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By A. Gene Collins

Some of the geochemical relationships that exist between subsurface fluids and the associated geologic strata in petroleum producing areas of Louisiana have been determined. Samples of petroleum-associated water were obtained from 126 wells in Louisiana that produced from sediments of three geologic ages: Tertiary, Cretaceous, and Jurassic. The samples were trans-ported to a central laboratory for analysis of chemical composition, using standard methods, to determine if the compositions varied with the geologic strata of their source and, if so, why. The dissolved constituents were com-pared with those of a brine that was concentrated by evaporation. The concentrations of bromide, calcium, and strontium were useful in distinguishing the brines produced from sediments of a late age from those of an earlier age. The concentration ratios of Mg' (total equivalent magnesium) and bromide indicated that dolomitization probably had occurred and altered the composition of the brines. A principal-components analysis of the data indicated an inverse relationship between depth and concentrations of bromide, strontium, calcium, and lithium.

Jan 1, 1970

By Van E. Shaw

Bastnaesite is a natural rare-earth fluorcarbonate of the cerium group that affords an abundant and high-grade source of the lighter rare-earth elements. A simple and efficient method has been developed by the Bureau of Mines for extracting rare-earth compounds from this mineral. Digesting of a flotation concentrate with sulfuric acid converts the rare-earth compounds from fluorcarbonates to sulfates. Action of the acid releases gaseous com-pounds of fluorine and silicon, leaving the sulfated material free of these elements; carbon dioxide from carbonate decomposition is eliminated at the same time. Calcining the sulfated material at 1,200° F. renders the gangue constituents insoluble, whereas the rare-earth sulfates are left in water-soluble form. Leaching with water yields a solution of pure rare-earth sulfates. Bastnaesite could become prominent as a source of cerium-group rare-earth elements. It is rich in the light rare-earth elements and comparatively easy to process; reserves of the mineral are extensive enough to supply a greatly expanded market for many years.

Jan 1, 1959

By Benton L. Tibbetts

Comprehensive geophysical measurements were made in the Tertiary Channel gravel deposits of Badger Hill, Calif., with the refraction seismograph, gravimeter, and well logging equipment, to develop a three-dimensional physical model of the gold-bearing gravels. Tests were also made of the applicability of magnetometer and electrical resistivity techniques. Results of 14 seismic profiles revealed four distinct layers with velocities of 1,600 ft/sec for loose gravel, 5,900 ft/sec for compact gravel, 8,600 ft/sec for cemented, blue gravel, and 15,500 ft/sec for bedrock. The depth to bedrock along the middle of the channel varied from a minimum of 100 feet in the hydraulically mined pit area to a maximum of about 300 feet in the upper bench area immediately south of the pit. These geophysical methods revealed that 40 percent of the drill holes necessary to delineate the deposit could be eliminated, at a cost saving of at least 30 percent.

Jan 1, 1971

By R. V. Ramani, R. Stefanko, G. W. Luxbacher

MINE VENTILATION NETWORK ANALYSIS

Jan 1, 1977

By M. L. Whisman

Radiotracer techniques were developed for stoichiometric studies of photochemical reactions associated with atmospheric smog formation. Stock blends of separate hydrocarbon and oxygenated compounds were prepared and calibrated. 14C-labeled reactants and products in reaction systems involving hydrocarbons and nitrogen oxides at the ppm level were analyzed for qualitative and quantitative data. Precision and accuracy of these methods developed by the Bureau were determined by replication and statistical treatment of data, and these methods are described.

Jan 1, 1969

By H. William Zeller

The Bureau of Mines performed laboratory research to determine the effects of a barium-based fuel additive on diesel particulate emissions. The test engine was typical of types used to power underground coal min-ing equipment. Test parameters consisted of baseline measurements without additive, three fuel additive concentrations, and five steady-state engine loads, all at 1,200 r/min. Additive effects on soot mass concen-tration, opacity, particle size distribution, volatile fraction, and NOx emissions were determined. Important findings are as follows: Using the manufacturer's recom-mended additive concentration increased the gravimetrically measured mass of particulate by 30 to 80 pct at four of the five steady-state load conditions. Soot measurements by optical methods did not agree with those by gravimetric techniques, for additive-treated fuels. The additive reduced volatile hydrocarbons adsorbed on filter deposits by up to 50 pet. At most engine loads, carbon particulate was also reduced. About 40 pet of the barium added to the fuel was accounted for in the exhaust. The health implications for miners were considered, but no firm conclusions were drawn or recommendations made because the results are for steady-state conditions, which may not be representative of real-world operation of diesel-powered equipment underground.

Jan 1, 1987

By Elaine T. Cullen, Albert H. Fein

Federal law mandates that all miners receive safety and health training when first entering the mining industry and at least 8 hours annually thereafter. Although the mining industry has historically relied on an experiential master-apprentice model for training new employees, the formal safety training provided to miners is generally done in a classroom, with mixed results. In a series of stakeholder meetings held by NIOSH across the West in 1997-2000, trainers identified significant gaps in materials that were available to teach new and experienced miners. They asked whether NIOSH could develop effective materials to fill these perceived gaps, as well as make training more effective for those who were required to attend, but who often refused to be attentive. Adult learning theories, social learning theories, mentoring, and storytelling were all employed in the development of a series of safety training videos that have become very popular in the mining industry. This Report of Investigations describes the theoretical frameworks that were used, the process that was developed to produce the videos, and the results of the evaluations as to whether or not they were effective in training new and experienced miners.

Jan 8, 2005

By W. H. Young, R. L. Anderson

"Physical conditions, such as thickness and character of the coal seam, dip or pitch of the seam, depth of cover, character of roof and overlying strata, mine water, etc., affect the productivity in bituminous-coal mining. Thickness of the coal seam being mined is probably the most important single item that determines whether the output per man per day shall be low or high; however, in strip mining the depth of cover or overburden to be moved is of equal importance.Bituminous coal is mined today from seams of exceedingly variable thickness - less than 2 feet to more than 50 feet; however, a large majority of the mines are producing .coal from seams 3 to 6 feet thick. The average thickness of the coal seams mined in the United States has not changed materially in the past 25 years. The average seam thickness for all bituminous-coal mines was 63 inches in 1920 4/ and 65 inches in 19)45. As thick seams have been exhausted in the older fields, other thick seams, have been opened in the newer fields.Productivity increased from 4 net tons per man per day in 1920 to 5.78 in 1945. This 45 percent increase in productivity resulted from increased mechanization. The percentage of underground production represented by coal cut by machines increased from 61 in 1920 to 91 in 1945 Mechanical loading increased from less than 1 percent of underground production in 1920 to 56 percent in 1945, and strip mining increased from less than 2 percent to 19 percent of the total production during the same period."

Dec 1, 1947

By Frank G. Schwartz

The Bureau of Mines developed a rapid test method for predicting the stability of motor gasoline during long-term storage. The amounts of gum and inorganic residue formed in 13 gasolines during a l6-hour oven test at 200° F were compared with the amounts formed in the same gasolines stored at 110° F, and analyzed following 8-, 16-, 32-, 44-, and 52-week storage periods. Satisfactory methods were developed for predicting gum and inorganic residue formation during fuel storage periods as long as 32 weeks at 110° F, the approximate equivalent of 5.7 years at 80° F. The only data required to apply the methods are the amount of gum and inorganic residue formed, and the amount of oxygen that reacted, during a l6-hour oven test. A direct relationship existed between inorganic residue formed during the oven test and during 110° F storage. Statistical treatment of the data showed predicted values were as reliable as determined values. By use of a modified Arrhenius equation, the 110° F storage time can be extrapolated to equivalent time at any temperature below 110° F. Thus by combining the stability prediction method with the mathematical extrapolation, the storage performance of motor gasoline for extended periods can be estimated at any temperature up to 110° F.

Jan 1, 1968

By Thomas E. Green

A solvent extraction procedure using 8-hydroxyquinoline and chloroform was investigated by the Bureau of Mines as a preconcentration technique for the determination of aluminum, calcium, cobalt, copper, iron, lead, magnesium, manganese, nickel, and zinc in large samples of high purity tungsten. X-ray spectrographic and atomic absorption methods were used to determine the trace metals after preconcentration. The presence of 10 grams of tungsten had a pronounced effect on the distribution of 8-hydroxyquinoline between the aqueous and chloroform phases. This change in the 8-hydroxyquinoline distribution in turn had an adverse effect on the extraction of the trace metals. Extraction efficiencies can also be adversely affected by an increase in the quantity of extractable metals present, as shown by radiotracer tests using 65Zn. Excess 8-hydroxyquinoline in the extracts did not interfere with the determination -of the serious interference in the combined ion exchange paper--X-ray spectrographic method. Although preconcentration by 8-hydroxyquinoline extraction was found to be partially successful, other preconcentrationn methods based on ion exchange and dithizone extraction were found to be superior.

Jan 1, 1968

By Lucia Kuizon

In 1986 and 1987, at the request of the U.S. Forest Service, the U.S. Bureau of Mines studied the Diamond Peak area comprising 183,000 acres in the Challis and Targhee National Forests in order to evaluate its identified mineral resources. More than 3,000 mining claims were located in three mining districts between the years 1882 and 1986. Approximately 230 mining claims in and the 150 claims adjacent to the study area were current in 1986, when Bureau of Land Management mining records were researched for this study. A total of 1,270 samples were collected from these sites (30 were for alluvial placer). Results of the investigation help determine the suitability of the study area for inclusion into the National Wilderness Preservation System. Lead-, silver-, zinc-, copper-, and gold-bearing minerals occur as veins and replacement bodies in shear and fault zones in Precambrian and Paleozoic calcareous Sedimentary rocks that have been complexly folded and faulted. Total production from the three mining districts in the study area was more than 150,000 tons of ore between 1901 and 1982. Approximately 11,600 tons of subeconomic resources consisting of lead, silver, zinc and copper were identified within the area. Over 37,500 tons of lead and zinc subeconomic resources were identified just outside the area. In addition, lead-, silver-, and zinc-mineral resources were identified at 4 mines within 2 miles of the study area. Iron mineral resources were also identified just outside the area.

Jan 1, 1991

By S. J. Schatzel, J. Cervik, A. A. Campoli

The cross-measure borehole technique is being studied by the Bureau of Mines as an alternative to the use of surface gob boreholes as a means of controlling methane in gobs during longwall mining. Small-diameter holes are drilled from underground locations into strata overlying the mined coalbed. When the roof strata are fractured by the mining opera- tion, a partial vacuum applied to the boreholes draws the methane out of the fractured strata and prevents it from entering the mine ventilation system. Tests in the Upper Kittanning Coalbed showed that 50 pct of the methane produced by the longwall mining operation was captured by the cross-measure boreholes. Borehole inclination and penetration into the gob are two important borehole parameters that affect the performance of the cross-measure borehole system.

Jan 1, 1983

By J. M. Gomes

The Bureau of Mines has investigated the occurrence and recovery of by-product heavy minerals from sand and gravel operations as a means of assessing the Nation's resources. Sand samples from 63 locations in central and southern California were treated to yield heavy-mineral concentrates. The mineral compositions of the concentrates were characterized by chemical and mineralogical examinations. Additional large quantities of concentrates were prepared from selected deposits that contained significant quantities. Beneficiation studies were performed on these concentrates to recover individual mineral products. Gold was recovered by amalgamation; platinum-group metals and radioactive minerals by flotation; magnetite, ilmenite, and chromite by magnetic and high-tension separation techniques.

Jan 1, 1980

By F. N. Kissell

The applicability of the "direct method" for determining the methane content of virgin coalbeds was tested. Preliminary results indicate that the direct method, when applied to exploration cores, can be successfully used to estimate coalbed gas content and also approximately predict the total gas emission from a prospective mine located in the coalbed at the exploration site.

Jan 1, 1973

By E. L. Burwell

Application of the in situ recovery process to oil shale was tested during two field experiments near Rock Springs, Wyo. The results of these tests demonstrate that a self-sustaining combustion zone can be created in an oil shale body, that this zone can be moved through the oil shale, and that the process will produce shale oil. Evaluation of the combustion process by monitoring produced fluids for physical and chemical properties and volumes is described. The material and energy balance obtained is compared with a second evaluation based on extensive coring of the test area after the test was terminated. Several side results of the research are noted such as ground surface heating by underground burning and production of low-to medium-Btu gas during retorting.

Jan 1, 1973

By M. A. Lucas

The Bureau of Mines has developed a computerized mathematical model to predict the distribution of accessory elements throughout a metallurgical process. The model can be used to determine process conditions that effect better accessory element control consistent with continued high primary metal recovery. The model presented is specific for determining the bismuth distribution in lead smelting but can be adapted to most extractive metallurgical processes. Thermodynamic, kinetic, and process parameters form the base for the model. Its logic and structure are described in detail.

Jan 1, 1983

By F. P. Miknis

Previous studies at the Bureau of Mines have shown that broad-line nuclear magnetic resonance (NMR) techniques have potential applications for rapid evaluation of oil-shale deposits. In a continuation of this study the techniques of pulsed NMR have been applied in a similar manner. The basis for the pulsed NMR oil-shale assay method lies in the assumption that the free induction decay (FID) amplitude following a 90° pulse is proportional to the potential oil yield. This assumption was tested on two groups of oil-shale samples, numbering 141 and 263 samples, from two different oil-shale cores. For both groups of samples a small number were selected as calibration samples. Free induction decay amplitude measurements were made on the 141 and 263 samples. The best least-squares regression line was obtained for the calibration samples, and the oil yields of the remaining samples were calculated using the slopes and intercepts obtained in the regression analyses. The agreement between measured and calculated oil yields was good, the indexes of determination being 0.93 and 0.89 for the groups of 141 and 263 samples, respectively.

Jan 1, 1974

By D. E. Shanks

As part of its effort to produce cell-grade alumina from clay, the Bureau of Mines investigated the hydrogen chloride gas-sparging crystallization of aluminum chloride hexahydrate (ACH) from aluminum chloride liquor, to provide information for optimizing the crystallization operation. Four parameters important in controlling the crystallization of the aluminum chloride hexahydrate and the concentration of impurities, particularly phosphorus and magnesium, in ACH crystals are (1) aluminum chloride concentration in the feed solution to crystallization, (2) hydrogen chloride gas flow rate, (3) temperature, and (4) concentration of phosphorus and magnesium also in the feed solution. Parameters 1, 2, and 3 affect crystal formation. The combined effects are very important because the phosphorus and magnesium concentrate in the crystals during the early stages of crystal growth. Aluminum chloride hexahydrate of cell-grade purity was crystallized from saturated aluminum chloride solutions containing less than 0.003 wt-pct P205 and 0.010 wt-pct MgO. Crystallization temperatures less than 600 C decreased crystal purity.

Jan 1, 1981

By E. Chin

The production of crude mineral commodities in Bangladesh was limited to natural gas, a small amount of construction materials, and clay for ceramics and bricks. No metallic minerals were mined. The only mineral commodity of economic significance was natural gas. Natural gas production has 'been climbing steadily and becoming an increasingly important source of energy for the country. Proved gas reserves were over 4.5 trillion cubic feet, but the amount has been increasing as exploration discovers large new deposits. Some sources quote reserves at over 10 trillion cubic feet.

Jan 1, 1984

By Wallace W. Roepke, Jon I. Voltz

"The Bureau of Mines determined coal-cutting forces and primary dust generation of four styles of radial gage bits as used on end rings of continuous mining machines. Direct comparisons for reference were made with two widely used conical plumb-bob types having 60° and 90° (nominal) included tip angles. The cutting forces for all of the gage bits were similar to those of the 60°-tip plumb-bob bit. All bits except the RAD-3 gage bit generated similar amounts of primary total dust at shallow cutting, but during deeper cutting, the amounts varied and the gage bits produced as much as 2-1/2 times the dust produced by the 60° bit. This seems atypical since past experience has always shown differences in dust generation at shallow cutting. The specific energy was more like that found previously with other bits, since the values were spread at shallow cutting but became nearly similar at deeper cuts. The 90° bit and the RAD-3 gage bit are not recommended for use except in extremely difficult cutting conditions where dust and forces are of secondary importance. The choice among the remaining four bits can be made on the basis of dust, energy, forces, or cost, as circumstances dictate. INTRODUCTIONThe Federal Coal Mine Health and Safety Act of 1969, with revisions in 1977, was enacted to ensure more healthful and safer working conditions for miners. The Bureau of Mines coal-cutting research facility at Twin Cities (MN) is examining fundamental aspects of the cutting system, including generation of primary dust causing pneumoconiosis in miners and ignition of methane by the frictional impact of cutting bits used on continuous mining machines (CMM's). The cutting system is defined as the cutter-mineral interface area with all its variables, e.g., forces, speed, cutter geometry, bit-mounting geometry, and wear. It has become obvious over the past several years that the cutting system directly affects the economics and design of the ""total system,"" which is defined as all areas of the operation, from the mine face to the preparation plant, which support the mineral recovery by cutting tools to obtain a salable product."

Jan 1, 1983