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By J. Bouchard, A. Clapperton, L. Ebacher, N. Singh

"Canadian Royalties Inc. owns and exploits the Nunavik Nickel project: a copper and nickel deposit in Nunavik, Quebec. Froth flotation is used to produce nickel and copper concentrates. As is the case at other operations, the presence of magnesium is detrimental to the flotation products. In the past year, the exploitation of a new deposit has increased magnesium in the feed. Thus, it has been challenging to meet the required ratio in the final nickel concentrate. In search for a consistent solution for this problematic, an empirical flotation simulator making use of selectivity curves was developed. The circuit was expressed as a system of linear equations, which considered the distribution of copper, nickel and gangue minerals in the different streams. The relative quantities of each mineral are given by the separation efficiency curves of the various banks in the circuit. Three sources of data were used to calibrate the simulator: historical plant data (metallurgical balance), infinite dilution bench-scale flotation tests, and direct sampling of flotation cells. The calibrated separation curves were used to predict the recovery of the different species based on a single mineral recovery. Validation of the simulator showed good fit for the valuable minerals. The simulator was then used to infer the optimal operating conditions of the flotation circuit to optimise magnesium oxide content of the nickel concentrate. Simulation of two re-arrangements of the circuit gave a promising solution with a Fe:MgO ratio 2.42 times higher than the minimum value.INTRODUCTION Canadian Royalties Inc. owns and exploits the Nunavik Nickel project: a copper and nickel deposit in Nunavik, Quebec. Figure 1 shows the location of the mine site. After crushing and grinding, froth flotation is used to produce nickel and copper concentrates. The flotation circuit is designed with multiple stages consisting of bulk copper/nickel flotation, copper/nickel separation, and a separate nickel circuit (bulk float and cleaning)."

Jan 1, 2018

By M. Kadiyski, V. Stoyanova, E. Visariev, V. Stoilov

"The present study deals with copper losses in slag from copper smelting. Copper slag cooling at Aurubis Bulgaria is traditionally done in pits. A new type of slag-cooling is introduced in the site, involving cooling ladles. In a previous study, the ladle cooling process was studied in detail, showing an improvement in the recovery of copper in the slag after flotation. The main reason for better recovery of copper is the increased cooling time, which allows for the accumulation and aggregation of copper droplets. The effects of the newly introduced slag cooling process are studied using optical microscopy and scanning electron microscopy. Cooling in pits and in ladles is compared, based on copper droplet size, distribution and content. Specialized image processing software is employed on images taken with an optical microscope. The results are then compared with a similar technique, available in SEM software. The availability of phase-analysing image software in combination with electron dispersive X-ray spectroscopy makes it possible to study the morphological properties, distribution and chemical composition of the copper droplets. The obtained results confirm the initial conclusions about size, distribution and composition of the copper-bearing particles. A large amount of copper particles is examined showing an obvious increase in their size from pit- to ladle cooling. The results show an increase in the average size of the droplets, which doubles from pit-cooling to ladle-cooling. There is a well-pronounced tendency of decrease of the percentage of droplets in the smallest fraction (<5 µm) in the ladle-cooled slag. In addition, the number of droplets in the larger fractions increases, compared to the ones in the pit-cooled slags. It is believed, that the developed methodology for analysis provides a relatively quick and reliable solution for comparison of the cooling rates in the slag. INTRODUCTION In the process of copper smelting and converting, iron-silicate slags are produced that contain various amounts of dissolved and entrained copper. Different physical and chemical techniques are employed for the valorisation of the remaining metals in the slag – magnetic separation, leaching, roasting, flotation, etc. According to Gorai et al (2003), about 2.2 tons of slag is produced per ton of metal. In 2016, about 20 million tons of copper have been produced globally (www.icsg.org). At an average of 0.5 percent copper content after treatment, these slags contain more than two hundred thousand tons of copper which is lost due to inefficient processing."

Jan 1, 2018

By T. McCallum, C. Cooper, C. Lewis

"Following a successful solvent extraction (SX) pilot plant demonstration in 2016, CYANEX® 600 has been used commercially to recover molybdenum from concentrate leach liquor since March 2017. Consistent with the piloting results, the commercial plant has achieved expected molybdenum recovery, a significant reduction in base consumption, and a step-change improvement in physical performance. This paper highlights the optimization activities and plant performance from startup through normal operation. INTRODUCTION Historically, tertiary amines have been the most commonly used extractant for molybdenum and rhenium recovery. Tertiary amines utilize a protonation of the ligand combined with an anion exchange mechanism as proposed in equations (1-2). R3N + H+ ???R3NH + (1) 4R3NH+ + Mo8O264- ???(R3NH+)4Mo8O264- (2) In addition to the transfer of Mo and Re, the amine transfers acid and other anions to the strip liquor. The undesirable transfer of other species increases base consumption during stripping, impacting operating costs. Additionally, lower solubility of molybdenum-amine complexes create operational challenges, resulting in diminished physical performance. The presence of colloidal Si in concentrate leach liquors and the formation of Pickering Emulsions adds to the physical plant performance challenges with the amine extractant. CYANEX® 600, a phosphinic acid-based extractant, uses a cation exchange mechanism proposed by equation (3). 2(H2R2) + MoO22+ ??(HR2)2MoO2 + 2H+ (3) The cationic exchange mechanism eliminates chemical transfer of acid and other anionic impurities and avoids some of the physical challenges of the amine extractant (emulsion and 3rd phase formation). In addition, the reagent offers high selectivity for Mo over Re, which may be desirable in certain moly pressure oxidation (POX) flowsheets. Alkali base (ammonium hydroxide, sodium hydroxide, sodium carbonate, etc.) is used for molybdenum stripping. Therefore, reduction or elimination of chemical acid transfer from extract can significantly reduce base consumption in strip. Extensive laboratory and pilot plant testing was completed to evaluate the use of CYANEX® 600 for molybdenum recovery at Freeport-McMoRan’s Bagdad operation. The test work and pilot demonstration confirmed a reduction in base consumption along with improved selectivity. In addition, the evaluation highlighted a step-change improvement in physical performance over the incumbent amine extractant. The decision was made to convert the commercial operation to CYANEX® 600 in March 2017."

Jan 1, 2018

By K. V. Raj, A. Miller

"Workers at mineral processing facilities are often exposed to high levels of dust generated when ores are processed. Crushing, grinding, screening, and other processes generate large quantities of dust, which can exceed the threshold VALUES (prescribed by the Mine Safety and Health Administration (MSHA). Many ores contain quartz (silica), which has been known to cause serious health problems in workers over time. Given the structure of mineral processing plants, the airflow regime is not coherent inside the building, which may lead to multiple recirculation zones. These recirculation zones can trap dust, and concentrations of dust can then rise over time. Therefore, there is a need to understand the airflow phenomenon that occur inside of mineral processing facilities and how these occurrences interact with the dust generation processes to identify zones of potentially high dust concentration. Computational fluid dynamics (CFD) modeling can give a better understanding of the airflow and help recommend designs and methods to mitigate the high dust concentrations in a mineral processing plant. This paper presents the CFD modeling of airflow inside of a mill building to demonstrate airflow patterns that will affect the generation and subsequent dispersion of dust due to crushing, grinding, and other activities. This study was conducted by researchers from the National Institute for Occupational Safety and Health (NIOSH). INTRODUCTION In a mineral processing facility, minerals go through various mechanical processes in order to reduce their size for separation of economic minerals from gangue minerals to produce a final marketable product. This research, conducted by the National Institute for Occupational Safety and Health (NIOSH), focuses on ore mills in metal and nonmetal mining (MNM) operations, but the applicability of the approach will be valid for any large structure where workers are exposed to airborne contaminants. The processes of crushing, grinding, cleaning, drying, and product sizing in these facilities generate a large amount of dust, creating hazardous conditions for the workers in these facilities. This is highlighted by the fact that MSHA sampling data for the years 1997–2012 indicate that 12.3% and 15.9% of the gathered samples were over 100 µg/m3 for silica for metal and nonmetal mills, respectively [1]. Mineral processing operations typically use some type of engineering control to address their most significant dust sources. Engineering controls include such approaches as bag-house-type dust collectors, scrubbers, and electrostatic precipitation [2]."

Jan 1, 2018

By S. Sheng, Y. G. Huang, W. Chai

"Polyacrylamide (PAM) is a typically synthetic depressant and may be used as a depressor of pyrite. The modification of polyacrylamide may improve its physicochemical properties and performances. Sulfonated polyacrylamides (SPAM) with different sulfonation degree (SD) were prepared using sodium sulfite as the sulfonating agent, and the interactions of SPAM and pyrite were investigated by the adsorption experiment in this work. The adsorption tests of SPAM on pyrite were conducted as a function of sulfonation degree, pH value and contact time. Pyrite and SPAM were constructed and optimized through MS software. The interaction mechanisms of sulfonated polyacrylamide and pyrite were simulated by molecular dynamics simulations. The results show that the adsorption capacities of SPAM at neutral and weak alkaline conditions are higher than that at acidic and strong basic conditions. The high sulfonation degree favors the adsorption of SPAM on pyrite surface. The adsorption process can be described best by the pseudo-second order kinetic model. Molecular dynamics simulations show that the adsorption of sulfonated polyacrylamide on pyrite is better than that of polyacrylamide. Sulfonated polyacrylamide can be used as a potential depressant of pyrite with the main interacting mechanism of hydrogenbond force.INTRODUCTIONPyrite is the most abundant sulfide mineral and often associated with valuable minerals such as galena, chalcopyrite, sphalerite, molybdenite, gold, diaspore as well as coal (Forrest et al., 2001; Jaiswal et al., 2015; Maier and Dobiáš, 1997; Qiu et al., 2017; Xin and Liye, 2010). Froth flotation is the most popular method to remove pyrite from valuable minerals. Pyrite could be floated as the flotation concentrate either by its hydrophobicity or activation by metal ions (Chandra and Gerson, 2009). What is more, pyrite could be seperated as flotation tailing by adding highly selective depressants including inorganic and organic modifiers. Polysaccharides polymers and lignosulfonate-based biopolymers are common natural organic depressants (Deng et al., 2017; Mu et al., 2016). While the synthetic organic products have proved to be particularly versatile in terms of molecule tailing capability and controlled structures (Boulton et al., 2001a; Raffa et al., 2015)."

Jan 1, 2018

By S. Rupprecht

"INTRODUCTION This paper addresses the prevalence of poor public reporting practices of Coal Exploration Results, Coal Resources and Coal Reserves in southern Africa. Currently, the reporting of coal tonnage without supporting coal qualities or “saleable” tonnes and quality is a poor reporting practice that occurs far too often. Not all coal is equal – therefore it is extremely important that investors or potential investors are provided with the full details of both run-of-mine (“ROM”) and Saleable coal tonnage, their associated qualities and other material and relevant information. Competent or Qualified Persons should note that publicly reported information should be sufficient to enable an informed reader to make a reasonable and balanced assessment of the significance of the information provide. “Companies are encouraged to provide information in their Public Reports, which is as comprehensive as possible” (CRIRSCO, 2013): too often this isn’t the case and material matters are either not reported or inadequately disclosed. According to the South African National Standard (SANS) 10320:2014 draft document - “tonnage and coal quality that will be available for sale, either in the raw ROM state (raw Saleable) at a specified moisture content, or after beneficiation of the ROM coal by processing operations to produce materials at specified qualities, size ranges and moisture contents. The assessments must demonstrate that at the time of reporting, the marketing of the products is reasonably justified. The basis of the predicted practical product yield to achieve the Saleable Coal Reserve must be stated. The moisture basis of reporting shall be stated.” As an example to why coal qualities are so important to the public, the requirements of South Africa’s electric public utility (Eskom) power stations are highlighted. The Kendal power station, commissioned in 1988, operates at a Calorific Value (“CV”) range of 19 to 20MJ/kg, an Ash content between 29 and 34% and Volatiles between 20 to 21%. Other power stations, such as Kriel or Hendrina, may require different qualities such as a CV range of 22 to 23MJ/kg, an Ash content between 20 and 28% and Volatiles between 22 to 23%. Thus, in terms of domestic saleable coal, it isn’t just about reporting the coal qualities but also informing the investor as to which power station the coal is intended to be sold as “boilers are designed to burn particular qualities of coal” and “it is not always possible to transfer coal between stations because of different quality requirements at each station” (Chetty, 2010). Sulphur content is also another important quality with the ideal coal content having a quality of less than 1% Sulphur."

Jan 1, 2018

"The JKMRC researchers have been redeveloping the suite of breakage testing techniques to more realistically align with the breakage environment in comminution equipment. Computational modelling, especially with the DEM, has highlighted the modes of impact and contact, along with the energies of these interactions in a wide range of equipment. This has driven the need to match these modes in laboratory ore characterisation tests. The objective has been to build a continuum of breakage tests and associated models that span the required range of breakage forces and environments. The ore sample is subjected to a sequence of tests covering: abrasion (surface breakage) of angular through to smoothed particles; single particle impact from high energy single impact breakage down to low energy; incremental breakage covering 60 mm down to 50 µm particles; particle strength distribution; and bed breakage over a range of compression and energy input. These tests are suited to multi-component ores with a distribution of strengths. A modelling technique is also being developed to utilise primary breakage for modelling breakage under different types of confinement. This paper draws together these techniques, previously published by the authors, into a coherent whole. The suite of tests is approaching the point where a fixed set of tests can be used to model the performance of a full range of equipment, removing the need to conduct repeat ore characterisation tests for each different piece of equipment incorporated in a circuit design. This path should open up the application of different circuit configurations and novel equipment in comminution circuit design.1 INTRODUCTION Comminution modelling utilizes a wide range of ore characterisation techniques and methods to deal with the range of comminution equipment available for production use. In general, the tests have been designed to correlate with specific pieces of equipment, using calibration factors to provide the link between the small-scale test and industrial-scale performance. The majority of tests focus on estimating the power requirement of process equipment to achieve a desired throughput and grind size. Overall, this approach has achieved acceptable outcomes in the past, but the reality is that equipment sizing suffers from considerable uncertainty, in excess of ±20% is not uncommon. This uncertainty is covered by safety margins and automatic scaling factors in equipment selection. In striving to improve reliability, the industry tends to add more adjustment factors to the tests, and design margin rather than question the basic validity of the testing process. As the tests are often correlated to production equipment via carefully guarded databases, they are also locked into historic operating inefficiency, not providing direction or revealing opportunities to improve production efficiency in comminution equipment or circuits. Safe in the knowledge that they are achieving the expected production based on test work predictions, a site is unlikely to set their sights on reducing specific energy consumption by 10%."

Jan 1, 2018

By D. Marcotte, R. V. Dutaut

"In mineral resource evaluations, geostatistical methods known as global change of support allow prediction of the theoretical histogram and gradetonnage curves prior to interpolations or simulations of grades. Two methods commonly used by professionals to guide the choice of interpolation parameters and assess results are the discrete Gaussian model (DGM) and the indirect lognormal correction (IndLog). These models rely upon an estimate of the dispersion variance of the blocks, which is derived by numerical integration of the variogram model over a discretized block. Due to difficulties in obtaining well-formed traditional experimental variograms (especially in the presence of outliers and limited clustered data), many professionals prefer to use ‘normalized’ variograms such as correlogram (non-ergodic variogram), pairwise-relative, or variogram of the normal score transform. A series of simulations with different grade distributions and variogram models are used to assess the performances and robustness of the various variogram estimators with respect to the DGM and IndLog global change of support. Our results show that the traditional variogram, the correlogram, and normal score variogram have better performances, compared to pairwise, for both DGM and IndLog. Moreover, DGM provided better results than IndLog for the grade distributions that are not strictly lognormal. These findings provide valuable guides for geostatistics practitioners. IntroductionWhen reporting resource estimates,practitioners are required to follow generalstandards described in the NI43-101 (CIMguidelines), JORC, or SAMREC codes. One cangenerally recognize three main parts directlyrelated to the block model:•,Pre-processing: exploratory data analysis (EDA), domaining, capping, compositing, declustering, variography•,Processing: block size, neighbourhood, interpolation types (linear or nonlinear)•,Post-processing: classification, reporting.Pre-processing aims to simplify and strengthen the processing step. Ideally, domaining, capping. and compositing is aimed at defining a single homogenous population. During the processing phase, a common practice is to use a block size corresponding to the planned selective mining unit (SMU). In most precious metal deposits (gold, notably), the SMU size is frequently smaller than the recommended half data spacing (Journel and Huijbregts 1978), resulting in high estimation variance and either a high degree of smoothing if the regression slope is managed or a high degree of conditional bias if it is not. Most actual resource estimates are made using block sizes between one-quarter to one-sixth of the average data spacing, sometimes even smaller. In addition to the block size, the interpolation choices for the neighbourhood selection and interpolator (e.g. inverse distance (ID) or ordinary kriging) are often based on the Qualified Person’s (the QP) experience and some basic validation plots that often do not consider the conditional bias (e.g. trends or SWATHs plots, which are designed to compare two sets of population using a one-dimensional graph)."

Jan 1, 2018

By Y. Y. Li, Q. Chen, Y. X. Cai, Q. Zhang, S. Mao

"Due to the influence of combustion conditions, the fly ash produced by some power plants has the problem of high-carbon content. The unburned carbon in fly ash can be removed by flotation, and the decarbon tailings should reach the national standard level I fly ash. The fineness of the requirement is one of the important indicators and is also an important factor affecting the tail ash activity. In this paper,adopting two methods investigate the effect of particle size on the flotation index: one is direct flotation of fly ash, and the other way is wet grinding + flotation of fly ash, comparing the two methods and selecting the appropriate process,which provides a way for the effective utilization of fly ash. INTRODUCTION Fly ash is a solid waste discharged from coal-fired power plants. The annual amount of emissions of fly ash are very large in China. The amount of fly ash were discharged from coal-fired power plants are increasing gradually, and the amount of fly ash stored has exceeded 2.5 billion tons, but the comprehensive utilization of fly ash is not high, which brings about a huge environmental problems( Lu et al.,2011). Carbon is a harmful component of fly ash in cement and concrete application (Zhang et al.,2008). Fly ash decarburization is an essential link to improve the utilization efficiency of fly ash and the reduce pollution ( Yang et al.,2012). Carbon is selected from fly ash to make full use of fly ash resources and improve utilization of fly ash (Li et al.,2008). In this paper, the flotation decarburization of high-carbon fly ash is studied, through comparing the grinding and not-grinding processes, optimizing the separation process of fly ash, which provides a way for the effective utilization of fly ash."

Jan 1, 2018

By G. Weingrill, H. Flachberger, J. Neubacher

The so called Bublon®-process is an innovative process for the controlled expansion of volcanic glasses such as Perlite and for thermal treatment of other minerals. In this manner, functional light fillers with astonishingly altered physical properties can be manufactured. In contrast to conventional Perlite expanding processes no fossil fuels are burned in order to achieve the expansion. Instead, the feed material is heated electrically mainly by radiation based on heat transfer from heating elements. The main advantage is the better controllability of the production process. Therefore, the heating elements are segmented along the flow of the particles, hence in direction of the ongoing expansion. Overheating of the particles, which ultimately leads to the destruction of the particle surfaces and consequently decreasing the quality of the expansion product, can be reduced significantly. Due to flow characteristics and settling behaviors of fines the lower particle size limit of the feed in this process is restricted to not less than 100 µm. Otherwise process instabilities are to be expected. Manufacturing industry demands light and fine hollow microspheres. Therefore, a proven cooperation between Montanuniversität Leoben and Bublon GmbH was formed to develop a new process called ‘Bublite’. This issue was addressed by changing the conveying principle into a pneumatically conveying system transporting particles from the bottom to the top of the kiln by the means of a drag flow. This approach makes it possible to handle the difficult flow patterns in the kiln and to control the retention time of the particles in the heat transfer zone. As a result, it is now possible to expand very fine Perlite particles into a high quality functional lightweight filler with a glazed-closed surface. The dependence of the polymer industry on importing this kind of fillers from overseas can be reduced by producing it close to sites of demand. Also the Perlite mining and processing companies benefit from this technology because the mine lifespan and the output of the processing plant can be increased.

Jan 1, 2018

By Ron J. Elliott, Dylan Wedgewood

A series of five signature holes were blasted at the Highvale Mine and the resultant seismic data was analyzed to make recommendations on how best to address neighbour complaints regarding blast vibrations. From an analysis of peak vibration levels measured at the closest neighbour for blasting during 2016, it was determined that the blast vibration intensity varied between 1.4 to 4.3 mm/sec (0.06-0.17 ins./sec.), well below the level of concern for the onset of minor damage to residential structures, however, the frequency of the blast vibrations was between 2.2 and 9.7 Hz, which is within the range of the natural resonant frequency for a single story home. This was determined to be the cause of the neighbour complaints, as the home would be responding to the blast vibrations.

Jan 1, 2018

By Thi Hien Tran, Ngoc Anh Tran, Thi Thu Hien-Dinh, Duy Anh Dao

"Natural graphite exists mainly in three types of amorphous graphite, flakes graphite and lump graphite. Graphite from Bao Ha mine, Lao Cai province is with 11.8 carbon-graphite %, forms in flakes and dense crystals. The paper presents the comparison among enrichment of Bao Ha’s graphite by two types of froth flotation with 90 g/t kerosene oil as collector, 50 g/t montanol 800 as frother, in natural pH, and at 20 wt.% of solid. The differences among three flow charts indicated that using middling flotation and re-middling flotation for the cleaning tails and the scavenger concentrates, the final concentrate was improved and containing up to 94 carbon-graphite % of flakes graphite, up to 82 carbon-graphite % of fine graphite with 93.48 % total recovery, moreover, carbon-graphite in the final tail is 0.86 % with 6.52 % recovery. However, a refining mill and a classification stage were applied before doing the middling flotation stages.1. INTRODUCTIONGraphite (black lead or plumbago) is used in many industrial applications due to its high electrical and thermal conductivity, lubricity, and chemical inertness. High quality graphite can be used in metallurgy, molding, brake linings, batteries, and fuel cells. Graphite, composed exclusively of the element Carbon, is rather common mineral, but fine crystals are rare. Graphite is soft (hardness: 0.5-1 Mohs scale); has a layered, planar structure; occurs in platy or acicular (occasionally) morphology (Minerals.net; Pierson, 1993).USGS (2017) reported, global consumption of natural graphite continuing increase in the period of 2012-2016. In 2016, China used up 35% while produced 66% of the world’s graphite. Graphite mining are being developed in Madagascar, Mozambique, Namibia and Tanzania, but production reduced in Canada from 2015. Based on the statistic of Statista.com shows from 2011 to 2014 and a forecast to 2020, the global graphite demand is mostly in refractories, batteries, others, lubricant/crucible, foundry and pencil, and that is increase every year.Graphite Vietnam lies on the fault of the Red river from Yen Bai to Lao Cai, the reserves is estimated around 29.3 million ton and mostly in Lao Cai province where has Nam Thi graphite mine and Bao Ha graphite mine (MOIT, 2008). Vietnamese graphite products could reached to ~92% graphite carbon (Cg) (Tran Thi Hien et al., 2008). Studied samples was collected in Bao Ha graphite mine, is located in Lao Cai province. Graphite Bao Ha exists in two types as graphite flakes and amorphous (Hoang Thi Minh Thao et al., 2017)."

Jan 1, 2018

By F. A. V. Guimarães, A. M. Costa

"The moisture in sintering is a very important parameter for the performance of the process. It allows that the granulation takes pace in an efficient way making the water bridges between the bigger particles used as nucleus and the finer particles that perform the coating of those coarse particles. The formation of the micro pellets is extremely important to prevent loss in permeability of the bed in the sintering grate, avoiding excessive fuel consumption and producing a quality sinter. The aim of this project is to use some of the methodologies for determine the saturation degree on ores and coal to determine the optimal moisture for sintering. In the sinter pot grate series, 3 to 4 assays in a series of 10 are required to determine the optimal moisture for the process. The saturation degree curve test has shown that is really viable to use this technique to skip those tests and go directly to the series to determine productivity and the coke / anthracite consumption. In an industrial scale can be used to adjust the water addition in the conventional mixing methods used in the sintering plants to increase productivity in the process.INTRODUCTION Sintering Sintering is a high temperature agglomeration process in which iron ore fines are partially melted and bonded together using fluxes and a source of fuel, usually coke breeze. The agglomerated product, sinter, has improved metallurgical properties making it an ideal ferrous burden that enable the passage of hot gases in the iron-making blast furnace. The sintering process is normally carried out over three basic stages: granulation, ignition/sintering, and product sizing. In the granulation stage, iron ore fines (usually a blend of selected ores), sinter return fines, fluxes and fuel, and are mixed with water and micro-pelletised in a drum or disc before being introduced in the main granulation circuit. (Wang, Teng, & Wang, 2017)."

Jan 1, 2018

By L. O. Filipov, N. E. Menad, A. Geneyton

"Zeta potential of synthetic monazites presenting various compositions were measured to investigate the effect of the main lanthanides substitutions on electrophoretic mobility and resulting IEP. The measurements are performed in a CO2 depleted and enriched solutions showing both reduced influence of monazite chemistry and strong influence of ions resulting from the solubilization and dissociation of CO2. The influence of oleic acid on the electrophoretic mobility of those monazites was also investigated. The influence of pH on oleate adsorption was studied using a bubble/particle adhesion system. Adhesion strength measurements were performed on pure synthetic monazite-(Ce) and monazite-(La). An extensive thermodynamic model of monazite in water was developed to highlight correlations between lanthanides hydroxides/carbonates species concentrations in the bulk solution and oleate adsorption. Based on electrophoretic measurements, advanced thermodynamic consideration and adhesion measurements, further details of the oleate adsorption model on monazite surface were proposed.INTRODUCTION Electrophoretic and potentiometric data on monazite and, a fortiori, other rare earth semi-soluble salts such as bastnaesite are extremely erratic (Chelgani et al. 2015). The isoelectric points measured with electrophoretic mobility methods range from 4.7 to 6.5 although sporadic data indicates an IEP (isoelectric point) far from that range. Different explanations are proposed in the literature to explain the IEP variability notably the numerous chemical substitutions that frequently occurred within monazite crystal lattice (Chelgani et al. 2015). Based on lanthanides speciation diagram, several authors highlighted the influence of specific lanthanide species on the flotation performance of rare earth semi-soluble salts when carboxylate or hydroxamate collectors are used. Although lanthanides ions have a great affinity for carbonates groups (Kragten et Decnop-Weever 1987), lanthanide (hydrogen) carbonates were not implemented in speciation diagrams. In this work, an advanced thermodynamic model is proposed to highlight correlation between flotation performance and lanthanide species predominance but also concentrations. Qualitative measurement of the monazite surface hydrophobicity are performed through tests of adhesion of coarse monazite particles onto bubbles. Since flotation and microflotation technics are highly influenced by hydrodynamic parameters, this method was investigated to obtain a sharp contrast between appropriate and inappropriate pH conditions. This paper is to investigate 1) the effect of lanthanides substitution on monazite surface properties through zeta potential measurements, 2) the mechanism of adsorption of carboxylates on monazite surfaces and 3) the effect of CO2 on monazite surface properties and carboxylates adsorption."

Jan 1, 2018

By G. B. Abaka-Wood

"The versatility of froth flotation has made it vital in the beneficiation of rare earth elements (REE) minerals from either high or low grade ores of complex mineralogy. There has been a significant increase in the tonnage of rich iron oxide tailings obtained from extraction of primary commodities such as copper and gold in Australia, which have been identified to have very low grade rare earth oxides (REO) (= 1%). There is a vast knowledge gap in the upgrade of REO from such tailings. The aim of this research is to investigate the feasibility of the use of fatty acids for the upgrading of REO from selected iron-oxide rich tailings. Two forms of fatty acid collectors (oleic acid and sodium oleate) were employed in this investigation. Bench scale flotation tests were carried out using a Denver D-12 cell.The effects of pulp pH, fatty acid dosage, particle size distribution (-150 +75 µm, -75 +38 µm and -38 µm) and conventional depressants (sodium silicate and starch) dosage on flotation recovery of REO were investigated. A comparison of the flotation results indicated that sodium oleate was the more efficient fatty acid for REO flotation at all the pulp pH investigated. The flotation performance is demonstrated to be particle size-dependent. The results on the effect of depressants dosage indicated that both sodium silicate and starch were unselective in reducing the recovery of hematite (Fe2O3) and quartz (SiO2) with corresponding decrease in REO recovery. Generally, Fe2O3 and SiO2 formed substantial contents of the flotation concentrates obtained, both in the absence and presence of depressants, which indicates liberation is a major challenge in achieving selective REO upgrade and recovery.The flotation tests carried out on the iron-oxide rich tailings suggest the possibility of REO upgrade using fatty acids, although particle size distribution and minerals liberation are key limiting factors in achieving selective REO upgrade and recovery."

Jan 1, 2018

By T. R. Kostecki

"Instrumented rock bolts are effective tools for assessing the reinforcement and condition of immediate roofs; however, instrumentation can have relatively high costs, which can be justified by high reliability and repeatable and representative data measurements. The instrument’s durability and operational life are of great importance, along with accuracy, applicability, and usefulness. This paper develops reliability models for three instrumentation technologies used in slotted rebar, drawing data from studies at five underground coal mines. Three case studies demonstrate instrument applicability and usefulness. Finally, two types of instrumented rock bolts are used to determine the direction of bend and maximum bending strain. RÉSUMÉ Les boulons d’ancrage instrumentés sont des outils performants qui permettent d’évaluer la consolidation et la condition des toits immédiats. L’instrumentation peut cependant se révéler très onéreuse, des coûts qui se justifient par sa fiabilité élevée ainsi que par des mesures de données reproductibles et représentatives. La durabilité de l’instrument et sa durée de vie opérationnelle sont très importantes, de même que son exactitude, son applicabilité et son utilité. En s’appuyant sur des données issues d’études menées dans cinq mines de charbon souterraines, cet article développe des modèles de fiabilité pour trois technologies d’instrumentation utilisées pour des barres d’armature nervurées. Trois études de cas démontrent l’applicabilité de l’instrument et son utilité. Enfin, deux types de boulons d’ancrage instrumentés sont utilisés pour déterminer la direction de la flexion et la contrainte de flexion maximale.INTRODUCTION Using instrumented rock bolts to monitor strain changes in a rock bolt array allows engineers to understand the per-formance and effectiveness of the rock reinforcement system and the response of the rock mass to such support; however, instrumentation remains a niche solution for solving complex ground-control problems—particularly for underground coal mines, which is where they are needed most. From 2000 to 2016, fall-of-ground fatalities still accounted for an average of approximately 30% of the total annual underground coal mine fatalities in the United States alone (United States Department of Labor, 2018). These tools would also be useful for deep hard-rock mining conditions. The main reasons for the lack of widespread use are not only cost but also accuracy, applicability, implementation procedures, intrinsic permissibility, and reliability (Peng, 2015). As a result, measurements of coal mine roof behaviour using instrumented rock bolts are quite scarce, not widely published, or inadequately presented to provide a seamless understanding of a roof’s response to support."

Jan 1, 2018

By A. Ockewitz, A. Trondl, D. -Z. Sun

"Numerical simulation of extrusion processes offers an efficient method for tool design and optimization of geometries and properties of extruded parts. However, until now there are few systematic investigations about influences of material model and different parameters e.g. for friction and thermal processes on calculated local and global responses. Since extrusion processes are essentially influenced by friction between billet and extrusion tools, new friction tests were performed in this work to develop a reliable friction model. Compression and torsion tests were performed at different temperatures and velocities to calibrate the material model for extrusion simulations. Extrusion processes for circular rods and U-profiles were conducted at TU Berlin with backward and forward extrusion for different extrusion ratios, billet temperatures, product velocities and cooling conditions. This work focuses on numerical simulations of the extrusion tests with the FE code HyperXtrude. Based on the calculated distributions of local strain, strain rate and temperature the recrystallized volume fraction and grain sizes were calculated with empirical models and compared with the experimental results from optical micrographs and EBSD scans. The calculated total and friction forces and temperatures were compared with the experimental results and the deviations between experiment and simulation were analyzed.INTRODUCTION Extruded aluminum components are widely used in vehicle constructions due to light weight and manufacturing consideration. Local mechanical properties in the components are inhomogeneous as a consequence of the spatial distribution of microstructure which is influenced by numerous factors like material composition, temperature, tool design, friction, extrusion ratio and speed during the extrusion process. For the optimization of the extrusion process with regard to all these factors numerical simulation can be an essential tool. Based on results of finite element simulations of the extrusion process the microstructure in the extruded components can be predicted and then the resulting mechanical properties can be numerically determined instead of by costly trial and error methods. The aim of the work presented in this paper is the development of a numerical method for the simulation of extrusion processes with modeling of microstructure."

Jan 1, 2018

By Wayne Rogers, Kell Monro, Arthur Pacunana

The Phu Kham Copper-Gold Operation (PKM) is a large-scale open pit mine located in northern Laos. It was developed and is operated by Phu Bia Mining Limited (PBM) a Lao-registered subsidiary company of Australian incorporated, PanAust Limited. Production commenced at Phu Kham in 2008. Since the second half of 2016, there has been a significant increase in ore hardness and this has negatively impacted the PKM concentrator and resulted in lower SAG mill throughput rates. Over the remaining life of mine, the changing ore body and increase in ore hardness is forecast to continue as the pit deepens and the availability of softer blending ores reduce. To manage this risk, PKM initiated a Hard Ores Management Program to determine the most effective way to improve the mill throughput of harder ores. This involved conducting a number of innovative and process control driven blasting trials to optimize run-of-mine (ROM) fragmentation and other blasting outcomes. From 2016 to 2017, the performance of high powder factor blasting, electronic detonators and fast timing, high velocity of detonation (VOD) explosives, double-priming, and deck blasting, were individually and systematically assessed. The success of each blasting trial was then based on a ‘value for money’ criteria. This criteria is a cost / benefit analysis that weighed-up the additional cost to implement the trial against the measured improvement in mill throughput. Electronic and high VOD 90:10 emulsion:ANFO blasts were determined to have the best value for money, achieving an increase in mill throughput of 54% compared to baseline. This paper discusses how the implementation of an innovative and process control driven blasting trial methodology was able to successfully manage the hard ore challenges at PKM. In addition, this success was achieved without any major cost implications, safety incidents or process plant set-backs.

Jan 1, 2018

By S. Cagirici, Z. Öztürk, A. Hassanzadeh

Many flotation kinetics models have been studied in the literature. Their applicability was extensively investigated and argued in detail. However, model selection criteria were not adequately discussed from the statistical points of view. In this investigation, the kinetic behavior of a complex copper sulfide ore was studied in a mechanical Denver flotation cell focusing on flotation kinetics of chalcopyrite, pyrite and molybdenite. Different flotation kinetics models including nine common empirical models and four mathematical models namely Hill, Chapman (Sigmodial function), single rectangular (Hyperbola equation) and exponential were applied to the experimental data. In addition to assessment of the goodness of fit criterion for each model, a factor of model complexity was considered using information criteria (IC) (i.e. Bayesian information (BIC), low of iterated logarithm (LILC) and Akaike information (AIC) indices). The obtained results showed that the IC indices could simply manifest the best-fitted model to the experimental data. Whereas, the coefficient of determination values (R2) were relatively same for all models. By taking the R2 and model complexity criteria into account, the exponential model was chosen as the best representative mathematical model to demonstrate chalcopyrite kinetic behavior. However, Chapman model was selected as the best one for the flotation of pyrite and molybdenite. In case of the common first-order flotation kinetics models, fast and slow flotation kinetic model (Kelsall) was reasonably fitted the best to the given data of chalcopyrite. However, the gas/solid kinetics adsorption model was chosen as the best-fitted one for pyrite and molybdenite. Furthermore, it was found that mathematical models represent better results in association with flotation kinetic behavior of chalcopyrite, pyrite and molybdenite due to the consideration of more parameters in modeling. Finally, it was concluded that the IC indices must be applied to the process of model selection due to consideration of goodness of fit, complexity of a model and model consistency.

Jan 1, 2018

By R. J. Sheets

"INTRODUCTION What is the primary responsibility for geo-engineers in mining? Early in my career, I was asked this question by an experienced engineer. After explaining some various tasks, I was informed that the main responsibility was to monitor. Although this proved true for many cases, I came to understand that monitoring is merely one means to achieve the primary responsibility of a geo-engineer – ensure the safety of all personnel. The potential for groundwater to impact stability allows this responsibility to be shared with hydrogeologists as well. Inherently, we monitor to identify risks; we analyze designs and develop models to mitigate risks; and we are provided opportunities to explain to supervisors the geo-risks to personnel and mine plans that will result from particular courses of action. A couple years ago, I took an opportunity to share experiences from the first several years of my career as a geotechnical engineer with junior geo-engineering staff within my company. The intent was to share situations that were a part of my development, so they could learn and understand their responsibility to the safety of all personnel. Similarly, the purpose of this paper will be to share these thoughts with new geo-engineers in the industry in order to help prepare them for the challenges they will face. WHAT IS OUR PURPOSE? A senior hydrogeologist shared an experience that occurred in their career. The experienced hydrogeologist had spent some time with the hydrogeology staff, most of them relatively new to the mining industry, to understand how they viewed, and carried out, what they perceived as their responsibility at an active mining operation. After a couple months of observing and mentoring, the senior hydrogeologist met with everyone and posed the question above. I am sure that most junior geo-engineers would start explaining different tasks or projects that they must complete. The list would include monitor groundwater levels, track slope movement, evaluate designs, build models, oversee drilling programs, etc. These individuals did as well their supervisor. After going around the room allowing each individual to answer, the experienced hydrogeologist provided them the real answer to the question: SAFETY. If you examine the root intent of nearly every responsibility geotechnical engineers and hydrogeologists have, it is to apply our professional skills to ensure the safety of our workforce. When the objective of safety from the geotechnical and hydrogeology disciplines is achieved, inherently accomplishing the mine plan should follow suit, or it should significantly minimize the impact by gravity or groundwater. The objective of a hydrogeologist is to ensure the soil or rock around an open pit or underground mine is dewatered; this specific objective will reduce pore pressures which could lead to a possible ground failure. They ensure a working bench/UG level is dry, so operations are not dealing with adverse conditions while mining. A geotechnical engineer is expected to use all available information and engineering judgement to provide design recommendations, so that the mine will not catastrophically fail. Additionally, they will implement the monitoring systems to identify hazards in advance in the event that the design is flawed and people need to be evacuated. We all know that safety is important to everyone; however, our particular set of technical skills play a significant role in ensuring the safety of a large portion of the global mining workforce."

Jan 1, 2018