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By J. S. Dunning

The Bureau of Mines investigated a series of Fe-Al-Mo alloys strengthened by ZrC (zirconium carbide) precipitates as chromium-free substitutes for stainless steels. Melting and fabrication methods were devised, and the effects of minor additions of columbium (niobium) and cerium on the mechanical properties and oxidation resistance were determined. Zirconium carbides could not be con-trolled reliably to produce fine precipitate dispersions. A more reliable carbide strengthening mechanism is required if the high-temperature strengths of types 304 and 316 stainless steels are to be duplicated. Workability and oxidation resistance of the alloy series were excellent.

Jan 1, 1982

By James E. Hill

In the course of exploratory drilling during World War II by the Bureau of Mines under the Strategic and Critical Minerals investigations Program, a problem arose as to the ultimate disposal of the drill core resulting from that program. The difficulties experienced in obtaining factual information to evaluate mineral deposits examined (during that program) influenced the Bureau in a decision to catalog and store the drill cores for future reference. Initially, the drill cores were stored at the nearest Bureau of Mines station that had space available for the purpose. Recently the Bureau stations at Minneapolis, Minn., and Denver, Colo., were designated as the locations of permanent drill-core storage facilities. Drill cores that are retained from Bureau of Mines mineral-exploration projects are stored at these two locations and are given preference in selecting cores for storage. Drill cores are accepted also for storage from other Government agencies, State agencies, private companies, or individuals on the basis of available facilities and consistent with the significance of the core in relation to Bureau of Mines objectives and national interest. Selection and acceptance of such drill core are determined by the Bureau of Mines. The drill cores stored at the two locations are available for inspection by any person having a legitimate interest in the mineral deposits represented by the cores. Approximately 1,850,000 feet of drill core can be stared in the facilities now available to the Bureau of Mines. Approximately 475,000 feet of drill care is stored or scheduled for storage at Minneapolis, Minn., and 240,000 feet of core stored or scheduled for storage at Denver, Colo. A list of drill core now in storage at the Bureau of Mines core-storage facilities at Denver and Minneapolis is included as appendix A.

Jan 1, 1957

By L. A. Stewart

"SUMMARYThis paper describes most of the chrysotile-asbestos deposits of Arizona. Mining methods are discussed briefly and asbestos-mill flowsheets are incorporated. Arizona asbestos mines are the only sources on the American continents of naturally iron-free chrysotile spinning fiber that is so urgently needed for electric-cable coverings, especially on warships.Asbestos was first recorded and recognized in Arizona in 1872, and a minor amount was produced from a deposit in the Grand Canyon in 1900. The discovery of a deposit in the Salt River district in 1912 initiated intensive prospecting, and deposits soon were developed. The total Arizona production of all grades of asbestos through 1953 is estimated at 30,000 to 35,000 tons.The deposits of the Central Arizona region, which are discussed in this paper, are scattered over nearly 2,000 square miles. The annual output is relatively small, because the asbestos occurs in thin, discontinuous veins and only in areas where intrusions of diabase are adjacent to or crosscut certain favorable units of the pre-Cambrian Mescal limestone. This stratigraphic limitation, combined with other essential geologic conditions, tends to restrict the size of the deposits.Virtually all of the deposits are in rugged, mountainous country, and many of the mines are on steep canyon walls. In the average mine, production of 1 ton of commercial asbestos requires removal of 30 to 40 tons of waste rock. Mining and transportation costs consequently are high.Several deposits of chrysotile that is somewhat harsh and of moderate tensile strength have been known for years but were not worked because of the former exacting demands of industry for high-strength, soft asbestos. However, improve¬ments in asbestos fiberization and spinning technique, combined with the urgent need for asbestos, have made this so-called semisoft fiber desirable, and deposits of this type now are being exploited."

Jan 1, 1955

By M. B. Cooke

An analytical method for the determination of the gum-forming material in gasoline has been developed by the Bureau of Mines, during a study nor in progress to determine the best rays for elimination of such constituents from gasoline. This method is similar in principle to that previously described by Smith end Cooke,2 which involved evaporation of e sample of gasoline in a small glass dish. The evaporation was started on an actively boiling steam bath and completed in an air oven at 105°C. In the improved method described below, the stem bath has been replaced by a steam heated oven in which an inert atmosphere is maintained. Air is excluded from the oven, consequently the precision of the determination is increased. Furthermore, evaporating dishes different from those previously described may be used.

Jan 1, 1925

By S. H. Katz

Artisans and laborers in mineral industries where the air is dusty with particles of reel: are subject to a peculiar pulmonary disease known as miners' phthisis or stone cutters' consumption. In granite cutters the disease is specifically designated as granite pneumoconiosis. Very fine particles of the harder rocks are especially injurious when inhaled into the lungs. It is estimated particles about one micron (1/23000 part of an inch in diameter) are most injurious, because larger particles are more readily removed by the cilia and,wet surfaces of the respiratory passages before reaching the lungs, while smaller particles either do not readily lodge or are more easily eliminated. Silica, of which quartz and flint are composed, and which forms a large part of granite, is one of the hardest of the common rock-forming materials. It is also very insoluble when silica lodges in the lungs elimination is difficult. Rock constituents of granite other than silica are probably injurious but in a lesser degree, and this is also probably true of limestone and the softer rocks. Ultimately a worker who daily inhales much granite dust has considerable deposited in his lungs. If he continues at his trade the lung tissue becomes harder and less elastic, he finds himself short winded, and in extreme cases death may come either directly or indirectly as a result of lung failure.

Feb 1, 1921

Water infiltration control techniques are designed to reduce the total volume of water entering an underground mine, and thus, reduce the volume of mine water discharge During the development of underground mines, water may be encountered in various quantities This water must be pumped from the mine during active mining, and in many situations, the weight of water removed will be more than the total weight of mineral extracted After abandonment of the mine, infiltrating water either floods the mine workings or discharges from the mine (27, 127) Infiltrating water may enter underground mines from above, below, or laterally through adjacent rock strata Earth fractures such as faults, joints, and roof fractures resulting from surface subsidence are commonly primary causes of water entrance Into abandoned underground mines Factors affecting the quantity of water entering a mine will be the depth of the mine, location of water bearing strata, and ground water flow patterns Investigations of the quantity of water entering underground coal mines have found the average rate of infiltration to range from approximately 6,262 to 10,280 liters per hectare per day (670 to 1,100 gal/acre/day) (27) Water flowing through underground mines flushes pollutants from the mine and may result in their discharge to the environment A reduction in the amount of flow usually results in a reduction in total pollution load discharging from the mine The techniques discussed in this section can be used to reduce the volume of surface and groundwater available to enter the mine system and transport pollutants The selection of a control technique will depend upon the characteristics of the mine system and the expected cost effectiveness of the technique In order for water infiltration control to be effective in controlling mine drainage pollution, the reduction in mine water flow must not be accompanied by an increase in concentration of pollutants (127) REFERENCES 2, 27, 51, 58, 127, 132

Jan 1, 1975

By Fred A. Williams

The cause of many deaths and extensive property damage in coal mines resulting from explosions and mine fires has been directly attributable to electric cable failures (including splice failures). The Federal Bureau of Mines data show that out of 355 underground coal mine fires investigated from July 1952 to January 1960, 103 (29 percent) were directly related to trailing cables. These cable failures resulted in the death of 7 men and injuries to 37 others. These potential hazards have become greater, obviously, through the widespread adoption of mechanized mining methods with electric-driven machinery powered through trailing cables according to Young,4 68.1 percent of the total bituminous and lignite production of the United States was mined underground in 1959. About 85 percent of this production was attained by mechanized loading methods. A large majority of the mines using the hand- loading methods also used equipment with trailing cables such as cutting machines, drills, and gathering locomotives. The problem of minimizing the loss of life, resources, and equipment from cable failures should be of concern to the management of all coal mines. It would be misleading to imply that no consideration has been given to the problem and its associated hazards. Through research cable manufacturers have endeavored to develop trailing cables that will withstand the severe service imposed by underground mining conditions. Technical research groups have undertaken studies for determining improved procedure and materials for field splices. Coal companies have instituted cable maintenance programs with a view toward the reduction of cable failures and consequent improvement in safety and efficiency of operations. Safety agencies are alert to unsatisfactory cable handling practices, poor workmanship in field splicing, mechanical

Jan 1, 1962

By D. S. Burgess

The characteristics of gas-phase detonations were observed in 20 instrumented firings within earthen tunnels, in 100 such detonations in a 24-in-diam by l63-ft-long steel pipe, and in about 200 smaller scale firings. Most of the fuels studied were representative hydrocarbons--acetylene, propane, gasoline, and a roughly equimolar mixture of methylacetylene, propadiene, and propane. In a pipe with two closed ends, the detonable limits were demonstrated to be very nearly the same as reported limits of flammability. The side-on impulses (pressures integrated over 200-msec intervals) were shown to be the same function of concentration regardless of whether deflagration or detonation had occurred. In a pipe with only the initiation end closed, the impulses of all fuel-air systems tended toward the same level when averaged over comparable ranges of fuel concentration; the lower pressures with saturated hydrocarbons were nearly compensated by longer durations of pressure transient. In all fuel-air systems, unexpectedly high impulses were obtained with slightly lean mixtures. In earthen confining structures, the impulse, of the explosion was efficiently converted into momentum of the failing wall. In the configurations studied, an earth velocity of about 20 fps was critical to overcome the soil's resistance to shear. The destructive effect was determined by gas pressure rather than by total energy release. The assignment of a "TNT equivalent" to an explosive gas mixture is discussed in terms of the confinement of the mixture.

Jan 1, 1968

By T. L. Hebble

The Bureau of Mines investigated a hydrometallurgical procedure to recover Co, Ni, and Cu from an electrolytic zinc industrial copper filter cake. The copper filter cake is presently unmarketable or of low value because economic and environmentally acceptable processing technology is lacking. Research by the Bureau of Mines has developed a multistage process for recovering or recycling over 93 pct of the Zn, Cd, Cu, Co, and Ni from this material. The stages involved are (1) wet sizing, (2) H2S04 leaching of undersized material, (3) H2S04-Mn02 leaching of H2S04 leach residue, (4) selective precipitation of As, Cu, and Co-Ni products, and (5) precipitation of manganese for recycling to the leach circuit. The final process residue is only 1.6 wt-pct of the initial cake and consists of lead sulfate.

Jan 1, 1981

By Bergerm L. B., S. J. Davenport

"INTRODUCTION Oxygen, because of its vital relationship to man's physical well being, is the most important chemical_ element. It may be breathed, however, only in a rather limited range of concentrations and pressures without producing ill effects. An excess of oxygen may be equally as harmful as too little of it. Because of the importance of these effects, the study of the physiological action of oxygen has received attention for many years and by many investigators. Much of the investigative work has been directed toward determining the limits within which oxygen in abnormal concentrations and at abnormal pressures may be breathed with safety in such applica¬tions as deep-sea diving, work in comprossod-air, aviation, the wearing of apparatus designed to permit entrance into irrespirable atmospheres, and in the therapeutic applications of the medical profession.The Bureau of Mines frequently receives requests for information on the effects of breathing essentially pure oxygen, because of the Bureau's association with the use of self-contained oxygen breathing apparatus for entering irrespirable mine atmospheres, and the use of oxygen in conjunction with artificial respiration as a moans of resuscitation. The purpose of this paper is to summarize briefly the effects upon the human body of the inhalation of oxygen in various concentrations and at various pressures and to give reference to other published information that deals in greater detail with the diverse phases of the subject. The literature in this field is voluminous; therefore, a complete bibliography has not boon presented in this paper. No paper on this subject would be complete without reference to the classic pioneering work of Paul Bert (1) 3/ in this field. Articles such as those of Stadia, Riggs, and Haugaard (2), Bean (3), Specht (4), and others cited contain extensive lists of references that will leadthe reader to information in a degree of detail that is not within the scope of this publication."

Jul 1, 1950

By K. K. Kershner

This report describes an investigation by the Bureau of Mines designed to provide background data for extending and improving the applications of chlorine metallurgy in extracting metals from ores. Optimum conditions are given tor chloridizing galena, sphalerite, and chalcocite by contact with chlorine gas. Petrographic and chemical analyses of the sulfides used in the experiments are listed. Graphs are furnished showing the extent of chloridization of each metal sulfide over the temperature range of the observations. In each case, the first tests were made with the reaction chamber at room temperature. This temperature was increased by regular increments in succeeding tests until the temperature was reached at which quantitative conversion of the sulfide to chloride was observed. The data are also plotted for screen-size fractions of the sulfide minerals investigated. Data show that the extent of metal chloride formation was affected by chloridization time, particle size of the sample, and usually, the temperature of the reaction chamber. At 300° to 400° C. an anomaly was noted for both galena and sphalerite. The temperature at which this anomaly was observed varied according to the particle size of the mineral. Comparisons are made between the chloridizing characteristics of the mineral sulfides and their chemically prepared counterparts.

Jan 1, 1961

By Rudolf E. Greuer, Linneas W. Laage, Xinton Chang

Data or input files are used to describe the mine's ventilation system and physical characteristics necessary for ventilation calculations as well as the physical or mechanical disturbance to be modeled and simulated Data files are organized into lines of categories or groups of information Each line contains multiple sets of information or data items Data lines are read by the program, and the data items provide information to the program variables The data file is in American Standard Code for Informa¬tion Interchange (ASCII) format, sometimes called a DOS text format Creation or modification of a data file is accomplished with text editor software Most word pro¬cessors are also capable of making the required ASCII type files A sample data file and its associated output are included in appendix B. When selecting software for editing the data files, the user should be aware that the software will also be used for viewing the output of the simulation The output file can be quite large (several megabytes), if a lengthy simulation is performed The output can be sent to a printer for a hardcopy fisting, however, the user should also be aware that most printers currently used with PC's print at rates of 100 to 300 characters per second and large output files may take several hours to print Viewing the output with a text editor can save much time and paper DATA FILE MANAGEMENT The data files describing the event and mine to be simulated can reside either on a floppy disk or in a directory on the hard disk drive When the program starts, the user is prompted for the data file location and name The user response is in the form of a standard DOS path and file name For example, if the data file is on a floppy disk located in drive B and the disk has a directory MYMINE with the data file MYDATA DAT in that directory, then, at the prompt

Jan 1, 1990

By C. D. Litton

The results of full-scale fire tests are used to determine optimum distributions of fire sensors for the protection of conveyor belt haulageways in underground coal mines. Empirical relationships are derived that relate the spacing of fire sensors to the rate of development of the fire hazard. For this application, a critical fire size is defined as that size of fire for which belt ignition and subsequent flame spread down the belt is assured. Detection and alarm, regardless of sensor type or sensing methodology, must be achieved at some point in time before the critical fire size is reached. Based upon this approach, it is found that the horizontal spacing for products-of-combustion sensors is in the range of 300 to 600 meters, while the required thermal sensor spacing is found to be ~4 meters or less. Additional design criteria are discussed for product-of-combustion fire sensing systems.

Jan 1, 1982

By David C. Peters, Robert S. Crosson

A method of error analysis has been applied to the location technique of non-linear least squares iterative inversion in order to evaluate the resolving power of several seismic array configurations with various assumed earth models and errors and inaccuracies in arrival times. The results obtained demonstrate that lateral accuracies of location are improved significantly when the depth of the miner is known. Lateral location to within 100 feet appears achievable in many instances. If it is possible to refine earth models significantly beyond what has normally been assumed in this work by the use of on-site data, or if the mine is shallow (300 feet or less), accuracies of-about 30 feet or so may be attainable. Inaccuracies in earth models of about 5% are found to contribute much more heavily to these location inaccuracies than errors of a few milliseconds in picking arrival times; however, arrival time errors of 15-20 ms or above will dominate these model inaccuracies. The expected accuracy of location is found to fall off very rapidly as the miner moves outside the array. The strength of this effect depends markedly upon the geometry of the array configuration and can be reduced by careful design. Also, as the size of the array is increased, expected location errors within the array are not altered much, but continue to match the error associated with the smaller array over a larger area (assuming that all stations can still pick up the miner's signals). Better location accuracy, especially with respect to depth control is achievable in an earth where the velocity is depth-dependent (increasing with depth) than in one which is homogeneous. This is an advantage since the

Jan 1, 1974

By Paul T. Allsman

THIS CHAPTER reviews the highlights of developments in mining technology during 1956 and presents a special report on the design of mine openings in stable ground. This special report is presented each year in an endeavor to stimulate use of the scientific approach to the solution of problems related to mining technology. Assuming that the literature on mining technology reflects trends in mining, it appears that two areas of activity were given most attention in 1956. One was research on mining technology,4 and the other was improvement of transportation, particularly trackless transportation, both at surface and underground mines.

Jan 1, 1958

By H. W. Kilau

The U.S. Bureau of Mines examined the wettability of bituminous and subbituminous coals before and after exposure to ambient air atmosphere, as part of an ongoing project investigating the coal-wetting abilities of surfactant solutions intended for the suppression of dust during coal mining operations. Exposure periods were generally 7 days or less, and the changes in wetting response were measured with a capillary penetration apparatus. Wetting solutions tested included a nonionic surfactant, two anionic surfactants, and pure distilled water. After exposure, higher ranked bituminous coals treated with nonionic surfactant solution and pure water showed increased wettability, but lower ranked subbituminous coals showed decreased wettability. With the anionic surfactants, the coals demonstrated opposite responses. The wettability changes appeared to be related to the coal moisture content. These changes may be amplified by specific, but incompletely understood, interactions between surfactant polar groups, absorbed water, and the coal surface.

Jan 1, 1989

By Mark R. Pettitt

After a long series of laboratory and in-mine tests, a cost- effective, mineworthy, reduced-noise auger miner cutting head was de signed, fabricated, and field-tested by Wyle Laboratories under contract to the Bureau of Mines. Compared with standard auger cutting heads, the new heads reduced noise by 10 dBA at the jacksetter's position and by 6 dBA at the operator's position. This report contains detailed fabrication instructions, including engineering drawings, that show how a standard auger cutting head can be modified to produce a reduced-noise auger.

Jan 1, 1984

By William M. Nabors

As a part of a program to promote conservation and efficient utilization of petroleum resources, Bureau of Mines engineers are studying secondary oil-recovery projects in the United States. Published reports that set forth the pertinent facts of these operations help others to profit by the experience gained. This report presents the results of a study of secondary-recovery methods used in Kentucky by the Cumberland Petroleum Co. on its L. C. Bailey lease, Oil Springs pool, Magoffin County, Ky. This is believed to be the first water-flooding project in eastern Kentucky (fig. 1).

Jan 1, 1958

By W. P. Diamond, B. M. Bench, C. M. McCulloch, Maurice Deul

As part of the Bureau of Mines methane control program, the Pittsburgh coalbed was studied in Washington and Green Counties, Pa., and in Marion and Monongalia Counties, W. Va., where this coalbed is now being mined at its greatest depth. The coalbed thickness appeared to be structurally controlled; the bed was generally thinner near the axes of anticlines and thicker near the axes of synclines. The overburden isopach shows a similar relationship. Most of the clay veins in coal occur in the synclinal troughs, generally under sandstone roof. Cleat orientations measured in 18 underground mines showed that face cleats are perpendicular to the axial trends of the folds, and the butt cleats are parallel to the axial trends, indicating structural control of the cleat. Measurement and analysis of surface joint orientations provide a method for predicting the cleat orientations of the coalbed, but linears measured from infrared photographs and photoindex sheets helped only to determine regional trends. The results of these investigations provide a geologic framework for rational planning for underground mine development to use the best available technology to cope with methane emissions, coalbed discontinuities, and related ground support problems.

Jan 1, 1975

By L. A. Neumeier

The Bureau of Mines evaluated the properties and anisotropy in properties of rolled Zn-Ti and Zn-1.0 wt pct Cu-Ti alloys containing up to 0.36 wt pct Ti. Finish rolling was at varied temperatures to total reductions as high as 92 pct. Alloy properties are very sensitive to various combinations of composition, rolling temperature, and reduction. Properly rolled Zn-1.0 Cu-Ti alloys are superior in strength to Zn-Ti alloys. Conditions are described that lead to best tensile properties. Creep resistance for Zn-Ti alloys decreases with increased rolling temperature when finish rolled to 92-pct total reduction: but not when finish rolled to 33- or 67-pct reduction. Creep resistance for 7n-1.0 Cu-Ti alloys improves with increased rolling temperature to about 480° F. Heavily cold-rolled Zn-1.0 Cu-Ti alloys have fine grain sizes and poor hardness, tensile, and creep properties, but high ductility. Thermal expansivity is markedly affected by the copper addition. Data show the anisotropy of tensile, creep, and thermal expansivity properties. Large idiomorphic crystallites of TiZn15 appear in both Zn-Ti and Zn-Cu-Ti alloys when more than about 0.2 pct Ti is present. A new Zn-Cu-Ti intermediate phase was also identified. Empirical equations are presented relating creep rates with major process variables.

Jan 1, 1971