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By G. C. S. Burns

"A system has been developed to simulate the mining of the Mufulira orebody. The main output from the system is a picture-gram from which the start date and effective life of all proposed mining faces can be measured. This information provides schedule dates for the completion of major capital development projects and stope preparation activities.The orebody must be divided horizontally into main levels and vertically into blocks of equal interval. Ore reserves are defined by specifying the tonnage contained in each block and main level. Mining faces are defined by their co-ordinates, and may themselves be split into sublevels. The simulation maintains an echelon between contiguous sublevels. Other face parameters control the speed of mining, the availability and relative priority of the face.The required production from each crusher/shaft system is specified. The technique of simulating the mining process in order to achieve the required production is described."

Jan 1, 2014

"Chairman: Professor E. P. PFLEIDER Rapporteur: Mr P. R. JANISCHPapers:Optimum design of an open pit by D. A. PhillipsAn open pit design system for stratiform ore bodies by L. A. J. Pronk van Hoogeveen, J. R. Cutland and M. WeirAn open pit design model by R. H. Robinson and N. B. PrennThe Chairman in opening the session highlighted the current situation in the United States of America where some 85 to 90 per cent of all mining (except for coal) is done by open pit methods, and where some 40 per cent of the coal is mined by open pit. The South African industry is, of course, dominated by the deeper level underground gold mines; however, with the aid of an extensive open-pit technology developed in other countries, South African companies arc continuing to explore possibilities of open-pit exploitation of base mineral, coal and diamond deposits. Several successful ventures are already in operation at Phalabora, Optimum Colliery, Kimberley and elsewhere, and South Africa is undoubtedly benefitting in this regard by drawing on the experience of others.The papers of this session were therefore particularly pertinent, particularly when viewed in conjunction with those presented at an earlier South African conference devoted specifically to open pit mining.Two themes dominated the discussion which followed presentation of the three papers at this session. The first related to the practicability of using the reported techniques as a tool for management, and their acceptability as such to mine management. This was, of course, not peculiar to this particular session, but rather the major point of debate over the entire conference.The second theme concerned the reliability of the initial drill hole data on which any open-pit design must necessarily be based. This gave added emphasis to the problem of practicability, for no management is likely to accept an elaborate pit design unless confidence can be placed in the ore reserve assessment.In noting these two features of the discussion, it should be remembered that all the three papers dealt largely with design and pre-planning; there was an unfortunate lack of papers or discussion on the subject of controlling the day-to-day mining of open pits, and this is an area where the potential impact which can be made by the computer is even greater.In introducing his paper, Mr D. A. Phillips pointed out that it was concerned only with optimization, and that it therefore assumed, firstly, an adequate subdivision of the orebody into ore blocks characterized by grade, rock type, structure, etc., and, secondly, an acceptable forecast of costs and mineral prices in order to generate a suitable profit matrix. However, programs dealing with these problems for both massive, disseminated and stratiform ore bodies are available to Roan Consolidated Mines. The method of optimization which he had described had been used on a region split into 28 000 blocks, for which the program used three hours of C.P.U. time on an IBM 360/40 computer. The computer design had provided a three per cent improve¬ment on a normal design of the same area."

Jan 1, 2014

By S. M. Graham, G. Mellis

"The determination of the oxidation state(s) of an element present in a solid sample may be required for a number of reasons, including the assessment of the degree of reduction which has taken place during a multi-step production of a metal. In addition, possible flaws in a metal may result from small amounts of oxides included in the solid. The analyte of interest may be present as a major component of a sample of interest, or as a minor impurity - beneficial or requiring removal - in another matrix.Numerous methods have been established for the analysis of species in solution samples - for example, Fe2+ and Fe3+ by titration, Cr6+ by colourimetric means, etc. With appropriate knowledge of the solution being analysed, many of these methods are fairly straightforward, extremely reproducible and accurate. In those instances where the analyte in a solution is known to be in only one form, the analysis is even more straightforward, since it can be achieved instrumentally (by AAS, rCP-OES or rCP-MS, for example).However, the situation with respect to the analysis of solids is not as simple. Various techniques - such as X-ray diffraction - are routinely used by our mineralogists to obtain information about the various minerals present in solid samples, and thus about the oxidation states of the analyte elements present. However, these techniques usually give results that are qualitative, or semi-quantitative at best. They are also usually time-consuming and expensive. One of our colleagues at Mintek, Deshenthree Chetty, has done extensive work in developing a method for the quantification of manganese species in solids using mineralogical methods, and this is no small achievement."

Jan 1, 2014

By J. Finch, F. Rosenblum, McGill University

The self-heating of sulphides can be a major hazard in mining operations and concentrate handling, particularly during transportation and associated storage. Self-heating results from the oxidation of sulphide minerals and can vary from being insignificant to potentially hazardous to life and infrastructure. It is essential that there be a reliable test methodology that can categorize a given sulphide material as to its self-heating potential. By their nature, sulphide ores and concentrates are complex and variable mineral combinations making it difficult to predict their self-heating behavior a-priori based on mineralogy or with a simple "snapshot" test. Furthermore, self-heating behavior will depend on the state of oxidation of the sulphides as well as time, temperature and humidity. A review of available testing apparatuses and protocols that can be used to assess self-heating potential is presented. Each of these methodologies was examined in relation to its ability to predict the latent self-heating hazard of a sulphide material. Several of the methods were compared to illustrate their strengths and weakness. The results indicated that a number of the test protocols may produce false negative indications of self-heating potential, constituting an obvious concern to the industry.

Jan 1, 2014

By J. A. Theron

"This paper provides guidelines on performing mass and energy balance modelling involving coal and coal derivatives. Usually, the inputs to a pyrometallurgical process would be specified in terms of elements and compounds. Reliable thermochemical data is more widely available for species involving uniquely defined, relatively smaller molecules. However, in the case of coal, the molecules are extremely large and not uniquely defined. Consequently, modelling processes involving coal and its derivatives have several potential pitfalls. These are outlined in the present paper. The main findings are as follows:•,Coal proximate analysis should not be regarded as absolute; it could vary with several parameters, including heating rate •,For modelling, the use of ultimate analyses should be considered a preferable option to proximate analyses, where, ‘fixed carbon’ and ‘volatiles’ are not defined in terms of chemical composition •,Significant errors could be made if the larger molecules are neglected during calculation of the calorific value (CV) of coal gas (the gas liberated when coal is heated in the absence of oxygen) •,For elemental analyses, the oxygen content (which is calculated by balance) should be checked to ensure it is within the expected range •,For representation of sulphur in coal, double-counting due to SO3 in the ash analysis should be avoided •,Potentially, oxygen in coal could be represented as O2, H2O, CO, or CO2; however, use of some of these species without considering the experimentally determined gross CV results in significant errors in the energy balance. If coal enthalpy is calculated from elemental analyses without correction, representation of coal oxygen as H2O(l) gives reasonable accuracy (up to 6.9% error for a set of South African coals). Coal volatiles could be represented by a complex mixture of compounds, even using different oxygen-containing species than the abovementioned four, provided the enthalpy is corrected •,It is recommended that an ‘enthalpy correction value’ is incorporated in energy balances involving combustion, devolatilization, or conversion of coal and coal derivatives, e.g. coke, char, or tar. That would imply that proximate analysis, elemental analysis, as well as the gross CV would be required for all solid or liquid coal-derived substances being modelled. No other correction due to the form of carbon being different than graphite should be used, as that would imply doublecounting some effects."

Jan 1, 2014

By Peter Ay, Elena Geldt, Satyanarayana Narra, Claudia Glaser

"As part of an extensive research and development project, the technical and technological implementation of the patents DE 10 358 245 B4 and WO/2006/056172 was developed with the goal to present a system for the innovative roll- agglomeration method exhibiting a) a modular setup, b) high productivity and c) suitability for the use of fibres of different applications and product qualities (high technical availability). The processability of the rarely adapted raw fibre materials into high-value intermediates brings forward their application in various processing industries dealing with the production of fibre reinforced plastic composites, heat and sound insulation materials as well as with the gas and liquid cleaning systems. The innovative fibre agglomeration presented in this work is performed by a combination of rolling and pressing the fibres inside a geometrically pre-defined roller table, in which the fibres are forced to bound through entanglement / interlocking and develop into agglomerate. The agglomeration process is carried out in a circular roller path with a rectangular cross-section. For improving the adhesive properties, and thus the quality of the agglomerates, the boundary surfaces can be covered / patterned / lined / coated with various materials. The resulting roll-agglomerates are characterized by different quality parameters such as mass, shape, porosity and stability. The properties of the agglomerates can be modified based on the end-product requirements by slightly modifying the process parameters such as filling ratio, residence time, roll-geometry, procurement of the boundary surfaces, etc. as well as the input material properties such as fibre type, fibre fineness, fibre length, etc. This work carries extensive work on the roll-agglomeration system to assess the effectiveness and the variability based on the product specifications. Agglomerates were produced with wide variations of system parameters with varying roller table liners and based on evaluation of the produced agglomerates with respect to their mass, the geometrical dimensions, their porosity and stability."

Jan 1, 2014

By Tsuyoshi Hirajima, Hideyuki Okamoto, Himawan .. T. B. M. Petrus, Keiko Sasaki

"Flotation of arseno bearing minerals from their copper ore has been an interest due to the increasing awareness on protecting the environment by minimizing the possibility of exposed arsenic compound. Some approaches have been proposed, but the mechanisms of separations have not yet fully understood. In this study, oxidation using oxygen was applied. Instead of the complex copper ore flotation results, pure single mineral of tennantite and chalcopyrite foatability was conducted using Hallimond tube. Resembled with the flotation results of copper concentrate containing tennantite, the separation possessed the best result at alkaline condition (pH 11) at where the arsenic content was reduced from 3300 ppm to 1800 ppm. In order to be able to understand the mechanism of the separation atomic force microscope (AFM) was utilized. AFM images showed changes in morphology and behavior when minerals were treated in both acid and alkaline condition. It was found that the morphological change showed the reaction products representing the rate of reactivity of tennantite and chalcopyrite. From the measured force of adhesion, it can be observed that in alkaline condition the surface of both minerals is more hydrophilic than that in acidic condition possessing higher value. This is in accordance with the X-ray photoelectron spectroscopy (XPS) spectra in which hydroxide moieties occupied the mineral surface in alkaline condition while elemental sulfur is in acidic condition."

Jan 1, 2014

By Milind Chikhale, Ranjeev Kumar, Keshav Tyagi

Ore characterisation including mineralogy and beneficiation testwork of an ore is very important for determination of possible products and their quality. The results of such study help in ascertaining the beneficiation process route for the ore. The present study deals with ore characterisation study and beneficiation testwork on the samples of hematite iron ore with goethite impurity. The characterisation study reveals that the hematite is under alteration stage to goethite which has become an integral part of hematite. High goethite/limonite content is enhancing the loss of ignition content of the ore and reducing its Fe content. The findings indicate that in case of hematite iron ore associated with goethite and limonite, it is difficult to achieve high grade of concentrate above 65% Fe. It depends on the amount of goethite and limonite minerals and their association with hematite. These minerals contain aluminous impurities and hence, their rejection becomes essential. Separation of limonite and of goethite to limited extent is possible. In case of goethite, effective liberation is not achieved where it occurs as surface alteration product of hematite grains. The gangue mineral reported are clay and gibbsite, and are closely associated with iron minerals. The test work results indicate the grade and recovery of Fe along with alumina and silica content in lumps, sinter fines and pellet feed fines that can be achieved for the different ore types vis-a-vis the percent of available hematite in the ore. The recovery of iron is dependent on the hematite available and the loss of iron values in tailings is more because of rejection of limonite and goethite.

Jan 1, 2014

By Jean Michel Marino, Jean-Pierre Slama

"The computer methods used by the French Commissariat a l'Energie Atomique, which are applicable to any type of ore deposits, are:(i) Ore reserve estimation. The data are either the core analyses or gamma leggings. To determine the spatial distribution of the ore, three different methods of interpolation are used. Two of these are based on the least-squares theory and the third one is an application of the regionalized variable theory. The interpretations of the orebody by the geologists are introduced in the computer program as often as possible.(ii) Optimal open pit design. From the spatial distribution of ore, the three-dimensional outlines of the optimal pit are determined by a geometrical algorithm which allows different slopes varying with the azimuth.Finally, the optimization of annual successive plans arc discussed."

Jan 1, 2014

By Trevor Saldanha, Stephen Grano

A key uncertainty in flotation modelling is determining, a priori, the proportion of each mineral which will develop a certain rate constant for different feeds of variable liberation and hydrophobicity. First and foremost is the ability to predict the proportion of minerals that will not be recovered, even at very long flotation times, and which therefore report to the tailing stream as the non-floatable fraction (i.e., having a zero rate constant). Recent empirical evidence has shown there are at least two factors which contribute to heterogeneity in flotation rates and, in particular, the appearance of a non-floatable fraction - heterogeneity in the distribution of adsorbed collector amount on a particle-by-particle basis, even for the same liberated mineral in the same size fraction, and the existence of a critical contact angle below which the bubble-particle union is unstable. In this paper, inferred measures of the critical contact angle for liberated particles are compared with stability model calculations. This has demonstrated that the dependency of the critical contact angle with particle size and mineral specific gravity are explicable by bubble-particle stability considerations. This argument is further extended to the flotation behaviour of composite particles, as a function of liberation class, in which the wetting perimeter of the attached bubble on the composite particle surface is constrained by the presence of a surrounding hydrophilic domain for the case of simple binary composites. Reasons for the different flotation behaviour of composite particles having different textures, as noted in the literature, are also discussed in terms of the stability of the bubble-particle union.

Jan 1, 2014

By F. H. Touwen, N. C. Joughin

"Simulation is a technique for studying the operation of systems by synthetic experimentation. With digital computers it is possible to simulate even the complex production processes in gold mining. This has great potential in that it enables the investigation, analysis and comparison of mining systems to be done accurately, rapidly and at low cost. Two programs have been developed to simulate the principal underground production processes in gold mining.These are the simulation of any stope contract and the simulation of underground transport operations. The programs synthesize these mining activities from a large number of small unit operations. The stope contract program simulates rockbreaking by drilling and blasting and the cleaning of the panels by face and gully scraping. The transport program simulates the functions and movements of all vehicles running on rails on one underground level. The simulation programs provide an effective means for experimenting with mining activities."

Jan 1, 2014

By R. P. King

"A model of the flotation process can be used effectively for design and control. For design purposes it can be used to predict the performance of a large plant from laboratory and pilot plant data. It can be used for control purposes to assess the utility of any proposed operating modification to an existing plant, and it can also be used to determine optimal control settings for best operating performance.A model has been developed that will allow for variations in feed properties and for variations in fineness of grind. The model can be used to assess the effects of reagent addition rate, aeration rate and pulp level on plant performance and these are the control variables that are used individually or together in all operating flotation plants. The model provides for a distribution in the values for flotation rate constants, particle size and mineral fraction, and, because of its complexity, requires a large computer when it is to be applied to a typical plant configuration. The computational method that is used to apply this model to such configurations is described in this paper, and particular attention is paid to the problem of allowing for feedback of tailings from cleaners and recleaners."

Jan 1, 2014

By Peter Ay, Vincenz Mehlstaubl, Satyanarayana Narra

"This study gives an insight into non-destructive testing methods suitable for porosity analysis at a small scale, firstly summarizing relevant state-of-the-art technology and pending patents, secondly realizing and documenting the start-up of the VHX-2000 digital microscope by the manufacturer Keyence and thirdly demonstrating practical application with the extended analysis of three fundamentally different agglomerates for which important application-related parameters are determined. Various analysis procedures on the different agglomerates the efficient and timesaving operational features of the digital microscope are outlined. Firstly an analysis of flax fibre agglomerates determines the process conditions best suited to produce agglomerates with specific properties by determining sphericity, cubicity, density and porosity as well as fibre damage and alteration. Secondly the production of iron-hydroxide - hemp-fibre agglomerates serves to obtain information on porosity values as a result of a cauterization of the fibres. The third analysis provides estimations of porosity values for acid-treated lignin agglomerates. Measurements were carried out with compact dry agglomerates and with soaked, expanded agglomerates, determining factors for total water carrying capacity. Practicability of non-destructive testing by digital microscopy is demonstrated and explained concerning the applications in this study by obtaining definite structural findings about the analysed agglomerates. Information on its operation is made available by a practice-oriented manual for the VHX-2000 digital microscope. Further suggestions for more in-detail analysis results with different instruments are given."

Jan 1, 2014

By Reinol Compañero, Ivy Gonzales, Herman Mendoza, Brian Buenaventura

"The extraction of gold in the Philippines has been a significant challenge for the past decades. Around 70-75% of gold mined in the country can be accounted from the small-scale mining industry which primarily use the traditional cyanidation and amalgamation; processes which have been advocated due to its adverse affects to health and environment. To address this challenge, an alternative clean and sustainable technology was developed for the small-scale miners to recover gold and other metal/mineral values efficiently from Philippine ores. An initial survey was conducted and followed through with extensive mineralogical investigations ascertain the best method applicable. It was determined that Philippine gold occur in ore as (1) very fine particles in the microns range, (2) free-milling, which is in abundance, and (3) locked particles with sulfides --- it was concluded that enhanced gravity concentration and flotation are viable alternatives. A comprehensive test regime was followed to check the response of the ores obtained from different small-scale mining districts across the country. It was shown conclusively that the gold ores respond positively, with recoveries using gravity concentration and flotation of at least 95% and 88%, respectively; exceeding the nominal recoveries using cyanidation or amalgamation. A specific process flow was designed for each type of ore with customized parameters. It was determined that while capital expenditure of implementing these alternative processes is higher than what is currently being used, the operational aspects show that it is much more economical to apply enhanced gravity and flotation. It should be noted that the process developed addresses the critical issue of environmental costs which should be more than enough to justify the shift from the current to the novel and sustainable technologies."

Jan 1, 2014

By X. Q. Ma

The beneficiation test on low grade phosphate ore from a state of Russia is carried out. The rougher-cleaner ? re-cleaner system is used in the flotation process, The fineness of grind is 39.07% minus 200 mesh. The result indicates that concentrate containing 31.25% P2O5 can be obtained from the flotation feed assaying 6.18% P2O5, with 93.54% P2O5 recovery. The test result is also a guideline for further development of some currently operated phosphate beneficiation plants.

Jan 1, 2014

By Andre Krzysik

"Fluidized bed technology has been used in the industry for almost 100 years. To fully understand the process hundreds if not thousands of researchers were and are involved in finding the way to predict the behavior of the solids when subjected to the flow of media through them and the conditions of the solids in the fluidized state. The difficulties in predicting the behavior of solids in the fluidized state stem from the complexity and abnormality of the parameters related to the solid particles. Theoretical calculations can in some degree account for some of them. Particle size distribution, their shape, density, moisture content and physical and chemical reaction that may exist in the fluidized bed reactor play an extremely important role and influence the behavior of the fluidized bed. This paper focuses on the practical examples of the fluid bed equipment and the use of different conditions to process various products.IntroductionEach process application has its own unique requirements and the designers of the equipment must take into consideration specific process requirements, specific properties of the material to be processed (both physical and chemical), and physical and chemical reactions/changes that are taking place in the reactor (heat and mass exchange, chemical reactions, isomorphic change etc.). Each individual piece of equipment must also satisfy specific requirements/ preferences of the client that will operate and maintain the equipment. Those often represent greater challenges than the process on its own, and are equally important to the satisfactory operation of the plant. That includes aspects like location of the equipment, environmental effects, and expected life of the equipment, process control, access, maintenance, and many others.Over the period of time a great deal of research, both theoretical and practical have been carried out and the results of that work are available for equipment designers. For the simple applications that information is usually sufficient and the selection of a suitable solution is relatively simple. In many instances, the available information is not sufficient, and often specialized test work needs to be conducted to obtain additional data. In many cases a pilot installation is built in which the required process is tested. Only then the commercial equipment is designed. The following deal with specific installations that were designed to satisfy specific requirements. In some instances, additional problems were discovered during the commissioning of the equipment that required on site modification. The continuous monitoring of the equipment that was supplied to the various clients allowed us to further develop and improve our designs."

Jan 1, 2014

By Kazutoshi Haga, Batnasan Altansukh, Shirchinnamjil Nyamdelger, Atsushi Shibayama, Narankhuu Ariunbolor, Gunchin Burmaa

In this study, the authors investigated the capability of an acidic thiourea solution and silicon-organic polymers (PSTM-3c, PSTM-3T) as ion-exchange resins to recover of gold from gold-bearing ore concentrates. Firstly, elemental gold present in flotation concentrates was dissolved by leaching with a solution of nitric acid and thiourea under the optimized conditions. The best result on gold thiourea leaching was obtained under a nitric acid concentration of 2 N, thiourea concentration of 2 %, and oxidant (Fe2(SO4)3) concentration of 3 %, solid:liquid ratio (S:L) of 1:20, leaching time of 6 hours at 20 °C with a gold recovery of 93.7 % for a gold flotation (unroasted) concentrate. For the roasted gold concentrate, the dissolution of gold was 94.8% under the optimized leaching condition as nitric acid concentration of 0.5 N, thiourea concentration of 2 %, and the oxidant concentration of 1 %, S:L ratio of 1:10, leaching time of 4 hours at 50 °C. Secondly, a series of sorption tests was carried out on a pregnant leach solution containing gold complex Au[S=C(NH2)2]2+ using silicon-organic polymers (PSTM-3c and PSTM-3T), respectively. The effects of solution pH, adsorption time and temperature in the sorption process are also studied. As the results, the PSTM-3c and PSTM-3T polymers were adsorbed about 94.4 % and 95.1 % gold from the pregnant leach solutions under the optimum sorption conditions, respectively. It was found that the both PSTM-3c and PSTM-3T polymers were effective for the recovery of gold from the pregnant leach solution of thiourea. Adsorption activity of the PSTM-3c and PSTM-3T polymers was confirmed by new peaks near 1700 cm-1 in the FT-IR spectrum of the gold-adsorbed polymers, respectively.

Jan 1, 2014

"TREVIICOS CorporationINTRODUCTIONThe Walter F. George lock and dam was constructed on the Chattahoochee River between 1955 and 1963 with the double function of improving navigation and generating power. Its 82 ft. by 450 ft. (25m x 137m) lock can accommodate large barge traffic and its four generating units with a plant capacity of 150 MW have an average energy output of 453,000 MWH. The dam consists of a 1,496 ft. (456m) long concrete structure housing the spillway, a non overflow portion, the power units and two earthen wing dams extending to the Georgia and Alabama sides, respectively 5,810 feet and 6,130 feet long (1770m and 1868m). As soon as the reservoir was impounded it became apparent that excessive seepage was occurring. From 1962 to 1985 a series of remedial works was performed using several techniques, but the problems continued under the dam, jeopardizing its generating potential and possibly undermining its stability.Finally, the decision was made to construct a deep cutoff primarily under the concrete portion of the dam to remedy the problem. PROCUREMENTOn July 5th, 2001 best and final offers were solicited by the Corps of Engineers (COE) for the construction of a deep cut-off to be built in front of the concrete portion of the dam from the bottom of the lake and tied into it. The cut-off had to cross an existing lock structure and an underwater retaining wall, as well as the remnants of a steel coffer cell left in place from the initial construction.The specifications required that the wall be built with a minimum thickness of 24” (600mm) and that it extended from the bottom of the lake to elevation -5 (1.52m) into the Providence formation, an impervious layer.While the land portions of the wall were on average 208 feet (63.4m) deep, the marine portion started from up to 90 feet (27m) of water and continued through different rock formations for another 100 feet (30m).Contractors were invited to propose their own method of constructing the cut-off and offers would be evaluated using several criteria, including technical, economical, organizational and experience.Three proposals were received and on August 14, 2001 an award was made to the Joint Venture (JV) of Treviicos and Rodio."

Jan 1, 2014

Nowadays, the more successful plants are those who have adopted effective and efficient strategies to optimise their plant operation. As the ?heart of the plant? could be viewed as the mil-ling/grinding area, one of the key steps in plant optimisation is, therefore, ensuring the mill is operating properly. In the past, when primary, secondary and tertiary crushers fed material directly to large ball mills, the energy efficiency of the concentrator was determined for the most part by the ball mill operation, whereas now the energy efficiency of a plant often rests largely on the semiau-togenous grinding (SAG) mill operation. As a result, mines have shifted their emphasis in optimization from ball mills to SAG mills. The grinding mill?s energy efficiency essentially depends on ore characteristics and the discharge rate of broken particles, which in turn depends on how efficiently the discharge pump (grate and pulp lifters) operates. The essential function of pulp lifter being to transport the broken material and slurry out of the mill, its design optimization therefore affects the discharge capacity (or mill throughput) of AG and SAG grinding mills. This paper will discuss how the optimised design of the pulp lifter/ discharger has helped to eliminate material transport issues such as flow-back and carry-over of slurry and pebbles to in-crease the energy efficiency of SAG mill using the actual operational data.

Jan 1, 2014

By Felipe Costa Hashimoto Bertin, Jorge Alberto Soares Tenório, Rodrigo de Souza Dalti Pereira, Denise Crocce Romano Espinosa

"The increasing amount of portable devices and their fast obsolescence generates an increasing quantity of discarded batteries. The recycling process of discarded batteries allows the recovery of metals for further use and avoids the contamination of soil and water. Even though there are several researches on the topic, few papers focus on mixed batteries. The purpose of this work is to characterize a mass of collected mixed batteries and study the hydrometallurgical process of recycling. The specific leaching parameters studied were pH, temperature and reduction potential. The specific goal was testing the selectivity of pH for leaching each metal. The results show that the optimal leaching occurs in acid solutions with negative pH at IM of sulfuric acid and at room temperature (25°C).IntroductionThe increasing portability of electronic devices in the past century along with their fast obsolescence produce tons of discarded materials yearly that could be recycled generating new materials for the industry. For example, metals such as cobalt and nickel, that are worth respectively US$ 30.00 and US$ 16.10 per kilogram[l,2] are disposed in urban trash yearly, which means that millions of dollars are thrown away instead of being recovered and reused[3].Besides the obvious fact that the society is throwing money away, most of these metals are toxic for the environment and all mammals, so when badly stored after use they can be found contaminating ground water which will contaminate the entire lifecycle. Some of these metals can cause cancer, serious lung problems and have bioaccumulative properties [4] resulting in lower productions of natural products and maybe death for consumers.So in compliance to new regulations such as the National Solid Residue Politic (PNRS) and the CONAMA-Resolution N°401 from November of 2008[5]- (that follows similar restrictions and regulations as the European directives) all those urban and electronic wastes need to be correctly disposed and treated before being thrown away on local dump sites.In Brazil the national rate of garbage recovery is around 70%, which only 5% is properly recycled, accordingly to the research of the UFSC, also electronic waste grows at 5% per year [6]The present study was motivated by the fact that recycling processes for batteries are not spread through the country and by the fact that most papers do not try to recycle a mixed mass of batteries, but a specific mixture which does not represent the composition of traditional household wastes."

Jan 1, 2014