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By A. Policard

The question, of the pathogenesis of pneumokoniosis is very important not only from the social and economic points of view but also from the purely biological. The study of the pathogenesis of the disease leads to fascinating problems of cytology and cytochemistry. Two problems present themselves for examination from an analytical and critical point of view: 1. The first reactions of the alveolar walls to inhaled dusts. 2. The precise nature of the action of mineral dusts.

Jan 1, 1947

By C. A. Pickles

Mixtures of silver chloride and copper chloride are produced during gold refining by the Miller process. A study was carried out into the reduction with iron of a synthetic Miller chloride containing 13.64 mass% Ag and 2.42 mass% Cu. The effects of smelting temperature and time and of additions of iron and borax were investigated. The results were interpreted in terms of metal recovery and quality. Temperature did not have a significant effect on metal recovery above the melting point of the metal product. Borax additions reduced vapour losses and improved metal recovery. With excess iron it was possible to achieve silver recoveries of about 100% and copper recoveries of about 70%. The metal product contained on average 76.1 mass% Ag, 7.5 mass% Cu and 12.8 mass% Fe.

Jan 4, 1993

By E. A. Brocchi, P. K. Jena

Complete extraction of copper from Salobo chalcopyrite concentrate can be achieved in less than 10 minutes by chlorination of the dry concentrate with Cl2 at 450 degrees C and in 5 minutes by chlorination of an aqueous slurry containing 5 wt% concentrate at 30 degrees C. In general, slurry chlorination appears to be faster than dry chlorination. The kinetics of dry chlorination of copper sulphide are controlled by an adsorption mechanism with an activation energy of 6.1 kcal/mole. The rate is independent of chlorine partial pressure when pCl2 exceeds 0.4 atm. In slurry chlorination the dissolution of copper sulphide follows a topochemical reaction model and the rate of chlorination decreases with increase in pulp density and also temperature. Dissolved chlorine appears to take part in the reaction in atomic or ionic form.

Jan 4, 1992

By Schwartz M.

The current status of the heavy and light rare-earth elements outside China is reviewed. New suppliers of the light rare-earth elements are Lynas (Australia/Malaysia) and Molycorp (USA), which are anticipated to process 11 000 and up to 10 000 t/y, respectively, and the most advanced heavy rare-earth elements project is Avalon's Nechalacho project at Thor Lake, Northwest Territories, Canada. U3O8 Corp has potential rare-earth elements production, e.g. ytrrium and neodymium, from its Berlin deposit in Colombia and Namibia Rare Earth's Lofdal project (Area 4) has potential to produce an average of 1 500 t/y of separated rare-earth oxides. With regard to the three historical producers, India has some small-scale production, Brazil has been a small-volume producer and has potential for new heavy rare-earth elements production, while South Africa has no current production

Feb 1, 2015

By G. Mellgren, O. Mellgren

The conductivity of a solution is often used industrially to control the salt concentrations of reacting systems, normally using electrodes made of glass fitted with platinised platinum electrodes. When a standard platinum conductivity electrode was used to control the acid fed to the leaching circuit for an ilmenite flotation concentrate at Titania, Norway, a deposit of calcium sulphate (containing some calcium phosphate) covered both the platinum electrode and the external glass fitting, rendering the electrode inefficient in the course of a few minutes. A new electrode consisting of a casing, two measuring tubes and an electrode stem is described and illustrated. A significant advantage of its design is that the useful range of conductivity measurement can be adjusted by adjusting the concentration of the electrolyte in the electrode. It has been in use at Titania for about four years with an electrolyte consisting of 0-1 n HCI. It is robust and demands little maintenance.

Dec 1, 1971

By F. G. Bell, S. E. T. Bullock

The investigation was undertaken as part of the environmental management programme that must be implemented on mine closure. It involved sampling and analysis of water from boreholes, the tin mine workings, trenches and pits as well as soil and dumps. Both ground- and surface water in the immediate vicinity of the mine was found to have been affected to varying degrees, mainly due to acid drainage from the pyrite dumps. Metal ions and toxic salts are taken into solution with increased acidity and precipitated in the soil when the pH rises again; there are concentrations of metal ions in the soils around the main dumps, but these do not seem to pose a major threat in a regional context. The low groundwater gradients, together with the dyke system in the vicinity of the main dumps and the impermeable nature of the Boschoffsberg rocks, make it unlikely that affected groundwater will migrate further than 1 000 m to the north and north-east. Nonetheless, it has been decided to remove the pyrite dumps

Dec 1, 1995

By Ruddle R. W.

Although copper has been smelted for many years, relatively small attempt has been made in the past to examine the fundamental physical chemistry of the processes involved. Therefore, technological developments apart, slow progress has been made with the development of improved or new principles of smelting. The methods at present in use in the majority of the world’s smelters are essentially those employed at the beginning of the present century; it is significant that many of the textbooks on copper smelting, written some 50 years ago, are still regarded as standard works. The book is divided into seven chapters. In the first the fundamentals of modern smelting processes are briefly outlined for easy understanding of the subsequent sections, while the next two chapters are confined to the more theoretical aspects of the constitution of mattes and slags. Some problems of considerable practical importance are discussed in the remaining four chapters; these are (1) magnetite formation, (2) copper losses during smelting, (3) the recovery of sulphur from the smokes produced during smelting, and (4) the elimination of impurities. A collection of thermodynamic data relevant to copper pyrometallurgy is presented in an appendix, and, for the convenience of readers not well acquainted with thermodynamics, a brief explanation of the thermodynamic terms and methods employed is given in a second appendix

Jan 1, 1953

By V. Distler, E. F. Stumpfl

Paper presented at the IAGOD international symposium on mineralisation related to mafic and ultramafic rocks held in Orleans, France, 1-3 September 1993. The massif contains large chromite bodies of "Alpine-type", ophiolitic affinity. Orebodies reach thicknesses of 150 m and sizes of more than 150 000 000 t chromite ore with average grades of 55-60 wt% Cr2O3. Chromites in the Main ore field are low-Al, high-Cr spinels which exhibit some variation in their Mg-Fe distribution. This differs markedly from high-Al spinels in peridotite host rocks and in narrow chromite pods which occur in the western and northern parts of the massif. Chromites carry silicate inclusions, often hydrous silicates such as amphibole. Chromites in massive chromitites contain micron size inclusions of platinum group minerals (PGM). Composite grains containing two PGM and, occasionally, a hydrous silicate are common. Os-Ir alloys rimmed by PGM sulpharsenides occur in narrow serpentine veinlets that cut chromite and are evidence for the reconcentration of PGE concomitant with introduction of As, probably during serpentinisation. Whole-rock PGE contents are highest in massive chromitites of Diamond Pearl mine (totals of 500 ppb). Chondrite-normalised PGE patterns of chromitites show negative slopes which are typical for ophiolitic, podiform chromitites in mantle sequences. The PGE patterns of host rocks are flat and rather depleted compared with those of chondrites and chromitites. Petrological data from unaltered host peridotites suggest a high temperature overprint leading to sub-solidus re-equilibration of olivine and spinel and to the growth of pargasitic and edenitic amphiboles

Jun 16, 1905

By D. H. Watkinson

Paper presented at the IAGOD international symposium on mineralisation related to mafic and ultramafic rocks held in Orleans, France, 1-3 September 1993. Part of the contact of the 4b orebody with the enclosing Murray granite is characterised by the presence of recrystallised and biotitic Sudbury Breccia; in places the contact is faulted and sheared. In other areas of the contact partly silicified granite contains disseminated chalcopyrite and quartz-chalcopyrite veins with other minor minerals. Both ore and veins contain platinum group minerals (PGM); predominant PGM are michenerite, kotulskite, merenskyite and sperrylite with Au, galena and Bi-tellurides. At some silicified-granite contacts Mn-rich garnets, some containing inclusions of PGM and quartz, are associated with biotite + epidote + stilpnomelane + quartz. PGM and Au also occur within Cl-rich biotite and ferropyrosmalite in massive sulphide and in siliceous ore. Quartz, chalcopyrite and feldspar in the contact rocks and in veins contain abundant, highly saline fluid inclusions. Studies showed that the fluids were trapped at intermediate temperatures. The 4b orebody is surrounded by a sheath of brecciated granite but is close to the Contact Sublayer. During and after emplacement of sulphide magma, saline formational fluid that was resident in the breccia interacted with hot massive sulphides in and near the Sublayer and remobilised Cu, Au and PGE. This fluid reacted with cooler rocks and ore in footwall fractures, enriching the 4b protore and producing the adjacent Cu- and PGE-enriched quartz veins. Exploration for Cu and PGE enrichment in footwall rocks of the Sudbury South Range is warranted not only in zones of magmatic ore in the Contact Sublayer but also in fractures and permeable units within Sudbury Breccia

Jun 16, 1905

By A. Hemami

In order to automate the operation of mechanical loaders it is essential to have a knowledge of the forces that act on the bucket and of the trajectory that the bucket should follow. A trajectory for the cutting edge of a bucket is derived from studies of the forces acting during the scooping phase. The proposed trajectory has a minimum energy consumption and is simple to automate. It is determined initially by setting to zero certain components of the resistive forces to the bucket motion which would otherwise result in unnecessary work and consequent energy wastage. The method for finding the appropriate trajectory is discussed on the basis of the properties of the material to be loaded and the loader size.

Jan 4, 1993

For the convenience of those who are unfamilar with thermodynamics, the following brief description and explanation is given of the thermodynamical terms and methods used in this book. It must, however, be strongly emphasized that the account given below is not an introduction to chemical thermodynamics; its sole purpose is to give the reader a rough understanding of the methods used in the earlier chapters. For further information, reference must be made to the standard textbooks on chemical thermodynamics by Glasstone.

Jan 1, 1953

By A. B. Holland-Batt

Deposition velocities play an important role in many fields of engineering and an impressive range of measured data has accumulated in the literature. Numerous workers have addressed the problems that are associated with the prediction of deposition velocity because of its particular relevance to the design of pipelines and pumping stations. However, despite this extensive effort, the calculation of friction heads still requires reference to experimentally based graphs to determine Durand factors and there is still scope for improvement in the prediction of the deposition velocity at different solids concentrations. Equations to characterise the relationship between the Durand factor and the volume concentrations of solids in the slurry are presented. A correlation for the prediction of the deposition velocity is also developed and tested against some of the classical experimental data. The application of predicted values of deposition velocity in assessing the potential for the sanding-up of spiral separators is then described and a case study is presented.

Jan 12, 1992

By B. H. Smith

"Most of the discoveries of nickel sulphide deposits in Western Australia have followed the search for gossans. The chances of further discoveries depend on improving our understanding of the cover of strongly leached and transported materials that obscure approximately 85% of the area of the Yilgarn Block that has nickel sulphide mineralization potential. The lateritic profiles that are observed on the Yilgarn Block today were formed over a period of more than 100 m.y. of warm and humid climates. This lateritized land surface has been preserved by induration during subsequent arid climates as well as by the structural stability of the Yilgarn Block.In geochemical surveys of lateritied terrain samples have to be taken from at least the saprolite zone usually by drilling so that confident predictions can be made of the significance of analytical data. Account must be taken of the mineralogy of samples, as well as the nature of the horizon of a laterite profile that is being sampled, owing to the concentrating effects on trace elements of Fe and Mn oxides.Multivariate techniques have been applied successfully to analytical data in gossan recognition when textural evidence is ambiguous. Pathfinder geochemistry has also been used in gossan recognition and the most significant recent advance has come from studies of platinum group metals in nickel sulphides and their dispersion during weathering."

Jan 1, 1984

By D. A. White

A simple model for hydrocyclone classification based on the crowding theory first put forward by Fahlstrom is presented. This is a mechanistic theory that postulates that the behaviour of a hydrocyclone is the result of an ordered process that is independent of its dimensions. The main variables that describe the process are the fractions of feed solids and water that are ejected from the underflow. A simple model is developed from basic properties of the classification process and is compared with theory. Agreement is good but improves when the cyclone has a high solids content

Dec 1, 1991

Discussion of papers with authors' written replies and closing remarks.

Jan 1, 1947

By R. W. Ruddle

"Besides copper, iron, silicon, and oxygen, a large number of elements may be present in copper ores, the more important of which are zinc, lead, arsenic, antimony, bismuth, selenium, tellurium, nickel, cobalt and the precious metals; impurities of less importance are calcium, magnesium, aluminium, barium, sodium, potassium, manganese, lithium, fluorine, titanium, uranium, vanadium, tin and molybdenum. All of these elements are eliminated to some degree in the subsequent roasting, smelting and converting operations.Information on the elimination of impurities during the smelting of copper is surprisingly meagre, however, rather more information is available on impurity removal during the smelting of the ore in reverberatory or blast furnaces."

Jan 1, 1953

By H. B. Bell, L. C. Smith

Measurements have been made of the activity of 'FeO' in 'Fe0'-Mn0-Ti02 melts at 1475 degrees C. The results obtained are discussed in terms of ideal mixing of titanates and in terms of a regular solution model. On the basis of the regular solution model activities of Ti02 and MnO in the Fe0-Mn0-Ti02 and Mn0-Ti02 systems have been derived. The data have been shown to be consistent with the liquidus lines in the phase systems. Examples are given of the application of the data to slag-metal equilibria, being used to derive slag-metal data between liquid iron and Fe0-Mn0-Ti02 slags

Dec 1, 1971

By R. Immele-Meziou, G. J. Long, D. G. C. Robertson, O. A. Pringle

The reduction of naturally weathered ilmenite concentrate occurs in two steps: reduction of Fe3+ to Fe2+, followed by reduction of Fe2+ to Fe. Small amounts of a magnetic phase were also observed and may correspond either to an Fe3O4-FeTiO3 ilmenite phase or to an Fe3O4-Fe2TiO4 spinel phase. The total amount of metallic iron produced after 12 hr was only 50% of the total iron present in the sample.

Jan 4, 1992

By D. F. Ball, P. R. Dawson, J. T. Fitton

Report of discussion at December, 1970, IMM general meeting (Chairman: M. J. Cahalan, President) and contributed remarks on the paper published in Transactions/Section C (Mineral Processing & Extractive Metallurgy), vol. 79, September, 1970, pp. C189-96, plus the authors' replies. Contributors included Cohen E., Hope B., Wasse D.G., Shakespeare A.G., Burwood D.S., Jones H.A., Dartnell J., Carter G.C., Henderson T.A., Relf G. and Clark S.W.

Dec 1, 1971

By J. P. Rees

Describes methods of dust-sampling such as weighing the dust caught on cotton-wool, the sugar tube, konimeter, circular konimeter and the thermal precipitator. Covers the work of mine dust inspectors, the Miners' Phthisis Prevention Committee and the Chamber of Mines Dust Department.

Jan 1, 1947