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By G. Akdogan, S. M. Bradshaw, A. P. Van Wyk, T. Punt

This study investigated the performance of citric acid as lixiviant for cathode material from end-of-life lithium-ion batteries (LIBs). Black mass containing 84.2 weight percent MNC (LiNi0.45Mn0.4Co0.15O2) and 15.8 weight percent LCO (LiCoO2) material was leached at solid-to-liquid ratios of 20, 50 and 100 g/L. Leaching with 1.5 M citric acid, 2 volume percent H2O2 and a solid-to-liquid ratio of 20 g/L at 95 °C extracted 90 percent Co, 95 percent Li, 94 percent Mn and 94 percent Ni within 20 min. At the highest solid-to-liquid ratio of 100 g/L with 1.5 M citric acid, 10 volume percent H2O2 and 95 °C, 84 percent Al, 84 percent Co, 87 percent Li, 86 percent Mn and 96 percent Ni were leached after 40 min, producing a leach solution containing 0.68 g/L Al, 20.0 g/L Co, 6.0 g/L Li, 13.6 g/L Mn and 19.3 g/L Ni. Using stepwise addition of H2O2, instead of initial bulk addition, did not significantly improve the leaching efficiency but did reduce the required leaching time. Temperature control of the reactor was also more manageable with stepwise addition of H2O2, and evolution of gas was less vigorous. It was observed that the leaching efficiencies of Co, Li and Mn decreased slightly at solid-to-liquid ratios of 50 and 100 g/L, while the leaching of Ni increased slightly. The solution leached at 20 g/L could be stored for six weeks without any spontaneous precipitation. However, solutions leached at 50 and 100 g/L showed changes in concentration after one month of storage, suggesting that processes that have a large material throughput and use high solid-to-liquid ratios around 100 g/L must ensure that the solutions are not stored for extended periods of time.

Apr 1, 2025

By W. Hu

Gravity concentration has been the main method for tin ore beneficiation, based on the significant difference of density between cassiterite and gangue in the tin ore. However, with the exhaustion of rich and coarse reserves, the proportion of tin distribution in slime be-comes as high as 50 to 70% and has a size range of -19 urn. In some sulfide tin ore, most of the tin is of the minus 10-urn size fraction, and thus slime processing has gained importance in tin ore processing. Some innovations are being developed, such as the centrifugal cone separator, belt concentrator, slime table, B-M separator, and slime flotation. Direct flotation with tolyl arsonic acid has been practiced with success.

Jan 1, 1989

By Brett P. Spigarelli

"To meet the growing need for CO2 capture and storage technology, Michigan Technological University is studying CO2 capture using alkali-based solvents. The objective of the present study was to find a way to increase the absorption rate of CO2 into an alkali solution without reducing the absorption capacity of the solution. One approach to increasing absorption rate is to use a surfactant to chemically alter the gas bubble size. The surfactant chosen for the study was a neutral-charge polypropylene glycol methyl ether (PPGME) with a molecular weight of 200. Experiments were conducted to study the absorption rate of CO2 at varying surfactant concentrations. Results showed that as the concentration of PPGME increased in solution, the absorption rate also increased. The CO2 absorption rate increased from 3.45 x 10-3 mol/min CO2 at 0g/L PPGME to 3.92 x 10-3 mol/min CO2 at 0.48 g/L PPGME. This amounted to a 14% increase in the CO2 absorption rate with no decrease in the absorption capacity of the solution. IntroductionChemical absorption using an amine solvent is currently the most mature carbon capture and storage technology available. Amines are advantageous in that they have a fast CO2 absorption rate, which leads to a high CO2 removal efficiency. However, amine absorption has some considerable drawbacks, such as high energy requirements, high equipment corrosion rates, amine degradation in the presence of oxygen, high waste generation and a large increase in plant footprint if new equipment is constructed (Herzog and Golomb, 2004; D’Alessandro et al., 2010). Due to these drawbacks, Michigan Technological University (MTU) is studying CO2 absorption using alkali-based solvents, which address the above disadvantages of amine solvents."

Jan 1, 2015

By R. R. Klimpel

The use of froth flotation as a means of separating and upgrading sulfide mineral concentrates is standard industrial practice throughout the world. It is ap-parent from observing the industrial practice of sulfide mineral flotation over the last decade that progress is being made in optimizing the operating aspects of flotation. Examples of this are the availability of improved instrumentation and related computer control devices, the modification of mechanical flotation cell designs, the introduction of column cells, better reagent dosage control, blending of feed ores, increasing attention to coarse and fine particle separations, the successful introduction of new frother chemistries, etc.

Jan 1, 1989

By M. S. Bickers

Prior to 1970, the environmental liabilities associated with mine construction and management were few. Mostly, they were aimed at health and safety matters. At that time less than two dozen codes were incorporated into the engineering design and they were somewhat static and well known by the engineering designers and managers. These codes issued by governmental agencies and professional associations are listed in Table 1

Jan 1, 1988

By J. F. Edwards

In situ extraction of copper through borehole injection presents a new technology for the mining of copper. For the successful application of this technology, copper recovery at the surface must be specifically designed for borehole injection and the general conditions of the well field. This paper describes the design of a solvent extraction / electrowinning facility specifically designed for in situ leaching of copper. This design is based on commercial solvent extraction / electro-winning with considerations of the requirements of this specific application.

Jan 1, 1988

By J. C. Rhodes

The demand for good white minerals for many industries including paint and plastics have made it necessary to import high grade industrial minerals from various parts of the world. Some of the calcium carbonate, barite and talc minerals are from China, Mexico, Jamaica and Haiti. These materials can be processed by custom processors. The custom processor can provide a service to the Industrial Mineral owner. The imported materials can arrive in various feed sizes from lumps (3"-6") down to 325 mesh. The materials can also be in various size shipments or container loads. The economics for importing should be investigated thoroughly. The two factors just mentioned can influence the quantity of material to be processed. These two factors can also influence the total cost for each end product.

Jan 1, 1989

By J. Hanna

Four Ca-bentonitic clays from Alabama were evaluated for use in Diammonium Phosphate (DAP) or Urea Ammonium Nitrate (UAN) fertilizer suspensions. The viscosity and gel strength of suspensions prepared with different proportions of a Western bentonite clay and sodium exchanged Alabama clays, were measured as a function of clay content and dispersant concentration. The results obtained suggested that three of the Alabama Ca-bentonites would replace about 40% of the more expensive Western bentonite in UAN and DAP fertilizer suspensions. The performance of the Na-modified clays, prepared according to the TVA soda ash method, was as good or even better than those observed for the Mg-, Na/Mg-or K-modified clays. The TVA clay modification procedure appears to be reliable and cost effective.

Jan 1, 1989

By Delbert Hamilton, Christopher Snyder

In the last three years there have been four uncontrolled heating events in mines that have been attributed to the use of polyurethane foam as a void fill product. These heating events are due to the exothermic reaction that occurs during application of these polymeric products. These events led the Mine Safety and Health Administration to issue a safety alert on polyurethane products used in void filling and ground consolidation in mining, with the goal of educating the mining community about this potential hazard. This paper provides an overview of various types of polymeric products and best practices, the factors that contributed to the heating events, and case studies involving polymeric products.

Jun 25, 2024

By Katherine Hynard, Colin Eustace

Suboptimal decisions introduced during the mine planning process are generally a consequence of both a myopic view of planning objectives as well as time and resources available to convert longer-term plans into execution plans. Erosion of strategic mine plan value in conversion to execution plans is likely to amount to billions of dollars each year. When integrated with operations data feeds, simulation and optimization tools can be used to preserve the value in the strategic mine plan. Optimization models are capable of both automating production of execution plans and improving performance. This reduces the manual burden of revising plans while improving alignment with long-term production objectives. Simulation models can also support the process of developing effective execution plans by providing forward visibility of mine operations performance. They can also be used to test the robustness of optimized execution plans and response to operational variability and disturbances.

May 1, 2025

By D. Leppert

Clinoptilolite zeolite may offer attractive, cost-effective alternatives for remedial cleanup of old minesites, smelters and other sites with heavy metal contamination. Previous research demonstrates the relatively strong affinity of clinoptilolite for numerous metals and clinoptilolite displays a particularly strong affinity for lead (Loizidou and Townsend, 1987), one of the most toxic and problematic heavy metals. Since clinoptilolite can also selectively absorb some radionuclides and organic compounds, it may offer practical solutions to a wide variety of environmental problems.

Jan 1, 1989

By J. J. Antony

The Cactus Gold Mine is a joint venture comprised of Middle Buttes Partners Ltd. (CoCa Mines, Inc.--operator, T. Congdon and W. Carey) and Compass Mining, Inc. The project includes 2.4 sq. miles of contiguous mining claims and leases in the Mojave Mining District, Kern County, California, approximately B5 miles northeast of Los Angeles. The property is readily accessible year round by all-weather roads and is within 6 miles of the main line of the Southern Pacific Railway.

Jan 1, 1988

By J. Hanna

The University of Alabama Mineral Resources Institute (MRI) has developed a unique process for selective fatty acid flotation of carbon-ate gangue from sedimentary apatites "francolite" in the pH range of 4-6 without collector conditioning of the pulp. The process, which does not require an apatite depressant, was modified to beneficiate a high Mgo siliceous phosphate matrix from south Florida. The modified process includes two flotation stages, one for carbonate removal, as mentioned above, and the other for phosphate recovery from the siliceous gangue. The selective flotation separation of the carbonate and phosphate, from siliceous constituents of the matrix at various pH levels and collector dosages are discussed. In the carbonate flotation stage, about 70% of the Mgo was rejected in the froth and the phosphate flotation stage produced concentrates analyzing about 31% P2O5,0.7% HgO and 4% insol. The overall P2O5 recovery in the two stages is about 85%.

Jan 1, 1989

By K. E. Hjelmstad

In the event of fire underground, it is essential that all miners be warned as quickly as possible. With mine air, rapidly depleted of oxygen and contaminated with smoke and toxic fire gases, any delay in the warning signal could have disastrous consequences. Unfortunately, present mine, fire warning systems, such as stench, audible or visual alarms, telephones, and messengers, are often slow, unreliable, and limited in coverage.

Jan 1, 1989

By W. de Bruijn

Differential reduction and expansion or shrinkage of hematite under the influence of intimately associated foreign oxides may be a source of stress formation and sinter degradation during blast furnace reduction. To study specific effects, synthetically pre-pared hematite powder evenly doped with 1% by weight of several elements present as oxides, was pressed into tablets and sintered at high temperature prior to reduction. Continuous thermo-gravimetric and dilatometric analyses were per-formed on the sintered tablets as these were being subjected to reduction under simulated blast furnace time/temperature/gas composition conditions up to 1183 K. These findings were coupled with observations on the microstructure of tablets removed from various stages of the reduction process.

Jan 1, 1988

By Y. Gonzalez

The reaction kinetics of sulfuric acid leaching of brass foundry flue dusts were studied. As received flue dusts were separated into two size fractions, a coarse fraction (median size 103.5 microns) and a fine fraction (median size 3.4 microns). Experiments were performed on both fractions al-though most results are reported for the coarse fraction. Leaching experiments were conducted in a stirred reactor to determine those factors which govern the kinetic response of the sys-tem. The kinetics were followed by determining the increase in the concentration of dissolved copper with time. The effects of temperature, concentration and oxygen partial pressure on the rate of copper dissolution were examined. In addition, reaction residues were examined by SEM, EDAX and X-ray analysis. An activation energy of 4.8 kcal/mole (20.08 kJ/mole) was calculated. The rate was found to be significantly dependent on oxygen partial pressure and acid concentration. The order of the reaction with respect to oxygen partial pressure and hydrogen ion concentration was approximately 1.50 and 0.37, respectively. Results indicate that the dissolution reaction is limited by diffusion and can be described by the following mathematical expression where ~ is fraction of copper extracted in time t

Jan 1, 1988

By Erica Frederickson

"Millennials. Doesn’t the word just make your blood boil? You’ve probably encountered one of those kids who think they know best despite a lack of any real experience.Hi, my name is Erica, and I am a Millennial. We often get a bad rap, sometimes for good reason. But we do have qualities that are often overlooked. For example, I am happy to share with my generation a real desire to make a difference in the world and a commitment to innovation. Does this mean I think we always have good ideas? No – especially not right away. After all, few of us came anywhere near a piece of construction equipment until arriving for our first job, as was the case for me. We may have fancy degrees, but not many of us learned to run a jackleg drill in school.Two weeks after graduating college in 2011, I packed up my bags and moved to New York City to work as a field engineer for Traylor Bros. Inc. on the Queens Bored Tunnels project (Granite/Traylor /Frontier Kemper, JV), part of NYC MTA’s multi-billion dollar Long Island Railroad East Side Access project. It was here I became acquainted with the notorious New York City union workers. Perhaps the greatest challenge of my career thus far was earning the respect of the field supervision and craft workers on this first project.The first time I asked a maintenance mechanic to clean a piece of equipment in accordance with our maintenance protocol I got a flat-out “No.” It was the most powerless I had ever felt. But why should these experienced workers trust a 21-year-old girl with her civil engineering degree and no prior experience? I realized no employee on the job had any reason to listen to me — not until I proved my worth. Fortunately, I arrived on the job site just as we were commissioning the slurry plant for the first tunnel drive. I dove into learning as much about the slurry tunneling process as possible and was able to quickly pick up the ins and outs of running the slurry separation plant. As none of the other engineers or management had first-hand experience on a slurry tunneling job, I soon became the go-to engineer in the slurry plant. No one questioned me if I asked to have something done around the plant after that, or if they did, they quickly learned that I had a convincing answer as to the need for the task. I was even able to play a large role in shaping our slurry monitoring and control methodology."

Jan 1, 2015

By R. K. Singhal

The underground coal mining systems have kept pace with the developments that have occurred in other types of mining industry. A diversified group of machines with high horsepower motors, built-in microprocessor technology and with numerous options to satisfy the miners need in a varying geological environment are now available. A brief review of this existing technology and its likely status within the next 21 years is presented. Discussed also are some of the on-going advanced developments in electronic mechanization, remote control and automation together with mine wide data monitoring and management systems and facilities to process and transmit data to remote computerized stations.

Jan 1, 1989

By J. A. M. Cano

A brief introduction is made on the existence of sulphides in the top gas of the Midrex Shaft Furnace, giving consideration to the operation of the furnace and the liberation of sulphur as well as its consequential effects on the reduction process. The text shows a study of sulphur distribution in the pellet, emphasizing the importance of this distribution in relation to the liberation of sulphur during the reduction. A study was made to determine the sulphur compounds that exist in the pellets, showing ways of controlling the sulphur distribution and reducing its liberation?during the reduction.

Jan 1, 1989

By K. E. Hjelmstad

Solution mining operations often encounter difficulty maintaining adequate leach solution flow into the ore formation because of loss of formation permeability near the injection well. Permeability loss caused by swelling and breakup of clays and fine particle migration can often be the cause of the problem.

Jan 1, 1989