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By Ivan Malinsky, Gérard Castonguay

"On a développé un procédé qui donne une fonte (2,3% C, 0,07% V) du V2O5 (99%) et un rutile synthétique (94% TiO2) à partir d'un minerai, dont les réserves au Québec sont importantes. Le procédé comprend les opérations suivantes: 1) la concentration magnétique du minerai (30% Fe, 9% TiO2 et 0,65% V2O5) pour produire un concentré (65% Fe, 7% TiO2 et 1,6% V2O5); 2) le smeltage du concentré aggloméré dans un four à arc, sans fondant, pour produire une fonte et une scorie (30% FeO, 40% TiO2 et 8,0% V2O5) qui contient plus de 95% du vanadium et du titane présents dans le concentré; 3) le grillage alcalin (37% Na2CO3) de la scorie suivi d'une lixiviation à l'eau et de la précipitation de l'hexavanadate d'ammonium à partir du filtrat; 4) la lixiviation du résidu par l'acide sulfurique pur ou usagé pour produire un rutile synthétique. Un estimé préliminaire de la valeur économique du projet laisse croire à sa rentabilité à la condition que l'investissement pour le smeltage soit inférieur à environ 400$/tonne de fer.IntroductionLes gisements de magnétites titanifères sont nombreux dans le monde. Ils consistent en une magnétite étroitement liée a l'ilménite, La teneur trop élevée en TiO2 empêche l'exploitation de ces gisements pour la production de fer. Cependant, dans certains cas, la magnétite a une teneur intéressante en vanadium qui peut rendre l'exploitation de ces gisements rentable. Aujourd'hui, les magnétites titanifères constituent la plus importante source de production de vanadium. On estime qu'environ 70% du vanadium produit provient de ces sources."

Jan 1, 1983

By G. W. Adams

Foreword While the literature on radium is voluminous, there is no single publication available from Canadian sources which attempts to cover at all fully the world radium industry. The comparatively recent developments in the Wilberforce area, and the consequent arousal of public interest in radium, seemed to call for the publication of such a paper which would be intelligible to the layman. To satisfy this apparent need, the writers submit this paper which contains material derived from various sources, and for which the writers make no claim of originality. Direct references are made throughout the paper to sources of information.

Jan 1, 1931

By W. van der Merwe

ABSTRACT With the gold industry processing more complex ores, the online measurement and control of cyanide addition to the gold leaching circuit has become more critical. This paper compares the two commonly employed ‘free’ cyanide online analysis methods (amperometric and potentiometric endpoint silver nitrate titration) with the rhodanine endpoint silver nitrate titration and ion selective electrode methods common at site laboratories. Measurement differences between these methods are presented and discussed for cyanide solutions containing copper and zinc with varying cyanide to metal ion ratios. The resulting cyanide available to leach gold is also compared using these measurement techniques.

Jan 1, 2013

By K. Liu

"In the present work, two-step heat treatments with preheating treatments at different temperatures (175, 250 and 330°C) as the first step followed by the peak precipitation treatment (375°C/48h) as the second step have been performed in Al-Mn-Mg 3004 alloys to study their effects on the formation of dispersoids and evolution of elevated-temperature strength and creep resistance. During the two-step heat treatments, the microhardness is gradually increasing with increasing time until to a plateau after 24 hours when first-treated at 250°C and 330°C while there is a minor decrease with time at 175°C. Results show that both the yield strength and creep resistance at 300°C reach the peak values after the two-step treatment of 250°C/24h+375°C/48h. The formation of dispersoids is greatly related to the type and size of pre-existing Mg2Si precipitated during the preheating treatments, in which that coarsened rod-like ß’-Mg2Si strongly promotes the nucleation of dispersoids while finer needle-like ß’’-Mg2Si has less influence. Under optimized two-step heat treatments and modified alloying elements, the yield strength at 300°C can reach as high as 97 MPa with the minimum creep rate of 2.2×10-9 s-1 at 300°C in Al-Mn-Mg 3004 alloys, enabling them as one promising candidate in lightweight aluminum alloys for elevated-temperature applications.INTRODUCTION Due to the rapid demand from weight-sensitive automotive and aerospace industrials for the light alloys, such as aluminum alloy on the elevated-temperature applications, Al-Mn 3xxx alloys has been developed to obtain the good properties at both room temperature (RT) and elevated temperature, in which the dispersoid-strengthening mechanism plays a significant role (Li & Arnberg, 2003; Li, Muggerud, Olsen & Furu, 2012; Liu & Chen, 2015, 2015). In our previous works (Liu & Chen, 2015, 2015; Liu, Ma & Chen, 2017), the yield strength and creep resistance at 300°C of Al-Mn-Mg 3004 alloy were further improved by modifying the alloying elements, such as Fe and Mo, to optimize the characters of dispersoids, including the size, distribution and the dispersoids free zone (DFZ). For instance, Mo was introduced in aluminum alloy to further improve the volume fraction of dispersoids and reduce the area of DFZ, leading to increasing on both the strength and creep resistance at 300°C (Liu, Ma & Chen, 2017). On the other hand, the mechanical properties became worse at higher Fe content due to its consumption more Mn to form Al6(MnFe) intermetallics, resulting in less available soluted Mn for the precipitation of dispersoids (Liu & Chen, 2015). Therefore, optimizing the characters of dispersoids is always the key to improve the elevated-temperature properties of dispersoid-strengthened aluminum alloys for elevated-temperature applications."

Jan 1, 2017

By J. I. Carroll, J. A. Walker

"Abstract - Camelback is a small (=200 000 tonnes), moderate grade (5%-7% Zn+Pb), volcanogenic massive sulfide deposit, which occurs within the Nepisiguit Falls Formation of the Ordovician Tetagouche Group. The host rocks are tuffaceous sedimentary rocks (Little Falls member) that overlie quartz-feldspar porphyritic tufflavas (Grand Falls member). The hanging-wall sequence comprises rhyolite of the Flat Landing Brook Formation, overlain by the Forty Mile Brook tholeiitic basalt. A dike of unaltered andesite was intersected beneath the massive sulfides, but was not found in the hanging-wall sequence in the vicinity of the deposit. The stratiform part of the deposit is made up of two, steeply south dipping, subparallel massive lenses that average approximately 4 m in thickness. Each lens is zoned, with an upper part consisting mainly of a pyrite and a basal part containing pyrite, sphalerite, and galena, with Ag values. The Au content in the massive sulfides is low (average = 52 ppb for 271 samples), but tends to be enriched in the massive pyrite near the top of each lens. Oxide facies iron formation is spatially associated with the massive sulfides, and has been traced up to 1800 m along strike. Footwall hydrothermal alteration is typical of VMS systems, and is characterized by depletion in K2O and Na2O, and enrichment in MgO and Fe2O3T with proximity to massive sulfides. The massive lenses are underlain by intensely chloritic, fine-grained, tuffaceous sedimentary rocks containing locally significant sulfide (chalcopyrite > pyrite > pyrrhotite) veins, which are interpreted to represent feeder zone mineralization. Unlike many VMS deposits, there is no evidence of silicification beneath the massive sulfides at the top of the feeder zone. The oxygen isotopic compositions (d18O = -1.5‰ to -0.3‰) of hydrothermal chlorite coupled with sulfur isotopic compositions (d34S ˜ 12‰) of the massive sulfides suggest that seawater was the dominant fluid in the hydrothermal system. Normalized rare earth element diagrams show flat Ce profiles and positive Eu anomalies, indicating that modified seawater was involved in ore formation; i.e., high-temperature (=350ºC), acidic, and reduced prior to entrainment into the hydrothermal cell. Although, seawater was the dominant fluid in the sulfide-forming system, d34S values of stringer zone sulfides (8.5‰) coupled with elevated Sn (400 ppm) in one massive sulfide sample indicate that there was at least some magmatic component in the hydrothermal cell."

Jan 1, 2006

By Dalton. J. L., H. P. Dibbs

An account is given of investigations into the application of two neutron methods to the on-line analysis of slurries. One deals with the application of the neutron moisture gauge principle to the determination of the water content of iron oxide slurries, and the other with the application of gamma radiation from thermal-neutron-capture to the determination of the composition of aqueous slurries of iron oxide, copper oxide, zinc oxide and sulphur. Linear relationships were found between the composition of the slurry and the neutron count-rate in the first study, and between the slurry composition and the prompt-gamma-ray count-rate in the second study. A mathematical relationship has also been developed which relates changes in the prompt-gamma-ray counts from hydrogen to changes in slurry composition.

Jan 1, 1973

By H. Marquis

This paper is concerned with an analysis of a number of failures of large-size, hypervelocity light gas gun chambers and barrels. A brief description of the light gas gun principle and of the various types of guns is first given. The failures and the investigations carried out are then described in detail, with the failures divided into two groups. The first group comprises those failures caused by certain conditions to which the guns may be submitted, and includes, for example, severe local heating of the bore surface causing hardening and cracking of the steel. These conditions were accidental and steps were taken to prevent them. The remaining failures were due to faults in the material or in the heat-treatment, manufacturing or assembling procedures. Specific problems, such as hydrogen embrittlement, and the use of high strength gun barrels above their ductile-brittle transition temperature by preheating prior to firing, are briefly considered. Some interesting observations are also presented on the use of surface markings, and angles of fracture of large fragments, as an

Jan 1, 1962

By Larry M. Southwick

Extraction of gold and other metals from ores suspended in liquid slurries often involves gases (such as oxygen) as a participant in the reaction. An important factor then in setting the rate of extraction can be mass transfer of the gas into the liquid and/or solids. A number of recent studies have indicated that as solids loadings increase, mass transfer rates of gas into solid-liquid mixtures decreases. This would seem to imply that lower solids loadings would be beneficial to increased reaction rates. However, since it is the solids which are being reacted, a most intriguing paradox is created. More solids should lead to more surface area to react, but it seemingly also provides less gas to react. So is the reaction faster or slower as solids loadings increases? The creation of this paradox is imbedded in how mass transfer and reaction data is collected and measured, how it is analyzed and correlated, and finally on the rate controlling steps in the reaction. An alternative analysis of these studies is presented which clarifies and eliminates the paradox. The analysis applies to water slurries as used in gold or other metal leaching processes or in bio-hydrometallurgy, as well as to molten metal/solid/gas mixtures such as might be encountered in submerged gas injection.

Jan 1, 1999

By M. S. Badollet

INTRODUCTION THE DEMAND for general knowledge on asbestos fibres has increased considerably in recent years. A few publications have printed data showing some of the physical and chemical prupertie3 of asbestos, but in many cases this information is difficult to find and is seldom available when needed. During the past ten years, Johns-Manville have received many inquiries on the physical and chemical properties of asbestos fibres. Fortunately, we had some of the information in our files, and we willingly supplied the data. To help relieve this need, we have tried to present briefly in this paper some of the interesting and out-standing properties of asbestos. This information was obtained over a period of years by search of the literature and by experimental investigations. PROPERTIES OF ASBESTOS FIBRES Table I (1, 2) presents, in convenient form for easy comparison, data on the principal properties of the several varieties of commercial 'asbestos' -actinolite, amosite, anthophyllite, chrysotile, crocidolite, and tremolite. Under each variety of fibre is a brief statement describing the properties in terms of structure, mineral association, origin, etc. Some of the more important data in Table I are expanded and presented in Table II (3). SOLUBILITY OF ASBESTOS A report ( 4, 5) discussing the effects of acids and caustic on asbestos fibres was published in Germany in 1927.

Jan 1, 1951

By A. R. Khodabandeh, T. Nematkhah

Correct selection of forging parameters is very important to produce sound superalloy parts. In this investigation nickel-iron base superalloy IN901 successfully forged and seal spacer, which is a part of airplane with about 11 kg weight has been produced. Forging has been performed on the basis of hot compression results, which show deformation above 1100°C associated with dynamic recrystallization (DRX) which can increase the workability of material. On the other hand annealing at 1100°C decreases the flow stress during hot compression, and then increases the material formability. Then billets annealed at 1100°C in electrical furnace for 24 hours and reheated again to 1100°C before forging. Initial square cross section billet with 128mm side and 202mm length forged immediately after reheating by 80MN mechanical press. Specimens forged in five steps: upsetting, three steps molding and finishing. Preformed and molded specimens reheated in electrical furnace before later step of forming. Finally specimens trimmed by 1 OMn mechanical press and hot set by hydraulic press and then cooled in air to room temperature. Results show that reheating temperatures has been selected correctly because there isn't any surface crack and die cavities filled completely by forging material. Material flow has been carried out properly and there isn't any defect in critical points especially in extradoses and intradoses. Microstructural examinations show that grain boundaries contain Ti-rich globular particles that formed during cooling.

Jan 1, 2006

By S. C. Tadolini

"Roof bolts are the primary means of roof support in underground mines in the United States. Presently, post installation loads are measured on about 10% of the expansion anchor and combination bolts by using standard torque wrenches that Unit the accuracy of the measurements to about ±30%. No system has been available for measuring the loads generated on full-column resin grouted bolts. Mine roof bolts are long, slender, non-uniformly sized, roughly forged, and placed in a corrosive environment, creating obstacles for researchers trying to utilize ultrasonic reflection techniques to measure strain. A complete measurement system has now been developed by the U.S. Bureau of Mines, Denver Research Center. This system is being used successfully in determining loads measured on expansion anchor and combination bolting systems, examining the transfer mechanics of full-column, resin-grouted bolts, and measuring loads generated on bolts in an underground roadway support system.IntroductionMillions of roof bolts are used each year to provide structural support in underground U.S. metal, non-metal, and coal mines. Approximately 45% of the bolts used are expansion anchor, 45% are resin-assisted combination or full-column resin-grouted, and 10% are friction anchored. The effectiveness of these bolting types is dependent on a number of factors including rock density, bolt length, in situ stresses, rock properties, bolt pattern, installation tension, etc. When implementing expansion anchor and resin assisted combination bolts , installation and post-installation tension, or load, is a major determinant of support quality and subsequent behaviour of the reinforced roof. The method by which these systems carry roof loads is well understood and documented(1,2).The importance of these installation and long-term bolt tension measurements is well recognized and are required in the federal government regulations(3). A statistical sample of the bolts, lout of 4 during installation and lout of 10 inby the last open crosscut, is required to be measured using current torque wrench technology. The disadvantages of this system are the disturbance and weakening of the anchorage and limitations of accuracy to approximately ± 30%. The method by which resin-grouted bolting systems carry roof loads is much less understood, mainly because testing procedures used to evaluate point-anchor systems are not effective on resin-grouted bolts.Due to these problems, the U.S. Bureau of Mines designed a measurement technique that provided a highly accurate, low cost-per- bolt system that led to the development of ultrasonic pulse echo instrumentation. The original system was designed to measure the tension only on expansion anchor bolts. Recent developments and system modifications have permitted measurements on resin-assisted and full-column resin-grouted bolts. The use of these types of support systems has been increasing steadily in underground coal mines.The development of this instrumentation has provided laboratory and field results that help to explain the mechanics and relationships between the applied loads and the interaction between the grouted bolt system consisting of the bolt tendon, grout, and rock."

Jan 1, 1990

By W. Tse, D. Wong

Dense medium separation (DMS) is one of several preconcentration methods used for early waste rejection from run of mine ores at relatively coarse particle sizes prior to additional milling and beneficiation. DMS has been used extensively in the coal, diamond and iron ore industries but lab scale and pilot test work has demonstrated successful separation and upgrading of other minerals such as lead, zinc, copper and lithium based ores using DMS. This paper reviews historical dense media systems, results from the pilot scale Condor DMS system as well as associated laboratory heavy liquid separation (HLS) test work.

Jan 1, 2014

By P. Mundell, R. Torbin

"There are many physical and operational obstacles in pipelines that make the passage of inspection robots impossible including:•,Small radius bends•,Low operating pressure•,Plug valves•,Large changes in pipe size•,No permanent access to the pipeline.The inspection of unpiggable pipelines requires the marriage of a highly agile robotic platform with NDE sensor technology operating as an integrated system. Foster-Miller and GE/PII are developing a robot that is essentially a battery powered, train-like platform. Both front and rear tractors propel the train in either the downstream or upstream direction. Like a train, the platform includes additional ""cars"" to carry the required payloads. The cars are used for various purposes including the NDE sensor module(s), the power supply, and data acquisition/storage components. The robot is designed with a slender aspect ratio and the ability to change shape as required by the physical obstacle presenting itself. The MFL sensor module must also morph itself through the physical obstacles, and thus, will require some level of segmentation. The segmented MFL magnetizers and transformable sensor module represent a major advance in the science of sensor technology and pipeline inspection."

Jan 1, 2005

By R. Le Houillier, M. Nagamori, A. J. Plumpton

"Asbestos tailings are a typical serpentine, hydrated magnesium silicate, consisting primarily of antigorite and a few per cent of unrecovered fibrous chrysotile. Serpentine has unique thermal properties in that dehydroxylating calcination at 600 to 700°C can yield an amorphous structure in which most of the magnesia is liberated from the original bond with silica and thereby rendered chemically active. The amount of activated magnesia can be quantified by selective leaching with a weak acid such as acetic acid. Many wet processes have been proposed to extract magnesium values from calcined or natural serpentine by means of various acids and their ammonium salts. However, the only commercial utilization of serpentine today is found in dry processes such as the production of fused magnesium phosphate fertilizer .The present paper reviews the physical chemistry of the dehydroxylation of serpentine and also various wet and dry processes in order to provide a general view regarding the chemical transformation of asbestos tailings.IntroductionAsbestos fibers occur as chrysotile, a serpentine polymorph. More than nine tenths of mined asbestos ores consist of massive non-fibrous serpentine, primarily the polymorph antigorite, which is discarded as tailings after fiber extraction. For many decades, Quebec has been a world leader in the production of asbestos fibers. As a result, colossal tonnages of serpentine have accumulated in the Eastern Townships'!'. Serpentine minerals are found in large deposit s throughout the world, and significant research efforts have been made, particularly in Japan and the USSR, mostly in attempts to extract magnesia or silica values therefrom.The chemical composition of serpentine (chrysotile and antigorite) may be ideally expressed as Mg3Si2Os(OH). which corresponds to 43.7% MgO and 43.3% SiO2. Natural serpentines often contain a few per cent of Ni-bearing magnetite and other impurities, and therefore the contents of MgO and Si02are both about 40% or lower.Serpentine (hydrated magnesium silicate) is virtually insoluble in weak acids. However, when dehydroxylated under controlled conditions, ' it decomposes to an amorphous state in which magnesia and silica are isolated and chemically active. The magnesia so activated is readily soluble in weak acids. This unique characteristic of calcined serpentine, first discovered in 1942,, has since attracted the attention of innumerable researchers, whence many processes have been proposed."

Jan 1, 1980

By Peter R. Drummond

THE paper consists of four sections: (1) a discussion of early work; (2) presentation of the results of a chemical investigation of Falcon-bridge nickel-copper blast-furnace matte; (3) application of the results of this investigation to mattes in general; and ( 4) a summary of conclusions. All general discussion will be confined to the fundamental system of ferrous-cuprous sulphides (FeS-Cu2S). Nickel-, lead-, and zinc-bearing mattes will be treated as minor varieties of the parent system. DISCUSSION OF EARLY INVESTIGATIONS Matte investigations may be divided into three classes: first, those treating the sulphides as alloys-theoretical studies of the system FeS-Cu2S, such as those of Hofman (ll)t or Carpenter and Hayward (2); second, chemical research on mattes made under smelter conditions, such as that carried out by Hawley (3) or Avetision ( 4); third, combinations of the . above, such as the investigations of Gibb and Philp (5) or Fulton and Goodner (6). Much research in the first of these classes, including determinations of . freezing points and of data for structure-composition diagrams of the system FeS-Cu2S, was carried out in the period 1890-1910. LeChatelier and Ziegler (1, 13) proved that FeS, when heated alone above its melting point, dissociated in part, and Friedrich ( quoted by Fulton, 6) showed the same for Cu2S. The reactions may be expressed by the following equations: [xFeS yFe + yS (volatilized)+ (x -y)FeS xCu2S )'Cu+ yS ( vohtilized) + (x -)')Cu,S ] Sulphur is lost by volatilization, leaving a melt of metallic iron plus ferrous sulphide in the one case, and of metallic copper plus cuprous sulphide in the other. If the mixed sulphides are heated far above their melting points, there results either an iron-rich matte containing Fe-FeS-Cu2S or a copper-rich matte containing FeS-Cu2S3-Cu, depending on the relative amounts of each sulphide in the mixture.

Jan 1, 1940

By J. G. Bennett

Coal consumption has increased globally by 57% over the last ten years. Underground mining typically provides coal of the highest calorific value and accounts for the greatest proportion of production. Despite a negative environmental image and indeed impact, this industry appears likely to thrive on the global scale for many years to come. Such mining consumes large amounts of electricity with implications for carbon dioxide emission at power plants and emits substantial quantities of the powerful greenhouse gas methane. In response to this significant carbon footprint, the European Union has funded research to examine the potential for a range of improvement technologies in a project entitled Low Carbon Mine Site Energy Initiatives (LOWCARB). Coal properties related to seams and mines, together with longwall characteristics, provide the basis for research into modelling optimally efficient methane drainage with a view to assisting mining as well as maximising electricity generation at surface and hence oxidation of the methane. Possible systems for the oxidation of very low concentration methane in ventilation air, which contributes the greatest greenhouse gas impact due to the volumes emitted, have been studied and modelled. Simulation and investigation of intelligent optimisation of electricity demand patterns provide the basis for reducing the demand peaks at mines and hence the cost and ultimately the carbon footprint of a mine, while specific investigations have been undertaken into ventilation efficiency at an unusually challenging mine and simulation of mine water pumping in order to develop an innovative method to monitor pumping systems efficiency. For post-mining use, the potential of disused shafts for compressed air energy storage to improve the operation of future electricity grids with high renewable energy penetration by reducing peak generation capacity requirements has been studied. While underground coal mining will always by definition be related to a significant carbon footprint, this paper provides an overview of a set of initiatives that can make a positive environmental impact while controlling costs across a huge global industry.

Aug 1, 2013

By H. O. Seigel

Induced Polarization includes many types of dipolar charge distributions set up by the passage of current through consolidated or unconsolidated rocks. Among its causes are concentration polarization and electrokinetic effects in all rocks and the phenomenon of Overvoltage in rocks containing electronic conductors such as metallic sulphides and graphite. In normal rocks the polarization effects may be usually con-fined within relatively narrow limits and any large departures may be at-tributable to the presence of electronic conductors. In practice, Induced Polarization is measured in one of two ways. In the first a steady current of some seconds duration is passed and abruptly interrupted and the slowly decaying transient voltages existing in the ~round are measured after interruption. This is known as the "pulse", "transient", or Direct Cur-rent Induced Polarization (D.C.I.P.).The second method entails a comparison of apparent resistivities using sinusoidal alternating current of two or more frequencies, generally within the range of 1/10 to 10 c.p.s. Induced Polarization extends the

Jan 1, 1962

By S. Klingmann

ABSTRACT In this paper, we used data collected from the Gibraltar mine to analyze the effect of the TyreSense tire monitoring system on tire performance by reducing tire wear and preventing premature tire failure or damage. We analyzed the relationship between tire temperature, tire pressure, and tire failure or damage to help better understand the importance of controlling high tire temperature and pressure. The results enhance and expand the knowledge of the management of tire operational pressure and temperature.

Jan 1, 2014

By Michel Jébrak, Claude Bellehumeur

Abstract - Regional and orientation geochemical stream sediment surveys were carried out by the Quebec Department of Energy and Resources in southwestern Quebec, over a part of the Mont­ Laurier Terrane of the Grenville Province. The area contains some small stratiform zinc deposits. The response of Zn mineralization to geochemical surveys is weak; the known mineralization is not defined by anomalous samples and consistent patterns. This study uses a technique that increases the geochemical signature of Zn mineralization in filtering out geochemical background components related to lithologies and surficial conditions. The background variations were modelled using principal component analysis, and the filtering technique consists of the partial reconstruction of the data matrix from results of principal component analysis . The filtering procedure considerably enhances the Zn anomalies located in the catchment basins of Zn deposits, and defines some new anomalies in proximity to the marbles of the Mont-Laurier Terrane, the principal metallotect of Zn mineralization.

Jan 1, 1993

By M. B. Kime

"A set of experimental batch leaching tests studied the effect of pH, time, temperature, and stirring speed on the relative Cu, Co, Ni, and Fe leaching yields of an oxidized copper-cobalt ore sample in an aqueous hydrochloric acid solution. The results were statistically analyzed and modelled using the structural equation modelling method. Models showed that Cu, Co, and Ni leaching yields were strong functions of the leaching time and leaching temperature, whereas the Fe leaching yield depended on the leaching temperature, stirring speed, and pH. Under optimum leaching conditions yields were 99.8% Cu, 82.4% Co, 91.3% Ni, and 30.6% Fe.RÉSUMÉ Une série d’essais expérimentaux de lixiviation en bâchée ont été menés pour étudier l’effet du pH, de la durée d’attaque, de la température et de la vitesse de brassage sur les rendements relatifs de lixiviation du cuivre (Cu), du cobalt (Co), du nickel (Ni) et du fer (Fe) d’un échantillon de minerai de cuivre-cobalt oxydé dans une solution aqueuse d’acide chlorhydrique. Les résultats ont été analysés et modélisés statistiquement à l’aide de la méthode de modélisation par équation structurelle (SEM, de l’anglais structural equation modelling). Les modèles ont montré que les rendements de lixiviation du Cu, du Co et du Ni dépendaient énormément de la durée d’attaque et de la température de la lixiviation ; le rendement de lixiviation du Fe, quant à lui, dépendait de la température de la lixiviation, de la vitesse de brassage et du pH. Dans des conditions optimales de lixiviation, les rendements étaient de 99,8 % pour le Cu, de 82,4 % pour le Co, de 91,3 % pour le Ni et de 30,6 % pour le Fe. INTRODUCTIONThe Katanga province in the Democratic Republic of Congo hosts the northwestern part of the Central African Copperbelt. This region abounds with large, rich deposits of sulfide and oxidized copper-cobalt ores. In general, the main valuable minerals present are malachite (CuCO3Cu(OH)2) and heterogenite (CoO(OH)). Common impurities found in heterogenite are Cu, Ni, Si, Al, Mn, and Fe. The substitution of Co by other cations (e.g., Cu, Ni, and Fe) has an influence on the crystallinity of heterogenite (Deliens, 1974). In general, well-crystallized varieties of heterogenite have lower impurity contents, whereas amorphous heterogenite types usually contain more impurities (Thys et al., 2009). Further, in heterogenite, Co can occur in the 2+ and 3+ oxidation states. The gangue generally consists of quartz (SiO2), talc (Mg3Si4O10(OH)2), kaolinite (SiO2·Al2O3·2H2O), limonite (Fe2O3·3H2O), and goethite (FeO(OH)). Oxidized copper-cobalt ores are often treated by hydrometallurgical methods, whereas sulfide ores are often treated by flotation or pyrometallurgy, depending on their grades. Hydrometallurgical methods typically entail selectively dissolving the metals of interest (Cu, Co, and Ni) in aqueous solutions (leaching), transferring the dissolved metals to an organic solution, and retransferring these to a second aqueous solution (solvent extraction). Copper and nickel are readily dissolved in an acidic aqueous media. In contrast, cobalt is difficult to dissolve, especially if it is present in the third oxidation state; however, this species becomes soluble after it is reduced to Co2+ (Mwema, Mpoyo, & Kafumbila, 2002; Kime & Makgoale, 2016)."

Jan 1, 2017