Search Documents

By P. Bacher, L. Dubourg, M. Jahazi, G. Dezaise

Effect of friction stir welding parameters and natural ageing on weld properties are reported. Using a Taguchi design of experiment, attempt is made to systematically examine the influences of the welding speed, tool rotation speed, forge force, tilt angle and pitch ratio on the weld size and ultimate tensile strength of FSWed joints. One millimetre thick plates of AA7075-T6 were welded in lap joint configuration. Samples were characterized by optical microscopy, hardness and tensile measurements. Trends suggested by the results and directions for further investigation are discussed.

Jan 1, 2006

By D. Seo, P. Au, X. Husang, D. Nagy

The production of single crystal (SX) turbine blades represents the current stateof- the-art in Ni-based superalloy design. With complex casting processes and alloy composition modifications, SX superalloys exhibit superior high temperature mechanical properties to their polycrystalline counterparts. Stresses and plastic deformation can occur in SX nickel-base superalloy engine components at various stages during their manufacture and use. For examples, stresses are created during initial solidification and also during solid state processing such as shot peening, grit blasting, blending, electrodischarge machining and welding. Stresses may also be created during service due to random events such as foreign object impacts. Subsequent exposure of SX to high temperatures during solution heat treatment and brazing repair can result in recrystallization which has been shown to be detrimental to both creep rupture strength and fatigue performance of the components. It is therefore the objective of this paper to understand the recrystallization behavior of two SX superalloys, PWA 1484 and 1483, subjected to pre-stressing and subsequent heat treatments.

Jan 1, 2006

By K. Bowes, M. D. Maley, R. J. Ring

The Honeymoon Uranium Project is an acid In-Situ Recovery (ISR) mine in South Australia. It was previously operated for approximately 18 months before being placed on care and maintenance in 2014, it was then acquired by Boss Resources in 2015. Boss has been performing a number of studies to plan for reopening of the mine, including a successful field leach trial (FLT) in 2017. The current configuration for uranium precipitation at Honeymoon is a batch process. Whilst this achieves effective uranium recovery, the precipitates produced are often very fine, with poor settling and solid/liquid separation characteristics. Continuous precipitation, involving recycling of solids, has reportedly been successfully utilised in other operations to increase the particle size and density of the product, leading to solids that can be more readily dewatered, dried and drummed, with less fines and dust generation. However, no operational data are available from such operations.

Jan 1, 2020

By E. Rosseland

Glencore Nikkelverk is operating its Chlorine Leach Process in Kristiansand, Norway, producing nickel, copper and cobalt metals by electrowinning. The copper tankhouse, with an annual capacity of 40 000 tons, is based on traditional technology with copper starting sheets and cast lead anodes. Due to the integration of this copper sulphate process in a nickel chloride refinery, operating conditions are unique. In recent years, operating costs have escalated, and health, safety and environment are top priorities. Test work on a new copper process involving permanent cathodes was therefore initiated in 2007, and a pilot plant was started up in 2012. The objective was to introduce innovative technologies and tailor these to be robust in the Nikkelverk process, to form a basis for a new sustainable copper tankhouse with a high degree of automation. Key learnings from more than 10 years of R&D work is presented, focusing on cathode materials and copper metal deposition including product quality, robotic stripping, coated titanium anodes, electrode contacts and alignment, electrode current monitoring with Hatch HELM tracker technology and acid mist capture using cell hoods with off-gas scrubbing. The new copper tankhouse project was approved in December 2018, and commissioning is planned in 2022. INTRODUCTION The Kristiansand nickel refinery was started up in 1910, processing nickel-copper matte originating from Norwegian mines. It was the first industrial plant in the world to produce nickel by electrolysis using the Hybinette electrorefining process. After roasting to burn off sulphur in the matte, copper was leached and recovered as cathodes by electrowinning with lead anodes. In the first years, the copper cathodes were fire- refined and cast into ingots for sale (Thonstad Sandvik, 2004). The Nikkelverk refinery was acquired by Falconbridge Ltd. in 1929, and since then matte from Sudbury, Canada has been the main feed source. The Hybinette process was in operation until 1975 when conversion to the newly developed Chlorine Leach Process was started (Stensholt, Zachariasen, & Lund, 1986). In this process still used today, nickel and part of the copper in the matte is leached using chlorine gas generated on dimensionally stable anodes in the nickel and cobalt electrowinning tankhouses, as illustrated in Figure 1. The presence of dissolved copper ions in the strong chloride leach solution is essential for effective chlorine absorption and nickel dissolution. To improve copper-nickel separation, slurry from the atmospheric leach is pumped to autoclaves and then to cementation tanks for precipitation of copper as copper sulphide, which is collected in filter presses. The leach residue, also containing the precious metals, goes through a 3-stage wash to remove chlorides before being introduced as a slurry to fluid-bed roasters for sulphur removal. The resulting calcine is then leached in spent electrolyte from the copper electrowinning tankhouse, to dissolve most of the copper and also some nickel, cobalt and other elements. After separation of the leach residue, elements like Bi, Te, As and Ag are removed from the strong copper sulphate solution by reaction with metallic copper in three columns in series filled with cut copper cathodes. The purified solution then passes polishing filters before being mixed with spent electrolyte and returned to the electrowinning cells.

Jan 1, 2019

By Qian Liu

Mining in highly stressed ground conditions has been an increasing challenge at the Brunswick Mine. Two large regional pillars were established on the 1000 m Level to support the ground for safe extraction of the surrounding ore. The South Regional Pillar contains about 5 million tonnes of ore and the North Regional Pillar has about 3 million tonnes of ore. In the fall of 2000, mining activities were suspended following a series of ground movements around the South Regional Pillar along weak geological structures. After extensive geotechnical investigations, a decision was made to carry out a mass destress blast in the West Ore Zone (WOZ) to cut the principal stress across an area of 135 m along strike and 86 m high. At the end of July 2001, the WOZ mass blast was successfully initiated. Following this success the mine decided to take a similar approach to destressing the North Regional Pillar (NRP). The final mass blast was taken in early February 2003. Advanced blasting technologies, including state of the art electronic detonators and blast simulation, played an important role in achieving the successful blasts. The high precision of delay timing and long delay duration of the electronic detonators ensured accurate and reliable initiations of over 800 blastholes in the WOZ mass blast. Orica?s DMC_Blast (Distinct Motion Code) simulation code was used to study different blasting blocks for the desired timing in the initiation sequence. This paper describes the process of applying electronic detonators in complex blasts, and discusses how blast simulation results were interpreted to guide engineering design of the mass blasts.

May 1, 2003

Building off the enthusiasm generated by Credit Suisse First Boston on the potential benefits of an industry-wide effort to market gold jewellery, a group of gold producers, led by Randall Oliphant, CEO of Barrick Gold, decides to investigate the long -term impact of launching a significant marketing initiative to stimulate demand for gold jewellery. The group establishes an international Steering Committee representing producers of differing sizes, members and non-members of the World Gold Council. This Committee comprises representatives from AngloGold, Barrick, Gympie Gold, Kinross, Randgold, and Sons of Gwalia and is supported by the Australian Gold Council, the Gold and Silver Institute, and CSFB. The Steering Committee hires McKinsey to assist it by conducting an independent review of whether investment in a large-scale marketing initiative for gold jewellery would be effective in increasing demand for gold, and ultimately of significant economic benefit of the gold industry. Based on McKinsey?s review* and its own discussions with key stakeholders across the industry, the Steering Committee strongly believes the case for marketing is compelling and sufficiently proven to persuade the industry to undertake a major initiative over the next few years. The Steering Committee, supported by McKinsey, conducts briefings with a range of gold producers to share its findings and to understand producers? perspectives on an industry-funded marketing campaign. The Steering Committee is asking for your support to bring this industry-funded marketing campaign to life.

May 1, 2002

By Ham. Y. M.

The corrosion behaviour of Al-B4C metal matrix composites immersed in 2500 ppm boron-containing H3B03, 0.5 M K2SO4, and 3.5% NaC1 solutions was investigated. Effects of B4C particle volume fraction on the corrosion behaviour of composites were studied using potentiodynamic polarization and electrochemical impedance spectroscopy techniques. Scanning electron microscopy was employed to study the surface morphology of the material before and after corrosion. Results show that all materials investigated are more corrosion resistant in 2500 ppm boron-containing H3B03 than in other solutions. No appreciable corrosion was observed in boric acid and sulfate solutions in contrast to an obvious pitting in NaC1 solution for both base alloy and composites. The preferential pitting sites are the interfaces of Al/Fe intermetallics for the base alloy, and the A1/B4C interfaces for the composites. Increasing the volume fraction of B4C particles in the composite decreases its corrosion resistance of Al-B4C composites.

Jan 1, 2011

By J. Beddoes

Many high strength aerospace alloys undergo solution heat treatment (SHT) and aging to develop precipitate strengthening. Most simply, SHT involves an isothermal hold in a single phase region followed by relatively rapid cooling to develop a super-saturated solid solution from which precipitates form during aging. However, subsequent properties are sensitively dependent on the details of the SHT, which frequently also serves a homogenization function. Altering the details of the thermal cycle during SHT significantly improves the properties attained during aging, as presented by examples of SHT design for titanium aluminide intermetallics, polycrystalline and single crystal superalloys, and 7075 aluminum.

Jan 1, 2010

By G. Goodall, D. Mercier, M. Brochu, C. Kaplin

A nanostructured CoNiCrAlY coating was obtained by thermally spraying cryomilled feedstock powder using the high-velocity oxy-fuel (HVOF) process. The oxidation behavior of the nanostructured powder and coating were compared to their conventional counterparts by performing static oxidation tests at 1000°C for durations ranging from 1 to 96 hours. It has been found that oxidation of the conventional powder yielded a duplex oxide scale composed of an inner layer of Al2O3 and an outer layer composed of Cr2O3, NiAl2O4 and other spinels. Interestingly, oxidation of the as-sprayed nanostructured coating yielded a similar duplex oxide scale while oxidation of the polished coating resulted in a single Al2O3 layer. These findings indicated that surface oxide seeds act as nucleation sites for the growth of the mixed oxide layer. Also, it was determined that nanostructuring of the coating promotes the nucleation and growth of a single and adherent a-Al2O3 layer by increasing both the number of diffusion channels and the aluminum concentration at grain boundaries.

Jan 1, 2010

By Warwick Bullen

A hypothetical economic model has been developed for diamond projects in the Canadian Arctic using data from recent exploration and mining projects. The model reflects economic conditions as it applies to the diamond mining industry in the Canadian Arctic at the present time. The economic model captures pre-production expenditures, production data, and post-production costs. Before- and after-tax cash flows are derived from the data along with the relevant economic criteria. From the corporate perspective, the model provides guidance as to the minimum size and/or in-situ value per tonne requirements of targets being sought in order to ensure economic success and probable exploration and development expenditures. From the government perspective, the model provides an indication of income and mining tax revenues that can be expected from a particular diamond project. The model shows, on average, diamond projects in the Canadian Arctic are expensive to explore for and develop, but are economically robust. They generate great economic return for mining companies and significant amounts of tax revenue for governments. The fact that diamonds can be transported directly from the mine site by air makes them particularly attractive targets for mining companies that operate in the Canadian Arctic.

Apr 1, 2005

By B. Grinbaum, A. Mazuelos, F. Carranza, N. Iglesias, M. Avila, J. L. Lozano, G. Perez, R. Romero, M. \/aliente

Following a failure of a tailings pond darn at a mine in Andalusia, Spain, a huge effluent stream, that contained about 1 g/1 Zn and significant amounts of ferrous, ferric, calcium, copper, aluminium and manganese cations has to be treated, to prevent pollution of a nature reserve. EGMASA, as the regional government environmental agency, suggested to improve the current depuration process by recovery of the Zn from the effluent. A solvent extraction (SX) followed by electrowinning (EW) was proposed and developed to remove zinc.. A pre-treatment stage consisting in bio-oxidation of ferrous iron by using a bacterial process followed by an alkaline precipitation was employed because iron in the effluent is incompatible with both the SX and the EW processes. The SX process was developed successfully at the laboratory scale and verified in a pilot plant on-site, using two Bateman Pulsed Columns for extraction and stripping of zinc. The results were satisfactory obtaining a recovery of 90% of Zn. The process was suitable for industrial application.

Jan 1, 2008

By F. Habashi

Lead is an ancient metal, has been produced to-date from its ores exclusively by pyrometallurgical route. The process suffers from high operating cost and excessive pollution problems. Extensive research has been going on since the beginning of the twentieth century to find a non-polluting process for its production and a solution for its complex refining scheme. It has been assumed correctly that the hydrometallurgical route should be the most promising. Pilot plants have been constructed and operated for a reasonable periods, but no process has proved to be satisfactory. As a result, a number of smelters and refineries have been shut down. The present review analyses the situation and suggests that the best route to treat lead sulfide concentrates is by leaching with fluoroboric acid, HBF4, containing ferric fluoroborate, Fe(BF4)3, and electrolyzing the solution in a diaphragm cell - - a process recently invented by Italian metallurgists. In this process, any silver present in the concentrate remains in the residue together with elemental sulfur and can be recovered by known methods.

Jan 1, 2008

By V. Songmene, A. Tahan, J. P. Michaud

The machining of thin wall parts, often used in the aeronautical industry still creates a number of problems, including panel deformation. Quality and productivity are often affected. This study seeks to determine the optimal conditions for cutting in order to guarantee a competitive fabrication of parts while still maintaining quality and delivery deadlines. The studied model (Spar) is a typical structural part used in the assembly of airplane wings. The main objective of this study was to improve two performance aspects: surface quality finish (quality criteria) and the rate of cutting by stock removal (economic criteria). To achieve this objective, we used an evaluation process of the geometrical error issuing from the machine-tool. We also determined the stability zones of the machine-tool's dynamic system. Finally, a series of high-speed machining tests (finishing cuts) were conducted using an experimental structured approach (16 000 - 24 000 rpm). Profile measures of surface roughness and cycle times registered during trials allowed us to establish optimal cutting conditions. Surface roughness improved as well as cutting by stock removal. Four parameters were taken into consideration: axial depth of cut, chip load, spindle speed, and cutting fluid. Finally, the influence of the type of cutting fluid was evaluated to show that it did not significantly affect machining results.

Jan 1, 2006

By W. S. (Steve) Vaughan

The Origins of Joint Ventures in Canada?s Mining Industry ? Among the most important financing structures used in our mineral industry today ? Virtually unheard of in the Canadian industry prior to the 1970s ? Borrowed from the U.S. oil and gas sector where it came into prominence in the late 1930s ? The Securities Acts of 1933 and 1934 in effect killed the sale of (equity) shares for financing oil and gas wells and start up mining companies

May 1, 2013

By R. W. Boyle

"PREFACEThis paper comprises two parts. The first part discusses lithochemical surveys based on major, minor and trace elements in whole-rock samples from primary enveloping halos. The second part continues with discussions of surveys based on leakage halos, zonation of elements, stable and radioactive isotopic distributions, geothermometric, geobarometric, thermolumin escent, pedochemical, hydrochemical, atmochemical and biogeochemical methods. A selected bibliography follows the second part of the paper.ABSTRACTAreal (two-dimensional) geochemical surveys, based mainly on secondary dispersion halos and trains in media such as surface waters, soils and drainage sediments, have proven particularly successful in recent years and have greatly assisted in the discovery of a large number of varied mineral deposits. Three-dimensional surveys based on primary halos and leakage halos have received relatively little attention by research organizations and the mineral industry. Such surveys offer many novel approaches for discovering blind mineral deposits deeply buried below overburden or within their host bedrocks. This paper reviews detailed methods for the discovery of blind mineral deposits based on sampling rocks (lithochemical methods), soils and other types of overburden (pedochemical methods), waters (hydrochemical methods), gases (atmochemical methods) and biological materials (biogeochemical methods) . All are applicable to the discovery of blind deposits; the efficacy of each or in combination depends essentially on the type of mineralization, the extent of the development of the primary and secondary dispersion halos, and the finances available for sampling techniques employing overburden drilling, bedrock drilling, and sophisticated water, gas and vegetation collection."

Jan 1, 1982

By H. A. Steane

THIS BRIEF PAPER presents the information available on the use of Dorrclon?is in the middling re-grind unit at the lead-zinc mill of Canadian Exploration Limited. The plant throughput is 1,650 tons per twenty-four hours. The flotation feed is ground to 60 per ?Cent passing through 200 mesh. It contains some composite 11articles of sphalerite in calcite, and these reported either in the final zinc concentrate, thus lowering the grade, or in the tailing, with loss of zinc. The re-grind unit was set up in the zinc flotation circuit to liberate the sphalerite from these middling particles, to raise the grade of concentrate and improve recovery. Grinding through 325 mesh should give substantial liberation of locked sphalerite. The middling regrind unit consists of two Dorrdones and one ballmill arranged as shown in the -accompanying flow-sheet. The Hardinge ball-mill, size 7 ft. x 36 in., was free for this use as a result of recent plant expansion. The two Dorrclones were purchased, and the necessary pumps and pipe lines were installed to complete the regrind unit. The unit has been developed over a period of two years by several steps and various flow schemes until reaching tl1e present flow scheme. These steps are not elaborated here, because the changes were made to determine the best product to work on for flotation metallurgy, and not because of the Domrolone classifying ability.

Jan 1, 1956

By Michael L. Free, Zongliang Zhang, Joshua M. Werner

In the copper electrowinning process, short-circuiting between the anodes and the cathodes is a critical problem that changes the current allocation among local electrodes and reduces the current efficiency significantly. Possible reasons for the short-circuiting include the improper alignment of the electrode, bent electrode, and nodules on the cathode surface. In typical tankhouses, there is often a time between shorting and harvesting as well as between shorting and clearing. Therefore, it is inevitable to have short-circuiting affect the operation performance in practical electrowinning operations. However, one key piece of missing data is the actual measurements of the current efficiency as short-circuiting is approached and allowed to continue. Consequently, short-circuiting tests that allow tracking of electrowinning parameters before and after short-circuiting were performed in a laboratory scale Cu electrowinning cell. In the tests, the electrode spacing change, the mass of electrodeposited Cu, the deposition morphology, and the current allocation as well as the current efficiency before and after short-circuiting were studied. Results show that the short- circuiting affects the current allocation and the current efficiency significantly. Moreover, it changes the Cu deposition on the short-circuited cathode and therefore causes problems for Cu electrowinning. INTRODUCTION Electrowinning (EW) is commonly used for copper production around the world, with a rated production from 120,000 to 200,000 tons per year per operation (Wiechmann, Aqueveque, Henríquez, Muñoz, & Morales, 2014). In Cu electrowinning, Cu ions in the electrolyte are reduced on the cathode surface as metallic copper with a DC current, while on the anode, a counter anodic reaction occurs with oxygen gas generation (Werner, Zeng, Free, Zhang, & Cho, 2018; Zhang, Werner, & Free, 2018; Zhang, Werner, & Free, 2018). In copper electrowinning, an average current density of 200 to 400 A/m2 is applied to the electrowinning cell (Wiechmann et al., 2014). As the Cu deposits on the cathode, the distance between anode and cathode reduces and most of the time, short-circuiting forms between some anodes and cathodes in a large tankhouse containing thousands of electrodes, reducing the current efficiency and increasing the energy consumption significantly. The current efficiency in well-run copper EW operations is typically above 90 %. Most of the unused current is wasted through short circuits, stray currents, and by-byproduct formation (Davenport, King, Schlesinger, & Biswas, 2002; Wiechmann, Vidal, Pagliero, & Gonzalez, 2002; Wiechmann, Morales, & Aqueveque, 2010). Usually, in the tankhouse, the short-circuiting increases the current in the involved cathode by up to 1500 A (Wiechmann et al., 2010). Multiple reasons can cause the short-circuiting in the cell, and the most common reasons include the uneven current distribution among cathodes, tilted electrodes, bent electrodes, and nodules formed due to the large deposition roughness. Recognition of this challenge in the Cu electrowinning process has led researchers to perform many investigations on approaches to avoid and reduce the short-circuiting in the cell. A series of research investigations have been conducted to develop and improve a new type of intercell bar for Cu electrowinning (Wiechmann et al., 2002; Wiechmann, Morales, Aqueveque, & Burgos, 2007; Wiechmann, Morales, & Aqueveque, 2009; Wiechmann et al., 2010; Wiechmann et al., 2014). The associated test results show that this new design limits the occurrence and magnitude of short circuits and allows operation at higher current densities. Sandoval, Clayton, Dominguez, Unger, and Robinson (2010) stated several keys to control short circuits, such as maintaining the straightness of the cathode, removing “edge hair” from the cathode starter, and maintaining electrode alignment in the cell. Prengaman and Siegmund (1999) from RSR technologies developed a new Pb-Ca-Sn anode to prevent the anode deformation, thereby reducing the short-circuiting in the Cu electrowinning cell. Although the negative effects of short-circuiting on the Cu electrowinning have been recognized, and various investigations have been conducted to address this issue, the actual measurements of the electrowinning behavior and performance as short-circuiting is approached and allowed to continue are seldom reported. However, in typical tankhouses, there is a time between when shorting occurs and harvesting/clearing are performed. One key factor in determining the harvest time is the frequency of shorting. Consequently, we have performed short-circuiting tests that allow us to track electrowinning parameters before and after short-circuiting.

Jan 1, 2019

By D. B. Nazzer

"ANY DISCUSSION of energy today is incomplete without consideration of nuclear energy. In the Maritimes, with plentiful supplies of coal, with relatively easy availabilty of imported oil brought in to the deepwater terminals, with future sources of large supplies of oil and gas anticipated from under our neighbouring continental shelf, and with the Fundy tides, you may question why nuclear energy should be considered. What follows may not give you a specific answer to that question, but it may provide a basis for better understanding. Energy from the sun, from hydraulic sources and from combustion has been available to man from prehistoric times, for thousands of years, but the most sophisticated source of energy, the actual conversion of matter into energy by man, has been developed entirely within the last one-third century, since the discovery of fission in 1939, and the application to generation of electric power has all been done within a generation or less. The pressure of military needs during and after the second world war was largely responsible for the speed of initial development, by funding and focussing the effort needed to develop the basic technology, and in particular materials. The U.S. defence program yielded, for example, the large-scale isotope separation processes for fissile U'35 and for heavy water. The nuclear submarine program yielded zircaloy, a key structural material for the core of the Canadian Candu type reactor."

Jan 1, 1972

By C. Doyle, D. M. Hoffman, C. Díaz, J. Hrepic, W. J. Koshut, R. H. Hanewald

"Recently, lining life of the INMETCO submerged arc furnace has been dramatically extended from an average of eleven months in the 1980s to a current record of 34 months. This paper summarizes test work and operating results describing the development and establishment of slag parameters that reduce corrosion of the magnesite-chrome refractory lining.The desired slag parameters are now maintained by utilizing waste streams as slag additives. This paper also discusses the successful evaluation of a rebonded-fused-grain magnesite- chrome refractory as a lower cost, more thermo-mechanically forgiving alternative to a fused-cast magnesite-chrome refractory that had been the refractory of choice in previous years at INMETCO.IntroductionSince 1978, INMETCO, a wholly owned subsidiary of INCO Limited, has been well known for recycling by-products from the production of stainless steel, namely, EAF bag- house dust, mill scale and grinding swarf. INMETCO operates the only smelter in North America dedicated to the recovery of nickel, chromium, and iron from hazardous and nonhazardous waste. The process was developed in the research laboratories of INCO. In recent years, the process has been successfully modified to accept a wider variety of other specialty steel waste streams including: spent pickling solutions, pickling and waste water treatment filter cakes, acid scale, carbon brick, spent bag-house bags, torch cutter dust, spent dolomitic and chromium-bearing refractories, and rechargeable nickel-cadmium batteries."

Jan 1, 1997

By K. M. Sarkar

"In many plant trial s(1,2) it has been proven that very small amounts (10 to 20 ppm) of uranium dissolved in mine water can be effectively recovered by the use of ion exchange resins and this uranium recovery has many advantages. In this paper an economic analysis at different levels of uranium contamination and at different market prices of uranium are described.For this study an operating mine-mill complex with a sulphuric acid leach circuit, followed by solvent extraction (SX) process, is considered, where contaminated mine water is available in excess of process requirements. lt is further assumed that the sulphuric acid eluant containing uranium would be mixed with the mill pregnant liquor stream that proceeds to the SX plant for final uranium recovery.Recovery by Ion ExchangeMine water, in this study, is defined as the water coming from the underground mine, or mine pits, and the run-off water from stockpiles, mine shops, crushing plant , washdown areas, etc.In nature, uranium mainly occurs in two stages; reduced (tetravalent) and oxidized (hexavalent) . The oxidation of sulphides present in the orebody often causes the presence of S04- and acidity in mine water, and this acidic water readily dissolves U+6 part of the depo sit. The react ion between hexavalent uranium, which is dissolved in water as U02+ 2 cation and S04 producing uranyl sulph ate as,"

Jan 1, 1984