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By Sylvie Lévesque, Cory Hennessey, Daniel Amariei

"In the iron ore industry, fine particles recovery is an important concern in terms of process performance and production costs. Continuous efforts are thus devoted to increase the efficiency in handling these fines.The Reflux Classifier (RC) is a relatively new technology that is mainly used in the coal and industrial minerals industries. The operating principle of this system is based on three mechanisms: hindered settling, autogenous dense medium and lamella settling. A preliminary evaluation of the Reflux Classifier technology for the beneficiation of iron ore fines was formerly done at the pilot scale using a RCTM300 unit. The good results obtained, using iron ore fines from screened spiral stream, made this technology very attractive for the iron industry. However, the high capacity of the RCTM300 unit (1–3 t/h), makes it unsuitable for R&D purposes. Thus, a smaller unit, the RCTM100, was assessed to validate the performances obtained with the RCTM300.This paper summarizes the performances obtained with the RCTM100. The challenges of the scale-down related to the adaptability of this technology to the iron ore industry are also presented. The results are compared to the RCTM300 performances, as well as benchmarked against sink-float tests. The metallurgical results on feed and products issued after the test work with the RCTM100 unit are supported by mineralogical characterization using a Mineral Liberation Analyzer.INTRODUCTIONFine particles recovery by physical separation means is a historical concern (Holland-Batt, 1992; Peukert and Wadenpohl, 2001; Srivastavaa et al., 2001; Majumder et al., 2003). Attempts to improve fine particle recovery at the laboratory, pilot and industrial scales adopting different strategies with traditional equipment or assessing new promising devices such as the MGS (multi-gravity separator), the Kelsey jig, the Yang jig, etc. (Kim, 2002; Goudreau, 2008; Kerr, 2012) have yielded variable success."

Jan 1, 2016

By E. Asselin

Electrochemical polarization experiments were conducted on alloy 625 in ammonia solution between 25 and 225°C and the results were compared with those of an oxygen solubility model. Results confirm that corrosion is under oxygen control, Normalized corrosion rates are determined based on the rate of oxygen diffusion to the corroding surface, and the corrosion rate at 200°C (-9.7 µA.cm-2) is roughly 24 times higher than the corrosion rate at 25°C (0.4 nA,cm-2), An oxygen-solubility model for Supercritical Water Oxidation (SCWO) conditions was generated using the Redlich¬Kwong-Soave (RKS) equation of state, Results of the model confirm many of the experimental observations from SCWO reactors which suggest that corrosion is at a maximum at temperatures just short of the critical point, The RKS/oxygen diffusion model predicts that the corrosion rate at 365° C is ?85 times higher than the corrosion rate at 25' C. Given that a normalized corrosion rate is obtained, this type of model could be useful for selection of SCWO reactor materials.

Jan 1, 2005

By Y. Huang

Corrosion of GaAs in aqueous electrolytes is a major limitation in implementing GaAs-based photoelectrochemical solar energy conversion systems, In this work, the corrosion behavior was investigated by electrochemical methods and surface analysis approaches, in both H2SO4 and NH3?H2O solutions, Open-circuit measurements showed that the cleaned GaAs surface was very sensitive to water/air, Impedance measurements for n-GaAs showed that an inductive loop only appeared at a high corrosion rate because a reaction intermediate is the oxidant for a further decomposition step in combination with chemical reaction with water, The results suggest that the same corrosion/decomposition mechanism occurred on n-GaAs in the two solutions, When the surface-hole concentration was low, the hole injection or generation process was the rate-determining step, At large reverse bias on n-GaAs, with high-hole concentration, the corrosion rate was limited by a Faradaic adsorption process, involving an adsorbed intermediate, The different surface compositions after corrosion in the two solutions can be explained by the dissolution of As(0), Further oxidation of As(0) to As(III) in NH3?H2O solution is still slow, as suggested from X-ray photoelectron spectroscopy (XPS) analysis,

Jan 1, 2005

By K. Krishnapisharody, S. Clark, M. Barati

Different gas purging methods to metallurgical baths have been applied to date, among which are top lancing and bottom blowing through tuyeres or porous plugs. Among these, the porous plug bottom blowing technique has shown higher efficiency in gas utilization than tuyeres and top blowing, due to smaller bubble size and lower liquid velocity. However, the studies related to bottom stirring of metallurgical baths are limited to slag-less or thin slag-covered melts. In particular, there is no examination of stirring ability in conditions similar to Falconbridge's Slag Make Converter, where the bath is covered with a thick slag layer and a stream of solids is charged on the bath from top. This study was undertaken to investigate the application of gas purging through a porous plug in stirring in and melting of the solid feeds. The spreading behaviour and melting time of a solid layer forming on a plume created by stirring were calculated using the existing models. The results show that formation of a thick solid layer, specifically in areas beyond the plume region is very likely. Nevertheless, the thickness of the layer and melting time do not appear unreasonably high. It is predicted that by proper controlling of gas flowrate and plug configurations, successful solid charging through the mouth can be practiced.

Jan 1, 2007

By K. Hanumantha Rao, A. Javadi

Our recent studies revealed that the sulfide minerals in contact with water during grinding produced hydrogen peroxide (H2O2) where the amount of H2O2 production by the minerals found to be in the order of pyrite > chalcopyrite > sphalerite > galena. The H2O2 effect on the oxidation of pulp components and its influence on the concentrate grade and recovery in flotation have been studied and the results have been presented and discussed in this paper. Studies have also been carried out to build correlation between percentage of pyrite in the concentrate, grinding conditions and concentration of OH•/H2O2 in the pulp and as well of controlling the formation of these species through known chemical means for depressing the generation of the oxidant. Flotation tests using a complex sulfide ore with the same reagent scheme that is being used at Boliden concentrator in Sweden but with the addition of i) collector and depressant, ii) Na2S reductant and iii) inorganic (EDTA) and organic (TETA) surface modifiers, during grinding stage have been performed to judge the beneficial or detrimental role of H2O2 on the selective flotation of sulfides. The results demonstrate that the selectivity of metal sulfides against pyrite increases with increasing generation of H2O2 in the pulp liquid. H2O2 is also found to be a better oxidant in chalcopyrite-galena flotation separation than the commonly used K2Cr2O7.

Jan 1, 2016

By K. El-Ouassiti, M. Zouadi, C. Bazin, D. Hodouin

Data reconciliation techniques are used to attenuate the effect of measurement errors and estimate unmeasured variables. This paper illustrates the application of data reconciliation to hydrometallurgy processes using measurements from leaching and solvent extraction obtained from laboratory experiments. The application of data reconciliation provides an efficient way to detect gross and systematic errors and produces reliable performance indices for process evaluation.

Jan 1, 2005

By H. Al-Kazzaz

The 2-mm butt joints of ZE41A-T5 sand castings were laser welded using 1.6 mm EZ33A-T5 filler wire and a continuous wave Nd:YAG system at a power of 4 kW, surface defocusing and various welding speeds, Compared with the base metal, the fusion zone showed significant grain refinement due to high cooling rate, No grain coarsening was observed in the heat affected zone (HAZ). The porosity area percentage and total solidification crack length in the fusion zone (FZ) were reduced as the welding speed increased from 4 to 7 m/min, Fusion zone area, total penetration depth, and weld width decreased with increased welding speed, The hardness in the FZ was similar to or higher than the base metal after a natural aging of about one year, but there was a drop in the hardness of the HAZ, The HAZ width decreased with increasing the welding speed, Tensile test showed that a joint efficiency of approximately 75 ? 90 % was obtained.

Jan 1, 2005

By R. C. Gilmore

Underground longwall coal mining sections may develop explosive mixtures of methane-air in the mined-out gobs. If the panel are operated as bleederless or sealed gobs, progressive sealing along the gate roads as the longwall face retreats limits the flow of fresh air into the gob and thus deprives potentially explosive atmospheres of oxygen. In a project sponsored by the National Institute for Occupational Safety and Health (NIOSH), researchers at the Colorado School of Mines have used computational fluid dynamics (CFD) modelling to simulate the flow of gases in longwall gobs. Modelling indicates that targeted injection of nitrogen through the seals along the gate roads inbye the face can be used to control the size and location of methane and air clouds within the gob and to minimize or eliminate the explosion hazard resulting from the formation of flammable methane-air mixtures in longwall gobs.

Aug 1, 2013

By Isabel C. B Rodrigues, Flávia D. Reis, Versiane A. Leão, Rosa M. F. Lima

Attention has been focused in recent decades upon the precipitation of metal sulphides from acid mine drainage (AMD) and pregnant leach solutions, due to the advantages of the sulphide precipitation process over traditional methods employing hydroxides. The aim of this work was thus to explore technologies for copper precipitation using either Na2S or biogenic sulphide. The recovery of copper sulphide was improved when the initial pH of the solution containing each metal was 4 or excess sulphide was employed. In such, a condition the removal efficiency was 99.9%, corresponding to a residual level of 0.1mg/L for copper in solution. Kinetic parameters for precipitation were determined from the particle size distributions using the method of moments, where the growth and nucleation rates, as well the agglomeration kernel, were calculated. The biogenic sulphide was a suitable alternative to sodium sulphide for copper removal as either sodium sulphide and biogenic sulphide can be utilized to precipitate such a metal allowing the effluent to be compliant with environmental legislation.

Jan 1, 2014

By M. G. Stamatakis, C. Zagouroglou, C. Helvaci, J. Kanaris

"Abstract -Borate minerals, such as colemanite, ulexite and borax, have been reported in Tertiary continental basins of West Anatolia, Turkey, and Samos Island, Greece.Tuffaceous rocks interbedded with the borates are rich in authigenic silicate minerals such as zeolites, potassium feldspar and opal-CT, all of which have a genetic association with the borates. Chemical analyses of the tuffaceous rocks show variation in major elements due to the varying percentage of carbonaceous, detrital, and volcanic derived material.The volcanic activity in the vicinity of each particular lacustrine basin created ion-rich fluids from which a series of borates were precipitated under arid climate. Additionally, the saline-alkaline character of these fluids was responsible for the diagenesis of the silicic glass of the tuffaceous rocks, altering them to silicates and silica polymorphs."

Jan 1, 1993

The SART (sulfidisation, acidification, recycle, and thickening) process is an effective way to separate copper and cyanide from each other in the waste stream of gold processing plants using cyanidation. Factorial experimentation has been conducted to create models of copper recovery, cyanide recovery, acid addition, and oxidation I reduction potential during SART. Economic analysis of the resultant models showed that SART is best operated with a sulfide to copper molar ratio of around 0.56, a pH of 4, and a minimised cyanide to copper molar ratio. The experiments also showed that thickening time may have drastic impacts on SART performance.

Jan 1, 2011

By H. J. McQueen

The irregular history of Mg wrought products is briefly described. The temperature and strain rate dependence of microstructural evolution, flow stress and ductility of Mg alloys in hot working, are described. The flow curves rose rapidly to a peak stress which was lower as temperature T rose and strain rate e declined and above 300°C the curves extended into plateaus until failure. Clearly grains not oriented for slip undergo mechanical twinning in the initial stages (a 0.15) at all temperatures. Basal slip proceeds in suitable grains and in the twins. The stress concentrations at grain and twin boundaries lead to slip on non-basal systems and to the formation of subgrains with greater dynamic recovery (DRV) at higher T or lower e. With increasing strain, misorientation builds up resulting in dynamic recrystallization (DRX) first at twin intersections and later at grain boundaries which have become quite serrated. Even after extensive straining at high temperatures, the new grains are found mainly along the boundaries of the original grains, leaving their centers with only basal slip except when nucleation at twins leads to completion of DRX throughout a grain. Despite similar shear modulus and melting point to Al, hot mechanical forming behavior of Mg alloys differ due to differences in crystal slip systems, twinning, and second phases. Moreover, the influences on forming of alloy additions (solutes, segregation in casting, dispersoids, precipitation) and impurities are not as well catalogued as for Al. Despite the benefits from dynamic recrystallization, varied grain orientation effects, heterogeneous substructures and the resulting stress concentrations result in considerably lower ductility for Mg alloys at the same stress level as for Al materials. Application of these theories to extrusion, rolling and forging and the effects on product properties are surveyed.

Jan 1, 2006

By Matt Manson

Diamonds in Canada: Recent Advances in Exploration Methodology and Advanced Stage Assessment 1. Exploration Methodologies ? Prospectivity Mapping ? Surficial Geochemistry ? Geophysics 2. Advanced Stage Assessment ? Petrology and Diamond Paragenesis ? Micro/Macro ratios and Macro grades ? Value Sampling and Modeling

Apr 1, 2005

By D. Song

In this paper, the differential equations governing the mass transport and the electrochemical reaction in a cathode catalyst layer of polymer electrolyte membrane fuel cells are solved based on the polynomial series expansion method. Explicit expressions for the polarization curve as well as for the distributions of oxygen, current density and overpotential are obtained when a quadratic, cubic or quartic polynomial is employed to approximate the oxygen concentration distribution. These kinds of explicit solutions are desirable for MEA design and diagnosis purposes. The comparison between the conventional numerical approach and the explicit solution approach proposed here shows that satisfactory accuracy can be reached by the first four terms of the polynomial series. The effect of the catalyst layer thickness on the accuracy of the obtained explicit polynomial solutions is also discussed.

Jan 1, 2005

By F. Habashi

Magnesium is the eighth most abundant element in the earth's crust, It occurs in nature in sea water, brines, and a number of minerals, Metallic magnesium was first isolated by Humphry Davy (1778-1829) in England in 1808 via electrolysis of anhydrous magnesium chloride with a mercury cathode, Antoine Bussy (1794-1882) in France extracted the metal in 1828 by reducing fused magnesium chloride with metallic po¬tassium vapour, The first industrial production of magnesium by electrolysis of molten carnallite began in 1886 in Hemelingen in Germany, In 1940 Lloyd M, Pidgeon (1903¬1999) in Canada pioneered the first industrial metallothermic magnesium extraction plant based on the reduction of dolomite with ferrosilicon under vacuum, Since then the magnesium industry developed further and a variety of processes are presently used.

Jan 1, 2006

By A. J. Brown

This paper presents an economic evaluation of resin ion exchange and solvent extraction for the purification and concentration of uraniferous solutions derived from sulphuric acid leaching operations. Capital and operating costs are related to the uranium tenors of pregnant solutions. The conclusions drawn herein apply only to cases where resin and liquid ion exchange are technically feasible process alternatives. It is shown that solvent extraction is economically favoured for pregnant solutions at tenors greater than 0.90 gpl U3O8. Pregnant solutions with tenors below 0.35 gpl U3O8 are best treated by resin ion exchange. Between these concentrations, the economics are marginal and the favoured process is indistinguishable within the limits of accuracy of this study.

Jan 1, 1979

By R. Gatzweiler

The Key Lake nickel-uranium deposits are situated within the Wollaston domain of the Churchill structural province. The host rocks of the two orebodies are of Aphebian and Helikian age. The orebodies occur mainly within a 5.2-km-Iong, northeast-trending zone which coincides with the intersection of the sub-Athabasca unconformity and a reverse fault striking east-northeast. The principal controls of mineralization are structural and lithostratigraphic (i.e., post-Athabasca faults, the sub-Athabasca unconformity and graphitic metapelites in the lower Aphebian, close to the Aphebian/Archean unconformity). Grades of up to 35% U3O8 and 20% Ni are recorded over intervals of up to 2 m. Some hypogene zonation exists and the nickel mineralization tends to underlie the high-grade uranium ore. The ore minerals include pitchblende, a-U307, coffinite, gersdorffite, millerite, niccolite, bravoite, zoisite, sericite, chlorite and kaolinite. The kaolinite is a post-ore, supergene alteration product. Chemical studies of the sub-Athabasca paleo weathering profile sho w that regolithization is characterized by depletion in Si02 and K20 and concomitant enrichment in Al203 and perhaps MgO. In the paleoweathering profile the ferromagnes ian minerals are chloritized, the Ksfeldspars sericitized and the plagioclase saussuritized. Preliminary geochronologic data from the ores reveal U/Pb ages of -1228 my, - 960 my and 89 my, and Rb /Sr data indicate basement ages of -1850 my and - 1372 my. Aphebian pelitic protoliths, carrying U and Ni, may have released some metals during post-Hudsonian weathering, and minor concentration in structural and geochemical traps may have taken place prior to the deposition of the Athabasca strata. However, it is felt that the bulk ofthe ore-grade mineralization wasgenerated after the deposition of the Athabasca formation and after faulting, probably during a major regional thermal/ intrusive episode of Grenvillian age. Several episodes of remobilization took place between 1228and 89 my ago.

Jan 1, 1979

By J. A. Bossert

"In 1957, the Department of Mines and Technical Surveys (now Energy, Mines and Resources Canada) issued their first certificate for a fire-resistant conveyor belt. The testing procedure used was a combination of those used in the U.S.A. and the U.K. Subsequently, certification was granted to fire resistant electric cables (1974), fire-resistant mine duct material (1976) and fire-resistant hydraulic fluids (1978).Until recently, the testing procedures were copied from either the U.S. or the U.K. However, since the founding of the new Canadian Standards Association (CSA) Steering Committee for Electrical/Mechanical Mine Safety in 1981, these requirements have come under the close scrutiny of new CSA technical committees who will attempt to adopt or change the existing procedures to meet Canadian needs. This paper outlines the existing test requirements and attempts to predict how they will appear after ""Canadianization"" by the CSA committees.IntroductionFires in underground mines have always been considered more serious than in other locations because of the confined space and limited atmosphere. A fire can make escape difficult or impossible if it is blocking all of the routes to the surface. Also, the products of combustion from an underground fire can asphyxiate anyone not having self-contained breathing apparatus.In an underground coal mine, the consequences of a fire can be even more serious because of the presence of methane and coal dust in the atmosphere (which can explode) and because the coal itself is combustible.For these reasons, the inspection authorities having jurisdiction over underground mine s in Canada are quite concerned about the flammability of any materials that are used in quantity in the underground environmentAs early as 1957, the Canadian Explosive Atmospheres Laboratory (CEAL) was asked to certify conveyor belting as fire-resistant. This is because many miles of this material are used in underground mines in Canada and, as it generally travels through the mine, it is a perfect vehicle for spreading a fire."

Jan 1, 1982

By Carl Pelletier

The Sigma-Lamaque Complex is considered a lode-gold deposit characterized by narrow vein structures, which have been mined historically by underground methods. In addition to the narrow vertical structures, mining also took place on horizontal veins, ?North Dipper? veins and dykes mineralized with sub-horizontal veins and stringers. Over the 60 + years of production, mining took place to a depth of 1.8 km. The upper portion of the deposit was considered all but exhausted, when viewed from an underground mining perspective. The year 1998 is considered a turning point for the Complex when a small open pit was mined at Sigma. The resource evaluation methods used underground were applied to surface mining, which allowed small pits to be mined. The resource evaluation method considered only the narrow vertical structures and was not well adapted to open pit mining. As a consequence, resources were consistently under evaluated. It became clear that a new geological approach was necessary to more accurately define resources (i.e., what was being mined). In order to integrate all characteristics (geometry, mechanics and chronology) of this complex lode-gold deposit, a new geological model was proposed. Due to this new approach, dating to February 2000 and updated in December 2000, the reserves evaluated in the first 180 meters now stand at 15 million tonnes @ 2.61 g/t Au (1,265,350 oz). Those reserves cover an east-west corridor extending 1,500 m by 750 m.

May 1, 2001

By Ltd. (CYMCO) Technology Center Yunnan Metallurgical Group Co., S. Jian, T. Song, J. D. Miller

"As sulfide zinc ore deposits become exhausted, nonsulfide zinc ore deposits become the other resource for zinc production. However, flotation for zinc recovery from nonsulfide deposits is much more difficult than the flotation of sphalerite from sulfide deposits and may become an option for zinc production only if a suitable processing technology is developed. In this regard, research efforts are being devoted to the flotation of nonsulfide zinc oxide minerals. Some common methods which have been used for the flotation of zinc oxide minerals include sulfidization-flotation, activation, and direct flotation with anionic and cationic collectors. The traditional flotation techniques have low efficiency and difficulty in separation and recovery of the zinc minerals from gangue minerals, for example, smithsonite (ZnCO3) from other carbonate gangue minerals and hemimorphite (Zn4Si2O7 (OH)2·H2O) from silicate gangue minerals. In this study potassium lauryl phosphate was evaluated as a collector for the flotation of nonsulfide zinc minerals. Results from contact angle and microflotation experiments at pH 6–9 show that hemimorphite (Zn4Si2O7 (OH)2·H2O) can be floated from quartz and that smithsonite (ZnCO3) can be floated from calcite. However, when dodecylamine, which is a common collector reported in literature for the flotation of nonsulfide zinc minerals, was used as collector, no significant difference between nonsulfide zinc minerals and gangue minerals was observed at any pH value. Initial evaluation suggests that potassium lauryl phosphate is effective at low concentration and may be a promising collector for zinc oxide mineral flotation.INTRODUCTIONBefore the twentieth century, zinc was mainly produced from nonsulfide ores (Large, 2001; Gilg, Boni, & Cook, 2008). With the development of differential flotation processes in the late 19th century major production switched from nonsulfide zinc sources to sulfide zinc ores (Hitzman, Reynolds, Sangster, Allen, & Carman, 2003; Gilg et al., 2008). However, as it is becoming more difficult to find new sulfide ores, recovery from nonsulfide deposits is being considered. Nonsulfide flotation for zinc recovery is much more difficult than the flotation recovery of sphalerite from sulfide deposits and may become an option for zinc production if a suitable technology is developed. Zinc and lead oxide ores are difficult to beneficiate ores due to their similar floatability with gangue, high solubility in water, and the influence of slimes (Fa, Miller, Tao, & Li, 2005). In order to improve the performance of oxidized minerals, lots of effort is being devoted to this field of study (Ejtemaei & Mahdi, 2014)."

Jan 1, 2016