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By R. V. Ramani, R. Bhaskar

"The National Academy of Sciences (1) recognized the importance of studying the spatial and temporal characteristics of respirable coal mine dust atmospheres. In this paper, the progress to date of a research project on dust transportation and deposition in mine airways is presented. A mathematical model is proposed for studying the transport of dust. A source representative of dust generation in underground coal mining is defined. The influence and applicability of surface roughness, dispersivities, coagulation and reentrainment to vine dust flow arc examined. A convective-diffusion model is proposed for the transport and deposition of dust in mine airways. Using the model, the spatial and temporal characteristics can be evaluated in terms of dust concentrations in the mine atmospheres.INTRODUCTIONThe prediction of the behavior of fine particles Is Important in many fields of science and engi¬neering including physics, chemistry, mining, mineral processing, and atmospheric science. In mining from the health point of view, fine coal dust is associated with the appearance of pneumoconiosis in miners exposed to the dust. Also, in addition to being a nuisance factor obscuring visibility and general mobility of miners, it can lead to sudden catastrophic incidences of explosions. This paper outlines the progress to date of a research project on dust transportation and deposition in mine airways. A mathematical model is proposed for studying the transport of dust for the various mechanisms. The dust dispersion is defined in terms of a dispersion term determined from experimental data by Skubunov (23). Coagulation is considered as one of the mechanisms that can lead to changes in the particle size distribution. Reentrainment as a possible secondary source of dust was examined during model development but was not included in the final model."

Jan 1, 1988

By James C. Cawley

This National Institute for Occupational Safety and Health study was conducted to focus future research on the most significant electrical problems in the mining industry. Data from 1,926 mine electrical accidents (including 75 fatalities) that occurred between 1990 and 1999 were studied. Coal and metalnonmetal operator- and contractor-reported data are presented. All data used in this analysis were MSHA closeout data, except 1999, which were preliminary data.

By Raja V. Rarnani, Robert L. Frantz

"Mining is one of the oldest of human occupations. The awareness of occupational illnesses associated with mining, even in ancient times, is evident from the writings of Hippocrates (460-370 BC), Pliny and Elder (AD 23-79), and Galen (AD 131-210). Georgius Agricola (1494-1535), in his De Re Metallica, refers to the diseases of miners and the need for their control through good planning and operating practices and responsible management (Schwerha, 1989). Coal workers' pneumoconiosis (CWP), often called Black Lung disease, is an occupational disease which results from inhalation of coal mine dust which usually contains relatively small amounts of free crystalline silica.A pneumoconiosis is best defined as the accumulation of dust in the lungs and the tissue's reaction to its presence [Lapp and Castranova, 1993]. Silicosis is the name given to the fibrotic disease of the lungs caused by the inhalation of dust containing silicon dioxide, primarily in the free crystalline form. Silicosis is the older and more well known of these mineral pneumoconioses. In contrast, CWP was not recognized as different from silicosis until the pivotal work of Collis and Gilchrist [1928].The U.S. Bureau of Mines (USBM) still regards worker exposure to respirable aerosols in mines as the most serious health problem in mining [USBM, 1994]. The National Institute of Occupational Safety and Health (NIOSH) is considering recommending a reduction in the standard for occupational exposure to respirable coal mine dust from 2 mg/m3 to 1 mg/m3 [NIOSH, 1993]. The Mine Safety and Health Administration (MSHA) may require new criterion for sampling procedures in the mine that would evaluate the ambient dust concentration in the mine atmosphere based on a single sample, instead of the current practice of averaging five samples (MSHA, 1992; Ramat* 1993). Several high-production longwall mining faces currently have extreme difficulty meeting the existing dust standards, and some already operate at reduced production levels to achieve mandated levels [USBM, 1993]. The importance of adequately protecting the miners from high concentrations of coal mine dust, as well as of reducing the incidence and severity of the Black Lung disease, cannot be overemphasized. The importance stems, first and foremost, from the humanitarian viewpoint and, second, from the perspective of the overall welfare of the coal industry.The histopathologic hallmark of CWP is the coal macule (Balaan, Weber and Banks, 1993). Autopsy or open lung biopsy reveals the coal macule to be an amorphous mass of coal particles, dust-laden pulmonary macrophages, reticulin, and collagen. No pathognomonic signs or symptoms identify workers with CWP. A CWP diagnosis requires that the worker experienced the appropriate dust-exposure setting (e.g., underground coal mining) and duration (usually 10 years or more) and, has the characteristic chest radiograph. Based upon the International Labour Organization (ILO, 1980) international classification, pathologists and radiologists have established case definitions for characterizing the pathology and the appearance of CWP on chest radiography (Weeks, 1993). CWP appears in two principal forms: simple, with small opacities, and complicated, with opacities larger than 10 mm in diameter. For all practical purposes, diagnosis of CWP in the living miner is wholly dependent upon the chest radiograph interpretation."

Jan 1, 1995

By E. J. Schneider

In view of the current interest in the constituents of low-temperature tar, the Synthesis of three known xylenols and their hydroxyacetic acid derivatives has been undertaken by the U. S. Bureau of Mines. One of these xylenols, the 1,3,2 derivative first reported by Steinkopf and Höpner,4 has been described by Brown and Branting.5 The other two derivatives, the 1,3,5 first reported by Schütz6 and the 1,2,3 reported by Steinkopf and Höpner, have now been studied in greater detail. In the present work the synthesis of 1,2,3-xylenol and 1,3,5-xylenol was repeated, with some improvements in the former. The hydroxyacetic acid derivatives were also prepared, and it was found that while the melting point of the 1,2,3 derivative agreed with that of Steinkopf and Höpner. that of the 1,3,5 derivative was found to be 111° instead of 85 to 86° as reported by Schütz, by Steinkopf, and later by Bruckner. The discrepancy between the melting-point figures is doubtless due to differences in the purity of the xylenols used in the synthesis of the acids. Schütz obtained his 1,3,5 acid by recrystallizing an impure sample obtained from a mixture of xylenols. The difficulty of obtaining a pure acid by starting with a mixture is demonstrated by Bruckner, who despite painstaking efforts was unable to obtain the pure 162.5° melting 1,2,4 isomer from a mixture that persistently melted at 138° C. Steinkopf did not repeat Schütz's work but merely used the latter's figures in compiling a table. Bruckner, on the other hand. apparently also made the acid (by an improved method), and it is difficult to explain his checking Schütz's figure, unless it is that he, too used a symmetrical xylenol obtained from a tar and not prepared synthetically, as was the one reported in this paper.

Jan 1, 1929

By R. D. Leitch

The work of the United States Bureau of Mines on stream pollution3 by coal-mine drainage has included a study of seasonal variations in acidity and volume of several streams in Pennsylvania. The acidity of these streams has been determined during the two or three years prior to 1930 and the results may be considered to represent "normal" low water conditions. The summer of 1930, however, was unusually dry and represents what may be termed "extreme" low water conditions on these streams. This report is a comparison of the results obtained for extreme low water of 1930 and for other years. The streams investigated were Buffalo Creek in Somerset County, Indian Creek (lower 5 miles) in Westmoreland County, Little Toby Creek in Elk and Jefferson Counties, Daguscahonda Run in Elk County and West Creek in Elk and Cameron Counties. These will be treated separately in the order given. Most of the descriptive matter and physical data pertinent to the streams and drainage basins are taken from published reports of the Pennsylvania State Water Supply Commission, 1917.4

Jan 1, 1931

By Carlton E. Brown

Broom and Yant6/ recently described a. microprojection method for determining the particle-size distribution and number concentration of samples of dust collected from the air by such samplers as the Owens jet dust counter) and the thermal precipitator8/ . This method was developed to obviate or reduce the eyestrain consequent to the regular filar-micrometer method9/ and to save time and work. The article stated that work was in progress on a micrcprojection method for counting impinger dust samples; this article describes the method developed. ACKNOWLEDGMENTS The assistance of the personnel of the ventilation Department of the Anaconda Copper Miring Co., Butte, Mont., in developing this method and particularly in suggesting a suitable material to use for the microprojector screen is sincerely appreciated. Much of the work was done in the laboratory of the Anaconda Copper Mining Co. on samples collected in Butte mines during a cooperative study with this Bureau.

Jan 1, 1938

By H. W. Davis, W. W. Adams, O. E. Kiessling

"Current economic problems frequently have focused attention upon the lack of adequate quantitative information indicating the relationship between human effort and output in various branches of the mineral industry. With the exception of complete records covering coal mining, only scattered information on the units of human energy required to produce a unit of raw material is available for most of the important industrial minerals. Fortunately a virtually complete statistical record is available covering this phase of the iron-ore mining industry.For many years iron-ore mining companies, whose interest in safety work is well-known, have reported annual data on employment to be used in the compilation of accident statistics. These data on hours of labor and other detailed employment information have been correlated with the statistics on production also reported annually by producers. The outstanding trends shown by this composite record for the 10-year period 1923-32 are included in the following discussion, supplemented by a summary table that presents the principal statistical background of the study. 5The substantial reduction in the number of men needed to produce the annual iron-ore requirements of the United States, as shown strikingly in the graphs, illustrates that in iron-ore production improvements in technology have been consistently winning a battle over the difficulties of nature. In 1923, for example, 41,294 men working 107,551,244 hours were required to produce 69,351,442 gross tons of merchantable ore, equivalent to an average output of 0.645 ton per man-hour. In 1929, however, only 30,763 men working 77,111,686 hours 'zero required to produce 73,027,720 tons of merchantable ore, equivalent to an average output of 0.947 ton per man-hour. Thus, from 1923 to 1929 the average number of men working decreased 25.5 percent and the total man-hours worked 28.3 percent, while the average output per man-hour increased 46.8 percent and total merchantable ore production 5.3 percent."

Feb 1, 1935

By Ellis S. Hertzog

The material published in this report is part of a special study of some of the chemical and physical properties of Alabama coals. The complete study included friability and grindability determinations, high and low temperature assay distillation tests, and ash fusion-temperature determinations. Proximate and ultimate analyses and. calorific values of the coal samples also were obtained. This paper is concerned only with grindabilities, although proximate analyses have been included to give a better picture of the problem as a whole. The growing interest in grindabilities of coals is a result of the increase in use of pulverized fuel in REscent years. The tenative ball-mill grindability method D409-35T4/was used in making all the determinations. The method of sampling and the technic of the testing procedure is described in Considerable detail in this report because the procedure was established quite recently. The ball-Mill grindability index is a measure of the ease with which coal may be ground, which may be an important factor in estimating pulverizing costs. Up to the present time few data on the grindability of Alabama coals have been published. The data in this paper show that the Warrior and Cahaba fields exhibit a wide range of grindability in their coals. The mines tested are well distributed throughout the productive areas of these fields, and it is possible to make rough estimates of the grindabilities of coals not listed in this report from the data given for mines situated in the same vicinity. ACKNOWLEDGMENTS This study was conducted at the Southern Experiment Station of the Bureau of Mines in cooperation with the University of Alabama. The Alabama liming Institute was of great assistance in furthering the investigation, and the work was undertaken largely as a result of its request that the Bureau of Mines should make certain studies of Alabama coals. Grateful acknowledgments

Jan 1, 1938

By Martin J. Gavin

During the present study of lubricating oils in the San Francisco laboratory of the Bureau of mines it became desirable to distill oils used in the experimental work at pressures as low as 10 mm., (mercury column) absolute. In the effort to overcome difficulties and eliminate sources of error the apparatus described below was finally developed. The distilling flask is essentially the Hempel flask used by the Bureau of Mines for the analytical distillation of petroleum3. The complete apparatus is shown in Figure 1. As air leakage at connections is an ever present or potential source of difficulty and error in vacuum apparatus, the, mouth of the flask is drawn down to one cm. internal diameter which materially simplifies obtaining an air-tight seal at this point. Before reducing the mouth, the spray screen is inserted and adjusted in position.

Jan 1, 1927

By P. L. Sibrell

Electrorefining of Ti in nonaqueous solvents has been studied by the U.S. Bureau of mines as a method for recycling impure scrap Ti. Electrochemical behavior of Ti species was investigated using cyclic voltammetry. Research results showed that Ti metal can be dissolved in polar solvents such as dimethylformamide or dimethyl sulfoxide. However, deposition of Ti from these solvents was not successful. Several solvent systems were investigated for electrodeposition of Ti but no deposits were obtained. Reduction of Ti4+ complexes to Ti3+ proved to be straightforward, but reduction to lower oxidation states could not be confirmed. In dimethylformamide solutions, cyclic voltammetry results demonstrated the reduction of Ti to an oxidation state of less than three, but no Ti metal was identified. In dimethyl sulfoxide solutions containing LiCl, it was possible to deposit Li metal. After adding Ti salts to the solution, electrolysis quickly passivated the electrode. Deposition of Ti was also investigated in solutions of dimethoxyethane and propylene carbonate but, again, no reduction of Ti to oxidation states of less than three occurred. Therefore, the prospects for a nonaqueous electrorefining system for Ti metal do not appear promising.

Jan 1, 2010

By Glenn E. Johnson

The Bureau of Mines investigated the production of hydrogen cyanide by reacting powdered coal (minus 300 mesh) with ammonia at 1,250° C in a bench-scale study. Both metallic and ceramic reactors were used. Yields up to 0.7 cu ft of hydrogen cyanide per cubic foot of ammonia consumed r- obtained. The resulting ammonia conversion of about 75 volume-percent approximates conversion obtained commercially in processes utilizing natural gas and platinum catalysts. The coals that had higher volatile-matter contents gave the best yields of hydrogen cyanide. Allowing the coal to adsorb ammonia before reaction resulted in increased yields of hydrogen cyanide. Cost studies for a plant with a 40-million-pound-per-year capacity indi-cate that hydrogen cyanide can be profitably coproduced with carbon black, from coal and ammonia, at the current market price of hydrogen cyanide (11.5 cents/lb). These figures are based on heating the reactor electrically. If a cheaper heating method were devised the economics of the process would be more favorable.

Jan 1, 1967

By K. Robert Dorman

Spray-applied polyurethane foam was used to insulate the walls of heated rooms excavated in permafrost. The experiment was designed to determine whether polyurethane foam can be sprayed successfully on frozen ground under freezing conditions and to measure the effectiveness of the insulation in maintaining--at elevated temperatures for an extended period--a room excavated in frozen ground. Two manufacturers' foams were investigated in the laboratory. Subsequently, one of the foams was employed to insulate two small rooms, one in frozen gravel and one in frozen silt, in an experimental tunnel belonging to the U.S. Army Cold Regions Research and Engineering Laboratory (USACRREL) near Fairbanks, Alaska. Following insulation, heat was introduced into the two rooms. Heat migration across the insulating barrier into the walls, in addition to wall closures, was monitored over an 8-month period. The results show that polyurethane foam can be successfully sprayed on frozen ground in below-freezing temperatures. Given this type of insulation, together with winter cold to supercool the surrounding ground, it should be possible to maintain a shaft or heated room in permafrost for several years.

Jan 1, 1970

By M. D. Carver

This investigation was undertaken by the Bureau of Nines to determine the effects of impurity levels on the mechanical properties of columbium at low temperatures. High-purity, electron-bombardment-melted columbium was purchased and used as a basis material. Variations in impurity levels were obtained by arc-melting charges containing definite amounts of added impurities. Tensile tests were conducted at low temperatures. Results showed the almost pure basis metal to be ductile at minus 194° C., the lower limit of the range used, Ductility of less pure columbium appeared to depend on interstitial element content. The ductile-to-brittle transition temperature appeared to be raised by increasing carbon content in the range of 50 to 730 parts per million, nitrogen content in the range of 50 to 200 parts per million, or total interstitial element content in the range of 240 to 1,380 parts per million. Some evidence was obtained indicating that decreasing cold work also raised the transition temperature, but recrystallization appeared to have no effect on it. Variations in interstitial element levels appeared to have little or no effect on ultimate strength of columbim in the range of room temperature to minus 194° C, Physical metallurgy studies of massive arc-melted and electron-bombardment- melted columbium were included in the columbium-tantalum research work assigned to the Albany Metallurgy Research Center in fiscal year 1959.

Jan 1, 1961

By Pedro Lilienfeld

The objective of this program was the development, design, and fabrication of six personal-sized completely self-contained dust monitors capable of real-time as well as time-averaged monitoring of the concentration of respirable particles in coal mines, in the range of 0.1 to 100 mg/m3. The operation of these monitors is based on light scattering and passive air sampling. The design stressed overall miniaturization, ruggedness, simplicity and versatility. These instruments incorporate a single-chip CMOS microprocessor to perform all signal processing, data display and storage, and timing functions. The overall dimensions of these devices are, approximately, 10 by 10 by 5 cm.

Jan 1, 1982

By Robert L. Mentch

CADMIUM is one of the metals apparently destined to remain relatively scarce. The en tire supply of primary cadmium is recovered as a byproduct, concurrently with the treatment of ores of other metals. Development of the cadmium industry is attributed to metallurgical improvements in the zinc industry; output depends almost wholly upon zinc production. Cadmium is a metal of specialized uses where its superior performance has developed a strong, expanding demand. The supply, however, has been relatively unresponsive to price because of its byproduct nature. Cadmium's outstanding properties would assure it a manyfold greater market if more were available at lower prices.

Jan 1, 1958

By William J. Campbell

This analytical method development and evaluation was undertaken by the Bureau of Mines to provide accurate determinations of eight minor elements in low-alloy steels prepared from ferrous scrap. Fluorescent X-ray spectrography was the principal method investigated. Confirming analyses were made by conventional instrumental and chemical methods. All X-ray data were processed by a timesharing computer. No corrections were found necessary for inter-element effects or overlapping spectral lines. Concentrations were calculated from the least-square fit of a linear calibration equation derived from measurements on three sets of standard steels. These studies show that X-ray spectrographic analysis of lathe-finished surfaces provides accurate determinations of aluminum, copper, chromium, manganese, nickel, phosphorus, silicon, and tin.

Jan 1, 1973

By K. E. Tame

The Bureau of Mines is studying possible modifications in conventional uranium ore-processing steps to confine and permit controlled disposal of radioactive wastes. Surveys of Ra226 contamination of liquid wastes from uranium mills indicated that the Vanadium Corporation of America plant at Durango, Colo., had one of the more urgent problems. A possible procedure for minimizing the waste disposal problem was to reuse the waste solution in the mill--in effect, erasing the need for disposal of liquid waste. In examining this possibility, interlocked bench-scale leaching and solvent extraction tests simulating the Durango flowsheet were made. The simulated reuse of barren raffinate for leaching and washing was carried through three separate campaigns of 9, 12, and 35 cycles each.

Jan 1, 1961

By Robert C. Ellman

Stockpiles containing 2.3 million tons of lignite constructed in the period 1948-56 in conjunction with the construction of Garrison Dam on the Missouri River demonstrate successful stable long-term storage of lignite. Uniform and thorough compaction of each of the I-foot-thick layers by which the piles were constructed produced a bulk density of 70 Ib/cu ft. Air penetration into the stockpiles was restricted to a degree that prevents spontaneous heating or deterioration of the stored lignite, A continuing record of observations beginning with stockpiling operations in 1948 has been accumulated, This includes periodic fuel analysis, analysis of pile gases, and measurement of pile temperatures on the first large stock-pile, pile 5. This report describes the stockpiling method, the changes in heating value, pile gas composition, and pile temperature and summarizes observations from 1953 to 1964, Data accumulated attest to the stability of the stored lignite. The variation of the average heating value of periodic pile-depth samples is only 160 Btu/lb (11,990 to 11,830) on the moisture" and ash-free (maf) basis during almost 10 years of storage. Temperature levels of the pile interior are progressively decreasing. At pile surface, cyclic variations occur with the season. The only problem encountered with the large stockpiles is wind and water erosion of the pile surface. The partially successful control measures used are described.

Jan 1, 1967

By G. W. Jones

An important activity of the Bureau of Mines is the promotion of safety in mining and industry. As a part of this program, the Bureau determines the explosion hazards of combustible gases, vapors, and solids and investigates means of controlling and preventing explosions. The limits of inflammability (explosive limits) of combustibles are not only of theoretical but also of practical importance, because many industries at one time or another contend with explosive mixtures of combustible gases or vapors in their manufacturing processes. At present many new organic compounds are being manufactured, transported, and used in huge quantities which a few years a ago were only laboratory curiosities.

Jan 1, 1941

By T. Estelle Gardner, A. R. Taylor

Heat capacity measurements were made on sodium bromide ( NaBr ) and sodium iodide ( NaI) in the temperature ranges of 7 ° to 300 ° K and 56 ° to 300 ° K using an adiabatic calorimeter . Smooth values of heat capacity, entropy , enthalpy function , and free- energy function were calculated from the heat capacity data at 10° K intervals and at 273.15° and 298.15° K. Entropy and free energy of formation values at 298.15° K also were calculated for the two compounds using entropy values determined in this study and other data reported in the literature . The entropy values calculated at 298.15 ° K were 20.75 ± 0.06 entropy units (eu ) for sodium bromide and 23.55 ± 0.07 eu for sodium iodide .

Jan 1, 1964