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By J. Kwon, D. Lee, H. Cho

"The use of the combined grinding and liberation model to predict liberation characteristics of iron ore comminuted by a ball mill was studied. Comminution characteristics were obtained using the one-size fraction method. The iron ore samples were crushed and separated into a number of narrow size fractions by screening. The size fractions were further divided by magnetic separation into three classes: concentrate, middling, and tailings. Subsequently, various size-grade classes were subjected to ball milling, and the results were analyzed in terms of the kinetic grinding model. The mineralogical textures of the grinding products were analyzed using mineral liberation analysis. The distribution of iron content within the size fractions was characterized by the beta distribution combined with the Andrew–Mica diagram. It was found that the grinding characteristics of the iron ore samples varied slightly with the iron content. However, the liberation characteristics were well described by the same set of liberation model parameters, regardless of composition. The variation in grinding kinetics with composition and the liberation model parameters was used in the combined comminution–liberation model to predict the evolution of the size-composition matrix as grinding proceeded. The predicted results agreed well with the experimental results. The developed model can be used to construct the yield–recovery graph and to calculate the liberation efficiency to determine the size reduction threshold for efficient separation. INTRODUCTION In mineral processing, comminution is usually the first step that ores undergo to liberate valuable minerals from gangue minerals. Generally, as the particle size decreases, higher liberation can be achieved. However, excessively small particles are unfavorable to subsequent processes, such as separation. Moreover, comminution is a highly energy-consuming process itself that accounts for approximately 60% of all energy used for processing. Therefore, there is a definite need to increase energy efficiency by applying adequate stress so that a high degree of liberation can be acquired at the coarsest size without overgrinding. To this end, it is essential to develop a model to predict the liberation of minerals as a function of size reduction."

Jan 1, 2018

By J. Botula

In the region of the North-Bohemian Coal Basin and its environment, there, in a row of places, are found the accumulations of rocks of the sedimentary and pyro clastic origin, the preliminary composition of those shows the possibility of their being utilized for the production of ecologically sparing natural Fe- and Ti- pigments and filling substances. In many places of the regions of Chomutov and Podborany and near Bilina and also in other places, there are found raw stocks perspective for the preparation of yellow up to ochre-brown, red, brown-red and green dyes. The target of project is the verification of dispensable reserves, their mineralogical composition and chemical and physical attributes, verification of treatment ways of Fe-and Ti-pigments separation (hydrocyclones, magnetic and electrostatic separation) and their stabilization and technological painting attributes for applications in colors, coating and plastic masses, mortar mixtures etc.

Jan 1, 2014

By A. Gül

This investigation was carried out with low grade Murgul-Cakmakkaya copper ore once used to be dumped away as waste material. Sulphide minerals in the ore sample observed are chalcopyrite, pyrite, sphalerite and to some extent molibdenite; quartz, calcite and dolomite are the gangue minerals. The ore sample assays 0.28% Cu, 2.94% Fe and 3.36% S. Mineralogical study of the ore sample showed that adequate liberation of chalcopyrite for flota-tion was achieved below 100 µm. In flotation tests Aerophine 3418-A was the collector employed, NaOH or Ca(OH)2were the pH modifiers. Deactivators used were sodium meta bi-sulphide, starch, dextrin and lime. MIBC was the frother used throughout the tests. Test results showed that starch alone was the most suitable depressant to give the optimum metal content and recovery val-ues. Activated charcoal was used to adsorb excess collector species in the flotation pulp during cleaning stages After two stages cleaning of the rougher concentrate using starch as the depressant a copper concentrate assaying 21.2% Cu was obtained with 79.5% recovery while the tailings contained 0.01% Cu and metal losses were about 3%

Jan 1, 2014

By Ping Fang, Dezhou Wei, Zichuan Guan, Wengang Liu, Yanbai Shen

A new cationic collector, bis(2-hydroxy-3-chloropropyl) dodecylamine (N23), that can be dissolved in water easily was synthesized successfully. Its flotation performance to quartz was investigated compared with dodecyl amine in hematite reverse flotation system. It was found that N23 showed stronger collecting performance to quartz than dodecyl amine. The maximum recovery of 98% to quartz was obtained at a collector concentration of 43.3 mg/L in the pulp pH range of 6-9. This collector can be used to float quartz from hematite when starch was used as depressant. Optimal separating results with 90.06% iron recovery and 66.3% iron grade to artificially mixed sample were achieved at a collector concentration of 43.3 mg/L and a starch concentration of 23.3 mg/L at neutral pulp pH when hematite and quartz were mixed at a mass ratio of 3:2. The adsorption mechanism of the collector on quartz surface was investigated by infrared spectroscopic analysis and zetapotential measurements, which revealed that electrostatic attraction and hydrogen bonding adsorption occurred between the collector and quartz surface.

Jan 1, 2014

By N. Nikolaeva, A. Romashev, T. Aleksandrova

Energetic characteristics identify energy consumption for destruction of prills and kinetic characteristics rate formation of finished size grade in the course of destruction and identify crushing and grinding equipment capacity. And if screen sizing or classification processes are applied in the cycle of ore preparation, then the use of characteristics of separation to size – separating characteristics – is required for theoretical description. Separating characteristics have a lower profile for ore preparation but, nevertheless, they have to be taken into account especially for balance and design calculations of crushing and grinding circuits. In most cases there are impregnations of minerals which vary widely in energy consumption and destruction kinetics and thus polyminerality must be considered as one of priority factor. Raw materials which passed through crushing and grinding processes can be assessed numerically by functions of fractional composition of two types: differential distribution function y ( €) and assay function B( c ) . A set of experiments on grinding of crushed raw materials at different time (up to various sizes) was conducted to analyze effect of grinding size of carbonaceous overburden on function y € and B ( c) as well as to justify the possibility of preconcentration of raw materials at the stage of ore preparation. Analysis of metals distribution per size grades showed that metals are concentrated in size grades of less than 0.315 mm (which is equivalent of cut point for this type of raw material), however, there is no overgrinding and oversludging of material, and enriched product for its further processing can be excluded with the help of classification. The stage of size segregation was tested as a method of preconcentration of raw materials for optimization of ore preparation and further separation.

Jan 1, 2018

By S. A. Bogidaev, M. Yu. Tiunov

"The paper describes the results of the flotation tests with complex rare metal ores from deposits in the Trans-Baikal Territory. Correlations between the quality of produced wolframite, hubnerite and mica concentrates with or without the presence of various alkaline modifiers are determined. Commonly, rare metal ores contain minerals of comparable value to main elements recovered in processing plants using gravitational methods. The paper describes the results of flotation recovery of valuable minerals – main and associated – from gravity tailings of deposits in the Trans-Baikal Territory. It was found that gravity tailings from the first deposit contained fine-grained wolframite, mica (muscovite, lepidolite etc.), feldspar; hubnerite, scheelite, beryl, fluorite, rubidium-containing muscovite from the second deposit, correspondingly. This paper presents the results of the stage flotation tests with the production of tungsten (wolframite, hubnerite), fluorite and mica concentrates from gravity tailings. Figure 1 demonstrates the flowsheet of tungsten ore minerals and mica stage flotation from gravity tailings of the first deposit.Wolframite can be floated using oleic acid with the presence of soda ash, a complexing collector (IM-50), under slightly alkaline conditions in combination with a nonpolar collector [1, 2, 3, 4]. The study included wolframite flotation using the combination of two alkaline modifiers. Flotation of wolframite was performed after pulp desliming, using tall oil saponified with soda ash. The recovery of wolframite in the concentrate of rougher flotation reached 80-85%; the concentrate contained up to 1% of tungsten oxide that can be upgraded to a saleable product using gravitational methods. This procedure was tested during flotation of wolframite, tantalite-columbite and pyrochlore, and provided high performance regardless of a season, at pulp temperatures of 8-10°C, though fattyacid collectors are significantly inefficient at such low temperatures due to low solubility, dispersion and increased collector consumption, consequently. The introduction of two alkaline modifiers in pulp appears to improve these characteristics.The first stage of the tests was focused on increase of iron-bearing tungsten ore minerals recovery from gravity tailings and stabilization of the cold pulp flotation process."

Jan 1, 2018

By A. Bahrami

Andalusite, silimanite and kyanite are polymorphs of aluminosilicate known as kyanite group. Minerals of this group are used in refractory. Sarband andalusite deposit is located in Markazi province in Iran. Mineralogical studies showed that the main minerals of this sample are andalusite (5%~10 %), mica, quartz and feldspar. Processing of the samples was carried out using two sizes, i.e. +500 µm and -500 µm. In the processing of +500 µm scrabble test was carried out on -4750 +500 µm and -2380 +500 µm. For -500+300 µm shaking table and magnetic separation were applied. For -300 µm fraction, flotation was carried out. The results of this tests showed that the processing of Shazand andalusite was not possible, because silica and iron impurities were diffused inside the andalusite mineral grains.

Jan 1, 2014

Datun Concentrator currently processes complex sulfide ores in Gejiu Municipality, Yunnan Province, China. The ore contains much higher arsenic than other ores. The run of mine ore is fed to the concentrator to recover copper and tin by bulk flotation and gravity concentration, and then the other sulphides, such as pyrite, arsenopyrite, etc. didn?t get utilized and are discarded as tailings due to the high arsenic content. In order to utilize the pyrites in the tailings, a series of tests have been conducted for finding the solution of arsenic removal from high arsenic-bearing pyrite concentrates through simple flotation process. By means of orthogonal experimental design, the optimized levels and main factors have been found out for the roughing stage. Through selection of the effective in-organic depressants for the arsenic-bearing minerals, the arsenic in the pyrite concentrate can be removed to meet the requirement of sulfuric acid plant (As%=0.5%) by the open flotation process, i.e., one-time roughing and two-time cleaning.

Jan 1, 2014

By Kaustubh Joshi, Pradip, Beena Rai, Venugopal Tammishetti

"Rapid depletion of high grade iron ores coupled with the increasing demand for the blast furnace grade iron ore in recent times has shifted the research focus on the development of appropriate technologies for the utilization of low - grade alumina rich iron ore slimes. These slimes are currently being dumped into tailing ponds owing to their high alumina content. Typical constituent minerals present in the Indian iron ore slimes are hematite, goethite, gibbsite and kaolinite. Considering the fine particle size distribution (<37 microns) in the slimes, selective dispersion-flocculation seems to be one of the most appropriate process which has been explored by us. We present our successful results on a natural iron ore slime sample obtained from one of the mines in India. We have been able to achieve a concentrate assaying >67% Fe, and <3% Al2O3 and 2.8% loss on ignition (LOI) from the slime sample assaying 60.4% Fe, 7.7% Al2O3 and 5.45% LOI with an Fe recovery of 62-69% simply by adjusting the pulp pH. We have scaled up the process to a semi batch scale as a prelude to commercialize it for the beneficiation of low grade iron ore slimes."

Jan 1, 2014

Traditional mineral processing techniques are more and more difficult to recover the increasingly low grade phosphate ores today. Although bioleaching method has been attempted to process low grade ores in hydrometallurgical field due to economical and environmental reason, it has been hardly used in leaching phosphate ore at home and abroad. Strains of Acidithiobacillus thiooxidans and Acidithiobacillus ferrooxidans were collected and separated from the acid drainage of a coal mine in Anhui province of China. Ultraviolet irradiation and Microwave inducement were applied to the bacterial cultivation process to produce strains of Acidithiobacillus thiooxidans and Acidithi-obacillus ferrooxidans able to tolerate extremely low pH conditions and generate sulphuric acid by oxidizing elemental sulfur or sulphide and the mutagenesis can achieve higher leaching rate. The bioleaching result will improve more by the addition of Tween series surfactants.

Jan 1, 2014

By Yongfu Yu, Xiaotie Wang, Fuguang Zhang, Liping Che

"The flotation process of native Rare Earth minerals such as bastnasite, monazite, mixed minerals of bastnasite and monazite, using the new effective collector Dh was studied in this paper, respectively, and the flotation properties are described. The good qualities of the new collector Dh were revealed through comparing with other collector of Rare Earth minerals. The test results of different ore samples show that at moderate pulp pH (8.5-9.5), Rare earth minerals can be effectively separated from barium, calcium and silicon bearing intergrowth minerals (barite, calcite and silicate minerals) and high quality Rare Earth concentrates can be obtained successfully by the new collector Dh, acid silica gel, turpentine and reagents fitting together rationally. In order to determine optimum technical conditions, the effect of pulp pH, pulp temperature, pulp density and the effect of dosage of reagents (Dh and acid silica gel) on the flotation were investigated in the test.Simultaneously, the paper explores the mechanism of the flotation of Rare Earth minerals from intergrowth minerals. The infrared spectra for Dh and Rare Earth cation by analysis in theory shows that Dh formed chelate complex with Rare Earth cation and were adsorbed on the surfaces of Rare Earth minerals. The mechanism of the intergrowth minerals depressed by acid silica gel can be explained as gummy colloid hydrolyzed from acid silica gel which are selectively absorbed on the gangue minerals, making them hydrophilic and depressed, with pulp pH value of alkalescent."

Jan 1, 2003

By Junwei Han, Wenhua Li, Wenqing Qin, Fen Jiao, Wei Liu, Jiaqi Xu

"A novel technology was developed to study the process of recycling copper from waste printed circuit boards (WPCBs), which are the main source of metal production in the next decades. The chemical compositions of the WPCBs were investigated. The results indicated that the PCB powder was mainly composed of copper (38.5 wt.%), iron, aluminum, and non-metallic materials. Copper is mainly in the form of Cu and is the most valuable metal for the recycle of WPCBs. The concentrated WPCBs powder, obtained by the mechanical process, were pressed as the anode, which was directly electrolyzed to produce copper. The effects of H2SO4 concentration, Cu2+ concentration, current density, pole pitch, and liquid-to-solid ratio on the voltage, current efficiency, and copper extraction were investigated. The results indicated that the optimum conditions were liquid-to-solid ratio of 30 mL/g, current density of 571 A/m2, sulfuric acid concentration of 180 g/L, 50 g/L of copper ion, polar distance of 3 cm. Under the conditions, a desired current efficiency could be achieved. Meanwhile, about 95.62% Cu was recovered from the WPCBs. The experimental studies also revealed that the purity of copper obtained at the highest current efficiency was higher to 99.98%. Produced copper sheet were characterized by X-ray diffraction (XRD). XRD analysis indicated that the copper was the main phase. INTRODUCTION With the rapid development of electronic industry, more and more waste electronic and electrical equipments (WEEE) are generated every year (Fogarasi et al., 2012; Liang et al., 2013). The production of printed circuit boards (PCBs) is the base of electronic industry, because it is the essential part of all electrical and electronic equipments (Schlummer et al., 2007). As a result, a considerable amount of waste PCBs containing plenty of heavy metals have to be treated. In general, PCBs contain about 28% metals that are abundant non-ferrous metals such as Cu, Pb, and Sn. Printed circuit boards can be considered as a secondary resource for recycling rather than wasting. The contents of gold and silver respectively reach 80 g/t and 3300 g/t, which are much higher than that of primary ores. Copper is the main metal of PCB and its content is as high as 26.8% ( Zhang et al., 2009)."

Jan 1, 2018

By E. Hulthén

Cone crushers are used in the mineral, mining, and aggregate industry for fragmentation of rock materials. Control systems for cone crusher settings are widely used to compensate for wear and to protect the machines. The eccentric speed in a cone crusher affects the number of compressions the material is exposed to and thus the particle size distribution of the product. Eccentric speed also affects crusher capacity. However, the speed of the crusher is mostly fixed, because speed changes must be made by shifting pulleys, a process which is quite time-consuming. By applying a frequency converter, which has decreased in cost during recent years, it has become possible to adjust the speed continuously. By also applying mass-flow sensors to the process, the crusher can be run optimally to yield the most sellable products in a given moment. Existing systems normally only protect the machine. The sensors can be mass-flow meters, e.g., conveyor-belt scales. To analyze data from the process and calculate the appropriate value for the speed, an algorithm has been developed. The developed algorithm was tested and evolved at a crushing plant for aggregates that produces around 350 kton a year. The algorithm was implemented in a computer that could communicate with the frequency controller, retrieve data from four mass-flow meters, and also interact with the opera-tor. The computer was reachable over the Internet for the researchers at Chalmers and the algorithm was tuned and improved on-line. The result is a crushing stage that consistently and maximally produces the most desirable product. The performance (yield of required products) increased by 4%. As a bonus, the lifetime of the mantles increased 27% on the evaluated crusher.

Jan 1, 2014

By C. A. Perez

Estimation of rock composition in mineral plants is important to determine rock size and grindability which in turn may improve control of the grinding process. Variations in ore grindability and size distribution directly affects mills power consumption and throughput. Therefore, it is desirable to develop new tools to estimate rock lithological composition. In this paper, a new method for lithological classification based on machine vision is proposed. The method is based on a single video camera and employs information about texture using several different spatial scales. Texture information is extracted from rock images using Gabor filters that can be adjusted at different spatial scales and orientations. After feature extraction, rock images are classified using support-vector machine (SVM). The method was tested on a database containing sub-images of 64x43 pixels of five ore types as follows: massive sulphide (MS), disseminated sulphide (DS), net textured (NT), gabbro (G), and peridotite (P). These ore types were assigned to three grindability classes: soft (MS), medium (DS and NT) and hard (G and P). The database was divided in 2 subsets for training, cross validation, and for test. Classification accuracy is compared with previously published results on a dataset with three different classes of rocks according to their hardness. Results show that our proposed method reached significant improvements (between 13%-20%) in classification accuracy relative to previously published results. Keywords: rock classification, lithological classification, grindability estimation, Gabor feature extraction, texture features

Sep 1, 2012

By Milind Chikhale, Yogesh Reja, Keshav Tyagi

"Using computer models for process design is a well-established practice in the mineral industry. In recent years, there has been emphasis on modeling of processing plant as a whole. This paper covers development of a model for iron ore processing plant. Basic purpose of this model is to use simulation for efficient plant design and help in minimizing risk at the very initial stage of project. Feed to the plant is Hematite iron ore from a deposit located in Eastern India. Major processes in plant include multi-stage crushing, screening, grinding, classification, gravity and magnetic separation. Models for different process equipment were developed using METSIM and Bruno simulation software. Customized black box models and known mathematical models were used for predicting behaviour of processes. Data needed was identified based on the model type. The required data was arranged as per project requirement and processed for development and validation of model. Equipment models were developed and validated on the basis of process design basis, theoretical and empirical data from technical references, and bench scale and pilot scale testwork results. Validated process circuits were assembled to simulate and represent the entire plant process. The result shows expected variation in plant output as a result of variation in the feed. Study concludes by discussing potential applications of the model in plant design."

Jan 1, 2014

By M. K. G. Vermaak

Kimberlite weathering has been a topic of ongoing research within De Beers for many years. Using kimberlite weathering as an alternative to crushing has many advantages e.g. power and reducing diamond breakage. Weathering could also possibly be used in conjunction with crushing just to weaken the material and reduce power consumption. These forces have driven current research to investigate whether kimberlite weathering could be utilised for these reasons. Weathering in this context does not refer to weathering over long period of time but rather to disintegration of the material in aqeous media in relative short time periods. Previous published work discussed that the presence of smectite renders kimberlite weatherable and that the amount of smectite determines the rate of weathering (Morkel and Vermaak, 2006). The current work investigates whether cation ex-change or the adsorption of organic species in the smectite interlayer could influence the observed weathering behaviour. The results show that cation exchange does take place in the presence of cation species and that the weathering behaviour can be drastically improved with especially Cu2+ cations. Concentration and time effects of the weathering was also investigated. Weathering tests with organic species such as ethanol, methanol, edta, pentanol, butanol, acetic acid and oxalic acid was performed. The results show that organic species does improve weathering but under these testing conditions was not as effective as cations.

Jan 1, 2014

By C. L. Xiao

With reference to the test report carried out by Guangzhou Nonferrous Metal Research Institute in 1983, the mineral process flow sheet of Yichun Tantalum-niobium mine is determined based on the characters of ores and successful experiences in light of the problems in the existing flowsheet: The ore is desilted before crushing; the primary slime is separately treated; the staged grinding process used while the fine slime is collectedly treated with tantalum and niobium as the main recoveries and lepidolite and feldspar powder as the secondary. The flowsheet is featured by comprehensive recovery, low investment and low energy cost.

Jan 1, 2014

By Evgeni Visariev

In Copper smelter Aurubis Bulgaria, the copper in slag from the Flash furnace and the Converters is recovered by flotation. The scheme of slag processing is crushing, two stage grinding (autogenous and ball) and flotation. Till 2010 the grinding cycle in the plant was in two stages ? the first stage was AG Mill 70?23 working with a classifier and the second stage was ball mill 3.6/5.5 working with a hydrocyclone. In 2010 a new AG Mill 65x78 with hydrocyclone was put in operation in order to increase throughput of the plant. The second stage of the grinding cycle is with the same ball mill. The Old AG mill processed 55-60 t/h slag with particle size -0.071 mm 75% or over 75 t/h with particle size -0.071 mm 35-40 %. The new AG Mill was designed for throughput 105 t/h with particle size -0.071 mm over 70 %. After the start up there were some problems with the equipment ? block up of AG Mill?s grate and pumps for feeding of the hydrocyclone. For optimization of the process a lot of general tests were made. One of the main problem was a wearing of the sand nozzles. Different materials (rubber, ceramic, metallic) for the sand nozzles were tested. The openings of the grate were changed. This paper presents: ? the optimal technological parameters of the old and the new working scheme; ? how the technological parameters of the new working scheme change when the hydrocyclone works with different nozzles; ? the effect of the change of the grate openings; ? the problems with the increase of the circulating load; ? a final decisions for improvement of the grinding cycle work. Keywords: spigot, wearing, classification, effectiveness, circulating load, autogenous, mill

Sep 1, 2012

By X. G. Liu

Bentonite is an excellent sealant mineral material because of its desirable swelling and self-healing characteristics, low permeability, sorptive qualities, and longevity in nature. A new type of water-swelling building sealant made from bentonite was studied in this paper. The building sealant is prepared by Na-base bentonite, vaseline and paraffin wax under different mass fraction of bentonite (which is 60%,65%,70% respectively). Under unrestricted state, some properties of samples were investigated. The volume expansion ratio at 24 h is 211%, 222%, 256% , and permeability coefficient is 2.86×10-8 cm/s, 4.15×10-8 cm/s and 4.78×10-8 cm/s respectively; low temperature flexibility of the sample (bentonite quality is 65%, 70% respectively) is good, and it does not flow heated for 2 h under 80?. The results of XRD and SEM indicate that bentonite is coated preferably by vaseline, and the spacing of layers of bentonite do not changed. The sample can keep full water swelling ability, and has good molding process. The test results prove that the properties of samples may reach the standard of building sealant.

Jan 1, 2014

By Bern Klein, Givemore Sakuhuni

Flotation is the dominant base metal extraction technique and it requires ore to be ground below the liberation size for effective recovery due to its dependence on mineral surface properties. For a poly-metallic ore, differential hardness of constituent minerals leads to over grinding of softer minerals before the harder minerals are fully liberated, which makes selection of a target grind size complex, and the complexity increases when treating leaner ores. Flotation recovery deteriorates above 100 and below 10 microns causing significant loses of valuable minerals in most flotation circuits. Although enhanced gravity concentration is known to be effective at recovering particles above 100 microns, which are difficult to hydro-dynamically transport, exploiting differential specific gravity for base metal separation was not an option in the past. This was partly due to the absence of high mass yield gravity techniques. The advent of continuous gravity concentrators with flexible mass yields, in the past two decades, has necessitated investigation of possible base metal applications. The Knelson CVD, one of the continuous discharge centrifugal concentrators, has an established application niche for sulphides associated with gold. However, its base metal applications have never been rigorously tested. Considering the dependence of flotation recovery on particle size, continuous discharge centrifugal concentration can be integrated in flotation circuits to capture flotation non-recoverable coarse particles. This paper explores how particle size, liberation and mineral hardness influence application of continuous centrifugal technology to regulate galena deportment in a polymetallic base metal plant. The results show that particle size affects galena recovery more than liberation. In view of these results, the CVD can be integrated in the primary grinding circuit to pre-concentrate the heavy sulphides at a coarser grind size with potential grinding energy savings.

Jan 1, 2014