist around this process. This paper outlines the approach used by the Southern African Institute of Mining and Metallurgy (SAIMM) to provide free open access to their journal papers and conference proceedings, as well as the work being done by OneMine.org to collect technical papers from a number of international societies and make them available to subscribers via a large database. An approach is outlined that should be of benefit to authors, readers, and society at large.INTRODUCTIONGeorgius Agricola (1494-1555) was not the first writer on the subjects of mining and metallurgy, but is well known as the author of De Re Metallica (‘of things metallic’ or ‘on the nature of metals’), a book that documents and illustrates the observations he made in the course of his extensive travels in the 1500s. Agricola wrote extensively about mining methods and metallurgical processes that were in place in the Middle Ages. The original Latin version of De Re Metallica was published in 1556, the year after Agricola died. It was translated into English by Herbert Hoover, a mining engineer and later President of the United States, and his wife Lou Henry Hoover, a geologist and classicist. The English version of De Re Metallica was published in 1912."

Jan 1, 2012

By J. D. T. Steyl

"This paper presents a phenomenological model of the rate of iron(III) precipitation in batch and continuous autoclaves at medium temperature operating conditions. The rate expressions are based on information obtained from the literature and experimentation at low and high pulp densities. Special allowance is made for the formation of surface nuclei, which appears to be promoted at a higher iron(III) precipitate surface area, especially in suspensions of lower terminal acidity. This leads to the formation of secondary particulates and provides the required link to simulate high pulp density leaching-precipitation systems, using low pulp density batch precipitation data. In particular, the model allows direct application of the simulation to the autoclave oxidation of iron-containing copper sulfide concentrates and provides a good estimation of the relative precipitation rate of hematite, the preferred product, compared to hydronium jarosite. Some interesting mechanistic understandings of iron(III) precipitation in autoclaves are further elucidated.INTRODUCTIONThe objective of this work is to describe the rate of iron(III) precipitation and the relative amounts of hematite compared to hydronium jarosite precipitation during batch and continuous chalcopyrite oxidation under medium temperature (MT) (~130 to 160ºC) autoclave conditions. Published information has not yet revealed sufficient mechanistic insights about this sparingly soluble salt system under these conditions. The rate expressions in this paper are based in part on current literature information, supplemented by qualitative experimental observation at low pulp density conditions, in particular the high-resolution backscatter electron (BSE) images and particle size distributions (PSDs) of the precipitates. A summary of this work and insights from the literature are presented first, after which the behaviour of iron(III) in high pulp density leaching systems is used to derive a phenomenological expression of the effect of existing iron(III) precipitate surface area on the precipitation rate. The overall regression encapsulates all the experimental results, i.e., those obtained in both batch and continuous autoclave configurations (Steyl, 2012a)."

Jan 1, 2012