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By C. A. Petch

Abstract - The High Lake polymetallic deposit is located in the northern Slave province, 40 km south of Coronation Gulf, Nunavut. The main zone, the AB zone, hosts an estimated resource of 3.56 Mt grading 5.0% copper, 1.1% zinc, 0.06% lead, 1.7 g/t gold, and 18.2 g/t silver. Archean felsic metavolcanic and metavolcaniclastic rocks are the dominant rock type and are associated with lesser mafic metavolcanic and carbonate-rich metasedimentary rocks. The sequence strikes north-northeast, dips steeply to the west, and is truncated to the west by a large granodioritic intrusion. The mineralization at the AB zone is comprised of massive and stringer chalcopyrite-sphalerite-pyrrhotitepyrite± galena. At the core of the mineralized zone, intensely chlorite-altered rocks are locally metamorphosed to form distinctive zones of anthophyllite-magnetite-cordierite-altered rock. Peripheral to the mineralized core, alteration consists of sericitization, silicification, and weaker chloritization. Primary morphology and facing direction of the zone are difficult to interpret in part due to poor primary metal zonation of the deposit. However, the irregular shape of the mineralized zone and the erratic zones of zinc enrichment at the fringes are consistent with the interpretation that the zone was formed by the replacement of a porous volcaniclastic pile.

Jan 1, 2004

By Michel Masse

1. A battery-powered wireless mesh network for dynamic diesel machinery tracking and operating status monitoring. 2. A real-time ventilation model and fan speed optimizer. 3. An OPC server for information interchange. 4. OPC linkage to existing control infrastructure. 5. A Human Machine Interface (HMI) providing data archiving, trending and reporting. 6. Live MS-Excel to interrogate the simulation, controls and optimizer. 7. The battery-powered network mesh also provides SCADA functionality to route optimized setpointsto the fans and automated regulators not linked to PLCs.

Feb 1, 2008

By J. Ji, A. Shi, B. Grcic

Floating copper minerals selectively against iron minerals such as pyrite has been challenging for most copper and copper/gold deposits, and many operations continuously strive to maximise copper recovery whilst meeting target concentrate grades. Maximising grade is achieved by selectively floating copper minerals and rejecting pyrite. This challenge is to minimise copper and gold losses in the roughers if this approach is used. A flotation testing program was conducted by Bureau Veritas Minerals on a high-level pyrite bearing copper/gold ore sample to establish the potential to reject pyrite in the rougher stage, but also maximise copper and gold recoveries, and ultimately final product grades. The test program included feed characterization, rougher and open-circuit cleaner flotation as well as locked cycle flotation tests. The main variables tested for achieving selective flotation of copper and gold were collector type and pH control, through lime addition. Grind sizes used in the rougher and cleaner tests had been established from previous test work. The collectors tested were SIPX, Aerophine® 3418A, Aerophine® 3421, Aerophine® 3422, Reagent S-11192 Promoter, Reagent S-11193 Promoter and FloMin C4150. The two best performing collectors were then tested in open-circuit cleaner tests, with the optimum conditions examined further in locked cycle tests. INTRODUCTION Bureau Veritas Minerals Metallurgical Division was retained by Eldorado Gold Corporation to perform a metallurgical testing program on a high-level pyrite bearing copper/gold ore sample from a gold- copper porphyry deposit to optimize flotation reagent scheme to improve gold and copper recoveries and copper content in the concentrate. The test program included feed characterization, rougher and open-circuit cleaner flotation as well as locked cycle flotation tests. Initially, various collectors were screened in kinetic rougher tests, and over a pH range of 8.5 (i.e the natural ore pH) up to 11.5, using a primary grind size of 80% passing 120 µm. The collectors tested were SIPX (sodium isopropyl xanthate), Aerophine® 3418A, Aerophine® 3421, Aerophine® 3422, Reagent S-11192 Promoter, Reagent S-11193 Promoter and FloMin C4150. The enrichment ratio, which is the ratio of copper to sulfur in the concentrate to that in the feed, was used as proxy for rating selectivity (i.e. degree of pyrite rejection or depression).

Jan 1, 2019

By M. Phylli Bray

"Mining has the reputation of being a very ""macho"" industry. Recently, wider educational opportunities for women in nontraditional occupations and changes in mine technology have combined to make mining a viable career choice for women also. To benefit from this new resource, the mining industry faces the challenge of developing a different work environment from the one now burdened with sexism. Management supported initiatives are needed to facilitate such a transformation. The same rethinking of gender attitudes might also be extended to mining women in their traditional role as ""wife of"". The assumption that the male worker's wife is an unpaid adjunct is being questioned. It is suggested that women's separate concerns both as helpmate and as part of the mining workforce should be considered when planning for mining into the 21st century.IntroductionI must confess that, during the preparation of this paper, there have been many moments when I questioned my temerity. After all, I am not male, I am not an engineer, and I have never had a position in mine management. But as the wife of a mining engineer and a long-time resident of Northern Ontario mining towns, I do have an interest in the mining industry. This interest has had little to do with the technical and management aspects of the industry. Instead my research has been concerned with the impact the mining industry has on the people involved, particularly women, whether directly as employees or indirectly as wives. As I look toward the 21st century, I believe that the whole question of gender relations in the mining industry is one of the critical management issues smouldering below the surface."

Jan 1, 1995

By So-Yeong Lee, Moosang Lee, Seung Hwan Ahn, Ho-Sang Sohn, Jongshin Chang

It is necessary to understand the characteristics, phase changes and chemical reactions of flue dusts introduced from a furnace to an off-gas line in order to achieve the stable operation and the improvement. This study is to develop the dust reaction model for chemical reactions of dusts in an uptake shaft of smelting furnace and a waste heat boiler. Phase equilibria and reaction paths in this system were determined by thermodynamic calculation with experimental and industrial data. The oxidation reaction rate of dusts was determined by the gas film mass transfer controlling. And the sulfation reaction rate was evaluated by the unreacted shrinking core model. Kinetic parameters were estimated by reference data including industrial ones. The present study with the developed model shows various effects of temperatures, dust particle sizes, and O2 gas partial pressures on dust reactions. INTRODUCTION The flue dusts from a copper smelting furnace move along a furnace off-gas stream into an uptake shaft and a waste heat boiler (WHB) and electrostatic precipitator(s). It is necessary to control the dust quality in order to stabilize the operation because the sticking behaviors differ depending on the phase of dusts. Phase changes of dusts are caused by chemical reactions at given conditions such as temperature and partial pressure of gases. Therefore, it is required to understand the phase changes and chemical reactions of dusts in order to perform the improvement and stable operation. The present study carried out the investigation to understand their fundamental knowledge. Especially, this study was focused on the kinetics of chemical reactions of flue dusts, developed the model. In particular, the scope of development and utilization of the model was defined as the uptake shaft of the Mitsubishi S furnace and the S-WHB radiation section in the Onsan smelter. Information needed for the modeling work referred to data from these processes.

Jan 1, 2019

By V. Caps

Gold has been often used as an alloying component in order to increase or modify the catalytic properties of an active metal. For example, in the hydroconversion of methylcyclopentane, Riahi et al [1] shown that the addition of gold to palladium or platinum enhances the activity which becomes greater than that of the pure metals whereas the selectivity towards products resulting from ring expansion increases. Molenbroek et al [2] presented a detailed study on Ni-Au catalysts which exhibit activity for steam reforming and have been proved to be more resistant toward carbon formation than the pure Ni catalysts. Blocking of highly reactive Ni edge and kink sites by Au atoms is assumed to be the reason for the increased robustness of the Ni-Au catalyst. Nevertheless, the own catalytic properties of pure gold have been almost ignored up to the pioneering work of Haruta et al [3] which demonstrates the high activity of gold for CO oxidation at low temperatures. Other reactions such as WGS reaction, propylene epoxidation or benzene total oxidation have then been shown to be catalyzed by gold [4]. This discovery induced the publication of papers devoted to analyze the different factors controlling the activity of gold catalysts. Among them the most relevant appears to be the gold particle size, the nature of the support [5] and the preparation methods [6]. Clearly distinguish between support and size effect is not straightforward. Indeed, the calcination step often needed to synthesize supported catalysts on different supports, leads to different particle sizes showing that particle size and support are interdependent. To circumvent this difficulty, Au-based supported catalysts have been synthesized by using laser vaporization and low energy cluster beam deposition. The as prepared catalysts have then been characterized and tested in CO oxidation reaction.

Oct 1, 2003

By Robert B. Parsons

"It is generally acknowledged that Canadian and foreign-based mining companies are spending relatively fewer dollars in Canada and more dollars abroad than was the case not many years ago. It is common to see the Canadian tax system being fingered as one of the causes in this shift in direction. However, if one takes the time to peel away the surface of our tax system, and to probe a little deeper into its substance, it will be found that the Canadian taxation of mining is generally quite competitive. IntroductionCross-border shopping in the mining industry? - Absolutely! Economics 100 teaches that dollars are votes in the capitalist system, and mining companies are going to cast their limited number of votes where they can achieve the highest return at the least risk. The Canadian consumer knows that taxes are a major factor in cross-border shopping, and mining company executives know that the same tenet holds true in their industry. Unfortunately, mining operations are subject to such a bewildering array of tax rules that making an intelligent decision is not always an easy matter.Statutory Tax RatesConsider, for example, the ""statutory"" tax rates shown in Table 1. (Statutory tax rate in this table refers to the simple sum of federal and provincial tax rates on profits as specified in the tax legislation.) Looking only at the total statutory tax rates (such as 66070 for Manitoba) , one might quickly observe that the Canadian mining industry is subject to a truly onerous tax regime, especially as compared to the United States where statutory tax rates can be in the 34% range."

Jan 1, 1992

By I. Silin, M. Stapelmann, H. Wotruba, K. M. Hahn, C. Gerold, J. Katzmarzyk

New deposits are often characterized as low-grade and complex ore bodies. To date, processing of fine grained ore deposits implies complex processing routes with high energy consumption. For that reason, the investigation of dry grinding, e.g. with vertical roller mills (VRM), is an approach to save energy reserves. It is already proven that dry grinding can influence subsequent processing steps. In terms of flotation, the surface characteristics of the minerals are crucial for a successful flotation process, e.g. the sufficient adhesion of mineral particles and air bubbles. Wet grinding results in different surface properties of the product entering the conditioning stage than dry grinding, which has direct influences on the subsequent flotation process. To investigate the consequences for flotation, processing of a copper sulfide ore containing chalcopyrite and bornite was investigated, including grinding and rougher flotation. The effects of wet tumbling mill and dry VRM grinding on the degree of liberation of valuable minerals are characterized using mineral liberation analysis by scanning electron microscopy. The obtained flotation results, as well as the recorded flotation parameters such as dissolved oxygen, oxidation reduction potential and conductivity are presented and discussed. INTRODUCTION Copper production is mainly connected to porphyry copper deposits as main source for copper sulfides such as chalcopyrite and bornite. State-of-the-art processing of these deposits is already established worldwide for decades, combining crushing, fine grinding and subsequent flotation with rougher, cleaner and scavenger stages (del Villar, Desbiens, & Maldonado, Bouchard, 2010). While the demand for copper is increasing, copper grades of the deposits are decreasing and the remaining ore bodies have more complex mineralogy and finer particle size distribution. This implies processing routes with high water and – due to the liberation of fine grained valuable minerals – high energy consumption by fine grinding. One of the main energy consumers in processing plants is the grinding section, which accounts for more than 50% of the energy consumption in processing plants and even 4% of the worldwide energy consumption (Jeswiet, & Szekeres, 2016). Therefore, dry fine grinding alternatives are applied to enhance the overall energy consumption of mineral processing plants: high pressure grinding rolls (HPGR) and vertical roller mills (VRM).

Jan 1, 2019

By S. Zakaria

"Inco's Automated Haulage Truck System (AHT) is a revolutionary automatic guided vehicle that performs all load, haul and dump operations without human intervention. The high level of sophistication and the short period it has been in operation has only allowed a select few Inco personnel to become familiar with the ART operation and maintenance. As an aid to operations an expert system using the knowledge gained from the experienced specialists was implemented in the field.The AHT operating and maintenance assistance expert system will reason through the information given, arrive at conclusions and give advice to operations, technical and management personnel. It will provide comprehensive real-time troubleshooting assistance for the hydraulic, electrical and mechanical subsystems of the ART. The ART expert system has many benefits to Inco which include increased skill levels of ART operations and maintenance personnel, reduction in ART downtime, standardization of troubleshooting procedures and reduction in ART operating and maintenance costs. In the future, the expert system application will be linked to SCADA (Supervisory Control and Data Acquisition), maintenance and statistical software to display current and historical trends of variables from a centralized historical database. As well, a wide variety of features will be integrated into the system including AutoCad drawings, graphics, photographs, voice and video capabilities."

Jan 1, 1994

By M. Thérien, M. Rémillard

"Data from two industrial plants are treated by mass balance package BILMAT. The first application concerned a base metals/precious metals (PM) producer and the second, implementation of a hydrocyclone for the recovery of iron chips in the granite industry. Also LOTUS 123 software can easily be adapted for laboratory test mass balances using an IBM-PC computer. INTRODUCTIONThe present paper deals with two different BILMAT program applications. The first application concerns a copper-zinc-gol d-sil Yer producer based in North-western Quebec and the second, concerns the iriplementation of a hydrocyclone for the recovery of iron chips in Quebec granite company.Afterwards, we deal with some LOTUS 123 software applications for laboratory test mass balances using an IBM-PC.1. Base metal and P.M. producerNoranda Inc, Mattagami division, which operates mines in North Western Quebec, produces copper and zinc concentrates from a sulphide ore. Small amounts of gold (0,34 g/t) and silver (20 g/tl are present. At the time of the study, only 30% of the silver content was recovered in the copper concentrate. The main objective of this study is, to evaluate the metallurgical behaviour of silver in the flotation circuits, to increase its recovery in the copper concentrate and therefore to improve its final economic value. It is then worthwhile to identify the silver bearing minerals and to determine the critical flotation stages where they are lost. The methodology proposed is based on the coupling of a mineralogical study and a detailed mass balance ca1cu1ation in the flotation circuit performed using the BILMAT mass balance package (1, 2, 3).The results are discussed with respect to the distribution of silver in the circuit. The recoveries obtained at the various separation stages for the minerals present in the ore are also discussed."

Jan 1, 1987

By Jonathan Peck, Jim Gray

"With the implementation of more advanced monitoring, control and locating systems in surface mines, there is an ever increasing need for their mine-wide integration toward achieving over-all optimization. AQUILA Mining Systems Ltd. is developing the basis for a comprehensive real-time monitoring, control and information system called the Total Mining System or TMS. This system is being designed to address both current and future needs of open pit mines toward improving productivity and minimizing costs, through better two-way information flow between each component in the operation. At a basic level, feedback from equipment and process monitoring will enable decision making to be based on quantitative, on-demand information, thus permitting proactive rather than reactive planning. Dynamic planning would be a valuable tool as market conditions fluctuate, equipment fleets age and variations in the grade, quality, geometry and hardness of the mined material all contribute to either changing production targets or levels of achievable performance. Such a capability could be implemented within the next two years.At a higher level, and within five years, autonomous operation and/or real-time supervisory control of mobile and stationary equipment in open pit mines will be achieved. A discussion is provided in regard to the development and implementation of an autonomous haultruck and blasthole drill, to demonstrate the need for such a system.This paper outlines a preliminary program for the design, development and implementation of this system, primarily in relation to high-level communications and its role in the future automation of open pit mobile equipment."

Jan 1, 1995

By Al Holmes

"In a recent survey of Canadian work values, 89% of the men surveyed and 97% of the women surveyed described the work in a mine as ""not at all auraetive"", Work in a mine, in fact, was rated by both sexes as the least attractive of all of the types of work surveyed. Confronted with this prevailing attitude, Canada's mining industry starts out with two strikes against it in its bid to attract and hold on to its fair share of available work force.Behavioural scientists have, for decades, been seeking answers to the questions:• ""Why do people work?""• ""Why do people choose a particular occupation?""• ""Why do people choose a particular organization?""• ""Why do people leave one organization for another?""• ""Why do some people stay in an organization?""• ""Why do some people work harder than others?""Their answers to these questions, although tentative and often contradictory, are being used by more and more organizations to solve people problems. Few industries can afford to ignore them, least of all, perhaps, the mining industry.Consider the following developments:I. General Motors and the United Auto Workers turn around the car assembly plant in Tarrytown, New York in seven years from the plant with the poorest labour relations and production record to one of the best under a program referred to as ""improving the quality of work life.""2. Shell Canada and the Oil, Chemical and Atomic Workers have designed a new petro-chemical processing plant in Sarnia using a set of principles that seek to optimize both the social and the technical system."

Jan 1, 1980

By Stavros A. Argyropoulos, Radhakrishna Valiveti, Bernard Closset

"The use of microprocessors in metallurgy is currently increasing at a very fast rate. A large number of companies are offering systems ""off the shelf"" which are aimed at the data acquisition and process control market. There are two main drawbacks to these systems: first, they are usually quite expensive, and second, they are not completely compatible with the target metallurgical application. An alternative is to develop a microcomputer-based system "" in lab "".A dedicated microcomputer system has proved to be very useful in many metallurgical research applications(1,2)). However, in this system the analog input signals had to be transferred over long distances , and significant noise was introduced despite the use of shielded cables. In order to overcome this problem a network of low pass-filter s was designed and built. The usage of the abovementioned system brought the need to digitize the analog signals in-situ and transfer the digital signals, which are much less susceptible to noise over very long distances. This distinctly different design philosophy has become a reality with the evolution of microprocessor technology over the last few years. This design philosophy is utilized in this development."

Jan 1, 1984

By L. Li

Iron removal is a common procedure in hydrometallurgy of non-ferrous metallic ores. Chemical precipitation and solvent extraction are currently the main methods employed for separation of iron from copper leach solution. However, chemical precipitation methods have the problem of producing large amounts of iron precipitates, and/or requiring high temperature and high pressure conditions for precipitation. The precipitates are difficult to separate from the solution. Emulsification is a general problem for solvent extraction, which causes loss of extractants and contamination of the electrolyte. A common problem for solvent extraction and chelating ion exchange processes is the difficult iron stripping process. Therefore, finding an efficient and environmentally friendly method for iron removal is of great significance. In this paper, new processes of using ion exchange resins to remove iron from copper leach solution have been investigated. Salicylic acid, amino carboxylic acid, amino phosphonic acid and hydroxy-oxime resins were employed to adsorb iron from a simulated copper leach solution containing 40 g/L of Cu2+ and 36 g/L of Fe3+. It was found that a hydroxy-oxime resin, named Z-Fe, has excellent adsorption selectivity on Fe3+. Desorption behavior of the resin was studied by two step elution using dilute H2SO4 and oxalic acid solution, respectively. After optimizing the adsorption-elution processes, the extent of removal of iron from the simulated copper leach solution using resin Z-Fe was 90%, while copper recovery could reach 100% in closed circuit processing.

Jan 1, 2016

By Gerhard W. Heinrich, Gerald V. Schroeder, Daniel A. Murphy, Daniel F. Suarez, Jamie B. Beauchamp

"Washwater 'Finger' sprays were installed and tested in the copper/nickel separation circuit at Strathcona Mill to improve flotation capacities and related metallurgical performances. The new spray design features submerged sideways introduction of wash water into the flotation froth through nozzles at the end of vertical pipes which are suspended from a header above the froth. This maximizes the effective cross sectional area of flotation vessels while maintaining effective froth cleaning and a desirably high density of the concentrate slurry. The plant tests gave increases of copper concentrate production rates of 17% to 20% for conventional cells and 16% to 20% in column flotation at target grades of 29% to 30% copper and of less than 0.5% nickel. Basic considerations and concepts of tests and evaluation procedures are described.IntroductionMeeting flotation concentrate grade targets at maximum production rates and recoveries is a challenge all too familiar to operators of base metal ore concentrators. Frothwashing is an option to improve grade/recovery performance by minimizing entrainment of impurities into the concentrate, which is commonly known since the sixties (Kaya & Laplante, 1989). It has been recommended for the flotation of sulphides and industrial minerals alike (Kaya & Laplante, 1989; Miller, 1969; Heinrich, 1989) and has found its ultimate application in flotation columns (Finch & Dobby, 1990). The washwater addition in a flotation column is most evenly distributed over the column's cross-sectional area thus ensuring almost complete displacement of feed water from the froth by a countercurrent washwater flow -provided, a positive bias is maintained. Therefore, flotation columns are ideal for cleaning flotation. However, there is usually less room for boosting the concentrate production capacity by increasing airflow or slurry level then with conventional cells because of the smaller cross-sectional area available."

Jan 1, 1994

Caterpillar Inc The world's largest manufacturer of construction and mining equipment, diesel and natural gas engines and industrial gas turbines. Technology leader in logistics, construction, transportation, mining, forestry, energy and electric power generation.

Aug 1, 2013

By R. J. Grant, D. W. Scott, M. A. Cooper, E. R. Shannon

"The Brunswick No.12 site concentrator processes 10,500 tonnes per day of a complex lead, zinc, copper and silver ore producing four concentrates by differential flotation. Research over the years has led to increased understanding about the mineralogical and flotation characteristics of the ore. A pilot plant study conducted at Lakefield Research, primarily designed to investigate the technical feasibility of semi-autogenous grinding, provided an opportunity to test recent theories about grind size,, reagent schedule and flowsheet configuration.A fundamental approach was taken with each of the unit processes involved in grinding and flotation. Basic operating and metallurgical criteria were established in each area and a step-by-step implementation program initiated in the plant.Significant improvements in metallurgical and financial performance have been realized through the application of basic grinding and flotation principles using conventional milling equipment and without major capital expenditure. Current operating practice is detailed and metallurgical advancements cited.INTRODUCTIONBrunswick Mining and Smelting operates one of the world's largest lead and zinc mines near Bathurst, New Brunswick. Brunswick is a publicly traded company with majority ownership held by Noranda Minerals (63%). In addition to the No. 12 underground mine, the company operates a lead smelter and phosphate fertilizer plant in Belledune, N.B. and maintains a 25% interest in a joint venture with Noranda Minerals' Heath Steele mine near Newcastle, N.B. Through the four operations, a total of 2000 people are directly employed with fixed assets totalling Cdn$187 million (BM&S, 1991)."

Jan 1, 1993

By Shantanu Patel, C. Derek Martin

"The objective of this work is to develop a practical numerical approach for applying the confining pressure to discrete element cylindrical triaxial tests. A layer of membrane particles with very low stiffness and extremely high contact bond strength was created around the lateral boundary of the cylindrical numerical specimen. To prevent the membrane particles from penetrating into the rock specimen on application of confining forces and to provide a smooth boundary surface, the space between the membrane and rock particles was filled using small-diameter packing particles. The results of this method were compared with those of rigid boundary method with confining pressure of 20MPa. The results obtained show that new approach gives both peak strength and post peak response that are in closer agreement with laboratory findings. BACKGROUNDThe discrete element method (DEM) has become the cornerstone for simulating both intact material and discrete fractures for low porosity strong rocks (ISRM Classes R3 to R6). Despite the advances in its application, simulating realistic behaviour of intact rock using the DEM remains a challenge. The bonded particle model was introduced as a potential solution for simulating the complex mineral grains in strong rock and other granular materials (Potyondy and Cundall, 2004; Utili and Nova, 2008; Salot et al., 2009). While some issues were resolved, a remaining challenge is the lack of the bonded particle model to simulate the brittle response commonly observed in strong rocks during the triaxial compressive test. Such behaviour is shown in Fig. 1 for Lac du Bonnet Granite at a confining pressure of 20MPa."

Jan 1, 2015

By T. Gonzales, M. Maleki, M. Caçador, B. Climenhaga, H. Ghorbani

The campaign life of furnaces in the copper making industry is greatly affected by damage caused by normal operation cycling and abnormal conditions. Proper monitoring and assessment of the existing conditions and safe remaining life of the vessels and their refractory lining is key to prevent an unplanned early replacement. This paper presents an industry-proven refractory management program as well as a typical fitness-for-service assessment of a rotary vessel shell in order to extend the campaign life of copper making furnaces and enhance safety. The furnace refractory management system involves a comprehensive audit and monitoring program which has been successfully applied to several copper flash smelting furnaces over the past 15 years. The fitness for service assessment provides a methodology to estimate the remaining life of the steel components by evaluating the existing damage and future damage rate based on the historical survey data. The above practices can provide the operator with cost savings by extending the vessel campaign life in lieu of implementing more rigorous refractory lining and shell audits. INTRODUCTION Primary copper smelting is generally divided into two categories of flash smelting and open bath smelting. There are many different types of vessels that can be used to convert the copper concentrate to blister copper including, flash, Mitsubishi process, TSL (ISA/Ausmelt), SKS Bottom Blowing, Anode and Teniente/Noranda furnaces, reactors, and Peirce Smith converters. Each vessel has its own complex and intense environment which requires careful refractory and steel design to withstand the severe thermomechanical and thermochemical attacks within its campaign life. The campaign life of furnaces is greatly affected by damage caused by normal operation cycling and abnormal conditions. Proper assessment of the existing conditions and safe remaining life of the vessels and/or refractory lining is key to prevent an unplanned early replacement. This paper presents an industry-proven refractory management program as well as a fitness-for- service assessment methodology to estimate the remaining campaign life of copper making furnaces resulting in cost savings and enhanced safety of the operating vessels.

Jan 1, 2019

By F. Rosenblum, P. Spira

"Self-heating of broken sulphide ore or waste rock underground can lead to ignition and cause serious problems in a mine operation. An extensive study has demonstrated that it is caused by oxidation of certain species of pyrrhotite. Self-heating was found to take place in two stages, first progressing from ambient temperature to 1000C with exothermic formation of elemental sulphur in the presence of moisture and oxygen, and proceeding to a second stage in which the sulphur oxidizes to SO2. Ignition may eventually follow. An apparatus was developed to assess the propensity of sulphide rock to self-heating and the potential for hazardous behaviour. The effect of temperature, time, rock size, and surface treatment with chemicals is presented. On the basis of these results, possible approaches for preventing a runaway reaction are suggested for further investigation.IntroductionThe oxidation of sulphide ore, waste rock or tailings backfill, which may cause hazardous conditions underground through heating, oxygen depletion and, in some cases, fire, is well documented (Farnsworth, 1977; Ninteman, 1978; Rosenblum et al., 1982; Reimers, 1987). The self-heating mechanism, nevertheless, has not been satisfactorily explained. The onset of heating from ambient temperature, in particular, has not drawn the attention of researchers. In the course of a previous study (Rosenblum et al., 1982) aimed at finding a method to assess the hazard from using sulphide tailings as backfill, the authors developed an apparatus to measure self-heating rate under controlled, near ambient conditions. This has since provided decisive information in backfill investigations in the Noranda Group.The test methodology devised for tailings failed to predict self-heating in a broken waste rock known to be active. Upon repeated testing, however, a freshly crushed sample began to exhibit appreciable heating and oxygen uptake (Fig. I). After 14 tests, the self-heating rate reached a plateau of about 4O°C/h and then fell progressively to < 5°C/h after 30 tests. It was hypothesized that weathering in the presence of moisture and oxygen during testing had caused the onset of self-heating. Active tailings, on the other hand, are exposed to natural surface oxidation and need not be weathered to show heating. Based on this finding, a new apparatus was developed capable of simultaneously weathering a sample of rock and monitoring its self-heating behaviour."

Jan 1, 1995