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By EJ. Reichhardf

The Molopo Farms Complex is a major, layered ultramafic/mafic, early Proterowic intrusion which is totally covered by sediments of the Karoo and Kalahari Fonnations and situated in southern Botswana and northeastern South Africa. The approximately 3000 m thick, generally fine- to medium-grained ultramafic and mafic cumulates are intrusive into equivalents of Thmsvaal Supergroup sediments and lavas. Multiphase defonnation resulted in tilting and segmentation of the Complex into individual tectonic blocks. Sr isotopes document at least two chemically distinct parental liquids which interacted in a complex manner to form an approximately 1000 m thick rhythmically layered succession which straddles the ultramafic/mafic boundary. Repeated mixing resulted in a complex cryptic layering pattern and numerous sulfide-enriched layers which contain significant PGE+Au concentrations.

Jan 1, 1994

By G. E. Rodger, R. Jugoon

"SUMMARYSamples of Aunor gold precipitates which varied widely in gold content were fluxed to produce a bisilicate slag with various oxidizers and combinations of oxidizers. On the basis of some preliminary tests a flux composition was chosen which appeared to show the most promise.The different components of this flux were then incorporated into a matrix for a 23 factorial design experiment to determine what were the most important variables and what changes should be made to the flux composition to optimize the resultant total bullion fineness.The results of the 23 factorial design experiment showed that the flux composition as calculated was very close to an optimum as only very minor changes were required to give bullion in excess of 995 fine.INTRODUCTIONEarly in 1969 the results from the Aunor Gold Mines refinery showed that wide variations existed both in precipitate grade and in total bullion fineness. An analysis of this data showed that as the precipitate grade increased, the gold bullion fineness also increased (see appendix 1). Therefore, to improve the refinery results test work was initiated to: 1) improve the precipitate grade and 2) to determine, with the help of statistics, a flux composition which would be able to handle wide variations in precipitate grade and give a total bullion fineness in excess of 950 fine."

Jan 1, 1970

By J. Wild, M. Ounpuu, G. Chevalier

"The requirements for a finer grind at Heath Steele have resulted in the investigation of agitated milling as a cost effective alternative to conventional tumbling ball mills.The grinding unit is a vertically agitated, or stirred ball mill. Grinding occurs as the result of the motion of a single vertical rotor equipped with protruding pins which impart a stirring action to the ball charge. A comparative evaluation of a 30 kW SALA Agitated Mill (SAM), and a 1.5 m x 2.5 m copper-lead regrind ball mill has been conducted at Heath Steele.An overview of agitated milling as it applies to the reduction of sulphide ore will be the primary topic for discussion. Specific parameters including energy efficiency, media consumption, operating costs, and the mechanical aspects of the SAM operation will be presented.Evaluation of the agitated mill has shown that improved grinding performance at much lower work indices than those of the conventional ball mill is possible. Media consumption has proven to be comparable on an average g/kWh basis, but the mechanical availability of the mill has been low.INTRODUCTIONConventional tumbling ball mill grinding has proven to be an energy inefficient process. Energy losses occurring within the ball mill itself can be attributed to particle friction without breakage, kinetic and potential energy losses, plastic and elastic deformation and the production of heat and sound (Lynch, 1977). It can be generally stated that a certain amount of the input energy will be converted to another form as a necessary by-product of particle breakage. Theoretical interpretation of experimental results indicate that the energy required for breaking the ore particles in a ball mill varies between I% and 25% of the total energy input (SME, 1985)."

Jan 1, 1993

By M. Proulx

"RÉSUMÉ Le diagramme ternaire Al2O3-Sr-Y est un nouvel outil servant à l’exploration de gisements de sulfures massifs volcanogènes (SMV) archéens. Le diagramme permet de discriminer entre les roches volcaniques à minéralisations à zinc dominant (domaine Zn+) et celles à minéralisations à cuivre dominant (domaine Cu+), ainsi que les roches volcaniques ayant subi une chloritisation hydrothermale pouvant aboutir à la formation de chloritites associées aux cheminées d’altération (domaine Cl+). Ces trois domaines délimitent des zones d’influence géochimique ou d’empreintes hydrothermales résiduelles ou fossiles produites par les cellules de convection hydrothermales générées par des magmas. Le diagramme permet aux sociétés d’exploration de déterminer de façon peu coûteuse la fertilité potentielle des roches volcaniques archéennes en ayant recours à leurs bases de données et aux résultats de leurs analyses de terrain, sans aucune manipulation des données. Le diagramme ne s’applique pas aux SMV aurifères.ABSTRACT The tertiary diagram Al2O3-Sr-Y is a new tool to explore Archean volcanogenic massive sulphide (VMS) deposits. The diagram can be used to discriminate between the volcanic rocks where zinc is the dominant mineralization (Zn+ domain) and the rocks where copper is the dominant mineralization (Cu+ domain), as well as the volcanic rocks that were subjected to hydrothermal chloritization that could have led to the formation of chloritites associated with alteration chimneys (Cl+ domain). These three domains define the zones of geochemical influence, or residual or fossil hydrothermal footprints produced by hydrothermal convection cells generated by magmas. Exploration companies can apply the diagram to determine, at low cost, the potential fertility of the Archean volcanic rocks by using their databases and the results of their field analyses, without any data manipulation. The diagram does not apply to gold-bearing VMS deposits."

Jan 1, 2015

By J. C. Ingles

"A survey of possible methods for controlling cyanide concentration indicated that the simplest method would involve the use of a potentiometric technique. Such a method was suggested by a paper from the laboratory of Mines Safety Appliances, which described a method for determining hydrogen cyanide in air. In this application, the cyanide was absorbed in caustic and a silver electrode immersed in the caustic solution provided a measure of the cyanide concentration. However, our attempts to use the silver electrode in this simple manner to measure the cyanide concentration of solutions were not very successful. A study of the mechanism by which a silver electrode responds to cyanide concentration made it evident why this simple procedure is not satisfactory.Basically, the silver electrode provides an indication of the free silver ion concentration of a solution, and generally speaking, ignores the other ions' present. It can be used to measure an anion if this anion complexes silver. This technique has been used in complexing studies to determine the activities of such anions as acetate, citrate, oxalate and chloride. To do this, the electrode has to be placed in a solution which initially contains a known concentration of free silver ions. Addition of the complexing anion causes a drop in the free silver ion concentration and hence a change in the potential of the silver electrode. The change in potential can be expressed in terms of the concentration of the complexing anion, and used to indicate its concentration in the solution being analysed. The determination of chloride-ion by a silver-silver chloride electrode is an example of an application of this technique. The solubility of the silver chloride with which the electrode is coated provides the initial free silver-ion concentration. Depression of this free silver-ion concentration by the presence of the excess chloride ion of the sample solution results in a change in the potential of the electrode which is proportional to the chloride-ion concentration."

Jan 1, 1965

By Sadan Kelebek, S. O. Fekete, Gerhard W. Heinrich, Peter F. Wells

"For many years, rejection of pyrrhotite at the milling stage has been a viable method for sulphur dioxide abatement. Pyrrhotite rejection options have included the use of selective pyrrhotite depressants in flotation; a depressant which has recently come into use is diethylenetriamine (DETA). This reagent has been the subject of recent research and development efforts in the processing of nickel-copper sulphide ores.In the present study, adsorption trends for DETA have been monitored under the dynamic conditions of flotation using a spectrophotometric method which has been adopted for this purpose at Falconbridge Limited. The results indicate that the adsorption of DETA is quite fast and in the majority of cases, accounts for the disappearance of 75-95 % of this reagent from pulp's liquid phase. The adsorption decreases linearly with an increase in the DET A dosage from 100 git to 600 git. The tailings produced in flotation tests were subjected to washing with deionized water at 60 °C to examine the desorption of DET A. These results indicate that the amount desorbed increases with increasing DETA dosage used during flotation but is less than 7 per cent of that adsorbed. It was found that adsorption of DETA alone, even at relatively high levels, does not always cause depression of pyrrhotite. A new combination of reagents identified in the metallurgical laboratories of Falconbridge Limited utilizes sulphur dioxide with DETA. These reagents together are capable of efficient depression of pyrrhotite on a consistent basis."

Jan 1, 1995

By I. Orford, V. Rozon

"The Sä Dena Hes Joint Venture Mill was designed to process 450,000 tonnes per year of ore grading 11.3% lead and 13.2% zinc.Run of mine ore is crushed in a jaw crusher and then ground in a closed circuit SAG mill and ball mill. A standard differential float in conventional flotation cells produces quality lead and zinc concentrates. Dewatering of concentrates is achieved using high rate thickeners, lamella clarifiers and pressure filters. Process water is 100% recycle.Plant design was based on metallurgical test work performed on drill core samples. The plant is operating at better than design specifications.INTRODUCTIONSä Dena Hes Joint Venture was formed in 1989 to develop the Sa Dena Hes lead/zinc sulphide mine, located approximately 45 km north of the Town of Watson Lake, Yukon. The mine is owned by a Joint Venture partnership between the operator, Curragh Inc. (87.5%) and Hillsborough Resources Limited (12.5%).The project was completed in a record ten months, working throughout the severe Yukon winter and through an abnormally wet spring and summer. The first truckloads of concentrate were shipped from the mine on August 1, 1991.The mill currently processes 550,000 tonnes of ore per year grading 6.9% lead and 11.5% zinc. Ore is crushed in a jaw crusher and ground to 60% passing 75 microns in a closed circuit operation of one SAG mill and ball mill. Using conventional flotation cells a 150,000 tonnes of concentrate is produced in a year with lead concentrate grading 78% lead and a zinc concentrate grading 60% zinc at overall recoveries of 89% and 90% respectively.Concentrates dewatering is accomplished using high rate thickeners, clarifiers and pressure filters. The lead concentrate and zinc concentrate contain 5.4% water and 7.8% water respectively. Concentrates are trucked to Skagway, Alaska for subsequent shipping to overseas smelters."

Jan 1, 1993

By W. A. Grell

"The oxygen meter has been in use at MacLeod Cockshutt Gold Mines for over a year, At MacLeod about 200 tons per day of reground concentrate containing roughly 10% pyrrhotite and 20% pyrite is cyanided in four 181 x 18' Dorr agitators. A survey by the Department of Mines showed that oxygen content of some of the agitators was rather low. Experience with our oxygen meter indicates that the oxygen content must at times have been too low for good gold dis solution.We have found that in winter, when pulp temperatures drop to about 50° F, oxygen saturation in the agitators is not difficult to maintain. In summer, however, when pulp temperatures rise to 70or 75°F, the oxygen content will drop very readily. It was found that a high oxygen content can be maintained readily if the pulp is sufficiently dilute. Thus at 50° F, a pulp of specific gravity 1. 75 i.e., about 55% solids, will saturate; but at 70 or 75° F, the specific gravity must be decreased to 1 .45, equivalent to about 40% solids, in order to maintain saturation. Very thick pulps, such as thickener underflows, are noticeably difficult to saturate in the laboratory, and lose their oxygen rapidly.Clear solutions, on the other hand, absorb oxygen readily and hold it. The primary thickener overflow, before agitation, is 100% saturated; after storage of 3 to 4 hours it is still 100% saturated at re clarifier tank. Barren solution after spraying in a launder is 100% saturated.We have not yet attempted to determine what percentage saturation is necessary for good extraction, but it is known that there is a point at which extraction decreases rapidly. So far, the measures required to maintain over 80 or 90% saturation have coincided with measures required to hold the reducing power to the point believed necessary."

Jan 1, 1964

By A. Jain

During sheet forming, metal experiences not only multi-axial load, it also undergoes strain path changes. For example, metal in the flange region may be drawn, may bend and unbend through a bead, before bending around a die radius, etc. Compression data were obtained from AZ31 sheet after pre-straining in compression along an orthogonal direction. The compression directions correspond to the sheet product (rolling-RD, transverse-TD, and normal-ND) directions. Three cases are examined: slip dominated deformation (ND) followed by twin dominated (RD or TD) deformation, twin dominated (RD or TD) followed by de-twinning (ND), and twin dominated (e.g. RD) followed by cross-twinning or secondary twinning (e.g. TD). Slip induced pre-straining simply hardens the material, while twin dominated pre-straining alters the texture allowing the material to either de-twin or re-twin upon changing the strain path. Polycrystal plasticity modeling has been used to predict qualitative features of the flow curves during strain path changes.

Jan 1, 2006

By Malcolm Powell

"Predicting the performance of the whole mining process is surely the holy grail of predictive simulation. This can be named ‘Integrated Process Prediction’.The objective is to be able to predict the response of the processing chain, from mining to concentration, to changes in the ore type. This can apply to greenfields design – selecting processing options to optimise the overall mine performance within the constraints and aspirations of the greater community and environment; expansion and optimisation of existing plant to deal with changes in economic drivers and ore types; and on-line control – predictive reaction to ongoing changes in ore processing types in an operation.In order to achieve this there are several broad key components that are required: ore characteristics based on in-situ rock properties; a reliable 3D map of the ore body by the key processing parameters; prediction of how the rock fragments and the energy requirement to break it; the ability to predict and track progressive mineral liberation of the rock through the reduction process; the response of rock to separation processes as a function of the rock mineralogical properties. This requires the identification of primary rock properties and associating them with the rock particles as they move along the mining process chain to a concentrate or various forms of waste.This paper looks at the value of this integrated approach; the challenges it poses; the technology and capability we require; and how as a mineral processing community we can address the challenges."

Jan 1, 2016

By E. M. Yates, H. M. Hamilton

"For the assent of any new mining project it is essential to determine a realistic value of revenue from the sale of concentrates.A description of the market factors influencing the concentrate terms will be presented along with a detailed review of historical terms of a smelter contract for zinc concentrates. OverviewFor the assessment of any new mining project it is essential todetermine a realistic value of revenue from the sale of concentrates.This applies at all stages of assessment through to the final feasibilitystudy. In forecasting revenue for a zinc mine the followingfactors must be considered:(a) mill recovery and zinc concentrate grade;(b) metal price forecast for all payable metals;(c) smelter terms; and(d) other selling costs.Normally, data from test work are used to determine mill recovery and concentrate grade.Market forecasting, and indeed all economic prediction is an inexact science and probably will always remain so. We have our econometric models our input/output models and a lot of other tools. But they are of no help in predicting the unpredictable. OPEC's huge increase in the price of oil was certainly the most dramatic example of this. It had a tremendous effect on the cost of producing most products world wide and on the price of these products. Any forecasts made prior to the OPEC action were obviously proven wrong."

Jan 1, 1994

By A. J. A. Janse

The Argyle diamond mine is located in the Kimberley region in the northern part of Western Australia at approximately 16°43'S, 128°23'E in subtropical bush/shrub savannah. The 46 ha (113 acres) pipe is situated in the Halls Creek mobile zone, which was cratonized about 1800 Ma ago and adjoins the Kimberley Block, a plateau upheld by Early to Middle Proterozoic rocks underlain by presumably Archean basement. The crater and upper pipe zones of the diatreme have been preserved within tilted and faulted strata of Middle to Late Proterozoic age. Its age of intrusion is about 1178 Ma. The diatreme rock is not kimberlite but olivine lamproite which was not recognized as a primary diamond host rock until 1978. The Kalumburu Joint Venture, a syndicate of local and overseas mining companies, started in 1972 to prospect the Kimberley Block with a modest annual prospecting budget of $125,000. Annual expenditure doubled each year and reached $1 million in 1975 after which CRA took over management of the newly-formed Ashton Joint Venture with an annual expenditure of $2 million (all figures are in current US dollars). The Argyle diatreme was found near the end of the eighth field season and after a total expenditure of $12 million. Annual production is about 34 million carats which places Australia as the world's number one diamond-producing country, although, because of the low value per carat, it is number four in terms of total annual value. The global cost required for a major diamond mine is between $300 and $400 million, with a discovery every 10 to 12 years. Because Canada contains large areas of prospective platform rocks underlain by Archean basement it is likely that a major diamond deposit does exist there. It is probable that it will be found before the end of this decade and exploration expenditure may be in the order of $100 million.

Jan 1, 1992

By Jose A. Caceres

Mine planning and mineral processing optimization are usually treated as two unconnected problems, especially at open pit and panel caving mines where the cut-off grade is practically the only variable optimized and analyzed for in the planning proposes. Using existing planning tool, the output is a reserve consumption strategy privileging higher grades. With the earlier consumption of the highest grades, every year produces revenues which are closer to the cost and potentially even below cost. However, there are other ore characteristics that can also affect the profitability of the operation. A new methodology has been developed, incorporating the grinding and flotation relationship into the mining economic models for the simultaneous analysis and optimization of the throughput-work index-recovery relationship through changes in the mining limits, sequence and redefinition of the reserve consumption strategy. A mine-site that implements this new planning strategy, can expect to increase the NPV from 5 to 15% depending on the actual operational settings. Two case studies have been developed, showing how the inclusion of the work index in the economic model changes the phase and mining sequence in an open pit mine and the caving sequence and the optimum column height in a panel caving mine.

May 1, 2004

By A. E. Reschke

Optimized mine planning of the Leeville Gold Mine, Nevada, necessitated the requirement for an average of 2540 tpd of high quality cemented rockfill (CRF) in primary stoping blocks and underhand cut and fill workings. To meet this requirement, a number of innovative design features were incorporated into the overall batching plant design. Foremost is the use of a dedicated skip to transfer crushed aggregate from surface down through the ventilation shaft to twin underground storage silos. Also, the use of a high shear colloidal mixer on surface to pre-slurry a cement/flyash binder with pipeline delivery to one of two separate underground CRF mixing stations was incorporated. Finally, the binder and aggregate are combined in a 9 m3 twin shaft compulsory type mixer before loading into teleram trucks for placement.

May 1, 2007

By J. Chao, C. Tan, N. Stubina

"Since J978, Falconbridge Limited has operated two electric furnaces at its nickel-copper smelter in Sudbury. As part of its S02 Abatement Program, the smelter has undergone many changes over the last seven years.This paper describes the impact of these changes on the operation of the furnaces. Some of the topics to be covered include: the installation of sidewall copper coolers; current operating conditions; and furnace heat and mass balances. HistoricalFalconbridge began smelting ores in the Sudbury area in 1930. The original smelter consisted of a 1.3 m by 3 m blast furnace and two 4 m by 6 m converters. The blast furnace was supplied with untreated mine are and molten slag/matte was discharged into a round settler.In 1933 the smelter began treating flotation concentrates. The concentrates were mixed with fine magnetic ore and flue dust, then sintered on down-draught Dwight Lloyd machines. This provided an agglomerate suitable for furnace burden which was charged to the blast furnace while still hot.Between 1930 and 1954 nickel production was increased by lengthening the 3 m furnace to 4.6 m, then to 6 m, and later by constructing additional furnaces. By 1958, the plant consisted of one 7.5 m blast furnace, a settler, and three 4 m by 9 m converters."

Jan 1, 1994

By Donald Leroux, Robert Grant

"Flotation is a complex and highly multivariate process. Using the conventional OFf (one-factor-at-a-time) technique, the optimization of flotation circuits through laboratory or plant testwork is difficult, time-consuming and therefore, expensive and often results in marginal improvements. The optimal operating conditions can be more efficiently estimated when a systematic approach like SDE (Statistical Design of Experiments) is taken.The concentrator of Noranda's Brunswick Mining Division (near Bathurst, New-Brunswick) is well known for the complexity of its differential copper-lead-zinc flotation circuits. One of them, the chalcopyrite-galena separation (or CuSep) circuit, is impacted by more than 20 variables.Statistical Design of Experiments (SDE) techniques were applied at the laboratory scale to improve the performance of Brunswick's CuSep circuit. Screening tests were conducted using Fractional Factorial designs while optimization tests were carried out based on Response Surface Modelling techniques like the Central Composite design. Every series of tests, without exception, revealed new information and process insights which led to significant circuit performance improvements in the plant So far, the metallurgical gain may be as high as four percentage points of copper recovery (in the CuSep circuit). Potential cost savings of expensive consumables (steam, activated carbon) have also been identified but will require additional circuit modifications before being realized.IntroductionIn spite of its apparent simplicity, flotation is a complex three-phase (solid, liquid and gas) separation process. Fundamentally, it is a highly multivariate process. Industrial flotation circuits are commonly affected by 10 or more process variables."

Jan 1, 1997

By Peter Heine

Diavik Diamond Mines Inc. (DDMI) has treated systems development as an integral part of the construction project when it built Canada?s second diamond mine. Fully aware that the proper collection and processing of operational data is needed to drive business decisions during production and planning, key Performance Indicators (KPIs) were defined to effectively manage operations when the mine went into production. The Production Information Management System (PIMS) allows KPIs to be measured, reported, and transferred to other systems in a reliable and convenient manner. PIMS provides a mechanism to collect real time production data from the various control systems around the site and acts as a tool to ?drill-down? and establish the important cause-effect relationships that impact the value of a KPI. Thus PIMS provides a data collection, storage, management, and an environment in which cause-effect relationships can be analysed and statistically verified. This understanding of the real cause-effect relationships, close to the source of the data and in the context of the operation, can be used to improve both operations and maintenance performance. The PIMS includes the PI Database implementation, its associated external interfaces with the various Control Systems, Cleaning Packaging Weighing System, Environmental System, Enterprise Asset Management (EAM) System, and Diamond Tracking System (DTS), as well as laboratory data collection, custom applications (downtime tracking, data reconciliation) and user clients. The interface with the EAM system provides material flow quantities and equipment availability on which the plant performance reports are based. The transfer of equipment usage to the EAM system is fed into the maintenance notifications and work orders functionality in the EAM. The environmental system interface provides the mechanism for capturing water consumption data required to generate the various regulatory reports. The interface to the cleaning-packaging-weighing system provides the mechanism for capturing batch data for transfer to the DTS for diamond product tracking at the production splitting facility in Yellowknife. The PIMS lab application provides a means of getting sample data into the system for critical metallurgical metrics, and the data reconciliation application provides a means of manually verifying the data before it is published or passed onto other systems.

May 1, 2003

By G. A. Barclay

"I - INTRODUCTIONSteel castings still comprise the largest volume of wear materials used in crushing and grinding in the Canadian mining industry. The range of impact and wear properties possible with steel castings enables them to be used successfully in both high impact crushing as well as milling where abrasion resistance is the main criterion. Approximately 15,000 tons per year of steel mill liners and crusher castings are used by Canadian mines.The properties of the main steel casting alloys used - manganese, pearlitic chrome-moly and martensitic medium carbon steels will be discussed with reference to their applications. Field data on a new application in primary gyratory crushers for martensitic medium carbon steels is presented. Liner wear life and mill efficiency can be improved through proper liner design.The liner wear pattern can be used as an indication for liner profile changes to improve wear life. Changes in liner configuration can improve through put and use of larger castings can reduce downtime. Casting performance can be improved and foundry production costs reduced by adopting certain design improvements.II - ALLOYS USEDTable I list the most common ferrous liner materials used in relation to their hardness and wear resistance (1). The most wear resistant materials are the irons at the top. In many applications the service impact exceeds the impact strength of the irons and tougher less wear resistant steels must be used. The impact resistance improves from top to bottom with manganese steel the toughest. The hardness of the martensitic steels approaches that of the Ni-Hards however the wear life, because of the absence of carbides, is less."

Jan 1, 1983

By W. M. Lupton

"Internal grinding mill entries are routinely done by mill personnel during scheduled maintenance periods. Reasons for entry include mill liner life profiles, liner inspcections and replacement and grinding media investigations. These entries require employees to adhere to safety regulations and policies including special permitting, testing, procedure-following practices and the wearing of proper personal protective equipment.A realized semi-autogenous mill entry safety hazard is the unpredicted breakage and occasional shattering of large diameter grinding media while personnel are inside. This was a concern to both media user and supflier. American Barrick's Holt McDermott Mine has improved mi l operational procedures and the media manufacturer has assisted by their developments to essentially eliminate this problem.This paper presents the improvements instituted; and the author's wish to communicate this potential hazard to other large diameter SAG ball users or potential users.INTRODUCTIONAmerican Barrick' s Holt McDermott mine is situated on Highway 101, some 70 kilometers northeast of Kirkland Lake, Ontario, 120 km east of Timmins and 90 km northwest of Rouyn Noranda, Quebec. The mine draws 160 employees from these surrounding areas to extract and process the underground ore, and recover near 60,000 ounces of gold per year. The mill department is completing it's fifth year of operation this spring.The company and the employees are proud of the safety improvements realized over the short history of the mine. Post accident/incident reviews and pro-active safety awareness programs have substantially reduced the mine's accident frequency and severity to date.One of the mill department's objectives is to provide a safe working environment for mill personnel, which includes the interior of the grinding mills."

Jan 1, 1993

By H. Soto, J. Jara, F. Nava

A method has been developed to recover cyanide and copper from cyanidation effluents contaminated with thiocyanate and copper-cyanide complexes. Copper is precipitated as copper thiocyanate or as copper cyanide depending on pH and the concentrations of thiocyanate and cyanide present in the effluent. The copper precipitate presents good dewatering characteristics and can be easily separated from the effluent by thickening and filtration. The solution containing the bulk of the cyanide is then oxidized with ozone to transform the remaining thiocyanate into cyanide. This results in a regenerated solution rich in free cyanide that can be recycled to the cyanidation process. Careful control of the pH of the solution is required. First pH of the effluent is lowered to optimize the precipitation and oxidation stages, then the pH is restored to an alkaline value to regenerate the cyanide solution. Recoveries of over 96% copper are obtained. Free cyanide in the regenerated solution corresponds to up to 160% of the total cyanide contained in the original impure effluent. (The balance being accounted for by the cyanide obtained by the oxidation of thiocyanate). The efficiency of the thiocyanate oxidation stage is 85% to 90%. The method has been demonstrated at bench scale with effluents of various cyanidation plants of northern Quebec. A preliminary economic evaluation indicates that the procedure would be profitable for effluents rich in copper and thiocyanate. This is the case for most barren bleeds of Merrill Crowe and heap leaching operations and also certain CIP tailings of gold ores containing copper impurities. Environmentally the procedure is a better alternative than the current detoxification methods based on the oxidation of cyanide that do not allow for copper recovery and that have difficulties in producing a final effluent with acceptable levels of contaminants such as ammonia, thiocyanate and copper.

Jan 1, 1996