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By Lijuan Chen

During the detoxification of chromium-containing slag by Achromobacter sp. CH-1, anionic surfactant Sodium Dodecyl Sulphate(SDS) and its mixed systems with different Tween surfactants(Tween 20, Tween 60 and Tween 80) were used to promote the interaction between the bacteria and the chromiumcontaining slag and the rate of acid-soluble Cr( ? ) leached from the slag. The effects were evaluated by the surface tension, the pH of the leaching solution and the leaching rate of total Cr( ? ) from the slag. The results showed that the surfactants systems improved Cr(VI) leaching and its detoxification of chromium-containing slag. The mixed surfactants of SDS combined with Tween surfactant revealed better effectiveness of detoxification than SDS only. When the mass ratio of SDS to Tween 80 was 1:1, the rate of Cr( ? ) leached from the slag increased by 12%.

Jan 1, 2009

Gas-liquid contacting in the packed bed is a common operation in metallurgical reactors. Research has shown that, unlike wetting flow, non-wetting liquid flows in the form of discrete droplets or rivulets. Thus, modeling of the liquid phase as a continuum is in contradiction to the observations. Also, for the non-wetting case, continuum models have failed to describe liquid flow path when the liquid source is a point source. The aim of the current work is to put forward a combined Lagrangian-Eulerian approach to model the liquid and gas flow in the packed bed. Liquid is assumed discrete and modeled using a force balance approach. Gas is assumed to be interpenetrating continua and modeled using k-emodel for turbulent flow. Structured packing is assumed and x- ray imaging technique is used to visualize liquid flow lines in the bed. Simulation results for liquid flow path compared with the experiments.

Jan 1, 2006

By Joseph Gambogi

In 1998, approximately 57,000 tons of titanium metal was consumed in the form of mill products (1). Only about 5% of the 4 million tons of titanium minerals consumed each year is used to produce titanium metal, with the remainder primarily used to produce titanium dioxide pigment. Titanium metal production is primarily based on the direct chlorination of futile to produce titanium tetrachloride, which is then reduced to metal using the Kroll magnesium reduction process. The use of titanium is tied to its high strength-to-weight ratio and corrosion resistance. Aerospace is the largest application for titanium. In this paper, we discuss all aspects of the titanium industry from ore deposits through extraction to present and future applications. The methods of both primary (mining of ore, extraction, and purification) and secondary (forming and machining) operations will be analyzed. The chemical and physical properties of titanium metal will be briefly examined. Present and future applications for titanium will be discussed. Finally, the economics of titanium metal production also are analyzed as well as the advantages and disadvantages of various alternative extraction methods.

Nov 26, 1999

A series of electron beam, cold hearth, single melt Ti-6Al-4V plates (nominally 2.5 cm thick) impacted by 2cm diameter, 4340 steel projectiles (with 54g nominal mass) at velocities ranging from 0.633 to 1.027 km/s were sectioned along the impact axis and examined by optical metallography to characterize the formation, growth, and microstructure of adiabatic shear bands. Near ballistic limit velocities, the shear bands propagate towards the rear of the target where they coalesce and grow to provide a cylindrical solid state flow regime for the plug volume.

Jan 1, 2006

By Liu Wei

In order to make clear the dissolving characteristic of the chrysocolla (CuSiO3?H2O) in the ammonia-ammonium chloride solution, a thermodynamic model of the chrysocolla (CuSiO3?H2O)-ammonia- ammonium chloride-water system is established using the exponential computation method based on both mass balance and charge balance equations. The equation group of the thermodynamic model is solved by the MATLAB Soft on PC. The condition which is favorable for dissolving high concentration of copper in solution is making out. The stable area of chrysocolla (CuSiO3?H2O) and the condition of chrysocolla (CuSiO3?H2O) converting to atacamite (Cu(OH)1.5Cl0.5) is also studied. A group of experiments are designed to validate the veracity of the results of the thermodynamic calculation.

Jan 1, 2010

By P. N. Anyalebechi

The effects of solidification rate on the cast microstructures of aluminum alloys 6009 and 6016 have been investigated with directionally cooled laboratory-size ingots, at 0.2-10.1 K/s and 0.4- 23.1 K/s, respectively. These ranges of solidification rate are within those observed in commercial-size ingots. In both alloys, the average dendrite cell size and second phase particle size decreased with increase in average solidification rate and with a decrease in average local solidification time. However, at comparable solidification rates, the dendrite cells and second phase particles are finer in the shorter freezing range alloy 6009 than in the longer freezing range alloy 6016. This is provisionally attributed to the earlier formation of second phase intermetallics at higher temperatures during solidification and to the formation of greater amount of the relatively coarse plate-like ß -phase (Al9Fe2Si4) phases in alloy 6016. In general, in both alloys, the types and relative amounts of the second phase particles in both alloys are independent of solidification rate.

Jan 1, 2006

By Elaine Araújo

Since the ancient times, clays were used as decolorant material for various types of oils. These clays were called ?decolorant clay?. They have the property to decolor dye materials present in mineral oils, plants and animals. Biofuel is a fuel derived from biomass of live organisms. As biodiesel is produced from renewable sources, the generation of employment due to industrial scale production may cause a reduction in the dependence on foreign diesel importing, as well as the reduction of air pollution by the addition of biodiesel to diesel. This study aimed to develop a technological process to decolor post- consumption oil to be applied as biofuel. The results were characterized by techniques of XRD (X-ray diffraction), X-ray fluorescence and FTIR (Fourier Transform Infrared). It was observed that the post-consumption oils presented a higher decoloration result after treatment with the Brazilian clay.

Jan 1, 2009

By Pinakin C. Chaubal

An industry ? university consortium was set up to develop advanced tools necessary to understanding of the various phenomena occurring in the hearth of the modern iron making blast furnace. The major driver for this work was to provide the technological support required to extend campaign life of blast furnaces, which, by current agreement is tied to the life of the furnace hearth. The hearth wear is significantly affected by the hot metal velocity, temperature distribution and refractory temperatures. Due to the difficulty in making measurements inside the hearth, novel approaches to gain a fundamental understanding of the detailed physical and chemical processes in the hearth must be developed. The approach used in this project was to develop a 3-D CFD (Computational Fluid Dynamics) model coupled with extensive validation efforts. The CFD model is being utilized (1) to understand the phenomena in the hearth, (2) to understand the impact of changes in the internal conditions of the hearth on wear patterns; and (3) to design a monitoring/controlling system for prolonging campaign. In this paper, the results will be reviewed.

Jan 1, 2006

By Huang Kai

By adding the solid oxalate acid powder into the solution of nickel chloride or its ammonia coordinated solution, the uniform compound particles were prepared and the precipitated particles were transferred to the mono-dispersed NiO particles by calcination. In this study, the various experimental conditions were investigated, the characteristics of the corresponding obtained particles were analyzed, and the formation mechanism of the particles was elucidated. It was found that the solid oxalate acid provided the solid-solution interface for the precipitation and induced the nucleation and growth of the product particles.

Jan 1, 2005

By Qingwei Wang

This study focused on acidic wastewater from producing sulfuric acid system in zinc smelter containing mercury 21.48mg/L, zinc 55.85mg/L, lead 38.50mg/L, copper 1.68mg/L, cadmium 10.25mg/L, As 29.86mg/L treated by biologics. The factors of pH value, the ratio of biologics to mercury, complexing time, hydrolytic time and temperature were studied in this paper. Experimental results indicated that at pH value 10, quantity of biologics to mercury ratio was 16, complexing time 30min, hydrolyzation time 20min, temperature at 40?, concentration of mercury in treated water was removed to 22.15µg/L. At same time heavy metals such as Zn, Pb, Cu, Cd, As was removed by biologics, the remained concentration in treated water was Zn 0.53mg/L, Pb 0.12mg/L, Cu 0.01mg/L, Cd low to 0.01mg/L and As 0.023mg/L. According to EDAX analysis, mercury content in complexing sediment reached 28.49% easily to recycle as raw material and low concentration of heavy metals in hydrolytic sediment easily to dispose and treat.

Jan 1, 2009

By Sadegh Firoozi

Experiments measuring the kinetics of oxidation and making visual observations of the oxidation of approximately 6 g static lead baths containing arsenic, antimony and tin were conducted in the temperature range from 500 to 600 oC. A range of repeatable behaviours were observed, notably: the formation of a coherent, solid oxide layers on pure lead and lead-tin alloys; the formation of liquid oxide droplets during the initial oxidation of lead-arsenic and lead-antimony alloys and the eventual formation of a complete oxide layer covering the entire free surface of these alloys. Thermogravimetric measurements revealed that the rate of oxygen uptake was strongly influenced by the form of oxides being generated at the melt/gas interface. Compared to the rates of oxidation of pure lead, arsenic increased the rate of oxygen uptake throughout the temperature range via the formation of liquid oxidation products. The presence of antimony resulted in a moderate increase in the rate of oxygen uptake as compared to arsenic. Tin was effective in lowering the rate of oxidation even in the presence of arsenic because the oxidation product was always a coherent layer that acted as a physical barrier to oxygen transport to the underlying alloy.

Jan 1, 2006

By Susan Jacob

The heat of fusion of silver was measured using high temperature differential scanning calorimetry (HTDSC). Heating rate, sample mass, calibration standard and cover gas flow rate were varied to determine their impact on instrument accuracy and reproducibility. Good reproducibility was achieved in most of the runs. Accuracy was not satisfactory in most of the runs, though three runs gave results within 1.7%, 3.3% and 3.5% of the literature value, within the acceptable limits. A larger mass and higher heating rate tend to generate more accurate results.

Jan 1, 2006

By Richard S. Dennis

Acid recovery employs ion exchange (I-X) resin as separation media for inorganic acids from dissolved metallic salts by physical adsorption and without the use of chemicals. This technology has been used for years on spent etching and plating liquors to recover acid for reuse in the bath and to reduce waste acid neutralization costs. It is also used for electrolyte treatment to facilitate valuable metal recovery via acidity reduction. TETRA's ccrxr'" I-X contactor has been used successfully for acid separation from its metallic salt counterpart in a simple, continuous operating mode using strong base anion resins. Efficient separation is enhanced by acid reconcentration to nearly its original strength or as high as 14-20%. Continuous treatment also recovers heat to the tankhouse or bath and improves metal quality due to consistent acid quality. Conventional fixed bed ion exchange (I-X) systems are impractical for acid recovery because of complex control design and large resin inventories needed to process very low liquid-to-resin treatment ratios associated with strong acid concentrations.

Jan 1, 1996

By F. A. Guo

Ultrafine-grained surface layers were obtained by surface mechanical attrition treatment (SMAT) in copper and titanium samples. The thermal properties of the deformed layers were characterized using a scanning thermal microscopy (SThM) that allows thermal conductivity to be mapped down to the submicrometer scale. A theoretical approach, based on this investigation, was used to calculate the heat flow from the probe tip to the sample and then estimate the thermal conductivities at different scanning positions. Experimental results and theoretical calculation demonstrate that SThM can be used as a powerful tool for the thermal property and microstructural analysis of ultrafine-grained microstructures.

Jan 1, 2006

By Pengfu Tan

Xstrata Copper at Mount Isa in Australia has operated one copper Isasmelt furnace and four P-S converters. The phenomena of foaming occur in above 10% of converter operations. A thermodynamic model of copper P-S converter and a viscosity model of converter slag have been developed to simulate the slag blow and copper blow. The model predicts the chemistry and viscosity of copper skims during copper blow. The effects of oxygen potential, charge of dirty materials, slag carry-over, under-blowing, over-blowing, and temperature on the foaming and viscosity of copper skims have been discussed. Some improvements of the industrial operations have been presented.

Jan 1, 2006

By C. E. M. Meskers

End-of-life Electronic and Electrical Equipment, o_cially called WEEE, is unjustly regarded as mainly a waste management problem. What is structurally overlooked is the enormous resource impact of these devices. EEE rep- resents a tremendous metal resource, which should be uti- lized through e_ective recycling, which has a much lower environmental footprint than primary production. The actual amount of end-of-life EEE recycled today is embar- rassingly low since insu_cient EEE is collected and part of the collected EEE is exported to developing countries, where it is largely not entering o_cial recycling systems. To achieve a global recycling society issues like technol- ogy, economics, life cycle structure, stakeholder aware- ness and legislation have to be addressed in a global, co-operative manner so that sustainable closed product cycles can be obtained. Requirements for a "global re- cycling society" are de_ned to address today's reality of global ows of used consumer products, taking into ac- count the likely needs of the future.

Jan 1, 2009

By Sergio N. Monteiro

Polymeric composites reinforced with natural fibers are increasingly been used in several engineering applications, from automotive parts to building construction elements. In addition to the relatively low cost, the natural fibers are also appraised by their renewable and biodegradable characteristics. Fibers extracted from the crust of coconut fruits, also known as coir fibers have been investigated for a possible use in composite materials. In the present work, the coirfiber/polyester matrix interfacial strength was evaluated by means of pullout tests. The variation of the pullout tensile stress vs. the embedded coir fiber length permitted to determine the critical fiber length and, thus, to calculate the interfacial strength. Observations by SEM complemented the results from pullout tests, indicating that coir fibers have a potential for application aspolymeric composites that could replace conventional materials such as wooden and gypsumpanels.

Jan 1, 2006

By David Norval

Water solidification of mattes, metals, alloys and certain slags with high metal entrainment has customarily not been practiced due to the belief that such processes are too dangerous and unproven in the Pyrometallurgical Industry. Slag granulation on the other hand is extensively applied, although in some cases crudely, with disastrous effects, as a result of not recognising the high heat capacities prevalent in slags. This paper will examine the most common air solidification processes and compare such processes with water solidification, mainly slag and matte granulation processes and design criteria for safe and reliable operation. Finally, purpose designed granulation and solidification processes will be discussed taking into account specific applications and the individual signatures of alloys and slags, emphasising that no slag, matte or alloy responds in similar fashion to a granulation practice.

Jan 1, 2006

By Bowen Li

Andalusite is an excellent raw material for refractory applications due to its high aluminum oxide content and phase transformation to mullite at high temperature. Granular andalusite in particle sizes of about 1 to 2 mm was traditionally utilized for the manufacturing of refractory brick. However, if powder andalusite in micron particle size is utilized in high-alumina refractory products, reinforcement on the refractory brick can be obtained and the sintering temperature can be decreased. The phase transformation of powder andalusite plays a key role for the difference.

Jan 1, 2006

By Hui Lu

The structural changes in solutionized AA2618 during natural aging and their effects on subsequent artificial aging were investigated by hardness measurements, X-ray diffraction, differential scanning calorimetry and transmission electron microscopy. The changes in lattice parameter and hardness during natural aging indicate that copper-enriched clusters form in the earliest stage, followed by the formation of magnesium-enriched clusters and coppermagnesium co-clusters. Prior natural aging consistently weakened the hardening during subsequent artificial aging at 180, 200 and 230 °C but had no effects on artificial aging at 150 °C. The decreased age hardening was attributed to the reversion of small clusters/zones that formed during prior natural aging. The lattice parameter exhibited erratic changes with increasing artificial aging time, reflecting the complex sequence of the reversion and precipitation.

Jan 1, 2006