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By W. D. Madeley

Synthetic minerals were made from pure starting materials and galena samples were doped with the title metals. Microscopic, microprobe and X-ray examination confirmed that the dopeants were in solid solution. Paired flotations in a Hallimond-tube apparatus were performed to determine relative flotation response using Aerofloat 238 promoter. Results of these tests show that silver-doped galena floats more readily than pure galena and that galena doped with bismuth floats less readily than pure mineral to a 95% confidence level. Galena doped with both silver and antimony as AgSbS2 shows no detectable effect. Antimony-doped galena followed the expected trend, but not to 95% confidence. The results are consistent with the theory that flotation by thiol-type anionic collectors is enhanced by p-type semiconduction.

Jan 1, 1978

By L. B. Kilius

The composite cathode system based on Ce0.9Gdo.1O2_,5 electrolyte with a painted cathode was used for an intermediate temperature (500-700°C) solid oxide fuel cell. This cathode system was chosen due to its excellent thermal expansion match to the electrolyte, its relatively high conductivity (115 S cm-1 at 700°C), and its low activation energy for oxygen reduction (99 kJ/mol). It was found that the decrease of sintering temperature of the composite cathode system produces a significant decrease in charge transfer resistances to a level of 0.25 SI cm2. The conductivity measurements of porous samples produced values between 40 and 88 S/cm for porosities of 30-40%.

Jan 1, 2005

By M. Walawalkar, C. K. Nichol, G. Azimi

Rare earth elements (REEs) are essential to the production of technologically advanced products, including wind turbines, electric and hybrid cars, automotive catalytic convertors, hand held electronic devices, and military defense systems. Their application in environmentally beneficial technologies puts them at a high priority for ameliorating environmental concerns. Because of their increasingly high demand and limiting resources, it is highly beneficial to find new sources for them. The present study is focused on leaching REEs from a phosphate based fertilizer by-product, known as phosphogypsum (PG). Global estimated world production of PG is about 240 million tonnes that is stored in the form of wet stacks adjacent to fertilizer production facilities, occupying vast amounts of land. PG also contains trace metals, which are detrimental to the environment, and hence it is crucial to monitor these stacks. We obtained our PG sample from Agrium Inc. (a fertilizer manufacturing company in Canada). We performed a comprehensive characterization of the PG sample and found that it predominantly contains Y, La, Ce, Nd, and Sm. For leaching purposes, we used hydrometallurgical acid leaching techniques. We investigated three acids over a range of operating conditions such as acid concentration, temperature, solid-to-liquid ratio, and residence time. We achieved an average leaching of 81% with hydrochloric acid as leachant using operating conditions that can be easily replicated in industrial settings. If our process is implemented, not only will it reduce the size of the existing PG stacks (mitigating their environmental risks), but also enable the development of new innovative routes for extracting REEs, making countries like Canada less vulnerable to supply disruptions.

Jan 1, 2016

By Andrukaitis. E.

The increasing use of electronic equipment by the Canadian Forces has increased the importance of electric power. A power source that is packed with energy and yet light, small and durable is the common request of military users. However, this needs to be achieved while also addressing the requirements of safety, reliability and low temperature performance. The potential use of fuel cells in a military environment has become a possibility in several areas in the 21st century. Some examples of power source requirements and the materials related R&D required to give better, higher energy power systems in the future will be discussed.

Jan 1, 2005

By H. Blaha, H. Wagner

"Room and pillar workings in salt mines are preferred sites for underground waste disposal. A critical issue in selecting waste disposal sites is long-term behaviour of such workings. The long-term behaviour of salt pillars is controlled by the pillar geometry, i.e. the height, width and length of pillars and the level of pillar stress. The latter has a strong influence on creep characteristics of salt pillars whereas the width to height ratio of salt pillars determines the strength of pillars and the deformation characteristics of salt pillars.Three different regimes of pillar creep behaviour of salt pillars can be distinguished, namely a stress level below which the rate of creep approaches a value of zero, a stress range where the rate of creep is constant and finally a stress level above which the rate of creep accelerates. Long-term stability of room and pillar workings can be assured only when the pillar stress level falls within the first stress regime. Strength and creep tests on model salt pillars have shown that at stress levels below 40% of pillar strength the rate of creep approaches a value of zero, between stress levels of 40% and 65% the rate of creep is constant but increases with stress level. Above pillar stress levels of 65% the rate of creep accelerates.Long-term measurements of pillar deformation and surface subsidence above relatively shallow room and pillar workings in salt mines have confirmed these observations. Long-term strength of salt was found that be between 60% and 65% of short term strength. The evaluation of salt pillar behaviour on the basis of critical pillar stress levels was found to be superior to the traditional factor of safety concept because it allows relating pillar deformation measurements to actual pillar conditions. The approach described in the paper was used successfully to evaluate the stability of room and pillar workings in a salt mine and to design strategies to stabilise critical pillar workings."

Jan 1, 2015

By Dallas W. Davis

Twin - Kennecott Deal Announced April 15, 2004 ! Kennecott earns 56% interest, if in 4 years, spends C$10 million and recovers at least 200 cts of +1 mm diamonds in all dimensions from any contiguous body ! Earn-in can take up to 6 years, but incurs stepped reduction of interest from 56% to 46% or 0% if $C10 and 200 carats not achieved ! By funding all costs through feasibility study, Kennecott earns 71% in 7 years, or, stepped reduction to 62% if completed after 8 years ! By achieving production within 10 years and funding Twin?s share of development and construction costs, Kennecott earns further 4% ! If no election to develop a mine within 2 years of feasibility study completion, Twin may present development proposal which Kennecott has 60 days to elect to follow or transfer management to Twin and dilute to 49% ! Each party has one time right to elect to market its diamond share ! On signing and annually, Kennecott will purchase $C250,000 of Twin shares at 130% of then prevailing market price until achieved earn-in

May 1, 2004

By S. Balideh

A good understanding of the behavior of rock helps us to make more informed decisions regarding geo-structures. Engineers need accurate equations to calculate the strength and deformation of rock before and after failure. Previous studies explain the failure of rock to ultimate strength, and laboratory tests adequately determine the ultimate strength and deformation modulus of rock. However, there are few comprehensive equations to determine the post-failure strength and deformation of rock. Previous work shows that the post-failure behavior of rock depends on the behavior of the broken rock particles after failure. The following question is then posed: How can the post-failure behavior of rock be determined by the behavior of broken rock particles? In order to answer the question, this study pursues three objectives: (i) to explain the behavior of broken rock at low confining pressure; (ii) to estimate the behavior of broken rock via the extrapolation of scaled laboratory testing; and to suggest a procedure (iii) to outline the post-failure behavior of a rock mass at low confining pressure commensurate with the behavior of broken rock in a rock mass.

Aug 1, 2013

By M. Gyenge, O. F. Coates, K. Barron

"It is suggested that artificial supports might be used to increase, with safety, the angle of hardrock open-pit slopes. Guidelines for designing such a support system, based on a simplified analysis, are given. The installation, construction and instrumentation of a trial support system is described and a breakdown of the construction costs is given. On the basis of this cost analysis, the economic benefits derived from reduced waste-rock excavation are compared with the support costs for a typical mine. In an example, it is shown that the slope angle in an open-pit mine 500 ft deep, with benches 50 ft high by 30 ft wide, could be safely increased from 37Yz degrees without support to an optimum of 53 degrees with support. In this case, the support costs would be approximately $900 per linear foot of pit wall and the savings due to decreased excavation of waste rock (at $0.34/ton) would be approximately $1,900 per linear foot, yielding an increased margin of profit of approximately $1,000 per linear foot of pit wall. This figure could be increased to $6,000 per linear foot if the steeper slope were used to extract more ore.More than 50 per cent of the support costs are accounted for by diamond-drilling the holes for the deep cable anchors. The use of percussion drills for this purpose would seem to offer a means of significantly reducing the support . costs and thus further increasing the profit margin available."

Jan 1, 1971

By D. A. Le, T. S. Nguyen

"In Canada and other countries, several types of rock formations are being considered for the geological disposal of radioactive wastes. In order to better understand the ability of these rocks to contain and isolate the wastes, the Canadian Nuclear Safety Commission collaborates with different international research organizations and has access to experimental data from Underground Research Laboratories (URLs) in the world. Such an URL is situated in Opalinus Clay, at Mont Terri, Switzerland. An experiment, consisting of the excavation of a tunnel followed by water and gas injections in a test section of the tunnel, was performed at the URL. The authors have developed a mathematical model, based on the poromechanics theoretical framework, to simulate those phases of the experiment. The constitutive relationship for the stress-strain behaviour of Opalinus Clay takes into account its inherent anisotropy due to bedding. The model was able to capture the main features of the experiment such as the prediction of the shape and extent of the excavation damage zone and its influence on water and gas migration.INTRODUCTIONIn Canada and many other countries, several types of rock formations such as crystalline rocks and sedimentary argillaceous rocks, are being studied for the disposal of used nuclear fuel from nuclear power plants. Geological disposal relies on multiple natural and engineered barriers for the long-term containment and isolation of the wastes. The host rock is a major natural barrier and is the subject of extensive research. The Canadian Nuclear Safety Commission (CNSC), Canada’s nuclear regulator, will be responsible for the licensing of future deep geological repositories. In order to evaluate the safety of deep geological repositories, CNSC staff keep abreast of scientific developments by collaborating with national and international partners on experimental and theoretical research on the long term performance of those engineered and natural barriers. Through that collaboration, the CNSC has access to data resulting from experiments performed at different Underground Research Laboratories (URLs)."

Jan 1, 2015

By Hani S. Mitri

Overhand cut-and-fill mining of narrow vein orebodies inevitably leads to the creation of horizontal pillars. As the thickness of the overlying crown pillar diminishes, stresses build up in the pillar. More often than not, this situation causes an increased level of seismicity and possible pillar burst. One well-known strategy to reduce the hazard of crown and sill pillar burst in cut-and-fill vein mining is that of destress blasting. The paper first reviews the methods used for the monitoring and assessment of potential pillar burst in narrow vein cut-and-fill mining. The influence of horizontal stress, mine depth and pillar thickness on stress build-up in the crown pillar is examined through a characteristic narrow vein numerical model. The paper then presents, with reference to three mine case studies, the benefits of destress blasting and the factors affecting its success as a ground control technique.

Oct 1, 2001

By J. R. Rodda

Stainless steels are widely used to handle concentrated sulphuric acid (H2SO4) solutions produced in the manufacturing process, The majority of corrosion rate data published for stainless steel in product acid conditions is typically complied in tables or in iso-corrosion diagrams (iso-corrosion rates plotted as a function of temperature and H2SO4 concentration), without any reported consideration as to the accuracy and relevance of the method used to obtain the data, Given the characteristic potential cycling associated with the active-passive corrosion behaviour exhibited by stainless steel in hot, concentrated H2SO4, weight loss is considered to be a more reliable method than electrochemical measurements to measure corrosion rates, Consequently, an effort is made herein to demonstrate the accuracy and relevance of weight loss to determine laboratory corrosion rates in product acid conditions.

Jan 1, 2010

By J. Petit

"In July 2004 workers at the ABI Smelter in Bécancour (Quebec, Canada) went on strike. Contingency plan were ready to face the situation and plan was done to operate one potline out of three. Two lines were stopped; keeping in mind the restart on cold metal after the strike was over. The subject to be presented and shared includes a summary of work organization including training, schedule of restart, pot cleaning, pot preparation, crash start method, follow up after crash start, safety and environment. This major project has been a very big challenge. It shows that people involvement is a must and the key success. It is then true to say : ""People who believe in success will work and act in order to get there"" and ""People who don't believe in success will act in such a way to fail"" Then both will prove they were right to think their own way ! Sharing such experience can be interesting because it's a true story and people like true stories."

Jan 1, 2006

By L. Yacher

Most metallurgical plants already have sophisticated control systems as well as a process-historian that manage thousands of real-time and historical variables. There exists a huge potential for operational improvement through the inference of patterns, correlations and cause-effect relationships within these records. The ability to run online and offline advanced multivariate statistical analyses represents a great potential for the mining industry, in various areas such as cathode quality improvement in an SX/EX plant, the analysis of the correlation between the ore characteristics and the mill throughput, the determination of early failure alerts for major equipment, etc. The background theory is described, as well as some practical experiences of operations in Chile and Peru. Cu2007

Jan 1, 2007

By R. D. Brown

In the spring of 1977, Revenue Canada announced its intention to proceed in 1978 with a plan to impute a taxable benefit on interest-free and low-interest loans provided to employees. Such loan arrangements are often an important aspect of the compensation packages provided by many companies to their employees. Since the original announcement, there have been many submissions to Revenue Canada opposing this change, and the Finance Minister has now brought down a compromise solution with the introduction of a proposed amendment to the Income Tax Act. The amendment, which would not take effect until the 1979 taxation year, would require an employee, a shareholder or a related person to include a benefit in income measured as the difference between the interest on any such loan computed at bank prime rate and any interest actually paid. Only the amount of such a benefit in excess of $500 in a particular year would be required to be included in income. Of particular interest is the exclusion from these benefit rules of loans up to $50,000 in respect of the purchase of a house on the relocation of an employee and loans provided for the purchase of shares of an employer corporation.

Jan 1, 1978

By J. D. Corbett

The spatial coincidence of the seven anomalies is obvious, even though the self-potential is offset northward. Because the ratio, as an indicator of conductivity, is a relative estimate at best, concise interpretation is limited in almost every instance to the location of a conductor or conductor axis. When related to the initial phase of an exploration program, magnitudes and ratios similar to those obtained from any one of the methods described, would be sufficiently attractive to warrant further investigation. The compilation shown is an empirical comparison of actual field results and no emphasis has intentionally been placed on the relative merits of one method in respect to another. Too many additional factors, i.e., size, depth and conductivity of overburden, etc., that cannot unequivocally be answered, enter into such a comparison before a relative evaluation can be made.

Jan 1, 1961

In order to avoid impurity problem and enhance absorption/desorption kinetics of Mg-based compounds, nanostructured Mg-based compounds were synthesized from Mg, Ni and other elemental nanoparticles produced by hydrogen plasma-metal reaction. XRD and TEM results demonstrate that homogeneous nanostructured Mg-based compounds with less impurity were successfully synthesized by this method. DSC in hydrogen atmosphere, pressure-composition isotherm and the kinetics of hydrogen adsorption/desorption were investigated at different temperatures. The results show that the nanostructured Mg-based compounds can absorb hydrogen in a high speed at a low temperature.

Jan 1, 2005

By C. Langer

Although the existence of precious metals, particularly those of the platinum group, in the nickel ores in the Sudbury district has been known for a good many years- almost as long as the ore deposits themselves- the Mond Nickel Company were the first to effect their recovery on a commercial scale. The precious metals values of the different Sudbury ores vary considerably, and are generally higher in the copper-rich ores. These values are so very small that a direct determination in the ores gives quite unreliable results. This is not surprising if one considers that some of the ores contain on1y one unit of total precious metals in about two million units of ore, and that this one unit will consist of seven different metals, each with a different chemical behaviour. It is only after the ores have been smelted to a Bessemer matte containing about 80 per cent combined copper and nickel that the precious metals content can be determined with some degree of certainty. From the figures thus obtained, the precious metals content of the ores can be calculated, provided the tonnage of ore used to produce one ton of matte is known. The recovery of these minute quantities of precious metals out of ?such a large amount of gangue and sulphides of iron, copper, and nickel seems at first glance a commercial and technical impossibility. Nevertheless, science has found a way to conquer all the difficulties, and quite substantial quantities of the precious metals contained in the Sudbury nickel-copper ores have been regu1arly recovered for many years by the Mond Nickel Company.

Jan 1, 1927

By H. A. Baxter

THE Eustis concentrator is located about nine miles southwest of Sherbrooke, on the main line of the Quebec Central railway. The concentrator is served by a side track parallel to the main line, and all supplies for both the mine and mill are delivered at the mill yards. The concentrator treats 250 tons of copper-iron ore daily by preferential flotation, whereby, first, the copper sulphides are floated and the iron pyrite is depressed, and, second, the iron pyrite is reactivated and floated, resulting in an iron pyrite concentrate and tailing, the latter going to waste. During 1934, 71,709 tons of ore were treated, averaging 3.712 per cent copper and 32.1 percent iron, with a small amount of silver and a trace of gold. The recovery was 93.77 percent of the copper, and 70.43 percent of the iron as iron concentrate. The copper concentrate produced averaged 25.623 percent copper and the iron-pyrite concentrate averaged 42.13 percent iron and 49.173 percent sulphur. HISTORY The first mill at the Eustis mine was built in 1904 (1). For a few years previous to this rime, some jigs had been operated to concentrate the fines from the mine, the coarse ore being hand-sorted. Both the fines and sorted lump ore were shipped to acid plants. The building of the mill was based on test work carried out by Professor Robert H. Richards at the Massachusetts Institute of Technology. The method of concentration consisted in careful classification in a Richards classifier, which made six different sized products. These products went to Wilfley tables, where a concentrate, middling, and tailing were made. The middling was returned to the rolls. Crushing was done by a jaw crusher and two sets of rolls, resulting in a screen size of about five-mesh.

Jan 1, 1936

Uranium mining remains controversial in many parts of the world, especially in a post-Fukushima context, and often in areas with significant uranium resources. Although nuclear proponents point to the relatively low carbon intensity of nuclear power compared to fossil fuels, opponents argue that this will be eroded in the future as ore grades decline and energy and greenhouse gas emissions (GGEs) intensity increases as a result. Invariably both sides fail to make use of the increasingly available data reported by existing uranium mines through sustainability reporting ? allowing a comprehensive assessment of recent trends in the energy and GGEs intensity of uranium production, as well as combining this with reported mineral resources to allow more comprehensive modelling of future energy and GGEs intensity. In this study, detailed data is reported for numerous uranium mines around the world, including production, energy and GGEs intensity and reported mineral resources. An important aspect included ? arguably unique and never before published ? is the relationship between ore grade and recovery, which is crucial in future projections of uranium mining. Overall, the paper shows the importance of continuing to improve reporting by the uranium sector as well as the ability to analyse key trends and future projections in energy and GGEs intensity of uranium production.

Aug 1, 2013

By Andrew Barnes

The adsorption capacity of peat collected from a proposed mine development in northern Sweden has been determined using laboratory column experiments in which peat was irrigated with a simulated (acidic) waste rock dump leachate. The simulated leachate was made using a hydrogen peroxide leach of composite waste rock from the proposed mine development. The waste rock samples were composited in proportion to their predicted extractable tonnage for the mine development in order to generate a more representative leachate solution for the waste rock facility. As expected the test revealed that the peat material shows a very high affinity for attenuation with greater than 70% of Co, 90% of Ni and 95% of Cu removed from influent solutions through the majority of the tests demonstrating the potential benefits in mine water treatment. In contrast, it was found that Fe is initially released from the peat at concentrations up to 100 mg/L and can mean potential problems for the water released depending on the receiving environment. The exact mechanisms for Fe release is uncertain, though it is suspected that ion exchange / competitive desorption is responsible. Inspection of the laboratory results and drainage data from the natural peat wetland receiving drainage during overburden prestriping and mine development at the mine site are comparable, confirm the validity of the experiments, and further emphasize the potential for future use of pre-stripped peat material in managing water quality.

Aug 1, 2013