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By Seth C. Schaefer

The Bureau of Mines has determined the standard Gibbs energies (AGf°) of CoS1.035 (cobalt sulfide) and Ni2.515S2 (nickel sulfide) with high-temperature galvanic cells using stabilized Zr02 (zirconia) as the electrolyte. Potential measurements were obtained for the cell Pt, CoS1.035, CoO, S02(g, 1 atm)//Zr02//02(g, 0.0114 atm), Pt, with the overall cell reaction C0S1.035(c) + 1.535 02(g, 0.0114 atm) = CoO(c) + 1.035 S02(g)¬ These results, combined with the best available data for ?Gf° of CoO and S02 from the literature, give the standard Gibbs energy of formation of CoS1.035 for the reaction Co(c) + 0 5175 S2(g) = CoS1.035(c) ?Gf° = -38.890 + 18.87 x 10-3T ± 0.185 kcal/mole (866.0 - 1,104.9 K), where temperature (T) is expressed in kelvins. Similar measurements were obtained for the cell Pt, N12.515S2, NiO, S02(g, 1 atm)//Zr02//02(g, 0.0122 atm), Pt, with the overall cell reaction Ni2.515S2(c) + 3.2575 02(g, 0.0122 atm) = 2.515 NiO(c) + 2 S02(g). Combination of these results with data for ?Gfo of NiO and S02 from the literature yields the standard Gibbs energy of formation of Ni2.515S2 for the reaction 2.515 Ni(c) + S2(g) = Ni2.S1SS2(c) ?Gf° -65.377 + 24.67 x 10-3T ± 0.541 kcal/mole (968.6 -1,053.7 K).

Jan 1, 1981

By R. R. Schehl

The Bureau of Mines analyzed the structure of a high-grade metallurgical coke, carbonized at different temperatures in the range 500° to 1,000° C, through X-ray diffraction studies. Growth in the crystallite size with increasing coking temperature was calculated from profile analysis and compared with values obtained from the radial distribution function. The carbonization temperature appeared to have little influence upon the stack height, whereas the layer diameters more than doubled in size between 500° and 1,000° C. These results are comparable to those obtained from other studies of poorer quality cokes.

Jan 1, 1974

The Bureau of Mines, in an effort to improve resource conservation, mine planning and development, is currently investigating the loading behavior of pillars in multiple-seam developments. The simultaneous mining of two or more coalbeds may cause instability between room-and-pillar operations resulting in an interaction known as pillar load transfer. Although pillars may be adequately designed for single-seam mining, the development of a second seam may complicate loading conditions in both operations. If pillars are not adequately designed to contend with this load transfer, failure of the mine structure may result. To improve multiple-seam development and pillar design, the Bureau studied the loading characteristics of pillars in three separate multiple-seam operations. In all three cases, instrumented pillars recorded increasing pressure after development of the second seam. Increases in the average pillar pressure ranged from 7 to 110 pct over predicted overburden loads. An analysis of pillar loading before and after second-seam mining indicates that the ratio of overburden to innerburden thickness is a critical factor influencing load transfer. Based on this relationship, safety factors for case study pillars are calculated and alternative design considerations are discussed.

Jan 1, 1988

By James A. Wasson

This report analyzes the petroleum-production potential of the basal Greenbrier dolomite zone, Sycamore-Millstone field, Sherman District, Calhoun County, W. Va., through the application of certain secondary-recovery methods. The well logs obtained and the core recovered from a well in this formation permitted an evaluation of the productive capability of the reservoir, Approximately 120,000 stb of oil may be produced from a 20-acre five-spot unit at breakthrough if the property is waterflooded. At an assumed limiting producing gas-oil ratio of 20)000 sef/stb, approximately 69,000 stb of oil should be recovered by low-pressure gas drive.

Jan 1, 1967

By Joan K. Kuenzi

The purpose of this U.S. Bureau of Mines information circular (Ie) is to discuss how job analysis methods taken from different disciplines can be used together to form a more complete picture of jobs in the mining industry. "Job analysis" is a term used by many researchers, but use of the term is far from standardized. Authors of papers on this subject often state that there is confusion in how or why jobs are to be analyzed, what the resulting information is to be used for, and what the "job analysis" actually means. The process of breaking a job into elemental tasks and analyzing them is used to determine what skills and knowledge are needed to perform a given job, to improve efficiency, and to develop safer job procedures. All are valid reasons to analyze jobs, but the methods used to accomplish the analyses may be very different. In order to create a more complete picture of a job, it may be useful to incorporate methods and information from different areas of study rather than choosing one method for analysis.

Jan 1, 1995

By F. D. Everett

Thermoelectric and metal alloying applications have changed the status of tellurium from oversupply to under supply . In a search for new sources of this element in Arizona , Colorado , New Mexico , Utah , and neighboring states , the Bureau of Mines analyzed more than 200 samples and obtained the results of tellurium determinations by private companies on more than 500 samples from a wide variety of mineral - bearing deposits . The About 40 minerals containing tellurium have been reported , mainly tellu- rides of gold , silver , bismuth , mercury , lead , copper , iron , and nickel . minerals usually occur in small quantities and identification in ores is extremely difficult . Samples containing more than 0.1 percent tellurium were taken from the Hilltop and Memphis properties in Dona Ana County , N. Mex . , and the Silver King property in White Pine County , Nev . , where development was chiefly for base metals . The Lone Pine mine in Catron County , N. Mex . , and the Bambolla mine near Moctezuma , Sonora , Mexico are potential sources of native tellurium occurring in small but high- grade pods . Much of the production of tellurium has come as a byproduct of electro- lytic refining of copper and lead- zinc ores in Arizona , Colorado , New Mexico , and Utah . Base -metal ore deposits will continue to be the most important pri- mary source of tellurium , although the concentration in ores is nearly always less than 10 parts per million . Any significant increase in output of tellu- rium probably will be related to production and improved efficiency in smelt- ing and refining base - metal ores .

Jan 1, 1964

By David C. Oyler

Three long horizontal holes were drilled from a directionally drilled surface hole at the Emerald Mine near Waynesburg, Pa. The purpose was to adapt the technique of directional drilling for use in draining methane from coalbeds. A 504-m (1,652-ft) long, 76-mm (3-in) diameter, circular arc pilot hole was drilled, using a downhole mud motor, to enter the Pittsburgh coalbed at a vertical depth of 305 m (1,000 ft). The hole was reamed to 222 mm (8-3/4 in) and was cased to a measured depth of 486 m (1,595 ft). Three 76-mm (3-in) diameter horizontal drainage holes were then drilled, totaling 2,909 m (9,544 ft) of horizontal hole. Improvements in drilling methods increased the average drilling rate from 20.4 ill (67 ft) to 64.9 m (213 ft) per day. The cost of drilling the directional and horizontal holes (using a Government-owned drill rig) was $1,169,530, a figure inflated by inexperience and by delays caused by lost-circulation problems and fishing operations. An estimated total drilling cost of $960,000 (including rental of a drill rig) for an improved system, was determined by a detailed cost analysis. Initial gas and water production from November 1979 through May 1980 was low because of caving of the horizontal holes drilled in shale near the bottom of the casing.

Jan 1, 1982

By Alan D. Hartman

Standard metering of electric arc furnaces usually uses root mean square (RMS) or true root mean square (TRMS) measurements for determining power. Only sinusoidal signals are accurately described by RMS meters, and dc or high-frequency components normally are lost in standard TRMS metering. This can lead to inaccuracies when electrical signals are not sinusoidal, contain dc components, or include fast risetime perturbations, as is the case with the electric signals from an electric arc furnace. Electric arc furnace electrical waveforms, observed in research carried out by the U.S. Bureau of Mines, show high-frequency components and significant deviations from sinusoids. These perturbations and distortions make metering difficult for standard power meters. The inaccuracies in metering can cause further problems if those sensors are used in control systems. For control strategies requiring rapid response, any averaging scheme loses information that can be used in control decisions. In order to obtain better signals for both monitoring and control, a study of instantaneous, RMS, and TRMS power monitoring devices was conducted. From this study it was concluded that precision integrated circuits should be used to obtain instantaneous power with a bandwidth of at least 25 kHz. The information from these devices is more representative than that of standard meters and can be used in predictive control.

Jan 1, 2010

By Alan R. Buehler

In 1986, at the request of the U.S. Bureau of Land Management, the U.S. Bureau of Mines studied part of the 256,430-acre Alvord Desert and part of the 22,240-acre East Alvord Wilderness Study Area (OR-002-074 and OR-002-073A, respectively), in order to evaluate their identified mineral resources. The study areas are located in Harney and Malheur Counties, OR, about 25 mi northeast of the small village of Fields. There are no mines, prospects, or identified mineral resources inside the study areas. Basalt flows within the study areas contain chalcedony-lined vugs and banded agate which may be of interest to rock hounds. An ignimbrite flow contains perlitic material, but crystalline contaminants make it unsuitable for commercial uses. Lacustrine (lake) sediments contain diatomite and clays, and evaporite crusts contain boron too low grade to profitably mine. Small quantities of common opal and petrified wood occur which might be of possible interest to rock hounds. Some of the petrified wood is black, free of fractures, and polishes well; it may be suitable as backing material for soft, thin, and brittle gemstones, such as precious opal. The lacustrine sediments also contain black, fetid layers which have above background, but economically insignificant concentrations of zinc, cobalt, nickel, barium, iron, manganese, aluminum, and potassium. Large quantities of fine-grained dune sands within the study areas are too far from markets for economic consideration. Ephemeral streams in the study areas contain small amounts of placer gold of no economic interest. The western portions of both study areas are reported to have moderate favorability for occurrences of natural gas, and both study areas are reported to have high favorability for the occurrence of geothermal resources. As of December 1986, oil and gas leases covered 3,100 acres in the study areas.

Jan 1, 1987

By H. J. Seim

An ion-exchange-instrumental analysis technique is described for analyzing impurities at 1 to 1,000 parts per million level in rare-earth metals. A cation-exchange flame photometric method is used for the alkali and alkaline earth groups of metals, and an anion-exchange procedure is used in conjunction with polarographic and X-ray fluorescence techniques for selected transition elements. The standard deviation is about 6 percent, and the average error, about 5 percent.

Jan 1, 1962

High resolution seismic refraction tomography has proved to be a useful tool to effectively estimate depth of blast induced damage in a mine face. Excavation blast damage can be as shallow as 1 to 2m and requires resolution at a fraction of a meter for effective imaging. We used an accelerometer with flat frequency response to 1000Hz to record data at spacings of approximately 0.25 to 0.5m along mine walls. First arrival times from the seismic data were used to produce P-wave velocity tomograms. The tomograms show transition from low velocity zones to velocity associated with competent rock. We interpret the low velocity zones to indicate residual fracturing from blasting. Experiments on a concrete test block and at two underground mine locations give results that are consistent with fractured rock transitioning to competent rock. Our method can be applied efficiently in an underground environment to provide continuous velocity information with depth into a mine wall over a span of approximately 10m.

Jan 1, 2009

By M. S. Oudenhoven

The Bureau of Mines conducted an investigation to determine the theoretical stress distribution in the vicinity of explosively expanded rock bolt anchors independent of their bolts. Plane-strain solutions applicable to this problem were obtained by combining the field pressure with the uniform pressure that would be produced by vertically placed anchors having 2-, 3-, and 4-foot spacings. High rock stress which would be produced by an anchor was localized, as would be expected from St. Venant's effect, and increased as the field pressure decreased.

Jan 1, 1967

By M. M. Wong

Salt mixtures consisting of KC1, BaC12, and HfCl4 with RbCl or CsCl were investigated as electrolytes for refining hafnium. The presence of RbCI or CsCl in the electrolyte appeared to suppress the volatility of. Best electrorefining was obtained with an electrolyte containing 50.7 percent KCl, 27.l percent BaCl2, 15.7 percent CsCl, and 6.5 percent HfCl4. In this electrolyte, hafnium metal with an average oxygen content of 470 ppm was produced from an anode feed containing l,600 ppm oxygen. All metallic impurities were lowered, except titanium, manganese, and tin.

Jan 1, 1966

By R. G. Dressler

The Federal Bureau of Mines designed, constructed, and operated a demonstration plant at Louisiana, Mo., to produce gasoline, liquid fuels, and organic compounds from coal by a modified Fischer-Tropsch gas-synthesis process. Satisfactory equipment was developed to produce and purify synthesis gas and convert it into the desired products. Coal or coke was gasified with oxygen and steam to make a gas consisting essentially of carbon monoxide, hydrogen, and carbon dioxide. Dust in the raw gas was removed by cyclone separation, water scrubbing, and electrostatic precipitation. Carbon dioxide, hydrogen sulfide, and organic sulfur were removed with diethanolamine, iron oxide, and activated carbon. The gas was passed over iron catalyst and was converted into synthetic liquids, which were then separated and fractionated into gasoline, diesel oil, other liquid fuels, and oxygenated organic compounds. A 39-day continuous run demonstrated the feasibility of the process. Addition of 3 milliliters of tetraethylead per gallon of upgraded (or finished) gasoline gave a product with an octane rating up to 90 by the research method. After a caustic wash, the diesel oil was of a superior quality; its cetane number was 60 or above.

Jan 1, 1961

By E. G. Davis

The Bureau of Mines made laboratory-scale experiments to examine the technical possibilities of reclaiming manganese from slags produced by oxygen lancing of high-manganese pig iron. Ferromanganese was added to molten pig iron to yield a 4-to 5-percent manganese hot metal, which simulated a product obtainable from the blast furnace. This was injected with oxygen to reduce the metal to 1 percent or less manganese and form a slag containing about 40 percent manganese. The molten slag was water-quenched, treated with H2SO4) roasted at 660° C, and water-leached to give soluble manganese and iron sulfates. The sulfates were precipitated as hydroxides, converted to the oxide form, and smelted to produce a standard ferromanganese containing 74.6 percent Mn and 0.01 percent P. As an alternate method of manganese recovery, a manganese cell feed was prepared from the leach solutions and electrolytic manganese was produced. Direct smelting of the high-manganese slag resulted in 74.2 ferromanganese meeting ASTM specifications except for phosphorus content. The high phosphorus content of the metal and high slag-to-metal ratio obtained made this approach unattractive.

Jan 1, 1966

By David T. Couillard

Task training is increasingly important in mining operations because of the ever-accelerating pace of technological innovations and the concomitant increasing complexity of mining equipment. This Bureau of Mines report describes two successful task training program In use in two open-pit taconite operations in northeastern Minnesota. The programs are different in approach, but both have improved safety and in- creased productivity while lowering costs. Methods of training both before and after passage of the 1977 Mine Safety and Health Act are described, and the impact of this act on task training at each operation is discussed. The report identifies four common principles that have contributed to the success of the two training programs and presents plans each operation has for improving future training through new technology.

Jan 1, 1984

By Charles W. Huggins

The Bureau of Mines investigated palygorskite, a natural asbestiform material, to accumulate knowledge that might serve as a foundation for future synthesis of a similar material. Unit cell, chemical analysis, DTA, TGA, optical constants, and electron microscopy data were obtained. Selected palygorskite samples of bettor than 97-percent purity were used to obtain this information. Chemical analysis revealed the following formula: (OH2)4 (OH)2 Ca0.01Fe0.02K0 .c3Mg2.10A12.00Si7.93020.3.91 H2O. The optical constants for sodium light are a = 1.522; S = 1.530; ?=1.533; biaxially (-). The following orthorhomibic unit cell constants were determined: ao = 12.690 A, Z = 2, bo = 17.857 A, Dx = 2.327. co = 5.207 A, Identical diffraction patterns resulted from the three palygorskite samples that were studied. X-ray, chemical, DTA, TGA, and optical data were compared with literature values for similar fibrous materials. X-ray diffraction lines were indexed. Several electron micrographs were made to compare the structures of palygorskite and attapulgite with that of chrysotile. The micrographs revealed extremely short laths for attapulgite, very long flexible laths for palygorskite, and tubular structure for chrysotile.

Jan 1, 1962

By Helen E. Edwards

The Bureau of Mines is engaged in a systematic evaluation of the thermodynamic properties of combustion gases. These studies are designed to provide basic thermodynamic information of high accuracy facilitating the theoretical study of flame and combustion phenomena. This report is the third of a series3/ presenting results of the study for particular fuel-oxidant systems. The equilibrium composition of the products of combustion and the adiabatic flame temperatures of specified oxyacetylene systems have been computed.

Jan 1, 1953

By James S. Browning

The Bureau of Mines conducted laboratory and small--scale continuous tests of weathered mica pegmatite ores from Hart County, Ga., to determine the technical feasibility of recovering commercial-grade mica concentrates by flotation. Two modifications of the Bureau-developed anionic-cationic method were used. In one method, sodium carbonate and calcium lignin sulfonate were used for pH control and quartz depression; this method yielded mica concentrates containing 98.5 percent mica with a recovery of 91.4 percent. In the other modification, lime and sodium silicate were used with the calcium lignin sulfonate; concentrates containing 98.9 percent mica with a recovery of 86 percent were obtained.

Jan 1, 1966

By Paul M. Tyler

This paper presents one of a series of digests of foreign mining legisla- tion and court decisions that is being prepared in advance of a general report relative to the rights of American citizens to explore for minerals and to own and operate mines in various foreign countries. This interpretation of the laws of Switzerland has been prepared from the best information available in ashington, but is released subject to correction and amplification, if necessary, by the proper American diplomatic and consuler officers, to whom it is being referred through the courtesy of the Department of State. Sitzerland is a small country in which little mining is done, yet it has a voluminous body of mining legislation. There are two salt-mining districts in Switzerland; that at Bez, Canton of Vaud, belongs to the Canton but the deposit is worked by a private company; and those at Schweizerhalle, Rheinfelden and Ryburg are worked by a joint stock company formed by the Cantons interested. Iron ore is mined at Gonzen, Canton of St. Gallen, and large beds of gypsum are worked, mainly for domestic consumption. In general, however, although many kinds of minerals are said to have been found in Switzerland, mining operations are irreguler end relatively unimportant. Even during the world war only about 2,500 persons were employed in mining establishments and most of these were in under round stone quarries. On the other hand, the republic comprises 22 Cantons, of which 3 are divided, making 25 units, and in the absence of generel Federal legislation, each of these units virtually has its own distinct mining la Under these circumstances, it is obviously inadvisable to review the mining lars of Switzerland in the same detail as those of other countries which Lave been digested in this series. For the lars of individual Cantons, as well as for a more comprehensive summary of the Swiss legislation as a whole, the reader is referred to a recent German publication." Many of the statements in the present paper can be traced to this source. Acknowledgment is also made of the brief analysis published by anot..er German authority..

Jan 1, 1933