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By B. D. Thompson

Many mines adopt necessarily conservative backfilling strategies due to a lack of understanding of their backfill behaviour. In the past five years, extensive instrumentation campaigns have focused on measuring in-situ cemented paste backfill behaviour. These tests have resulted in optimised backfilling efficiency through elimination or reduction of cure periods where; i) controls on backfill behaviour are understood, and ii) barricade pressures are demonstrated to be within a safe range using routine monitoring as a required QA/QC procedure. Recently, this work has been extended to consider hydraulic backfill operations. Two stopes have been instrumented at Vale?s Coleman and Garson Ramp mines. The instrumentation and deployment methods are discussed, and representative total earth pressure, pore pressure, and temperature data are presented. In one case, pressures in the stope are relatively low as drainage causes strength gain in the fill and so pressures are arched. In a second example, again, drainage causes strength gain in the fill, but increasing temperatures correlate with pressure increases even during downtimes in filling. These pressure increases are thought to be caused by thermal expansion of the backfill in confined locations. Generally, the instrumentation approach has proven successful in measuring hydraulic backfill behaviour and offers good potential for incorporation into a procedure to safely maximise backfilling efficiency through routine barricade pressure monitoring, when combined with safeguards to ensure adequate fill drainage.

Aug 1, 2013

By K. Stankiewicz

Projects as regards state-of-the-art mechatronic systems aiming at increase of safety in the mining industry and at improvement of coal production technologies, which have been completed at the KOMAG Institute of Mining Technology, are presented. These projects cover automation, monitoring and visualization systems, systems for implementation of artificial intelligence techniques, and database recording systems. iRIS system for electronic marking, identification, and recording of components of powered roof supports, which was implemented in 31 Polish mining enterprises, is presented as an example of the work directly associated with an increase of operational safety. Specialists from KOMAG, ELSTA, Ltd., and Silesian University of Technology in Poland, have developed flexible, configurable, and scalable system for data management, which refers to all fixed assets of mining enterprises, meeting the requirements of users as regards marking and identification of fixed assets. The system for control of roadheaders using intelligent algorithms, based on artificial intelligence techniques is also the example of innovative actions. This system aims at increasing the safety and effectiveness of teamwork due to a possibility of remote, semiautonomous operation. Introduction of artificial intelligence technology enables adaptation of roadheader mining system to the present mining-and-geological conditions. Moreover, work aiming at implementation of state-of-the-art system for control of mine jig?s beneficiation node, integrating machines and equipment in one system, is carried out as regards automation, information integration, and visualization in coal beneficiation process. Work on recovery and conversion of thermal energy, which is a by-product during operation of machines and equipment, especially mine diesel drives, is presented. Systems for energy recuperation are more and more important due to the necessity of continuous increase of power production efficiency.

Aug 1, 2013

By Marco Quirion

The Daniel-Johnson dam, formerly named Manicouagan-5 (Manic-5), is located 800 km northeast of Montreal (Quebec) in Canada. This is the largest multiple-arch concrete dam in the world consisting in 13 arches and 14 buttresses. Since its construction in 1969, various type of cracks have appeared on both downstream and upstream faces of almost all the arches of this concrete dam. As a part of the Daniel- Johnson’s dam safety assessment program, Hydro-Québec is currently performing structural analysis of the dam with advanced numerical models to better understand and predict the dam behaviour. Because the buttresses transmit all the arch loads to the rock mass, determination of the properties of the dam foundation should not be neglected in dam global safety analysis and also to insure that reliable input parameters are used in the dam numerical simulations. This paper summarizes the past and the more recent investigations of this foundation used to assess its safety and stability. Moreover, the use of rock mass classification to estimate the deformation modulus, based on empirical equations, gives values in the range of 30 to 40 GPa that are higher than expected values. Using those values in the numerical simulations for dam structural analysis gives an excellent correlation with displacements monitoring of the buttresses.

Jan 1, 2015

By Julian V. Simela

Conventional methods of underground surveying use theodolites/total stations and 3D laser scanners to obtain information about the underground environment. Current methods of geo-referencing these instruments to a mine reference system include triangulation, trilateration and resection. However, despite technological advancements, surveying procedures have remained slow, laborious and relatively unchanged during the last half-century. Recent innovations in the robotics community have shown that automated mapping of underground mining tunnels can be undertaken using 2D/3D laser scanners. These techniques have the potential to, in turn, improve upon current underground surveying and mapping methods. Automating surveying and mapping using current surveying tools without changing the setting up procedures or removing current constraints, or even changing the type of equipment used, does not change the status quo. The problem of moving from a static, tripod based surveying and mapping system to an unconstrained mobile surveying and mapping system is the subject of this paper. A current challenge for automated mapping is the ability to automatically geo-reference a mobile mapping system to a mine reference system. For a mobile mapping system that uses a horizontally mounted 2D laser scanner to gather data of the underground environment, the challenge of determining its position and orientation within the mine environment is magnified even more. This paper introduces Mobile Automated Scanner Triangulateration (MAST), a technique under development at Queen?s that is designed to geo-reference a mobile mapping system to a mine reference system for the purposes of underground mine surveying. MAST quickly and automatically determines scanner 2D position and orientation (azimuth) in a mine reference frame by using minimal human input.

Aug 1, 2013

By E. Larsen

Marine tailings disposal may in some cases be the best solution to one of mining’s major environmental problems. The public standing of this solution is poor, partly because of past bad practices. Among the tailings problems spreading of super-fines and toxic substances stand out. The two are often interrelated as heavy metals, insoluble to sea water, tend to adsorb on fines and spread piggyback on them. Only one paper seen, has addressed the mineralogy of fine particles in suspension. The topic was a secondary tailings deposit. Studies on the sedimentation of fines in large river estuaries show that different minerals sediment sequentially as the salinity of the river increase. Mineralogy in the particle size range where particle separation takes place, has so far, naturally been in focus for the mineral processors. Next to nothing is known about the fines which may cause environmental problems. Tailings disposal has, due to its complexity, to a large extent been taken over by specialists in other fields, biologists, engineering geologists, chemists. The basics of the subject ought also to be given more input by the mineral processing community. A drawn out battle about tailings discharge into some fjords has taken place in Norway. The detractors focus at fine particles (could be dangerous nanoparticles) spreading and emphasize the effects. Calculation is simple: 5 million tonnes tailings annually discharged, containing 1 wt. % < 1µm determined by laser diffraction, results in 50 000 tonnes of nanoparticles let loose in the environment. The industry`s difficulty to answer, is lack of basic research on this topic. Test work to develop a methodology to address the problem is described. One thing the mineral processors know is that final tailings may be comprised of tailings from separate separation processes, with different properties, some of which may require special treatment. One tailings stream from a Norwegian mine is investigated in such a context.

Jan 1, 2016

By G. G. Li

"A dynamic ventilation-modeling package, VREX, was used to simulate the mine activities through tracking the equipment movements in underground workings and determine the airflow demand for a new production scenario in a ventilation-on-demand (VOD) system. It incorporates the mine development data from a discrete event simulation and balances the ventilation network using the CANVENT ventilation solver. A case study was performed to demonstrate the capabilities of the software, evaluate the performance of the network and determine the potential energy savings for implementing VOD in a deep mine operation.INTRODUCTIONThe ventilation cost of an underground mine can be significant—up to 50% of the mine’s energy consumption could be used to run fans and provide heat/refrigeration to meet the specified production environment for workers and equipment. The VOD system has proven to be more efficient in operating the fans and supplying the amount of air corresponding to the mine activities taking place in underground workings (Hardcastle, Kocsis, & O’Connor, 2006). In order to properly solve and evaluate the VOD system, a dynamic ventilation modeling software VREX—the ventilation rules engine has been developed to simulate the mine activities and determine the airflow demand for each production scenario within an operation period (Dasys & Cameron, 2011).VREX is a decision support tool, backed by the CANVENT mine ventilation solver (Li, Kocsis, & Hardcastle, 2009), for determining the outcomes of network configuration changes over time. The software incorporates the mine development data with ventilation modeling through the discrete event simulation (DES) performed by SimMineTM. As it simulates the air requirements for different vehicles and activities, VREX can evaluate both the performance of the ventilation system and the potential economic benefits of making operational or technological changes (Pritchard, 2010). For example, the model can be used to assess the economic and environmental impacts arising from modifying regulations to support the use of electric or lower emission vehicles. The combination of DES and ventilation modeling provides a new technology to generate the production scenarios according to mine schedules and activities and to determine the potential benefits for various levels of ventilation control, such as time interval and work shift change."

Jan 1, 2019

By A. S. MacNeil

In the operation of any colliery, a factor of prime importance is power, of which there are three sources available--man, horse, and mechanical. It is obvious that man-power is by far the most expensive, .and that animal-power, also, is more costly than mechanical. In recognition of this fact, mine owners must, for economical ?reasons, reduce the use of man-and horse-power to the minimum by the increased use of machinery. In other words, they must aim at as complete mechanization as conditions will permit, taking advantage of existing physical factors that are favourable and making the necessary adjustments and modifications to meet the less favourable conditions. Intensive coal-mining, or the concentrated production of coal, has two distinct objectives: First, the maximum production from a limited area, in a given time, thereby reducing the pit-room to be maintained; and second, reduction in cost. To this end the coal should be mined, loaded and delivered to the surface by mechanical means wherever possible. To do this, however, requires the solution of many problems arising out of the varying conditions that obtain underground. The system of longwall mining lends itself to a more efficient scheme of mechanization than does pillar-and-room, as, in the former, the first step has already been taken by the removal of all the coal in one operation, and the opening-out of one face, the equivalent in mining area of fifteen or more rooms. Much has been clone of late towards mechanization in the longwall mines of the Sydney coal-field, and with gratifying results, but not without great difficulties and frequent disappointments. In 1923, an attempt was made with shaker conveyors. The introduction of conveying was a step to bridge the gap between the face, where the coal is produced, and the main transportation arteries leading to the slope or shaft. The receiving of the coal at the faces and its delivery to main loading points on main haulage-ways was the part allotted to the conveyors.

Jan 1, 1932

By M. Fujikawa

The Kamioka Zinc Smelter was converted from the jarosite process to the goethite process in the year 2000. The reasons for the conversion of the process were that the silica content of the raw material increased and the iron content decreased. The silica easily turns to a gel in sulfuric acid solutions and this causes the solid-liquid separation characteristics to deteriorate. The basic behavior of silica in sulfuric acid solution was investigated and it was found that the goethite process is the most suitable to effectively separate and remove silica from solution. Furthermore, Fe has the capability to remove elements such as Ge that have an adverse effect on zinc electrolysis. This means that, when the Fe content of the raw material decreased, the impurity removal capability also decreased and there was a risk of a build-up of impurities in the process. Iron precipitates in many forms in sulfuric acid solutions. The capability to remove elements such as Ge differs depending on the compound precipitated. Goethite has a higher capability than jarosite to remove elements such as Ge. In this report, the results of applying the process established by investigations of the basic behavior of Fe, silica and Ge in the zinc refining plant are presented.

Jan 1, 2006

By C. D. Smith

Numerous studies have shown the potential of air rate profiling to significantly improve the flotation performance of a bank of cells. To date many profiles have been implemented; balanced, increasing, decreasing and combinations of these. Previous work has typically shown using an increasing air rate profile, where the air rates are increased proportionally to each cell down the bank, yields a higher grade for a given recovery compared to other profiles. Air rate profiling can then be thought of as having two distinct components; determining the correct distribution of a given volume of air and, perhaps more importantly determining the correct total volume of air to add to the bank. To date no method for this second component has been established. In an alternative technique the air rate to each cell is adjusted in order to optimise the air recovery from that cell. Air recovery is the fraction of the inlet air which overflows the weir of a cell as unburst bubbles. The peak in air recovery (PAR) is a robust measurement that indicates optimal performance for the operating conditions in the cell, and sets the PAR air rate. By doing this for each cell in the bank, the optimal total air rate to the bank and the optimal distribution of that air can be simultaneously determined. In this study plant trials evaluated different air rate profiles, and profiling based on PAR. The total air rates to the bank for all profiles tested were approximately equal, allowing direct comparison. The results showed that the highest cumulative mineral recovery was achieved by operating at air rates which gave the PAR for each cell down the bank. Different distributions of the same total air rate to the bank gave the same cumulative upgrade ratio, but lower cumulative recoveries. In this study, the increase in cumulative mineral recovery, at the same upgrade ratio, was more than 33%. Peak in air recovery (PAR) based optimisation of air rates to banks of cells and to the individual cells has been shown to significantly improve flotation performance as it simultaneously determines the optimal air rate to the bank, and the optimal distribution of that air.

Jan 1, 2009

By K. J. Aglias, M. Jeffery, J. V. Simmons, J. A. Johnston, S. G. Fityus

"Shales and mudrocks undergo weathering in the near-surface geological environment, and degradation when directly exposed at the surface. Despite having superficially similar appearances, many shales have very different degradation behaviours. For example, some shales break down readily upon exposure whilst others remain more or less intact. Further, for those shales which break down, the style of degradation can vary greatly. A phenomenon is described where fresh shale blocks that are exposed at the surface undergo rapid breakdown to a fragmented texture which then persists for relatively long times, without further breakdown to finer soil particles. This is illustrated for some coal mine waste rocks. Furthermore, this metastable fragmented texture seems to be particular to each particular type of shale. The paper presents a conceptual model for this physical breakdown of shales which accounts for the differences in fragmental texture that are observed. The importance of several factors including strength, permeability and expansive clay content are identified for their contribution to the degradation behaviour of different shales.INTRODUCTIONShales and MudrocksThe term shale is applied widely to a class of mudrocks having a range of distinctive but gradational appearances and mechanical behaviours. Mudrocks are sedimentary rocks primarily composed of silt and clay sized particles (Tucker 1982). Mudrocks form in low to very low energy environments such as flood plains, lakes and deltaic environments, where the finest detrital particles are able to settle out of suspension (Reeves et al., 2006; Stow, 2005; Tucker, 2001).Unlike coarser siliciclastic sedimentary rocks, mudrocks do not present with a wide variety of sedimentary structures and textures. The most common texture is a preferred orientation of clays and micas parallel to the bedding plane. This textural component is related to the property of fissility or the ability for such textured mudrocks to split along smooth planes that are parallel to the bedding. Another common structure is lamination, formed by variations of grain sizes and types during deposition, Massive texture describes the situation where no sedimentary structures or textures are apparent (Boggs Jr., 2009; Tucker, 2001). The term shale varies between sources and contexts, with Reeves et al. (2006) stating that a shale is a fissile mudrock, where “fissility is a property that has developed at a certain stage of weathering”."

Jan 1, 2015

By L. Sun

In this work, strontium doped lanthanum ferrite (LSF) and their composite cathodes were fabricated by screen printing on yttria-stabilized zirconia (YSZ) electrolytes. Their electrochemical properties were evaluated by using electrochemical impedance spectroscopy and steady-state polarization methods. All the cathodes were screened by comparing their total polarization resistances before and after activation processes at different temperatures. The improved LSF composite cathodes were also screen-printed on YSZ/NiO half cells to fabricate solid oxide fuel cells (SOFCs), which have reached the output power densities of 170 mW/cm2 at 650 °C, 230 mW/cm2 at 700 °C, 304 mW/cm2 at 750 °C and 388 mW/cm2 at 800 °C.

Jan 1, 2005

"With the plethora of cable bolts on the market, geotechnical engineers can be baffled by the differences in performance claims from the manufacturers but perhaps more importantly they are sometimes at a loss in making an optimal selection matching behaviour with a particular site condition. To this end a new testing methodology has been developed that can cater for the varying types of cable bolt behaviours. The methodology is based on the laboratory short encapsulation pull test (LSEPT) as recommended in the British Standard and overcomes several deficiencies such as cable rotation. Of most significance however, is its inability to measure the post-peak residual performance of high load transfer capacity cables and consequently, there is an inference that these cables may be susceptible to sudden anchorage failure with relatively little yield. This paper details the results of anchorage performance tests of a range of cable bolts and the differences in performance with rock strength and drill hole diameter.INTRODUCTIONA research project was undertaken to develop a new laboratory-scale test apparatus to study the axial performance of fully grouted cable bolts that are used in the Australian underground coal mining industry. Work by Thomas (2012) and others in recent years found there were a number of deficiencies in the testing methodologies making it difficult to determine and compare the performance of the dozen or more different types of cable bolts on the market. This has meant that geotechnical practioners have been hamstrung in optimizing the design of ground support systems in underground environments that are increasingly more arduous.A cable bolt is a flexible tendon consisting of a quantity of wound wires that are grouted in boreholes at defined distances between holes in order to provide ground reinforcement of excavations (Hutchinson & Diederichs, 1996). They were initially introduced into the underground hard rock mining industry in the 1960s (Thorne & Muller, 1964) and since the early 1970s have been brought to coal mining operations."

Jan 1, 2015

By M. R. Julien

"The geomechanical behavior of rocksalt shows very distinctive features. The response of this most ductile of all low porosity rocks is dominated by inelastic processes that are strongly time- and historydependent. These characteristics must be taken into account when analyzing underground openings. Different constitutive models have been proposed and used for this purpose, and this paper presents the general formulation and applications of one of these. The SUVIC model relies on a unified approach with internal state variables producing mixed hardening to represent the inelastic behavior, which lead to specific solutions for plasticity and creep. The model equations have been implemented into a finite element code to perform numerical analyses. Simulations results are presented to show that this model captures essential aspects of rocksalt behavior under simple and complex laboratory testing conditions. Simulations are also conducted to analyze the response of underground openings. INTRODUCTIONPredicting the response of man-made excavations in rocksalt can be quite a challenge as it requires a reliable constitutive model to represent the material behavior. This softest of all low porosity rocks shows a highly non-linear inelastic behavior, very sensitive to history and rate effects (e.g. Senseny et al., 1993; Cristescu & Hunsche, 1997; Julien, 1999; Wittdke, 2014). The many deformation (micro) mechanisms acting locally in rocksalt make the construction of appropriate constitutive equations quite complex. Nonetheless, there have been significant progresses made over the last two decades or so; many of these developments have been included in a series of specialized Conferences Proceedings (Ghoreychi et al., 1996; Aubertin & Hardy, 1998; Cristescu et al., 2002; Wallner et al., 2007; Bérest et al., 2012)."

Jan 1, 2015

By L. Voisin, K. Itagaki

In the reductive smelting of the copper concentrate like a blast furnace operation using coke as fuel and reductant or in processing the copper concentrate which contains coal in the bulk, a sulfur-deficient matte phase often coexists with an iron base alloy in the bottom of the smelting furnace. This alloy is generally called furnace residue or speiss when considerable amount of arsenic or antimony is contained in the alloy and in the extreme case of reducing condition the alloy is saturated with carbon. As a fundamental study to know the behavior of some precious metals such as silver, gold and platinum between the sulfur-deficient matte and the furnace residue or the speiss which are in equilibrium under reducing condition, the phase relations and distribution of precious elements in the Cu-Fe-S-As and Cu-Fe-S-Sb systems saturated with carbon were determined at 1473 K by a quenching method.

Jan 1, 2007

By W. Mirihange

Considerable mechanical property decline is always observed at the Heat Affected Zone (HAZ) of AA 5083, This occurred as a result of the thermal effect on the hardened material, It is highly beneficial to have a prospective metallurgical procedure to overcome this decline of properties. Therefore, experiments were set to evaluate the effectiveness of a quick post weld heat treatment process with the AA 5083, Optimum results were obtained at 473K and with approximately 600 seconds time, The interplay between the time, temperature and mechanical properties are possible to explain by the Lifshitz-Slyozov-Wagner (LSW) theory and by considering the composition of the material.

Jan 1, 2005

By A. Plugatyr, C. P. Baxter

"Bessemer matte iron content is a critical process parameter that needs to be closely monitored and controlled in order to achieve optimal Ni/Cu smelter returns. Current process control practices during Ni/Cu converting often rely on visual observations and typically involve matte sampling to confirm that target composition was reached. A high-level techno-economic analysis study was carried out to evaluate potential direct benefits of advanced process control during the final stages of Ni/Cu matte converting. The results indicate that the magnitude of direct benefits will largely depend on matte iron control practices already implemented as well as matte iron set point. Preliminary assessment suggests that under the assumptions used in this study, implementation of advanced process control can potentially result in additional revenues ranging from several hundreds of thousands to tens of millions of US dollars per year per converter producing about 200 tonnes of Bessemer matte per day based on Ni, Cu, and Co metal recoveries alone.INTRODUCTION Real-time measurement of molten metal elemental composition, arguably, remains one of the key unresolved issues impeding full automation and real-time optimization of pyrometallurgical operations in different industrial areas, including non-ferrous metals and ferro-alloys. In particular, current process control practices during Ni/Cu matte converting often rely on visual observations and typically involve matte sampling in order to confirm target matte composition. In addition to being time consuming, this approach relies heavily on operator experience and diligence, and, therefore, requires continuous performance and quality control efforts. For instance, the need to improve quality of the Bessemer matte (BM) at the Copper Cliff smelter has prompted an impressive staff engagement and training campaign that was carried out by Vale’s team in the late 2000’s (Zanini, Wong, & Cooke, 2012). This training exercise was executed to address the compounded effect of several operational challenges, namely demand for higher throughputs, changes in the feed concentrate composition, increased feed variability, loss of process knowledge and expertise due to retirement, as well as lack of a comprehensive approach to improving the overall performance of the flowsheet rather than meeting production targets for intermediate products. Although the campaign was very successful and has resulted in significant improvements in the Bessemer matte quality, it has also highlighted the need to move away from “the-art-of-converting” and develop analytical tools that would enable real-time process monitoring."

Jan 1, 2018

By E. H. Mulligan

THE ERRINGTON B-I mine is located on the Errington orebody of Steep Rock Iron Mines, Limited, at Steep Rock Lake, Ontario. In 1946, this orebody entered the shipping lists of the Lake Superior iron ranges as an open-pit operation. During the period 1946 through 1953, the mine produced a total of 9,000,000 tons of iron ?ore. In 1950, as the mine approached the economic limits for open-pit operations, ground was broken for an underground development to exploit the deposit at depth. The mine is designed for an ultimate production of 1,500,000 tons per year by the block-caving system of mining. The initial shaft is 1,200 feet deep and will produce or-e from the 700 and the 900 levels. The 1,100 level will be used as a drainage level and as a haulageway for waste rock, which is hoisted to surface by skip. Ore from the two production levels moves by a system of ?ore passes to a crushing plant located below the 900 horizon and is hoisted from this point to surface by conveyor belt. At the present time, all material handling on the levels is by tramming, but as tram distances increase conveyor haulage will probably be installed. The initial stage of the Errington B-1 development is expected to produce 6,000,000 tons of ore over a period of four years. The second stage will require deepening of the shaft and development of lowe1? production levels. The conveyor hoisting plant will be extended to serve these new levels. We visualize the mining of this orebcdy down to 2,500 feet by these methods.

Jan 1, 1956

By E. Ghali, C. Su, G. Houlachi

"The influence of lead ions on zinc electrowinning process was investigated by means of electrochemical noise measurements (ENMs) and cyclic voltammetry in conjunction with scanning electron microscopy and X-ray diffraction. All electrochemical experiments were performed in sulphuric acid electrolyte containing different lead ion concentrations as impurity. Lead was added in six trace levels between 0.05–0.8 mg/L in the bath. The lead content of the zinc deposits was dependent on the introduced lead concentrations. The overpotential associated with zinc electrodeposition shifted to higher values with the increase of lead concentration in the solution. An appropriate correlation was found between the different concentrations of lead in the electrolyte and the morphology of zinc deposit by ENM. The results showed that the increase of lead ion concentrations is generally accompanied with the decrease of skew and increase of kurtosis values that could be related to the morphology of zinc deposit. Effectively, the morphology changes from well-defined hexagonal platelets to large hexagonal, layered platelets and finally to non-symmetric refined crystalline structure, respectively.INTRODUCTION In commercial zinc electrowinning, zinc oxide is leached from the roasted calcine with an aqueous acid sulfate electrolyte. Then the zinc-rich solution is purified and transferred into an electrolytic cell. During electrolysis, zinc is deposited on aluminum cathode where lead-silver or pure lead is served as anode. Electrodeposition of zinc could be influenced by several parameters such as bath acidity, temperature, current density, the nature and concentration of impurities as well as additives in electrolyte. Metallic impurities play a complex role during zinc electrowinning and they can adversely"

Jan 1, 2016

By Andrew Artzer, Michael Moats, Jack Bender

Antimony and bismuth in copper electrorefining electrolytes can cause cathode contamination, leading to the careful control of their concentrations. This study examined the laboratory scale removal of bismuth and antimony from an electrorefining electrolyte using a solvent extraction mini-pilot plant. The ability of a proprietary phosphonic acid ester extractant (REX-2) in a commercial diluent was studied in a simulated commercial setting. Antimony and bismuth were both extracted effectively from the electrolyte (72% Bi and 70% Sb removed) and Bi was effectively stripped (92% Bi recovered) with 400 g/L sulfuric acid. A final strip solution was obtained from the SX circuit containing 0.36 g/L Bi, 0.043 g/L Sb, 1.3 g/L Cu, and 0.18 g/L As. Unfortunately, most of the extracted Sb remained in the organic phase. Following the pilot study, experiments were performed to examine the precipitation of bismuth from the aqueous strip phase and the removal of antimony loaded on to REX-2. INTRODUCTION For many years, antimony and bismuth have been some of the most problematic impurities in copper electrorefining (ER) (Bardwell & Lapee, 1933). Along with surface roughening, high concentrations of Sb and Bi can contaminate the copper cathode and precipitate at the copper grain boundaries. This drastically reduces the drawing ability of the metal (Bender & Emmerich, 2016). For these reasons, it is necessary to control Sb and Bi concentration in the cathode, which is done by controlling their concentration in the electrolyte. Conventionally, Sb and Bi concentrations are controlled by maintaining a proper As/(Sb+Bi) molar ratio in the anode and arsenic concentration in the electrolyte. Antimony and bismuth are removed during electrolyte purification using liberators (electrowinning cells) and/or ion exchange. Liberators treat an electrolyte bleed stream from the ER circuit and electrodeposit increasingly impure copper as the copper concentration of the solution decreases. Traditionally, first stage liberators reduce the copper concentration from ~45 g/L to ~15 g/L and produce saleable copper. Second stage liberators decrease the copper concentration to ~8 g/L (Biswas & Davenport, 1980) which results in contaminated cathode that is returned to anode production (Biswas & Davenport, 1980; Wang, 2004). Further electrolyte purification is not always required but third stage liberators can be used to reduce copper concentration below 2 g/L which results in significant removal of As, Sb and Bi and very impure deposits which are recycled to a smelter or used for As production. However, liberators do not have very high energy efficiency (Acharya, 2014; Ando & Tsuchida, 1997) and below 0.5 g/L copper, highly toxic arsine gas may form (Biswas & Davenport, 1980).

Jan 1, 2019

By H. R. Wilson

"This paper describes the evolution of the Waste Management Program at the Lupin Mine through the years 1982 - 1988. The program was developed in response to the terms and conditions of the Water Licence issued to the mine in 1981 by the Northwest Territories Water Board. Echo Bay Mines Lupin Mine is located on the western shore of Contwoyto Lake in Canada's Northwest Territories about 80 km. south of the Arctic Circle.The gold mine commenced production in 1982 and the Waste Management Program was based originally on the total containment concept. Due to an expansion of the mill circuitry and increased throughput, it was apparent that the total containment concept would require reevaluation since discharge from the pond would be required within a few years. During the initial years of production, an investigative program was established to determine the most effective means for treating the tailings pond water. This program incorporated both laboratory studies as well as monitoring of the tailings pond contents and environmental conditions as the impoundment area was filling. The program showed that natural degradation phenomena, if properly utilized, are effective in lowering the concentrations of all contaminants to within Licence limits with the exception of arsenic. To ensure compliance with arsenic limits, an iron salt was added to cause arsenic to precipitate from solution in the tailings pond.As a result of our studies, the tailings management system finally implemented at Lupin Mine includes the following components:Tailings pulp retention cells constructed by dyking off one end of the tailings impoundment area.Two tailings ponds in series operated in a sequential decant and fill fashion.An iron salt solution preparation and metering system.A syphon system into which the iron salt solution is injected as the contents of the first pond are decanted into the second pond.A second syphon system for decanting the contents of the second pond to the receiving streamThis paper discusses the findings and conclusions of the waste management investigative program, describes the civil work completed to reach our final operating scenario, describes the sequence of operating the treatment system, reviews performance data, and comments on abandonment and restoration of the tailings impoundment area."

Jan 1, 1989