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By Armin W. Stuedlein, Jim Zammataro, Bernie Hertlein, Daniel Belardo, Qiang Li, Antonio Marinucci

"An experimental program focusing on four drilled shafts was conducted to determine the effect of high strength steel reinforcement bars on lateral resistance, steel casing on axial and lateral resistance, and steel casing without internal reinforcement on lateral resistance. Thermal Integrity Profiling (TIP) Thermal Wires and crosshole sonic logging (CSL) access tubes were installed in each shaft, and thereafter the corresponding non-destructive testing (NDT) was performed on each shaft to assess the integrity of the shafts and to compare the results from the different NDT methods. The results of the CSL tests using scored PVC tubes are compared against those conducted in 73/56 fully-threaded steel hollow bars, whereby the results indicated that the threaded bars served as a good host for performing the CSL tests. The data from the TIP Thermal Wires is compared against the results from the CSL tests for each of the four shafts, and the similarities and discrepancies between the two methods are discussed. This paper will serve as a reference to those interpreting the measurements and data obtained by performing nondestructive integrity tests on drilled foundations.INTRODUCTIONNon-destructive tests (NDTs) embody a set of critical tools for the evaluation of the integrity of constructed deep foundations, particularly for cast-in-place foundation elements. Construction defects may require the rejection of the foundation element by the owner’s representative, resulting in costly repairs or replacements and delays to the project schedule. The use and appropriate interpretation of the results from the NDTs provide the information required when evaluating the integrity of these constructed elements. A cooperative research program was conducted to assess the effects of various construction variables on the axial and lateral performance of drilled shaft foundations, which provided an opportunity to compare the established Crosshole Sonic Logging (CSL) test method to the newer Thermal Integrity Profiling (TIP) Thermal Wire method. This paper presents an overview of the experimental program performed at the geotechnical test site at Oregon State University (OSU), details of the CSL and TIP installation and testing methods, and the results of the NDTs on the constructed drilled shafts. Because one of the shafts was constructed with fully-threaded longitudinal steel hollow bars, this experimental program also allowed the assessment of the use of the hollow bars as access tubes for the CSL tests. Both the CSL and TIP test methods indicated that the shafts were of good quality and free from defects or anomalies; the data obtained using the TIP method also provided an estimate of the as-constructed shaft diameter and the reinforcement cage alignment, which will prove helpful when back-calculating axial and lateral load transfer during future loading tests."

Jan 1, 2016

By I. D. Dayal, Anil Kumar Jain

"Cutoff walls are frequently used to slow down or prevent seepage of water through and/or around dams. Cutoff wall is a type of seepage barrier structure designed to reduce the flow of water underneath temporary or main dam. There are number of techniques for the construction of cutoff walls including concrete, Jet grouting and permeation grouting. NHPC LTD, a premier Govt. of India undertaking has been instrumental in the hydropower development within the country & in nearby countries like Nepal & Bhutan since last four decades. NHPC LTD has completed more than 20 hydro-electric projects with total installed capacity of 6587MW (including capacity addition by JV- NHDC). In all these projects, different types of dams and spillways were constructed in not so benign to extreme challenging geological set up. There has always been challenge associated with the temporary diversion works. The project sites sometimes incur huge river bed excavations in case of concrete gravity dam founded on rock foundation at large depth. The challenges for minimizing the seepage have been well taken care by constructing the dedicated seepage barriers. The construction of cut-off walls have progressed from “conventional continuous trench backfilled with conventional concrete or plastic concrete” to “grout curtain”, to “jet grouting” to the “concrete cut-off wall” , the last being the most sophisticated & credible seepage barrier.The efficiency of the cut-off walls are monitored by the seepage quantity observed (reduction of the seepage flow), uplift pressures or exit gradients after construction of cut-off walls. For construction of the main concrete dam, required space is created by the river bed excavation for placing the dam foundation on sound rock. Sometimes there is deep river bed excavation from 30 to 40 m depth or even more as per the available rock profile. Temporary coffer dams are constructed for diverting the river flow through diversion tunnels / channels etc. In deep river bed excavation; there are high chances of the significant seepage through the coffer dam foundation / river bed material due to high hydraulic gradients. Seepage and piping are the main causes of the failure / damage of the temporary coffer dams. If the seepage quantity is too high, then it becomes difficult to handle it by dewatering in the dam pit. Dam concrete is required to be placed unhindered to have a monolithic construction of dam blocks & to have faster construction in the working season. Cut-off walls increase the seepage path considerably thus reducing the exit gradient and further reduction of the seepage thus helping in maintaining the seepage free area for working."

Jan 1, 2016

By David Gatto, Nicolas A. Willig-Friedrich, Jeff A. Segar

"With the increasing demand for electricity, and requirements to generate this power cleanly, more producers are turning towards hydroelectric power. A project in Iowa currently under construction will retrofit an existing Army Corps of Engineers Dam with a hydroelectric generating facility. The design of the intake structure requires the construction of a diaphragm retaining wall. The T-shaped diaphragm wall elements retain an unbalanced fill height up to 21.3 meters (70 feet). The design required a single production element be constructed, tested, and instrumented prior to beginning construction of the rest of the elements. The testing included extensive concrete mix design development, coring, and Cross Hole Sonic Logging. Installed in the other production elements are 10 inclinometers, 4 pressure cells, 4 piezometers, and multiple survey monuments. Some of these instruments require manual readings while most are monitored by an automatic data acquisition system and instantly transferred to a website providing real-time graphical display of the data. This paper will discuss the construction of the diaphragm wall from the contractor’s perspective when working on a site only large enough for two service cranes and a Hydromill excavation unit, without any storage area on the construction pad, describe the testing performed and the quality control procedures employed, and investigate the information gained from the automated instruments providing real time measurement readings.INTRODUCTIONIn 1964 the US Army Corps of Engineers (USACE) constructed a dam by raising the surface grade approximately 34.7 meters (114 feet) above the natural ground line using a combination of fill types. This earthen dam stretched slightly longer than a mile intersecting the flow of the existing Des Moines River. The center of the dam is a concrete spillway consisting of 12 monolith sections. On each end, three of the sections extend 42.6 meters (140 feet) from the spillway to transition from the concrete dam sections to the earthen dam section. Adjacent to these three sections on the East end is where the contractor is actively working, for a private developer under a lease agreement with USACE, on this site to convert it to a Hydroelectric facility licensed for an output of 36.4 megawatts, enough power to meet the needs of about 18,000 homes. To create this, a powerhouse structure, housing two vertical Kaplan turbines is being added to the downstream side of the existing dam. From the power house, two penstock pipes will be cored through the existing concrete monolith sections and connect to the Intake structure on the upstream side of the dam. Protecting and reinforcing the dam adjacent to the intake structure is a new diaphragm wall. This wall is constructed using T-shaped diaphragm elements, acting as a cantilever retaining wall for the intake platform. Figure 1 shows a diagram of the upstream features of the construction."

Jan 1, 2016

By Fabio Santillán, Mario Mauro, Raffaella Granata

"This paper presents the utilization of slurry walls methods for the recent remediation of three high hazard active dams in the United States. Tuttle Creek Dam, located in Manhattan, KS, required seismic retrofit. To this extent, transverse shear walls were installed on the downstream slope using self-hardening slurry (SHS) to reinforce the liquefiable foundation soils. Herbert Hoover Dike, located around Lake Okeechobee, FL, is subject to potential failure because of internal erosion, piping and slope instability at high water levels. The innovative use of the hydromill equipment with SHS allowed the successful construction of the cutoff wall through heterogeneous soils and rock. At Bolivar Dam, located in Bolivar, OH, under-seepage negatively affects the structural stability of the dam, and a partial seepage barrier wall is required through the upstream slope of the dam. In this case, the Contractor selected the plastic concrete seepage barrier, excavated by a combination of clamshell and hydromill equipment. The main features of the three projects are summarized in Table 1. IntroductionTuttle Creek Dam was constructed by the U.S. Army Corp of Engineers (USACE) on the Big Blue River in North-East Kansas in the 1950s for flood control. Tuttle Creek Dam is a zoned earthfill embankment, 7,500 ft long and about 137 ft high with a crest width of 50 ft (Fig. 1). It is located in an area of moderate seismicity associated with an old continental rift zone located just to the east of the dam. The USACE, under the Dam Safety and Assurance Program, determined the need for remediation. Site investigations and geotechnical analyses identified the upper alluvial foundation sands as being susceptible to liquefaction when subjected to the Maximum Credible Earthquake.In 2005, USACE awarded a construction-manager-at-risk/early Contractor involvement contract. The USACE and the Contractor closely cooperated to identify the most effective technologies, materials and configurations to be used in the remediation. The original remediation design required both the upstream and downstream slope stabilization of liquefiable foundation. Results of refined seismic deformation analyses revealed that the stabilization of the downstream slope and toe was needed to protect the downstream seepage control system and to provide assurance that a liquefaction-induced flow slide would not occur (Stark et al., 2012)."

Jan 1, 2016

By Chunli Wei, Mark Jen, Xiaojun Wang

"After more than 85 years of service, a critical link between New York and New Jersey, the Goethals Bridge over the Arthur Kill waterway, is being replaced with two new parallel bridges. Each bridge includes 1,650 feet long signature steel composite cable-stayed bridge, a 2,789 feet long New York approach and a 1,889 feet long New Jersey approach. The superstructure of each approach is supported on a series of two-column concrete piers and each column is supported on a single large diameter drilled shaft varying from 4.5 to 9 feet in diameter and anchored 45 feet below ground into the underlying rock.A performance-based methodology was followed for the strength and extreme event limit states design of the drilled shaft foundations. The design for seismic loads has been performed using the AASHTO Guide Specifications for LRFD Seismic Bridge Design. For all strength and service loads, the AASHTO LRFD Bridge Design Specifications were used. Since the longitudinal and confinement requirements in the two specifications vary, the minimum longitudinal reinforcement was based on the more stringent requirements of the two codes. A design example is presented to illustrate the methodology in bridge deep foundation design using nonlinear time-history global analysis results with soil-pile interaction represented by sets of horizontal and vertical nonlinear soil springs along the drilled shaft, based on the soil and rock properties from the boreholes test results. In this paper the design methodology implements strain limits related to earthquake intensities and damage levels to calculate the capacity using XTRACT analysis, which aids designers to adopt applicable provisions that meet specific design requirements.INTRODUCTIONAfter more than 85 years of service, a critical link between New York and New Jersey, the Goethals Bridge over the Arthur Kill waterway, is being replaced with two new parallel bridges designed to carry vehicular traffic and a future mass transit corridor. They include two 1,650 feet long signature steel composite cablestayed bridges with 260 feet tall V-shaped concrete gateway towers (Figure 1). The approaches consist of continuous pre-stressed concrete girders. The New York approach is a single structure consisting of 18 continuous spans, sloping at 4% for a total length of 2,789 feet without expansion joints. Similarly, the longest continuous portion on the New Jersey approach, with a similar slope, consists of 11 spans for a total length of 1,889 feet without expansion joints. The superstructure of each approach is supported on a series of two-column concrete piers that vary in height from 121.3 feet near the cable-stayed bridges to 11.8 feet near the abutments. Each column is supported on a single large diameter drilled shaft varying from 4.5 to 9 feet in diameter and anchored 45 feet below ground into the underlying rock."

Jan 1, 2016

By Paul C. Schmall, Kevin Clarke, Paul J. Lewis, John M. Stanbury

"The $200M rehabilitation of the more than 100-year-old Gowanus Flushing Tunnel and pumping station located on the Gowanus Canal in Brooklyn, NY required deep excavations in an extremely congested urban environment. The environment posed significant challenges, including: support of excavation for protection of existing structures, excavation through man-made fill while eliminating groundwater inflow due to potentially contaminated groundwater chemistry; discharge and disposal impacts; and potential settlement of surrounding structures. This paper will present the design and construction challenges associated with the construction of a new combined sewer overflow (CSO) chamberwhich included a jet grout bottom seal, to mitigate groundwater inflow during excavation. The foundation for the finished structure also included a unique system incorporating the jet grout bottom seal elements with deep jet grout columns (piles) acting as the foundation system for the final structure. Design and construction challenges included highly variable soil conditions such as man-made fill, obstructions from previous construction, presence of an organic stratum, and conflicts with existing timber foundation piles. The jet grout bottom seal was constructed in loose sands with the deeper jet grout foundation elements extending to bear on a dense sand stratum. Challenges associated with the bottom seal included grid spacing and construction sequencing. Wet in wet sequencing was used to mitigate potential windows in the bottom seal further complicated by shadowing from existing timber foundation piles.Introduction And BackgroundModernization of the Gowanus Tunnel Pumping System required deep excavations in the extremely congested urban environment of Brooklyn, NY. The project location is shown on Fig. 1 and 2. The focus of this paper is to present the design and construction challenges associated with the support of excavation, control of groundwater, and ultimate foundation support for the combined sewer overflow (CSO) bypass chamber extension. The project site was tightly constrained by adjacent, active roadways and underground utilities, as well as residential and industrial structures. Therefore, excavation support was required to limit ground movement and maintain the integrity of the surrounding facilities. Excavation depths to as much as 16 ft below ground level, 8 ft below groundwater, required that seepage and groundwater be controlled so as to minimize pumping and disposal of groundwater and maintain the surrounding groundwater levels to avoid potential settlement of adjacent roadways, utilities, and structures. In addition, the subsurface conditions required that the proposed CSO bypass chamber extension be supported on a deep foundation to avoid differential and total settlements that may be detrimental to the existing and expanded structure. A plan view of the existing CSO bypass chamber and the proposed extension is shown on Fig. 3."

Jan 1, 2016

By Alexander Filotti, Richard Kalson

"In the last decade, the construction industry has witnessed significant changes in the project delivery systems and contractual relationships between the general contractors (GC) and Deep Foundation Specialty Contractors. The Deep Foundation industry, especially including industry specialty subcontractors, have experienced a significant increase in requests that project risks be transferred through contract documents to subcontractors and suppliers with a decrease in margins for the industry. GCs regularly revise their form subcontracts to take into account recent experiences/contractual trends and newly issued judicial precedent, an exercise that is less frequently undertaken by subcontractors and suppliers. These contradictory trends are at the base of the ethical analysis of subcontracts that comprises the subject matter of this paper. Using contracts as a risk management tool in order to mitigate the general contractor’s risks in the context of dynamic changes in the legislative environment will also be addressed. Furthermore, another possibility for risk mitigation for the industry is to actively promote the introduction of the latest technical developments into the contract documents.CONTRACTS’ ETHICSFor thousands of years, ethics have been a constant presence in our lives and have been debated by different branches of philosophy. In modern times, ethics in business started to be an imperative for the success of a globalized economy.“Ethics are standards by which one should act based on values. Values are code beliefs such as duty, honor, and integrity that motivate attitudes and actions.” (Rumbaugh 2004). Some of these values and actions have been carved in legislation in general and in business legislation in particular. More and more, unethical business practices (e.g., corruption) are identified as the root cause of poverty, underdevelopment, and war around the world. In the context of contract ethics, three aspects are of interest:•,Ethics of contract construction•,Ethics of contracting processes•,Ethics of risk allocation in contracts"

Jan 1, 2016

By Lynn Salvati, Colin LaVassar, Loic Galisson, Joel Theodore, Lynette Sla

"Sound Transit’s University Link and Northgate Link projects will add 6.75 miles (10.9 km) of twin-bored tunnel to Seattle’s light rail system, extending the route north from downtown Seattle. The tunnels are being constructed primarily in glacial soils using pressurized-face tunnel boring machines. Cover over the tunnel alignment varied from 13 feet to over 300 feet (4–91 m). Since the tunnels are located in densely populated urban areas, controlling ground movements and monitoring settlement were essential to success of these projects. Hundreds of geotechnical instruments, including extensometers, surface settlement points, and near-surface settlement points, were used in both projects to monitor settlement. The observed data were compared to settlement predictions made prior to tunneling, and analyses performed to update empirical factors to better estimate settlements. Recommendations for designing efficient and cost-effective settlement monitoring programs are provided based on the review of the monitoring data and analyses.INTRODUCTIONThe paper includes data from Sound Transit’s University Link and Northgate Link projects. These projects will add 6.75 miles of twin-bored tunnel to Seattle’s light rail system. The tunneling for University Link will extend the light rail system from downtown Seattle to the University of Washington. Tunneling from downtown Seattle to the Capitol Hill Station was completed under the U230 contract, and tunneling from the Capitol Hill Station to the University of Washington Station was completed under the U220 contract. The Northgate Link extension will extend the light rail line north of the University of Washington, including approximately 3.5 miles (5.6 km) of twin tunnels between the University of Washington Station and the Maple Leaf Portal and two stations, U District Station and Roosevelt Station. Tunneling for the Northgate Link project is still underway as part of the N125 project. At the time of writing, tunneling from the Maple Leaf Portal to Roosevelt Station has been completed. Therefore data labeled as N125 in this paper only include the portion of the alignment from the Maple Leaf Portal to Roosevelt Station."

Jan 1, 2016

By Shengli Wu, Laixin Wang, Minyin Kou, Xinliang Liu, Weidong Zhuang, Yujue Wang

COREX process has obvious advantages in environment protection but still has some disadvantages, for example, it has a higher sulfur content of hot metal than blast furnace. In this paper, the thermodynamics and dynamics of desulfurization have been investigated to obtain the main operation parameters related to the mass fraction of sulfur in the hot metal. In addition, statistical analyses have been carried out to study the relationship between operating parameters and sulfur content of COREX hot metal based on actual plant data. It has been found that the mass fraction of sulfur in hot metal is significantly influenced by the C content in hot metal, MgO/Al2O3 in slag, the concentration of MgO in slag, the temperature of hot metal and binary basicity (R2).A linear model has been developed and subsequently used for reducing the mass fraction of sulfur in hot metal, improve the quality of hot metal and contribute to low carbon ironmaking.

Jan 1, 2016

By Sun Ying, Zhang Jing, Li Qiuju

A new process of enrichment Cu in molten copper slag under electric field is presented in this article. The experiments were carried out in the laboratory on a kilogram scale. The mobility of copper slag was improved by the technique of carbon reduction. The effects of temperature, electric field strength and intermittent feeding speed were investigated on Cu migration. The results showed that the best experimental conditions were the temperature at 1523K, electric field strength was 1.5V•cm-1 and feeding rates was 15 g•(10min)-1. The copper content of the slag decreased below 0.6wt%. The process was compared to the traditional electric furnace process of slag cleaning, there was reduced the energy consumption and heat loss, and also harmful gas emissions such as SO2 and CO2, accompanied by improved the efficiency of slag cleaning.

Jan 1, 2016

By Xingye Guo, Yeon-Gil Jung, James Knapp, Zhe Lu, Jing Zhang, Li Li

La2Zr2O7 is a promising thermal barrier coating material due to its low thermal conductivity and superior high temperature stability. In this work, Bilayer La2Zr2O7 and conventional 8 wt% yttria stabilized zirconia (8YSZ) coatings were deposited using plasma spray technique. Both singlelayer La2Zr2O7 and double-layer 8YSZ/La2Zr2O7 coating architectures were designed. Thermal cycling and thermal shock tests were used to evaluate coatings’ thermomechanical properties. All La2Zr2O7 coats were delaminated in the furnace cycle test in less than 20 cycles. This is because residual thermal stresses accumulated during thermal cycling. In the jet engine thermal shock (JETS) tests, the SCL La2Zr2O7 and DCL dense 8YSZ/La2Zr2O7 coatings were fully delaminated. In contrast, the DCL porous 8YSZ/La2Zr2O7 coating sample only partially delaminated on the edge. This is because of the porous 8YSZ layer provides strain compliance. The findings will help to propose efficient thermal barrier coating systems.

Jan 1, 2016

By Peter Sylvén, Darwin Morales

Despite being crucial for the smelting process, furnace tapping using oxygen lances has not been considered an operation that brings value. Therefore, these important tools have not seen a significant change in over 100 years. Problems related to the use of oxygen lances include: • Inaccurate tool: causing damages shortening the life of the taphole refractories. • Safety: extended exposure to the operator in an unsafe area of the furnace. • Cost: high oxygen consumption & high lance consumption. • Time consuming and frustrating to connect one lance to another. This paper will suggest a very good solution; new concept thermal lances. We will show how these provide an outstanding performance for a more efficient, faster and cost-effective furnace tapping operation. These new lances are very accurate tools that enable the operator to perform a more controlled operation; resulting in longer taphole life, fewer repairs and less down-time.

Jan 1, 2016

By Jian-hua Ren, Guang-liang Wu

A lot of dust is produced in iron and steel enterprises, giving rise to serious environment pollution, with which all countries are trying to find methods to deal. The influence of relevant technological factors on dephosphorization was investigated in laboratory, and the effect laws of that were analyzed. The results demonstrate that, in the given conditions of the best slag-metal proportion for hot metal dephosphorization is 1:10, and the optimum temperature is 1350 , The phosphorus distribution ratio of dephosphorization agent containing converter dust of 30% has the maximal value, with dephosphorization rate reaching 85%. Under the optimal conditions, premelting dephosphorization agent can significantly improve the ability of dephosphorization, dephosphorization efficiency increasing to 92%. Therefore, the dust can substitute the oxidant and fixative of dephosphorization agent, be used in hot metal dephosphorization, to enhance the efficiency of utilization.

Jan 1, 2016

By QinGuo, Shenghui Guo, Jinhui Peng, Linqing Dai, Libo Zhang

This paper adopts a simple and novel preparation. Taking cellulose as a template, a tubular morphology structure of micro/nano ZnO crystals was obtained by microwave roasting at high temperature. The higher the microwave roasting temperature, the larger the degree of crystallization. The experiments indicate that the best photo catalytic effect can be obtained at 850 : At this temperature, the oxidation of cellulose is complete. Large quantities of hexagonal shaped ZnO crystal can be observed, specifically the (0001) crystal face. Under ultraviolet-visible irradiation, taking long arc mercury lamp as light source, the material had good photocatalytic activity. The decomposing efficiency of methylene blue reaches 97% in 60min, which is superior to that of preparations without templates at the same temperature.

Jan 1, 2016

By Huimin Lu, Zegao Sun, Zhijiang Gao

The traditional Ti6Al4V alloys were obtained by the smelting reduction of V-Ti bearing beach placer by rotary hearth furnace and aluminothermic reaction in laboratory. First, it gets he lp from combined rotary hearth furnace and grinding magnetic separation process to prepare titanium slag containing vanadium. In this study, a neural network model was used. The comparisons between experiment results and neural network simulation results show that genetic algorithm (GA)-based on back propagation (BP) method can predict the degree of reduction and separation of iron and slag with higher prediction accuracy. Then by aluminothermic reaction process, the optimized process parameters for Ti-V-Al alloys were searched. Al can deoxidize metal V and Ti from the metal oxides of artificial rutile containing vanadium. Finally, traditional Ti6Al4V alloy can be obtained by remelt and adjust the constituents.

Jan 1, 2016

By Bo Liang, Hongmin Zhu, Kai Huang, Shafiq Alam

A new approach of recovering platinum and palladium from electronic wastes by hydrochloric acid leaching followed by selective adsorption on low-cost and environmentally benign biomass sorbent prepared from easily available agriculture waste is suggested. The obtained adsorbents were prepared by a combination of chemical modification and hydrothermal carbonization process with (NH4)2C2O4. It was found that the maximum adsorption capacity of hydrothermal carbonized garlic peel for Pt( ) and Pd( ) was 1.64 and 0.42 mol/kg respectively. The Langmuir adsorption isotherm was applied to describe the adsorption process. Kinetics of the Pt( ) and Pd( ) ions adsorption was found to follow pseudo-second-order rate equation. The adsorbents were examined by scanning electron microscope (SEM), and Fourier transform infrared spectroscopy (FT-IR). Based on the characterization results, a possible mechanism of Pt( ) and Pd( ) ions adsorption with the hydrothermal carbonized garlic peel was proposed. This study provides a promising adsorbent with efficient adsorption property for platinum and palladium recovery from the leach solution of electronic wastes.

Jan 1, 2016

By Mehmet Bu daycı, Onuralp Yücel, Ahmet Turan, Murat Alkan

In this study, iron based alloys (Fe, Fe-Cr-Ni-Mo, etc.) were produced by using metallothermic methods starting from Mill Scales obtained continuous casting processes. During the process, the combustion was realized by ignition and the produced wave propagates throughout the reactant mixture yielding the desired product. In this work, Mill scale used as an iron source, which includes +2, +3 values iron oxides. Aluminum, Magnesium and Silicon were used as reductants. In these metallothermic experiments, different ratios of reductants were examined, and their effects on the metal recovery and alloy compositions were investigated. The samples were characterized by using chemical analysis (AAS), XRD and XRF techniques.

Jan 1, 2016

By M. Wenzel, Dang Thanh Tung, Nguyen Anh Duc, Nguyen Huu Luong, Dang Van Sy, N. Kelly, K. Gloe, K. Kretschmer, Phuc Nguyen Le, K. Schnaars, S. Robles M, L. Götzke, J. J. Weigand

The recovery of rare earth metals from secondary sources has attracted much attention due to their ever expanding demand in the high-tech industry. The studies reported here focus on the hydrometallurgical recovery of lanthanum and cerium from spent fluid catalytic cracking (FCC) catalysts in a two-step process: leaching with nitric acid and solvent extraction by tri-n-butyl phosphate (TBP) and di(2-ethylhexyl)phosphoric acid (D2EHPA). The experiments show a high dissolution yield of about 93% lanthanum and 42% cerium in a single leaching step with 2 M (126 g/L) HNO3 at 80 °C; only 11% aluminum has been dissolved simultaneously. In the subsequent solvent extraction step the best results for this leach liquor could be achieved using a 1:1 mixture of 25% (v/v) TBP (0.92 M) and 25% (v/v) D2EHPA (0.76 M) in n-decane without the need for any pH adjustment. In that case La(III) and Ce(III) can be extracted with 60% and 74% yield respectively in one stage from the majority of accompanying matrix elements. In particular no extraction of Al(III) could be observed under these conditions.

Jan 1, 2016

By Shengqin Zhang, Yousef Mohassab, Feng Chen, Hong Yong Sohn, Mohamed Elzohiery, Amr Abdelghany

A novel ironmaking process is under development at the University of Utah aimed at producing iron directly from iron oxide concentrate in a flash reactor. This process will reduce hazardous emissions and save energy. The kinetics of magnetite reduction with hydrogen was previously investigated in our laboratory in the temperature range 1150 to 1400 oC at large temperature increments (~100 oC increments). Due to the significant melting that occurs above 1350 oC, the reduction kinetics was measured and analyzed in two distinct temperature ranges of 1150 to 1350 oC and 1350 to 1600 oC (~50 oC increments). Experiments were performed using magnetite concentrate particles of different sizes under various hydrogen partial pressures and residence times. Reduction degrees of more than 90 % were achieved in a few seconds at temperatures as low as 1250 ºC. Different rate expressions were needed to obtain reliable agreement with experimental data.

Jan 1, 2016

By Qiang Zhong, Bin Xu, Qian Li, Wei Gao, Yongbin Yang, Yaxuan Wang

Lump coal with high volatility is used for providing heat and reductive gas, and ensuring permeability in COREX. However, it is apt to be pulverized in transport and storage process. Therefore, comprehensive utilization of the pulverized coal to produce coal briquettes with appropriate binders is significant, among which the molasses binder cannot meet the technological requirements. In this paper, coal tar pitch binder and BJ additive were used in briquetting and carbonizing process of coal powder. The results showed that BJ effectively activated cold state cohesiveness of the pitch and make it bond the coke particles to a firm briquette at room temperature .Carbonizations of coal and coal tar pitch achieved obvious constriction and formed a carbonized skeleton. The drop resistance of wet briquettes reached over 50 times/1meter. When cured at 1000 °C for 1h under nitrogen atmosphere, the compressive strength of carbonized briquettes came to 6.43 Mpa.

Jan 1, 2016