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By G. Barrasso, E. Nordheim

"The European aluminium industry, through its member organisation the European Aluminium Association (EAA), initiated a program on sustainable development for the aluminium industry in 2001. The first step involved the development of a set of sustainable development (SD) indicators for the industry, taking into account of the different interests involved and also the different existing conventions. The indicator set was developed during 2001 and 2002 with the assistance of recognised partners, including Wuppertal Institute from Germany and Versailles University from France. As well, both internal and external stakeholder groups were involved in order to validate the indicators. This has resulted in a set of thirty-four indicators used in the first survey exercise. In the survey the EAA, together with the national aluminium associations, attempted to cover all European plants producing alumina, primary aluminium, rolling ingots, extrusion ingots, foil and recycled aluminium -covering approximately 800 plants. The survey used two points in time, 1997 and 2002, in order to start developing a trend for the individual indicators and to measure progress over time. The industry response to the survey was very positive, with a total industry coverage based on tonnage reported of over 80% for 2002 data and 70% for 1997 data. The results also show a solid progress for most indicators and particularly for social indicators such as training performance, community involvement and employees health programmes. The EAA is committed to conducting this as a regular exercise and is engaged in a number of stakeholder workshops in order to present the survey results, to review the indicators used and to also consider adjustments of these based on feedback from stakeholders and experiences from the first data collection."

Jan 1, 2005

By M. Imazu, Ö. Aydan

"A new rock classification, Rock Mass Quality Rating (RMQR) proposed by the authors is briefly explained and its application for the design of tunnels and large underground openings support systems is described in this paper. RMQR is an index to evaluate the state of rock mass. The preliminary support design may be based on the concept to prevent structurally controlled failures of rock mass. RMQR can also evaluate the yielding characteristics of rock masses so that it is possible to design a support system to prevent or control the deformation of surrounding rock through the utilization of the proposed rock mass classification and some analytical and numerical techniques.INTRODUCTIONThe first three authors proposed a new rock classification system named Rock Mass Quality Rating (RMQR) (Aydan et al. 2014). RMQR quantifies the rock mass state, and using the classification system together with intrinsic geo-mechanical properties of intact rock, possible geo-mechanical properties of rock masses can be estimated. The instability modes of underground openings can be structurally controlled because of the orientation of discontinuities in rock mass and the in-situ stress induced (Aydan 1989; Aydan et al. 1993, 1996; Aydan and Genis, 2010). The authors (Aydan and Ulusay, 2013; Aydan, 2016) have also tried to apply this system to the design of a tunnel support system. The authors presented initial guidelines for the RMQR classification system earlier (Aydan and Ulusay, 2013).In this paper, the authors provide further guidelines and establish some criteria for support system design that considers loading conditions and types of underground structure according to RMQR. Guidelines are alsos proposed for selecting the proper size of rockbolts, rock anchors, shotcrete, steel ribs and concrete liner. These guidelines are based on past experiences with various underground structures, theoretical understanding and the anticipated behavior of rock mass under given in-situ stress conditions and excavation techniques. The authors also utilized some databases developed for large underground caverns and tunnels excavated in squeezing or rock-bursting ground conditions."

Jan 1, 2016

By W. Petruk, D. B. Sikka

Lithium-bearing lepidolites from three deposits in the province of Goias, Brazil, were investigated to determine whether there is a correlution between the lithium content of the mineral and the color of lepidolite and associated tourmaline. Such a correlation can be a useful guide to field geologists for outlining high-grade lithium ore zones. It was found that mauve-pink lepidolite associated with pink tour-maline, and brownish lepidolite associated with black tourmaline have high lithium contents, but that the color of lepidolite is not due to lithium. The pink color of lepidolite and tourmaline is likely due to Mn3+, and the brownish tint of lepidolite and black color of tourmaline to Fe3+. Lepidolites appear to be lithium- rich when the lepidolite and associated tourmaline contain relatively high amounts of Mn3+ and/or Fe3+.

Jan 1, 1988

"Controlling dust generation and keeping it below permissible limits at the working face of a room and pillar mine is a challenge for mine operators. With the recent changes in the respirable-dust regulation, it has become increasingly difficult. The current most effective practice of dust control at a continuous miner face in an underground mine is the use of a flooded-bed scrubber. A study carried out by the National Institute for Occupational Safety and Health (NIOSH) stated that a flooded-bed scrubber, under its optimum condition, can achieve cleaning efficiencies between 58 and 90 percent. The performance of such a system can be maintenance intensive. Other industries face similar dust control issues. The University of Kentucky partnered with Toyota Motor Manufacturing for the development of a novel wet scrubber for capturing paint overspray, with capture efficiencies in excess of 98 percent and minimal maintenance. The aim of this study is to assess the ability of this novel wet scrubber to capture respirable dust in an underground coal mine. This paper presents the conceptual design and the computational fluid dynamics (CFD) modeling of this novel wet scrubber. It discusses the results of the CFD simulation performed on the novel wet dust scrubber. INTRODUCTION Dust generation from underground coal mining is an inescapable phenomenon. No matter the practices employed, it inevitably occurs. Elevated concentrations of coal dust are potential health and safety hazards. Although dust in an underground coal mine cannot be completely avoided, its influence can be mitigated through good engineering practices. The effect of dust on the health of mining personnel has had a significant impact. The prolonged exposure of airborne respirable dust (< 5 µm) can cause coal workers’ pneumoconiosis (CWP), silicosis, emphysema, and chronic bronchitis, collectively known as black lung (U.S. Department of Labor, 2014). According to the National Institute for Occupational Safety and Health, black lung has killed more than 10,000 miners between 1995 and 2004 (NIOSH, 2008). In addition to being a health issue, coal dust is also a safety issue to the underground coal miners. The generated dust, if not captured, is dispersed into the mine air through the ventilating air and deposited downwind on the return entries’ surfaces. In the event of a methane explosion, the coal dust, if insufficiently diluted with rock dust, triggers a coal dust explosion which is much more severe than a methane explosion and causes more damage (Kenneth et al, 2006). The Jim Walters No. 5 Mine and the Upper Big Branch Mine disasters which together killed 42 people and resulted in damage worth millions of dollars in property are the examples of coal dust explosions (U.S. Department of Labor, 2001 & 2010)."

Jan 1, 2016

By Nora M. Hutt, Kevin A. Morin

One technique for controlling ongoing acidic drainage is to relocate and submerge net-acid-generating waste rock in a lake or water-retaining impoundment. This can lead to the overall improvement of water quality and the reduction In short-term environmental liabilities. A case study of this technique is the Eskay Creek Mine in northern British Columbia. Some findings of the study are: (1) the addition of lime to each truckload of rock, based on its rinse pH, neutralized the accumulated acidity and suppressed the accumulated-metal release, (2) only 10-20% of the dump&apos;s neutralization potential had been consumed when acidic drainage appeared, (3) water chemistry in the watershed recovered roughly three years after relocation, and (4) environmental liability was reduced due to the cessation of on-land acidic drainage with no degradation of lake chemistry.

Jan 1, 2000

By Jason Saldanha, Andrew Evans, Jonathan Baber

"INTRODUCTION The need for a new road crossing at Silvertown is the result of three key drivers:- •,Severe congestion and delay at the Blackwall Tunnel and surrounding road network; •,A lack of network resilience and reliability resulting from a lack of alternative road crossings in east London and the impacts of unplanned closures; and •,The need to support substantial economic development in east and south-east London (jobs and homes) These drivers directly informed the main objectives for a road-based river-crossing solution. The traffic-related problems at Blackwall Tunnel are long-standing and before Transport for London (TfL) assumed control for the strategic road network in London in 2000 the Department for Transport (formerly Dept of Transport) had investigated various relief options including a third tunnel bore and new bridge. This resulted in a new crossing alignment being safeguarded (by direction of the Secretary of State for Transport) and this was refreshed in 2001 in favor of TfL. In recent years (since 2009) TfL as part of the East London River Crossings Programme has undertaken detailed optioneering and feasibility work to address the above ‘need’. This led to the conclusion that a new road tunnel would offer the best solution in preference to bridge, ferry or demand management options. In 2012, in response to a formal request by the Mayor of London, the Secretary of State for Transport confirmed a new road crossing at Silvertown as a Nationally Significant Infrastructure Project (NSIP) by Section 35 direction under the Planning Act 2008. This NSIP designation meant that TfL as scheme promoter must comply with the National Rail and Road Networks National Policy Statement (NNNPS) and must seek the necessary powers to build and operate the crossing by means of a Development Consent Order (DCO) under the Planning Act 2008."

Jan 1, 2016

By Tetsuo Yamazaki

Natural cold seepages are characterized as rapid upward transports of methane from deeper parts of geological structures to the seafloor. Thermogenic and/or biogenic methane generated in deep sediments moves up to seafloor, and major part of methane is consumed in anaerobic oxidation of methane (AOM) and hydrogen sulfide is created in anaerobic sulfate reduction by consortium of microorganisms. Then the hydrogen sulfide is utilized by chemosynthetic communities near the seafloor, such as Acharax, Calyptogena, Bathymodiolus, and the mat-forming bacteria Beggiatoa (Fig. 1). When the supply of methane is large or rapid, remaining methane escapes from seafloor, and it is aerobically oxidized in seawater. A mass balance ecosystem model of chemosynthetic community around natural cold seepages in sediment layer and on seafloor has been created and improved by the authors (Yamazaki et al., 2005; Takeuchi et al., 2007). The model is constructed from 3 main processes as schematically shown in Fig. 2: (1) Methane supply process; (2) Ecosystem process; (3) Water column process. The part of chemosynthetic communities is in the ecosystem process. A numerical model CANDI (Carbon And Nutrient Diagenesis) was developed by Boudreau (1996) to simulate the biogeochemical processes such as organic matter, oxidant, nutrient, bi-product, and pH diagenesis in aquatic surface sediments. Then, the improved version named C. CANDI was developed (Luff and Wallmann, 2003; Luff et al., 2004). The authors created the same type carbon and nutrient diagenesis process model with calcium carbonate formation like C. CANDI (Yamazaki et al., 2005), and have added the sulfur oxidizing and immobilization processes (Takeuchi et al., 2007). The sulfur oxidizing and immobilization processes are connected with the carbon and nutrient diagenesis process model.

Jan 1, 2008

By D. T. Kirkwood

The practice of impounding mine water and liquid fine waste in underground mines is increasing. Often these underground impoundments are created by constructing seals or bulkheads designed to withstand the expected hydraulic pressures. Occasionally seals are built for another purpose, usually to act as explosion-resistant ventilation barriers. Due to factors such as clogged drain pipes or unexpectedly high inflow rates, these explosion-resistant seals sometimes become subjected to hydraulic pressures. The incidence of seal failures due to inadequate design and/or construction is also on the increase. Fortunately, to date, no lives have been lost by water seal failures, but a clearer understanding of the design and construction considerations specific to water seals is vital to keep this from occurring in the future. This paper presents technical considerations for the design and construction of seals which will specifically be required to withstand hydraulic pressures in underground mines.

Jan 1, 1995

By Ehsan Moosavi, Kamyar Tolouei

In open-pit mines, the long-term production scheduling optimization problem (LTPSOP) is a complicated problem that contains constraints, large datasets and uncertainties. Due to its dimensions and NP-hard nature, it is usually difficult to find an ideal solution to the LTPSOP. The optimal schedule generally restricts the ore, metal and waste tonnages, average grades, and cash flows of each period. In this paper, to synthesize grade uncertainty into the strategic schedule, a stochastic integer programming (SIP) framework is presented to LTPSOP. The objective function of the SIP model is to maximize the net present value and minimize the risk of deviation from the production targets considering grade uncertainty simultaneously while satisfying all technical constraints and operational requirements. Instead of applying one estimated orebody model as input to optimize the production schedule, a set of equally probable orebody realizations is applied to synthesize grade uncertainty in the strategic schedule and produce a more profitable and riskbased production schedule. To solve the LTPSOP, the hybrid approach with the augmented Lagrangian relaxation method, the Harris Hawks optimization, the Random Forest method and Monte Carlo method was proposed. To indicate the applicability of the model, a case study on a gold mine was implemented. The framework displays the capability to minimize risk and improvement in the expected net present value and financial profitability .

Jun 25, 2023

By P. Sander, M. Spiegl, J. Reilly, A. Van Droogenbroeck

Although the outdated idea of calculating risk as the deterministic product of its likelihood and impact is not entirely a thing of the past, a multitude of organizations have adopted the usage of probabilistic methods for risk analysis, as they better reflect the inherent uncertainty of cost and risk estimates with ranges. But are these advancements sufficient in a complex environment such as tunnelling projects, where inadequate modelling of cost and risk can result in estimate discrepancies that run into millions of dollars? This paper explores two advanced probabilistic modelling techniques for tunnelling projects. The first one demonstrates how the cost and schedule uncertainty related to changes in excavation and support classes can be modelled with correlated variables. The second example models the risk related to explosive ordnance clearance on construction sites using a probabilistic event tree.

Dec 1, 2022

By C. W. Nelson, A. G. Moody

This paper describes the design, equipment selection and onshore fabrication of the largest facilities module ever installed in a single lift in the Gulf of Mexico. Measuring 35.5 x 70.1 x 21.3 m (110 x 230 x 70 ft), the three operating level structure houses Frasch process sulfur mining equipment and weighed nearly 49 million N (5500 tons) during lift. An operating weight of over 74 million N (8300 st) combines with bridge reactions acting on the in-place module and results in a total operating vertical load on the supporting platform deck of about 107 million N (12,000 tons). A Vierendeel truss structural system was selected for framing the module to allow maximum equipment access and routing flexibility for complex, insulated large diameter process piping. Research and finite element analysis of crimp plate siding behavior in shear was carried out during selection of siding type for the module. An interactive design sequence was carried out that incorporated in-place operational criteria, onshore fabrication considerations, complex process equipment requirements, plus load-out, ocean transport and offshore lift analyses. Project schedule dictated that design, procurement and fabrication be fast-tracked with parallel activities accelerated to the maximum extent possible. Design and construction of this largest and most complex module was done concurrently with 52 other components of the project including jackets, decks, process and living quarters modules as well as two 122 x 22 m (400 x 72 ft) sulfur tankers. Total tonnage of steel structures for the project exceeded 90.7 kt (100,000 st). The 5 kt (5500 st) mining module proved the viability and costeffectiveness of larger modules than commonly used in Gulf of Mexico waters. This technical advance can be matched with economic opportunity for other large-scale offshore installations.

Jan 1, 1994

By B. M. Ghadiali, J. B. Putnam, T. P. Smirnoff, M. A. Elioff, P. F. Ryan

Geotechnical investigations for the Mid-City Extension of the Los Angeles Metro revealed high concentrations of toxic hydrogen sulfide (H2S) gas as well as methane. Testing techniques employed to determine the extent of gasses, and to identify potential treatment measures, included gas sampling with cone penetrometers and soil-gas extraction with air injection testing. A gas reservoir model was developed to predict inflows into excavations. Other studies included a hazard evaluation and a general data search for other H2S occurrences and geologic conditions that could facilitate the accumulation of H2S. The paper describes the investigations and proposed design and construction alternatives.

Jan 1, 1995

By L. K. Lepley

A marine sonic sub-bottom profiling system and a hovercraft were used in an engineering geophysics survey of the tailings being deposited at the Mercur gold mine. Detailed density sections with vertical resolution of one meter were desired for computations of strength, permeability and potential self-compaction. The logistical problems of conducting a geophysical survey and in collection of geotechnical soil samples from an active tailing impoundment was solved by using the amphibious hovercraft for towing and transport on the impoundment. The "chirp" sonic system produced continuous, real-time geophysical cross-sections with vertical resolution of ten centimeters showing possible trapped gas. The hovercraft provided a platform over water, ice, slurry, and solid beach for collection of geotechnical information and physical samples.

Jan 1, 1994

By Michael Jatczak, Joseph A. Sopko

Ground Freezing was used for excavation support and groundwater control of a 12.8m (42-foot) diameter, 61m (200-foot) deep drop shaft for the South Bay Ocean Outfall Tunnel in San Diego, California. Approximately half way through the excavation, excessive groundwater inflows from the base of the shaft resulted in suspension of excavation and evaluation of the frozen earth wall. This paper discusses the forensic methods used to identify the zone where groundwater intrusion occurred and the methods associated with evaluating zones of high groundwater velocity. The use of remedial grouting and localized liquid nitrogen injection are discussed and evaluated. Concepts of frozen shaft design are discussed, including a new method for permitting the launch of the Tunnel Boring Machine through the frozen earth wall and associated freeze pipes.

Jan 1, 1999

By Hans Ehdwall, Erling Strandon, Friedrich Steinhäusler, Victor A. Leach

INTRODUCTION The basis for any measures in radiation protection is the quantitative assessment of the radiation exposure. Due to the extensive requirement in health physics manpower and related cost it is necessary to develop certain criteria regarding the necessity of monitoring and the selection of population groups to be monitored. Depending on the overall objective of the particular programme, the specific requirements for the measurement of atmospheric levels of radon, thoron and their daughters for practical radiation protection purposes differ significantly for those in the case of research applications, such as use of data for epidemiological studies. As part of the OECD-NEA Programme on Radon Dosimetry and Monitoring Task Group 1 reviewed available models for lung dosimetry in the case of inhalation of radon 222, radon 220 and their daughters (James et al., 1981). Using defined reference atmospheres for underground- and open-pit mining conditions as well as for dwellings, normalized conversion factors were calculated for the mean bronchial dose (mGy) per Working Level Month exposure (WLM). Task Group 2 discussed the features and adequacy of the Working Level (WL)-concept as a physical correlative of the absorbed lung dose and its limits of confidence and accuracy (Johnson and Leach, 1981). The WL-concept was found acceptable for radiation protection purposes provided that modifying factors like particle size, unattached fraction and respiratory minute volume did not cause the effective dose equivalent per WLM as calculated by either the James-Birchall or Jacobi-Eisfeld lung models to be more than 50 % above that given by ICRP of 0.01 Sv/WLM. For application in epidemiological studies the WLconcept is considered acceptable if the calculated absorbed dose to the tissue does not vary by more than 50 % (at the 95 % confidence level) from that given for defined reference conditions. In the following, objectives and requirements for the measurement of radon, thoron and their daughters are discussed for operational health physics routine and special research applications according to the scheme outlined in Fig. 1.

Jan 1, 1981

By H. Saito

To Japan, which is scarce in natural resources, limestone is the only mineral resource comparatively rich in ore reserves and having broadly recognized outstanding quality. Distribution of the limestone deposits extends from Hokkaido in the north to Kyushu and Okinawa in the south, and the deposits are located in a manner of framework formation of the Islands of Japan. Studies of the geological ages of these ore deposits reveals that almost all of the main ore deposits west of Kanto Area belong to the Carboniferous Period - Permian Period of the Paleozoic Era. Also in the east of Kanto Area, deposits belonging to the Paleozoic Era constitute the main part, although recently there are increasing examples of reclassifying the geological age of the deposits heretofore considered as Paleozoic Era to the Triassic Period of the Mesozoic Era by the recent discoveries of the fossils of conodont, etc. Large ore deposits and main ore deposit groups are given in the Figure 1, which shows that the deposits are roughly found well distributed throughout the country.

Jan 1, 1982

By C. M. Liu

"The Freeport-McMoRan Sierrita Crystal Plant produces Copper (II) Sulfate Pentahydrate (CuSO4·5H2O) through a series of cooling crystallizers. In this process, high supersaturation and unwanted spontaneous nucleation promote fine crystals. Seeding through recycled crystal classification can manipulate the crystal size distribution (CSD) for larger crystals. Proper selection of the crystallizer for seeding can prevent spontaneous nucleation and promote final crystal size. This study shows when seeding temperature is closer to the crystallizer temperature, suspension densities in the crystallizers are promoted and overall CSD shifts to a larger size of crystals. INTRODUCTION Figure 1 shows an overview of the crystallization process. The in-plant feed flow, called Pregnant Mother Liquor (PML), enters the first crystallizer and is subsequently cooled through a series of four crystallizers. Specific temperatures are targeted for each crystallizer to ensure the crystallization process is operating within the metastable zone (MSZ). The discharged flow from crystallizer #5 then enters two cyclones. The overflow from the cyclones contains smaller crystals providing seed crystals for crystallizer #5. The underflow from the cyclones begins the drying process. The overflow from crystallizer #5 enters cyclone #3 for removal of fine crystals and seeding purposes. The underflow from cyclone #3 has the capability to provide seed crystals for crystallizer #1 or crystallizer #2. The overflow leaves the system as Spent Mother Liquor (SML). Undersize crystals dissolve into the PML and return back to crystallizer #1.THEORIES AND METALLURGICAL TESTS Seeding requires an understanding of the crystal size, solution temperature and amount of crystals that enter the crystallizers (1). For the seed crystal size, classified crystal seeds can prevent fine crystals returning back into the system which eventually leads to excessive agglomeration (2). Proper selection of the crystallizer can ensure seeding at an appropriate temperature. Seeding at a temperature much lower or higher than the saturation temperature promotes spontaneous nucleation. Typically, seeding between 4-5°F below the saturation temperature is acceptable (5). A general rule of thumb is to add the seed crystals at the temperature between the solubility curve and the metastable zone. An experiment conducted by Mettler-Toledo AutoChem, Inc. indicates seeding close to the solubility curve rather than the metastable zone promotes a lower supersaturation and nucleation rate but yields a higher growth rate and a greater number of larger crystals (1). The amount of seed crystals can not only change the suspension density but also narrows the width of the MSZ in the crystallizers. An experiment conducted by Jaroslav Nyvlt reports with the crystals absent, the maximum allowable undercooling is 6.3 degrees at a cooling rate, 5°C/hour. With the presence of crystals, it narrows the MSZ width to 2.2 degrees (4). Industrial crystallizers normally operate at suspension densities between 15% and 25% by mass. When suspension densities are lower than 15%, it increases the risk of primary nucleation and the probability of incrustations; on the other hand, if the suspension densities are greater than 25%, it can cause a greater attrition rate and increase the probability of deposits (6). Moreover, operating suspension densities between 15% and 25% are also sufficient to minimize supersaturation rate which promotes crystal growth over nucleation (2, 6)."

Jan 1, 2015

By Ken Wangerud

The benefits of historic mining to this country have been many, but have come at a cost to the environment that has only begun to be understood over the past twenty years. While estimates vary, it is generally recognized that there are over 200,000 inactive and abandoned hardrock mines, with most of them located in the western U.S. Only a fraction of them are believed to be sources of metal releases with significant adverse environmental effects to the watersheds and receiving streams. State water-quality and natural resource management agencies have noted that hundreds of miles of streams are metal-impacted, and the aggregate effects of these sites within watersheds and drainage basins is poorly understood. Resources for the environmental assessment of abandoned mine land (AML) sites and watersheds have been and continue to be limited. Few hardrock mining states receive substantial reclamation funds under the (coal) Surface Mining Control and Reclamation Act. EPA Region VIII (EPA8) has an estimated 90,000 abandoned mining, milling and smelter sites, mainly in Colorado, Montana, South Dakota, Utah and Wyoming. An estimated 13,000 of the sites may have metal releases causing Clean Water Act and CERCLA non-compliance. Results of inventories by states and federal land managing agencies, indicate it is plausible that only 3,000-4,000 of these sites may be causing significant environmental degradation.

Jan 1, 1999

By Shailesh K. Patel, Shaaban Ben-Poorat

In order to ascertain the environmental fate of flotation reagents (fatty acids, fuel oils, and amines) associated with phosphate rock processing with confidence, it was necessary to first establish laboratory methodologies to identify and quantify flotation reagents. This approach was necessitated by the fact that the reagents used in the flotation process are either reclaimed or by-products of other industries and is dictated by their cost. Initially, several blind performance evaluation samples were prepared by spiking water samples with known amounts of either single reagents or reagent mixes and then analyzed. Reagent recovery for the blind performance evaluation samples was within acceptable limits for similar compounds established by the US Environmental Protection Agency. Averification process involving the use of standards and the refinement of analytical methods was utilized to develop standard operat- ing procedures (SOPS) and method detection limits (MDLs) specific to the identification and quantification of the flotation reagents used in the phosphate industry. These procedures and MDLs were critical to support the project&apos;s primary goal of assessing the fate of selected flotation reagents in the environment.

Jan 1, 1999

By J. M. W. Mackenzie

Three major developments have dominated the recovery of gold from ores, viz; 1846 Elsner's studies of gold solubility in aerated alkaline cyanide solutions 1887 MacArthur and Forrest's process based on zinc precipitation 1980+ Large scale development of the CIP process The brevity of this list for a metal whose extractive metallurgy has been as widely studied as any metal reflects the fact that the chemistry of the gold recovery process, as opposed to the engineering has seen few significant breakthroughs in over a century of application. to The purpose of this paper is introduce a new chemistry for gold recovery which may, in the future, add significantly to the technology of gold recovery. This new chemistry is based guanidine functionality - (R2R2N) 2 C = N R2 on the In developing the use of the guanidine functionality for the recovery of gold as the aurocyanide anion from leach solutions and pulps, Henkel has, as its objective, the development of an effective gold selective ion exchange resin. As will be seen, the initial investigation of the properties of the guanidine functionality in the solvent form for gold recovery lead to some significant metallurgical developments of their own but, the foremost objective was, and remains, the development of a resin for gold recovery. As a part of this development project, Henkel has entered into association with Mintek, South Africa, and this ongoing association has the potential to develop RIP/RIS technology for the gold industry. More details on Henkel's gold recovery technology and Mintek's role in this programme are given in (1). an The application of ion exchange resins to gold recovery is not new and many reviews have been published on the advantages of this process, and on the current state of the art of gold recovery by ion exchange resins. (2)(3)(4) Widespread application of ion exchange resin based processes for gold recovery has, however, not occurred to date. Fleming and Cromberge (5), described some significant pilot plant RIP trials in South Africa and the partial success of these pilot plant trials held out the tantalising possibility of a breakthrough in gold recovery based on RIP technology. Despite this pioneering work, only two really significant applications of RIP technology for gold recovery exist today. These are the Golden Jubilee Plant in the Eastern Transvaal South Africa and the widespread, although in some respects technically backward, use of ion exchange for gold recovery in the former USSR. There are two main reasons for the current scarcity of RIP and RIS plants used for gold recovery. These are: 1. 2. The perceived problems of engineering RIP plants The lack of a resin having suitable chemistry for both gold loading and gold elution The problems of engineering RIP plants have been largely overcome in the last 25 years. Much of the development in RIP plant design took place in the uranium industry during the rapid expansion of that industry in the mid 1970's. In addition, the development of CIP engineering systems has lead to the development of in-pulp solid extractant based metallurgical plant designs which can, with limited modification, be adopted to RIP. The lack of a resin having suitable chemical properties has almost certainly been the main reason for RIP/RIS not being introduced into the gold industry over the past decade. Attempts to use RIP/RIS have focussed on either conventional we ak base or conventional strong base resins. The weak. base resins have the disadvantage that they

Jan 1, 1993