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By John E. Pahlman

The Bureau of Mines has conducted research on a dual leaching method that offers the potential for the economic recovery of the silver, as well as of the manganese, contained in some domestic manganiferous silver deposits. The method consists of an initial leach of manganese with aqueous sulfur dioxide (S02) followed first by a neutralization rinse, and then by a second leach with cyanide solution for the extraction of silver. Refractory silver in these ores was either (1) intimately associated with the manganese, (2) chemically resistant to cyanide leaching, or (3) rendered inaccessible to cyanide leach solution by the surrounding manganese mineralization. Less than 10 pct of the silver was extracted when minus 2.5-plus 1.3-cm ore pieces were leached directly with cyanide. However, extractions of 25 to 82 pct of the silver and 65 to 96 pet of the manganese were attained in laboratory column-leach tests using the dual leaching method on equivalent-sized ore pieces from seven domestic deposits.

Jan 1, 1987

By R. V. Ramani, R. Bhaskar

"While the National Academy of Sciences has stated that gravimetric sampling technology for compliance purposes is adequate, research into various aspects of respirable dust control require data on many other parameters of airborne dust. These, in turn, have created the need to use many instruments, other than personal gravimetric samplers, in mi ne environments for dust measurement. There is a need to evaluate the performance of these instruments under conditions of potential use.As part of research in the Generic Technology Center for Respirable Dust, cascade impactors, gravimetric personal samplers and gravimetric samplers collecting dust using isokinetic sampling principles were employed for dust measurements under identical conditions in a mine airway. During the course of the experiments, 8-stage cascade impactors and gravimetric samplers drawing air isokinetically were located in the center of a mine airway at various stations. Two types of data were examined - concentration of dust and size distribution of the dust collected in the samplers. The data show that the amount of dust collected by an impactor is less than half the amount collected isokinetically. The size distributions of the dusts collected from the two instruments, though comparable, show a consistent difference in median diameters. The cause for this bias is examined.The paper presents and discusses the results of the tests, including the concentrations and size distributions obtained from the two instruments for different experimental conditions. There is a need to document the performance of various dust measuring devices in mine airflow conditions.INTRODUCTIONThe sampling of airborne dust in mines can be done for several purposes. Traditionally, dust sampling has been restricted to the gravimetric measurement of airborne respirable dust to comply with the regulations governing the mining industry. Instruments such as the MRE gravimetric sampler, and personal gravimetric samplers that have collection characteristics similar to the human respiratory system have been in use for the last two decades. Presently available instrumentation for the purpose of regulation have been considered adequate by the Committee on the Measurement and Control of Respirable Dust in Mines (National Academy of Sciences, 1980),"

Jan 1, 1989

By R. O. Dannenberg

This Bureau of Mines report describes the results of research to develop a process for recovering additional beryllium from a commercial mill waste product, fluoferrate leach residue. Forty-five percent of the total beryllium in the leach residue was recovered in a beryllia product assaying over 98 pct Be0 by a process comprising (1) leaching with 1 N sulfuric acid, (2) adjusting the acidity of the leach liquor to pH 2, (3) extracting the beryllium with di-2-ethylhexyl phosphoric acid (EHPA), (4) stripping the loaded extract with sodium hydroxide solution, (5) boiling the sodium beryllate strip solution to precipitate beryllium hydroxide, and (6) calcining the beryllium hydroxide. Calculated reagent requirements per pound of Be° recovered by a proposed flowsheet were 28.1 lb sulfuric acid, 0.04 lb flocculent, 0.15 lb EHPA, 0.06 lb isodecanol (IDA), 0.22 gal kerosine, and 6.3 lb sodium hydroxide.

Jan 1, 1966

By Rees D. Groves

The Bureau of Mines conducted research on reactions of copper sulfide minerals with chlorine in an aqueous system. Selected samples of covellite, chalcopyrite, chalcocite, bornite, and pyrite were leached with aqueous chlorine solutions. The mineral samples were sized on to minus 100- plus 325-mesh, individually mixed with precleaned sand and leached in an enclosed percolation column. Each mineral was leached in stages to achieve about 90 percent mineral dissolution. The chlorine leaching solutions were produced by reacting sodium hypochlorite with hydrochloric acid within the closed system. The study showed that when the mineral dissolution was complete, the reaction products (copper, iron, and sulfur) were in their highest oxidation states and a stoichiometric amount of chlorine was consumed. Although elemental sulfur formed as an intermediate product, it was oxidized to sulfate during the leach.

Jan 1, 1973

By B. J. Scheiner

The Federal Bureau of Mines has successfully demonstrated an electrooxidation-solvent extraction-carbon adsorption process for recovering molybdenum and rhenium from offgrade concentrates. The flow sequence consists of dissolution of metal values by electrooxidation, liquid-solid separation by thickening, acidification and chlorate ion removal by sulfur dioxide treatment, solvent extraction to concentrate the molybdenum and rhenium, separation of molybdenum and rhenium by carbon adsorption, and metal recovery by crystallization. Molybdenum and rhenium were recovered as ammonium paramolybdate and ammonium perrhenate. Electrolysis of brine-concentrate pulps to generate a hypochlorite oxidizing agent in situ resulted in the dissolution of 98.9 and 99.1 pct of the molybdenum and rhenium, respectively, at an energy consumption of 13.7 kwhr/lb of molybdenum extracted.

Jan 1, 1976

By Stuart Bjorklund

This paper is one of many reporting various aspects of the Bureau of Mines program initiated in August 1939 by passage of the Strategic Minerals Act J the scope of which was greatly expanded by subsequent legislation. In its program of investigation of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. The occurrence of chromite in the Knik Valley near Palmer, Alaska, was brought to the attention of the Bureau of Mines in September 1941 by George Johnson, of Anchorage. At that time a preliminary investigation was made by Robert S. Sanford, an engineer of the Bureau of Mines. The area was investigated on June 4 and 5, 1943, by Henry R. Joesting and Leo H. Saarela, engineers of the Territorial Department of Mines. In August 1942, a second chromite occurrence, the Highway deposit, in the Knik Valley, was reported to the Territorial Department of Mines by John E. Ryan of Anchorage.

Jan 1, 1948

By Perry G. Cotter

The borides of the transition metals in Groups IV and VI exhibit, in addition to a certain degree of hardness, considerable resistance to heat and oxidation. They have high melting points (1,850°-3,060° C.) and low coefftcients of thermal expansion and can be bonded with other materials and hot-pressed to desired shape (cermets). Suggested uses for the borides include use in rockets and jet engines, as thermocouple protection tubes, as containers for molten metals in die casting, as flame-plated coatings on less refractory compositions to prevent erosion by hot gases, and as control rods and neutron shielding material in nuclear engineering, The Federal Bureau of Mines investigation of zirconium diboride started in 1950 at the Boulder City Nev,, Metallurgy Research Laboratory, Its purpose was to reduce the cost of raw materials for the production of zirconium diboride.

Jan 1, 1961

By T. J. Ballard

The Ore Knob mine, in Ashe County, N.C., was one of the largest producers of copper in the eastern states during the 1870's. The ore occurs in a fissure vein, which strikes N. 64° E. and dips nearly vertical. The country rock is granite gneiss. Drilling indicated that the vein structure is approximately 200 feet wide and 1,500 feet long. The vein material shows evidence of replacement of the original gneiss by sulfides. Solution cavities in the vein were noted in some places. The ore minerals and pyrrhotite, chalcopyrite, pyrite, and minor quantities of sphalerite. The gangue contains biotite, magnetite, albite, calcite, and many silicate minerals.

Jan 1, 1948

By A. D. Garman

The mining ordinance of Costa Rica dates from 1830. In spite of the numerous attempts to enact a new ordinance , it has been so much amended and reamended during the hundred years of its existence either expressly or , more often , by implication , and sometimes by Executive Decrees of which the validity has been called in question - that in most cases no one but a lawyer thoroughly conversant with Costa Rican mining practice could properly advise with reference to it . The present attempt at a digest of these laws is based on the 1929 edition of Bolandi and Johanning - the only source available in Washington . Apparently this edition has no official character , and the editors themselves often made surmises although one would think that definite facts would be available in Costa Rica where it was published .

Jul 1, 1930

By William A. Beck

"The Piedmont Manganese Belt extends from Taliferro County, Georgia, 70 miles in a northeasterly direction through Greenwood County, South Carolina, and conforms with the trend of the Piedmont Province. The total area of the belt is reported to be about 1,000 square miles, and the maximum-width is about 24 miles.Manganese has been known to exist in the belt since 1845. M. Tuomey mentioned a deposit in the Edgefield district on Hard Labor Creek in South Carolina in a report on the geology of South Carolina published in 1848.Ore was first mined about the time of the first World War, when the Colley mine, near Lincolnton, Ga., was. Opened. The only operation in the area at present is that of the Abernathy & Kehaya Mining Co., at McCormick, S. C.The geographical position of the belt is from west longitude 82° 57’, north latitude 33° 39' to west longitude 82° 06', north latitude 34° 08'. The towns of Washington and Lincolnton, Ga., and McCormick and Greenwood, S. C., are in or near the belt.An exploratory project of the Bureau of Mines was started on the McCormick, S. C., deposit in April 1944, and trenching, test pitting, and hand-auger drilling-were done on a small scale until early in October 1944. (Fig. 1.) In November 1944 work was begun on a property 12 miles north of McCormick, known as Parsons Mountain, which is leased to M. H. McKnight by the United States Forest Service. From March 15 to March 24, 1945, work was done on the property of Mrs. H. B. Ross, which is known as the Morgan farm.The Abernathy & Kehaya manganese mine contains what is locally known as the Dorn gold mine; mineral rights on the property were owned by M. G. & J. J. Dorn, Inc."

Apr 1, 1946

By D. J. Bauer

A solvent-extraction system employing selective stripping of a pre loaded organic phase was investigated for recovering Sm203 from a light-group rare-earth mixture. The samarium concentrated in the organic phase, and a >99-pct-pure samarium oxide product was obtained at 76-pct recovery in a 20-stage operation using di(2-ethylhexyl) phosphoric acid (EHPA) as the organic phase. The stripping agent was a 1.5-pct hydrochloric acid solution containing 200 g NH4C1/1.

Jan 1, 1972

By George L. Gates

The Bureau of Mines developed a rapid instrumental method of analyzing oil well scales containing primarily barium sulfate. After removal of oil and water by carbon disulfide) the scale was dissolved in strong hydrochloric acid. The cations, barium, calcium, strontium, magnesium, and iron, were determined with the flame photometer using the method of additions. Sulfate was deter-mined colorimetrically after separation by selective adsorption on an alumina column. Phosphate was determined colorimetrically and carbonate titrimetrically. The method was reasonably accurate, although iron and magnesium were found to have mutual interference.

Jan 1, 1965

By Ralph H. Espach

The value of careful fractionation in the manufacture of petroleum products is recognized more and more by petroleum refiners. Recent studies have shown that the quality of the products depends largely on the type of fractionating equipment and on the care used in operating the equipment. For example Rue3 has shown that careful fractionation of pressure distillate will greatly reduce the amount of chemical treatment necessary to produce finished gasoline. The advantages of the combination of pipe still and bubble tower in obtaining good fractionation are well recognized in the petroleum industry. However, the equipment designed in the past has in general been much too large for convenient laboratory use. The present paper describes a continuous-distillation apparatus for the laboratory study of fractionation. This apparatus has given very satisfactory results in the study of different crude oils and petroleum products. A discussion of the theory and action of bubble towers has not been given, as this subject has been discussed previously by Cooke and Rue4. It is believed that the distillation curves of the products obtained from this apparatus show clearly its capabilities.

Jan 1, 1928

By W. L. Anderson

Standard tellurium analytical procedures were modified to obtain the greater sensitivity needed to support a survey of tellurium resources by the Bureau of Mines. Resulting volumetric and spectrophotometric methods for determining tellurium in all types of tellurium-containing materials are described. Sample decomposition and preliminary separations of interfering selenium, gold, and silver are the same in both procedures. The volumetric method is applicable to samples containing a minimum of 10 parts per million of tellurium, In this method the tellurium is reduced to elemental form, and the colloidal suspension is titrated with 0.01 normal iodine solution. The weight of sample for analysis, from 0.25 to 10 grams, should be selected so that the sample contains 0.1 to 5 milligrams of tellurium. To insure accuracy, duplicate samples should be run and the results averaged, particularly on samples of low tellurium content: The limit of determination is 0,001 percent tellurium, which is equivalent to 0.1 milligram of tellurium when using a 10-gram sample. The spectrophotometric method is particularly applicable to low-tenor materials containing from 0.5 to 50 parts per million of tellurium. Up to 10 gram samples are required for making accurate determinations in the low-concentration range. The sample used should contain between 5 and 100 micrograms of tellurium. The turbidity of a colloidal suspension of tellurium prepared from such a sample is determined in a spectrophotometer .t at a. wave-length of 440 millimicrons, and this value is compared with those of standard samples containing known amounts of tellurium.

Jan 1, 1963

By Frank J. Wiebelt

The Carbonate King zinc mine is on the west slope of Kokoweef Peak, Ivanpah Mountains, San Bernardino County, Calif. It has produced more-than 10,000 tons of ore with a 39-percent?zinc content since mining operations began in 1940. The ore, consisting principally of calamine and smithsonite, occurs in replacements of the YellowPine limestone. Milling, has been done from the surface to a depth of 275 feet. Eight holes, aggregating 2,121, feet were drilled by the Bureau of Mines in an endeavor to establish extensions of the worked-out ore bodies and to develop new ones. Although indication of mineralization was found in several of the holes, no new ore bodies were developed.

Jan 1, 1949

By John W. Cole

Ore deposits in the? vicinity of Philipsburg, Mont., have been mined continuously since discovery of the Hope mine in 1865. Although originally famed chiefly for its silver production, since about 1917 the district has been the only important producer of battery-grade manganese ore in the United States. Also, it has produced substantial quantities of zinc ore and during World War I and World War II contributed notable amounts of manganese for metallurgical consumption. Nearly the entire production of base metal ores has been mined from the outcrop area of? a dolomitic limestone bed that plunges beneath overlying beds of limestone and shale northward from the outcrop area. The Hope silver mine, with a production record of over $4,000,000, was in one of the overlying limestone beds about 3,000 feet north of the base-metal producing area and about 1,000 feet vertically above the projected downward position of the dolomitic bed that has produced the base-metal ores. Furthermore, the Hope ore bodies were controlled, in part at least by east-west fractures similar to those that controlled the deposition of the base-metal ores.

Jan 1, 1949

By Richard J. Mainiero

The U.S. Bureau of Mines in cooperation with Jim Walter Resources, Inc. (JWR), Brookwood, AL, evaluated the use of sheathed explosive charges in breaking up large stones that can jam the feeder¬breaker or pan conveyor on longwalls and halt operations. Use of the sheathed charge reduced the downtime of the longwall panel to 15 to 30 min as compared with the 1 to 2 h required to drill and shoot the stone. Firing the sheathed charge at the face caused no significant damage to Iongwall equipment. Use of the sheathed charge also represented an improvement in safety by eliminating the exposure of miners to the inherent hazards of the face for extended periods of time. Another benefit, which is difficult to quantify, is the elimination of the temptation to shoot mudcaps or adobes, which is illegal in U.S. underground coal mines.

Jan 1, 1990

By J. B. Ligon

Blast induced stress waves, propagating along the surface of a drift of an underground hardrock mine, were recorded and analyzed. Resistance strain gages, accelerometers and a velocity pickup were used in making the measurements. Although a full face blast was recorded, the stress waves were initiated by single borehole blasts for the majority of the project. A special instrument trailer was designed, constructed and utilized during the project. A reliable strain wave transducer was developed for measuring the stress waves propagating on the drift surface. A correlation study between strain and acceleration signals for P-waves was made which agreed well with theory. The use of stemming was found to reduce strain and acceleration magnitudes as predicted.

Jan 1, 2011

By Deno Pappas, Gregory Molinda, Eric Bauer, Christopher Mark, Daniel Babich

Groundfalls are much more likely to occur in coal mine intersections than in entries. NIOSH is using the experience of U.S. coal mines to determine the factors which influence intersection instability and provide guidelines for the safe excavation and support of intersections. Detailed field investigations have resulted in a database of U.S. coal mines containing 12 mines and 639 roof falls so far. By using the roof fall rate as the outcome variable, correlations between roof geology (CMRR), intersection span, and roof support have been established. Case studies have indicated that replacing 3- way intersections with 4-way intersections may not reduce the total number of roof falls. Additionally, the size of intersection spans tend to decrease with lower (weaker) CMRR. Protocols have been established for the collections of roof bolt parameters. The performance of individual roof bolts can now be tracked with roof fall rate.

By Helen W. Lang

This report describes a monitoring system applied by the Bureau of Mines to provide rapid, continuous determination of the main constituents of exhaust gas during the Bureau's approval schedule testing of diesel engines for under-ground use. Commercially available continuous analyzers with strip chart readout are employed for nitric oxide (mass spectrometric), carbon dioxide (nondispersive infrared), methane (NDIR), carbon monoxide (NDIR), and oxygen (polarographic). Good correlation is obtained between the continuous instrumental results and those obtained by batch chemical and gas chromatographic methods.

Jan 1, 1969