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By K. O. Bennington

Enthalpies of formation of three sodium titanates were determined by hydrofluoric acid solution calorimetry, The values obtained for formation from the elements at 298.15° K are -370.9±0.5 kcal/mole for Na2TiO3, -832.1±0.9 kcal/mole for Na2Ti307, and -1,510.9±1.7 kcal/mole for Na2Ti6013. Tables of enthalpies of formation and Gibbs energies of formation are given as a function of temperature both from the elements and from the component oxides for Na2Ti03 and Na2Ti307.

Jan 1, 1973

By L. B. Berger

"Additions to List Published in Information Circular 7444 NEW APPROVALSThe following respiratory protective devices have been approved by the United States Department of the Interior, Bureau of Mines, since Information Circular 7444 was issued (March 1948):Gas Masks Approved Under Schedules 14, 14A, 14B) 11+D, and 14E Type N: Universal Gas MasksUniversal gas masks with filters that afford respiratory protection against smoke from ordinary fires and limited respiratory protection against dusts, fumes, mists, and fogs but do not afford respiratory protection against the toxic smokes of warfare.Willson WUG-Nl universal gas mask. Approval BM-1443, issued to Willson Products, Inc., May 25, 1948.Bullard universal as mask. Extension of approval BM-1443, issued to E. D. Bullard Co., January 12, 19 9.Supplied-air Respirators Approved Under Schedules 19 and 19A Type C: Air-line Respirators4. METCO air-line respirator. Extension of approval BM-1920, issued to Metallizing Engineering Co., Inc., December 8, 1948.Type CE: Abrasive Blasting Helmets, Hoods, or Masks9. M.S.A. abrasive mask. Approval BM-1920, issued to Mine Safety Appliances Co., April 30, 1948."

Apr 1, 1949

By Willard L. Hunter

The separation of tantalum and columbium by solvent extraction was under-taken as part of the Bureau of Mines research program to improve methods for extracting, separating, and reducing these elements to metal. The diethyl ketone aqueous HCl-HF system was one of several systems studied to determine the effect of metal and acid concentrations in aqueous solutions upon the transfer of tantalum and columbium into selected ketones. The tantalum-columbium oxide mixture used in this investigation was obtained by chemical extraction from Geomines slag. The investigation showed that tantalum 99.4 percent pure and columbium 97.2 percent pure can be produced by the selective transfer of tantalum into diethyl ketone from a solution of 2-N HF and 1-N HC1. The relatively low acid concentration necessary for tantalum transfer and the excellent selectivity of the system recommend its use for the separation of tantalum and columbium.

Jan 1, 1961

Crosson and Peters treat the errors that result in miner location due to errors in the overburden earth model used for computing location. A parallel effort by J. Powell of PMSRC is discussed here, where the location method used is that of the Westinghouse location program - "Miner". This location program was tested by Powell by using arrival times generated from the overburden earth model of Table l* rounded to the nearest millisecond. Location computations were then made using 3 geophones at a time. The average location is tabulated for all geophone triplets except when 3 geophones are in line. Geophone arrays were as shown in Tables 2 and 3. The manner in which the test was done is illustrated in Figure 1. I. SUMMARY OF RESULTS The arrival time differences, based on the Table 1 earth model, together with geophone locations based on the array geometries of Tables 2 and 3, were entered into the computer, together with a stated depth of 700 feet and an estimated overburden seismic velocity of 10,000 feet per second. These parameter values were processed by the location program - "Miner". Figure 2 illustrates the interpretation of the plots and data. The tabular data and plots of Table 4 and Figures 3, 4, and 5 illustrate the location error results obtained. These plots indicate that for sources within the array, the errors are considerably less than the measured errors obtained during field tests of the present location system. The possible reasons for this discrepancy are noted in Part Eight (Earth Models).

Jan 1, 1974

Eliminate accidental tramming of a cleanup tractor. Approach A switch was installed in the operator's seat cushion to pre-vent the cleanup tractor from tramming without an operator in the driver's seat. How It Works The operator must be seated, and the Forward/Reverse Switch (that controls tramming direction) must pass through the NEUTRAL position before the vehicle will tram. See Figure 1. A pressure-sensitive seat cushion switch, a solid-state relay, and a double-contact relay were added to the control circuitry of an S & S BMUAT -88 cleanup tractor to create this tramming interlock. The weight of the operator on the cushion closes the seat cushion switch (Figure 2, A). This activates the solid-state relay (B), which completes the initial circuitry. Moving the For- ward/Reverse Switch (C) to NEUTRAL energizes the coil in the double-contact relay (D) and closes both contacts. One contact completes a sustaining circuit which keeps the double-contact relay energized. The second contact transfers power to the remaining contacts within the Forward/ Reverse Switch. These circuits are shown in greater de- tail in Figure 2.

Jan 1, 1978

By Tobias W. Goodman, Joseph Cervik

This Bureau of Mines report investigates the horizontal trajectory of boreholes drilled in coalbeds using the rotary drilling technique. Test holes drilled in coalbeds showed that the path of a borehole in the horizontal plane depends on drilling assembly configuration, drill bit rotation, and coalbed geologic features. An assembly that contained an 18-ft (5.53) long drill collar and two centralizers had the best horizontal stability evidenced by trajectories that deviated less than 16 ft (4.9 m) from a target at 1,000 ft (305 m). Removal of one of the centralizers resulted in a loss of control of hole trajectory in the horizontal plane. Generally, holes tended to turn to the right, presumably because of right-hand rotation of the bit. Deviations from the original bearing line were as much as 200 ft (61 m) or more at a depth of 1,000 ft (305 m).

Jan 1, 1988

Improve transmission of data from an underground mine monitoring system to a remote, mass-data storage system. Background Instrumentation systems in underground mines must operate under environmental extremes of dust and humidity, local electromagnetic/radio frequency (EM/RF) interference fields, and potentially explosive atmospheres. During a recent roof-bolt study performed by the Bureau of Mines, it was necessary to transmit a large quantity of data to a data storage system. Conventional wire cable transmission presented several limitations which often required special electrical isolation or physical protection. Because conventional wire cable presented certain problems, the Bureau of Mines investigated alternative means of data transmission. The research investigation led to the selection of fiber optic cable for data transmission applications. The fiber optic method of data transmission offers several advantages: ? Since the transmission medium consists of light waves, it is safe to use in gassy mines. Where applicable, MSHA permissibility standards for peripheral devices must be met. ? It is lightweight and rugged. ? It can operate up to 131000 feet (4km) without repeaters and without EM/RF field interference.

Jan 1, 1986

By A. L. Engel

This report describes laboratory-scale experimental treatment of six base-metal ore samples taken by engineers of the Bureau of Mines, Region II, while investigating ore deposits in California and Nevada. The information is of interest in developing the mining districts represented or when similar ores from other sources are being studied. Simple treatment methods were employed as far as possible. More complex treatments also were tried when necessary. The possibilities and limitations of the methods applied to the several ores are shown by the data herein reported.

Jan 1, 1960

Three -dimensional boundary value problems are difficult to solve. Indeed, while the separation of the scalar wave equation can be effected in 11 different coordinate systems, an analytic solution requires that the boundaries, both external and internal, possess the same symmetry as the coordinate system. Numerical methods are thus of great importance for the solution of such problems; however, despite the availability of high-speed, large memory digital computers , the solution to a significant three -dimensional problem is by no means trivial. It is unfortunate that the results reported here by Jones are invalid. Jones discusses a model in which a three-dimensional island lies off a linear coastline where all the interfaces lie in the coordinate planes in a Cartesian system. A downward plane em wave polarized with the electric field parallel to the linear coastline, and two of the islands coast, is incident downward. This, of course, requires that the incident electric field is perpendicular to the other faces of the idealized Cartesian island. The significant equation used by Jones for his finite difference calculations is [ ] where n2 = sµ? . is the conductivity, µ=µo is the permeability of the appropriate medium, and w is the angular frequency of a Fourier component of the incident field. We see that the displacement current term is omitted, which is an excellent approximation for the parameters of interest in this model. In the similar equation for the y- component of the diffusion equation, the same considerations which we are about to discuss are equally valid. It can be seen from the equation that the field components are related and thus any errors introduced will be propagated into all three components. The difficulty arises when Ex or E is perpendicular Y to one or other of the surfaces of discontinuity in s. The continuity of current at the air-earth interface (upper surface), e. g., jy, requires

Jan 1, 1973

By P. W. Jeran

The Beckley mine is one of five new mines in a heretofore unmined portion of the Beckley coalbed. The remoteness of these new mines from prior mining and their greater overburden preclude applying methane emission experience obtained in the old mines. Four sections of the Beckley mine were monitored. The data gathered show that variations in methane emission cannot be explained by variations in coal production. Although overburdens varied by as much as 30 pct, no correlation with methane emissions could be determined. The rib emissions increase with increased length of rib from a section advancing into virgin coal and do not decline over a prolonged idle period (32 days) whereas some decline has been measured for a section not mining into virgin coal. The indication is that degasification prior to mining will reduce the hazard of methane emissions in this area of the Beckley coalbed.

Jan 1, 1977

By Fred N. Kissell

In This Chapter [Early indicators of a gas problem How the methane hazard is reduced Ventilation principles for gassy tunnels Monitoring for gas Eliminating ignition sources and The all-important human factors component] This chapter gives guidelines for preventing methane gas explosions during tunnel construction. Emphasis is placed on assessing the hazard potential, on ventilation principles, and on monitoring for gas. The chapter also emphasizes the importance of human factors in reducing explosion risk. Ensuring safe conditions is much more than just good engineering design. It also involves the every-day vigilance of those working underground. This does not imply that the engineering design can be ignored, only that the job of providing safe conditions has just begun with design. EARLY INDICATORS OF A GAS PROBLEM For the engineer planning a tunnel project, reliable early indicators of methane are scarce. How-ever, the local geology can often provide some information.2 Carbonaceous rocks and tar sands are a likely methane source. Gas is also a distinct possibility if it is known to be present else-where in the same sequence of geologic formations. Swampy areas, sewerage systems, and landfills are also candidates because the decomposition of organic materials produces methane. The gas in a tunnel can originate in the strata being excavated, or it can migrate a considerable distance from adjacent strata. Test borings at the project site can also serve as initial indicators of gas. Methane has no odor, but may be emitted along with gases that do. If gas is emitted from the borehole, a sample may be collected by inserting a tube into the hole as far as possible and pumping the gas out. The gas sample should be collected in a sampling bag or canister for later analysis by a chemical laboratory.3

Jan 6, 2006

By David Hoadley, Kenneth R. Maser, Ashok B. Boghani, James E. Billar, D. Randolph Berry, Mackenzie Burnett, Robert H. Trent

5. General Escapeway Requirements 5.1 Escape Routes Present escapeway regulations state "Every mine shall have two separate properly maintained escapeways to the surface which are so positioned that damage to one shall not lessen the effectiveness of the other, or a method of refuge shall be provided when only one opening to the surface is possible." "Escape routes shall be a. Inspected at regular intervals and maintained in safe, travellable condition, b. Marked with conspicuous and easily read direction signs that clearly indicate the ways of escape." "Application. "Regular" intervals means at intervals no greater than monthly where conditions are stable and oftener where conditions may change." "Designated escapeways inclined more than 30* from the horizontal shall be equipped with stairways, ladders, cleated walkways, or emergency hoisting facilities." As can be noted in present and proposed regulations there must be two separate properly maintained escapeways. In most operations, the escapeways will consist of one route that is the normal travelway used in day to day operations. The second route is usually a return airway through old work areas. Based on this generally accepted practice, we will designate the two types as primary and secondary.

Jan 1, 1976

By Donald W. Fausett

This Bureau of Mines publication presents a system of thermal decompositions providing an adequate description of the mechanism of oil shale pyrolysis. Specific rate constants for systems of thermal decompositions studied are estimated via a least-squares procedure. The estimates thus obtained provide a mathematical model of the corresponding thermal decomposition system. A model that generates a good fit to published Bureau of Mines experimental data, in comparison with other models studied, is based on a thermal decomposition system consisting of two first-order reactions and three second-order reactions. Values computed for the specific rate constants corresponding to this system are shown to exhibit a temperature dependence that is in good agreement with the Arrhenius equation.

Jan 1, 1974

In the past, mine management has been concerned with removing water from active mining sections primarily because it hampered the movement of mining equipment and aggravated the working condition of the miners. Pumping water to sumps and gravity drainage by ditching have proven successful in mines for minimizing section down time due to water influx. However, with the advent of more strict pollution laws the mining engineer must now be concerned with keeping water out of the section and also with preventing it from causing pollution. A review of the handbooks and textbooks used in the mining engineering curricula reveals that little has been written concerning acid mine water prevention or control in underground coal mines. Additionally, the review of the curricula of mining schools indicates they are not teaching the engineering students the necessary techniques of mine water management as they relate to the abatement of mine water pollution.

Jan 1, 1970

By David Hoadley, Kenneth R. Maser, Ashok B. Boghani, James E. Billar, D. Randolph Berry, Mackenzie Burnett, Robert H. Trent

3. Application of Proposed Revised Standards 57.11-50 to Mines Surveyed 3.1 Subparagraph (a) 1 "Each mine shall have at least two separate and properly maintained escapeways from each working place to the surface which are so positioned that physical or environmental damage to one will not lessen the effective¬ness of the other, and which meet the requirements of travelways and man hoisting standards These escape¬ways shall reach to within 1000 feet horizontally or 300 feet vertically of each working place " 3. 1. 1 Discussion This section will deal with the 1000 and 300 feet distance requirements, Section 3. 5 will deal with the "environmental damage" provisions. During the course of the mine surveys, it became obvious that one mine's 1000 foot distance was nowhere near equal to another' s --not in the actual distance but in the time required to traverse that distance. This -Ls true for the 300-foot requirement as well. The most obvious example is that one could traverse down a 300-foot raise much faster than climbing up the same distance. The temptation is strong to recommend that the distance requirement be changed to travel times instead. However, this approach would unfortunately lead to a lot of subjective evaluations. Having a time requirement for an entire mine evacuation (Subparagraph 6) is one thing, time requirements and the requisite inspection proce¬dures for each working place are quite another.

Jan 1, 1976

By Charles C. Hwang

In this Bureau of Mines report, a previously developed theory of reverse stratified flow in ventilated duct fires is applied to mine-related ventilation systems that utilize an exhaust fan to supply the forced airflows. The coupling between a fire and the ventilation airflow in a single-entry duct is analyzed to relate the air velocity in the absence of a fire to air velocity during a fire. By combining the derived coupling equations with the results of the previously developed theory of reverse stratified flow, it is possible to calculate critical flow velocities required to prevent reverse stratified flow in the event of a duct fire. The sample calculations shown agree with the few experimental results available from small-scale tunnel fires.

Jan 1, 1978

By G. M. Wilemon

The Bureau of Mines conducted preliminary investigations on the use of an acid-alcohol leaching technique for recovering phosphate values from phosphate matrices. H2S04 and methanol were used as the leaching agents. Starting-matrix particle size and acid-apatite ratio were found to significantly affect the efficiency of phosphate leaching. Phosphate extractions of more than 80 pct were obtained when minus 200-mesh ore was used and the acid-apatite ratio was 8:1 or more. The iron and aluminum oxide impurities (R203) present in the crude acid products were monitored, and R203-P205 ratios are reported. Phosphate extractions in excess of 80 pct also were obtained when phosphatic clay wastes were leached. Typically, leach slurries filtered using test leaf filters ex-hibited filtration rates of 100 lb/(h·ft2) or more.

Jan 1, 1987

By P. W. Jeran, M. C. Irani, D. H. Lawhead

The Beckley mine is one of five new mines in a heretofore unmined portion of the Beckley coalbed. The remoteness of these new mines from prior mining and their greater overburden preclude applying methane emission experience obtained in the old mines. Four sections of the Beckley mine were monitored. The data gathered show that variations in methane emission cannot be explained by variations in coal production. Although overburdens varied by as much as 30 pct, no correlation with methane emissions could be determined. The rib emissions increase with increased length of rib from a section advancing into virgin coal and do not decline over a prolonged idle period (32 days) whereas some decline has been measured for a section not mining into virgin coal. The indication is that degasification prior to mining will reduce the hazard of methane emissions in this area of the Beckley coalbed.

Jan 1, 1977

Simplify the spraying of sealants onto coal mine roofs. Approach A nonclogging system in which dry-fed sealant is mixed with water down-stream of the spray nozzle, has been developed and tested. How It Works The two-channel nozzle of this spray discharges two separate flows, a mixture of air and dry sealant from a central cylinder, and an encircling spray of water from a concentrically mounted water ring (a ring-shaped manifold). Downstream of the nozzle, the water mixes with the air and sealant to form a wet sealant spray that adheres to mine surfaces with very little rebound. (See photograph.) Extensively modified commercial spray machines are used to feed the sealant to the spray nozzle smoothly, without raising dust. Plugging of the nozzle is practically eliminated by two self-cleaning design features of the nozzle. These are the air gap and the tapered bore of the cylinder, (See drawing.)

Jan 1, 1979

By J. E. Pahlman

The Bureau of Mines conducted re-search to determine the resistance of basic refractories to corrosion by ash slags that would result from the burning of coal and lignite in metallurgical operations. Basic refractories are of economic interest because they are from one-third to one-half as expensive as 90-to 99-pct-alumina refractories. Static tests were performed at 1,300° C and dynamic tests at 1,400° to 1,650° C to investigate the stability of refractory specimens in a slag environment. In alkali-containing lignite ash slags, in order of decreasing resistance, magnesite, magnesite-chrome, and chrome-magnesite refractories all had corrosion resistances equal to or better than 90-to 99-pct-alumina refractories. These basic refractories formed slag penetration layers in dynamic tests, which helped protect them from further attack. Chemically bonded basic refractories in general did not have as good a resistance to slag attack as did burned refractories of the same composition. In very acidic coal ash slag, a chrome-magnesite refractory containing 30 pct MgO plus a slag inhibitor and direct-bonded magnesite-chrome refractories with 60 pct MgO had good resistance to attack. Chrome-magnesite refractories (30 to 40 pct MgO) were moderately to severely attacked, and refractories with greater than 70 pct MgO were severely attacked by this same slag.

Jan 1, 1982