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By M. M. Wong

A brief investigation was made to determine the feasibility of electro-refining beryllium in a KCI-LiCI-BeC12 bath. Thin, platelike crystals of beryllium metal were produced by electrolyzing technical-grade beryllium metal beads (about 94-percent purity) as the soluble anode. Operating cell conditions were: Temperatures of 450° to 600° C.; an inert atmosphere; bath compositions of (1) 38.1 mol. percent KC1, 54.8 mol. percent LiCl, and 7.1 mol. percent BeC12 and (2) 36.7 mol. percent KC1, 52.7 mol. percent LiCl, and 10.6 mol. percent BeC12; cell voltages of 0.30 to 0.80; and initial cathode current densities of 50 to 435 a./sq, ft. Current efficiencies ranging from 87 to 96 percent were obtained. Qualitative spectrographic analyses of the metal products indicated that impurities were reduced. This technique offers the possibility of producing a grade of beryllium purer than that now generally available, which may have better mechanical properties.

Jan 1, 1960

By W. K. Kleysteuber

This report covers the design and testing of a novel bulk materials conveying device by the Bureau of Mines. The transport concept of the device is to create a traveling wave with a steep front so that the bulk material slides and cascades down the front of the wave with some horizontal motion. Ideally, the front should act like a continuous chute. The concept of moving bulk materials along a belt without any forward movement of the belt itself was demonstrated. The conclusions reached were that the mechanism as designed could not overcome the inherent major disadvantages that would make the undulatory conveyor suitable for practical applications.

Jan 1, 1974

By R. V. Ramani, R. L. Grayson, R. L. Frantz, V. A. Marple, W. R. Myers, K. L. Rubow, Mutmansky. J. M., T. J. Stobbe

"An investigation of protocols for research performed from 1953 to 1988 on pneumoconioses (with emphasis on diseases related to coal and silica) was conducted in the Generic Mineral Technology Center for Respirable Dust. In addition, interviews were conducted with prominent U.S. medical researchers, aerosol scientists and engineers in government, industry, and universities to determine dust sources, dust preparation methods, laboratory protocols, and determinant variables related to in vitro and in vivo research and assess the comparability of results.Since the original report on the protocol project, additional research regarding free radical existence in freshly produced dust particles and the shape and contamination of particles generated for research purposes has further heightened scientists' concerns. As indicated by current research, fresher dust particles and those with more angular shapes may have a different level of reactivity in biological systems than do older or more rounded particles. Therefore, research on dust preparation methods for biomedical studies was undertaken and will be outlined here.Results of protocol review and interviews are summarized. Research on size reduction methods and their particle characteristics plus some recommendations concerning dust preparation methods and reporting in biomedical publications are also presented. Recent evidence indicates that these recommendations may be of importance in comparing and interpreting research results."

Nov 1, 1995

By Edward L. Burwell

The Bureau of Mines conducted laboratory experiments to determine the change during retorting in the apparent permeability and the degree of compaction of beds of broken oil shale. Grades of oil shale studied ranged from 20.6 to 46.7 gallons of oil per ton (gpt), and the simulated overburden pressures applied to the shale were from 300 to 900 psi. Linear regression analysis of the data produced equations describing the response of the oil shale. Oil shales of approximately 20 gpt experience only minor apparent permeability reductions under test conditions, but richer shales (30 to 50 gpt) lose essentially all permeability. The permeability reductions were accompanied by corresponding decreases in bed height that ranged up to 37 percent of the original bed height.

Jan 1, 1974

By Cloyd M. Smith

Progressive mine management is placing increased emphasis on improved ventilation as a contribution to better safety , health , and productivity of miners . Management is on the alert for means of bettering the working environment by increasing the flow of air and distributing it more effectively to the working places , having in mind the necessity of avoiding exorbitant ventilation costs . A basic need in planning betterments of this kind is knowledge of existing rates of flow and air pressures , infCoorrmmaattiicon that is supplied through ventilation surveys . Some companies make partial surveys from time to time , but few make complete surveys on a routine basis . This report describes the practice of a large British anthracite -mining company , which operates 24 collieries in South Wales , in carrying out a routine program of ventilation surveying . Ventilation characteristics and climatic conditions in the working places of its collieries are determined at frequent intervals with a view to increasing the effectiveness of ventilation and protecting the health of workers . It is thought that many of the points of the procedure used in making the surveys and in compiling and reporting the results will be applicable to American practice and that a discussion of the program may be helpful to colliery managers who are planning similar work .

Oct 1, 1949

By N. F. LeJeune, Earl C. Lane

This is the third of a series of reports on a survey of petroleum prod- ucts manufactured on the Pacific Coast from California crude oils. California crudes differ in many characteristics from the petroleum produced in the other parts of the United States, and the claim has been made that some of the present Federal Specifications for petroleum products tend to discriminate against Cali- fomia products. The purposes of the present survey are to determine what par- ticular specification requirements Califomia petroleum products characteristical ly fail to meet, how widely the products deviate from these requirements, and if possible to show whether the fault lies with the specifications or the products, or along what lines investigation to determine this question should proceed. The first report of the series gave the physical and chemical properties of the samples of gasoline and mineral spirits. A second report**, gave the physical and chemical properties of samples of lubricating oils. The present report deals entirely with burning and fuel oils. The refin ing companies have continued their very cordial and helpful cooperation. Seven samples of kerosene, four samples of Diesel fuel and eight samples of fuel oil were obtained. The methods of analysis used are those adopted by the Interdepartmental Petroleum Specifications Committee, published by the Bureau of Mines in Technical Paper No. 323. The specifications used for corparison are those officially adopted by the Federal Specifications Board for the use of the various Depart- ments and Independent Establishments of the Government, effective February 3, 1923, and published by the Bureau of Mines in Technical Paper No. 323, Part 1. Specific gravity, degrees A.P.I., viscosity and other special tests al- though not required by the specifications have been given for comparison. All temperatures are recorded in degrees Fahrenheit. Tables have been prepared giving data on physical and chemical propertios of the individual samples. Before each table the classification and specifica- tions for the particular class of oil considered in the table are given. Follow- ing each table, brief notes show wherein samples deviate from specification re- quirements.

Aug 1, 1923

By R. Karl Zipf, Z. T. Bieniawski

"A set of fracture profile photomicrographs is presented for fractures generated under mixed mode loading of the Pittsburgh coal. The fractal dimension is used· to characterize the irregularity of these profiles and a tentative relationship is presented between the fractal dimension and the fracture toughness. Surface roughness appears to depend solely on the stress intensity and no other dependence was observed with fracture loading mode, loading rate· or specimen orientation. Observations of crack bifurcations.in fracture profiles can indicate crack growth direction whereas direct surface observations generally cannot in materials such as rock and coal.1 INTRODUCTIONThe production of fine fragments of material as a result of some loading event occurs in many industrial processes. In crushing and grinding, the efficient production of fine fragments is the desired end result; .however, in coal cutting, the production of fine fragments may lead to high levels of respirable dust in the immediate atmosphere with the danger of human lung diseases. Two of the most important sources of fragments in the 1 to 10 micron size range during a cutting process are 1) severe crushing in a zone near the loading tool and 2) subsequent shearing along major crack surfaces that form the larger fragments during material reduction. These and other sources of fine fragments generation are discussed by Roepke (1984) and Zipf and Bieniawski (1986). The physical character of the nearly created major crack surfaces is believed to have a strong influence on the amount of fine fragment generation that occurs during subsequent shearing movement. When the major large fragments initially form, they are ""locked"" in place by the irregular character of the new fracture surface. Only after some relative motion has occurred between fragments are they actually liberated, and the net result is the formation of additional fine fragments. The fine fragmentation is not necessarily limited to the shearing of high points from the macrocrack surf ace since material remaining in the wake of the crack tip is damaged to a substantial depth below the actual crack surface."

Aug 31, 1989

By Vernon C. Davis

"INTRODUCTION This report describes the work done and presents the data obtained from limited diamond drilling at the lead-zinc deposits cf the Belle Eldridge Gold Mines, Inc., in Lawrence County, S. Dak. during the summer and fall of 1943. The work was undertaken in an effort to increase reserves and step-up production of zinc and lead so vitally important to the war program.The geology, topography and existing mine workings were mapped and studied. Subsequently, six vertical core-drill holes were put down from surface sites.ACKNOWLEDGMENTSIn its program of investigation of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our natural resources to the end that they make the greatest possible contribution to national security and economy. The Mining Division, Lowell B. Moon, chief, conducts preliminary examinations, does the actual investigative work, and prepares the final report. The Metallurgical Division, Oliver C. Ralston, chief, analyzes samples and makes beneficiation tests, if such are necessary.Special acknowledgment is made to John Paul Gries, geologist, South Dakota School of Mines, for mapping and interpretation of geology and topography, logging of cores obtained, and his assistance in guiding the drilling."

Mar 1, 1948

By Charles Prasky

This report describes fluidized bed techniques employed by the Bureau of Mines at Minneapolis to differentially sulfatize the manganese in two samples of low-grade manganiferous ferruginous carbonate slates from the Cuyuna Range district, Minn. Suitable mechanics of operation were established. A space rate of 1.25 to 1.5 fps, a retention time of 3 to 3.5 hours, a temperature of 700° C, and a 10 percent sulfur dioxide gas in air were adequate for sulfatizing the slates by fluidization. Under these conditions the overflow product removal rate from the 4-inch-diameter reactor was 4 to 5 pounds per hour. The sulfur dioxide was used more efficiently in the two-stage treatment than in the single-stage treatment. However, approximately 80 percent of the manganese was converted to sulfate by either treatment.

Jan 1, 1963

By M. E. Tyrrell

Mixtures of zirconium diboride and iron, cobalt, and nickel were resistance sintered to high-density compacts using modified electric welding equipment. To evaluate the use of iron, cobalt, or nickel as binders for zirconium diboride, the sintered compacts were examined in polished section and tested for crushing strength, hardness, microhardness, oxidation rate, and resistance to mechanical shock. Each of the zirconium diboride-metal mixtures produced brittle cermets, but the hardness was generally satisfactory. The iron- and cobalt-bonded cermets exhibited rather poor oxidation resistance. Cobalt provided the least brittle bond, and nickel, the hardest and most resistant to oxidation. Iron tended to form chalky compacts with low resistance to mechanical shock.

Jan 1, 1963

By L. J. Froisland

The U.S. Bureau of Reclamation requested U.S. Bureau of Mines (USBM) assistance in developing design data for moving lead-zinc-gold tailings from their current location without disrupting the existing chemically stable conditions. This report presents results of USBM work in determining (1) the minimum required time to air dry the tailings to approximately 20 pet moisture under various drying conditions both in the laboratory and in the field, (2) the degree of oxidation or reduction that occurs during drying, (3) the effect of lime or cement addition before drying, and (4) the likely equilibrium conditions of the dried tailings after deposition at the new location. The limited number of tests performed by the USBM in the available time frame established trends in oxidation levels but did not provide absolute statistical validity of data values. All data from drying and oxidation testing are included in appendices to this report.

Jan 1, 2010

The question of earth models has repeatedly arisen in our work. An accurate representation of the seismic properties is required for three reasons: 1.To be able to determine from a set of received arrival times, the location of a seismic source in the earth, and secondly the degree of accuracy required in the model used for calculating source location from the set of arrival time differences. 2. To be able to determine the expected arrival times at an array of geophones produced in response to a hypothetical source in the earth. 3. To be able to estimate received signal strengths more accurately. The work reported here on earth models is based on information from sever- al consultants and from others who expressed an interest in the problem and supplied information to us. II. COAL MINE GEOLOGY On one of our earlier assignments for the Bureau of Mines, Earth Science Research Inc. of Cambridge, Massachusetts prepared for us a short description of the lithology to be expected at coal mine sites. This description follows, together with the ranges of compressional seismic velocities (Figure I*) associated with typical materials comprising the layered structure of a coal mine area. Coal is primarily associated with fresh water sediments including sandstones, shales, and clays, and occasionally may be metamorphased to varying degrees. In the Appalachian Basin the coal beds occur within cyclical sequences of non-marine shales, sands tones, conglomerates, limes tones, and clays. The beds range in thickness from a few inches to 60 feet, averaging between 2 feet and 10 feet. They have generally broad areal extent, occasionally up to 5,000 square miles, and have an overall tabular or lens-like shape. Within a particular lens, local changes in thickness are normal.

Jan 1, 1974

By R. W. Van Dolah, N. E. Hanna, F. C. Gibson

Measures that were taken to eliminate noise resulting from explosives work at the Bureau of Mines facility at Bruceton , Pa . , are described . A method for monitoring sound transmission characteristics of the atmosphere and control of the explosives testing is presented as a noise control measure that offered partial relief during the period in which the modifications were made . Design details of the replacement gallery , used for permissibility testing of explosives , and the modifications of four types of bombproofs are given . Operation of the closed facilities are completely satisfactory , and the noise problem has been entirely eliminated .

Jan 1, 1964

By D. K. Deardorff, Laurance L. Oden, H. Kato, M. I. Copeland

The equilibrium relationship of hafnium and tantalum was studied to facilitate alloy and property investigations . The data obtained are presented graphically as the equilibrium diagram . Alloys were prepared from high - purity components by nonconsumabletungsten- electrode arc melting . Data for the equilibrium diagram were obtained by optical pyrometry , metallography , X- ray diffraction of heat treated specimens , X- ray diffraction using a high- temperature camera , and differential thermal analysis . During the investigations , a casting apparatus was constructed , and the existing melting - point apparatus was improved . The bcc allotrope of hafnium forms a continuous series of solid solutions , called beta , with tantalum which exhibit a minimum melting point at 20 wt pct tantalum and 2,110 ° C. At 24 wt pct tantalum and 1,050 ° C , hafnium- rich beta decomposes in a monotectoid reaction to yield alpha and tantalum- rich beta . The monotectoid isotherm extends from 5.5 to 60 wt pct tantalum . The twophase region , in which hafnium- rich and tantalum- rich beta solid solutions are immiscible , rises to a maximum temperature of 1,265 ° C at 38 wt pct tantalum . The solubility of hafnium in tantalum decreases from 40 wt pct at the monotectoid temperature to 20 wt pct at 750 ° C.

Jan 1, 1964

By Florence L. Feicht, H. H. Schrenk, Carlton E. Brown

This report describes the dropping - mercury electrode , its use in analysis , and the procedure of the Health Division of the Bureau of Mines in determining lead , cadmium , and zinc . The dropping - mercury electrode or polarograph is an electrolytic device , one electrode of which consists of mercury issuing in small drops from a capillary tube . Such electrodes have been in existence for more than 50 years, but they were not used for analytical purposes until about 1922.6/ Developments since have been rapid , especially in Czechoslovakia , Germany , Italy, and Japan and more recently in the United States . A recent bibliography / contains references to, 825 articles issued from 1903 through 1940. In 1939 Kolthoff and Lingane presented the first comprehensive critical review, in English , of the device and its use in analysis . They have recently issued a book on the same subject. Similar information also is included in a recent book10/ by Kolthoff and Laitinen . Much of the information in this and the two following sections on this device and its use in analysis was obtained from these three publications . The use of the dropping - mercury electrode in analysis is based upon the fact that the kind and amount of electro - reducible and electro - oxidizable constituents in solution can be determined from the current -voltage relationships revealed by this electrode or electrolytic device .

May 1, 1942

By Karl-Heinz Frohne

This report presents the findings of a study of a portion of the Clover-Rush Run oilfield located in Roane County, W. Va. The study was made to investigate the possibilities of secondary oil recovery in the Big Injun sandstone underlying the William Kaufman lease. Reservoir properties, original reserves, and primary oil recovery are also presented. The investigation is based on a core analysis and related laboratory tests, well records, field production data, and subsurface information from the Kaufman property. A theoretical primary oil recovery of 9.7 percent of original oil in place is predicted for the reservoir. A waterflood performance prediction of a hypothetical pilot area was made by use of a computer. The prediction showed that, based on laboratory oil water relative permeability curves, the water-injection time needed to initiate oil production is excessive and that the stabilized water-injection and corresponding oil-production rates are very low. This precludes waterflooding the reservoir on an economic basis. A prediction for secondary oil recovery by gas injection was attempted but could not be completed because essential reservoir data were not available. In July 1965, the lease operator initiated, and is currently conducting, a gas-injection program, but there had been no increase in oil production up to November 1966.

Jan 1, 1967

By Seth C. Scharfer

"As part of the Bureau of Mines effort to provide thermodynamic data for the advancement of mineral technology, the Gibbs energies of formation of MoS2 (molybdenite) and WS2 (tungsten disulfide) were determined with high-temperature galvanic cells employing stabilized Zr02 (zirconia) as the electro¬lyte. In the temperature range from 867 to 1,209 K, potential measurements were obtained for the cellPt, MoS2 , Mo02 , SO2 = 1 atm // Zr02 // 02 = 0.0112 atm, Pt, with the overall cell reactionMoS2(c) + 3 02(g, 0.0112 atm) = Mo02 (c) + 2 S02(g). (1)These results, combined with the best available values for Gibbs energies of formation (?G°f) of Mo02 (molybdenum dioxide) and SO2 (sulfur dioxide) from the literature, give the standard Gibbs energy of formation of MoS2, ?G°f, for the reactionMo(c) + S2(g) = MoS2(c) (2)?G°f = -96.681 + 43.76 x 10-3T±0.538 kcal/mole, (3)where temperature (T) is expressed in Kelvins.Similar measurements in the temperature range from 872 to 1,210 K were obtained for the cellPt, WS2 , W03 , SO2 = 1 atm // Zr02 // 02 = 0.0114 atm, Pt, with the overall cell reactionWS2(c) + 3.5 02(g, 0.0114 atm) = W03 (c)+ 2 S02(g). (4) Combination of these results with the best available data of ?G°f for W03 (tungsten trioxide) and SO2 from the literature gives the Gibbs energy of formation of WS2 in the temperature range from 872 to 1,210 K for the reactionW(c) + S2(g) = WS2 (c)(5)?G°f = -92.429 + 43.88 x 10-3T ± 0.280 kcal/mole. (6)A third-law analysis yields a standard enthalpy (?H°f) for the reaction298Mo(c) + 2 S(rh) = MoS2(c), (7)?H°f = -67.36±0.60 kcal/mole, (8)298where the standard states are pure crystalline MoS2 / and rhombic sulfur."

Jan 1, 1980

By M. S. Oudenhoven

The Bureau of Mines conducted an investigation to determine the theoretical stress distribution in the vicinity of explosively expanded rock bolt anchors independent of their bolts. Plane-strain solutions applicable to this problem were obtained by combining the field pressure with the uniform pressure that would be produced by vertically placed anchors having 2-, 3-, and 4-foot spacings. High rock stress which would be produced by an anchor was localized, as would be expected from St. Venant's effect, and increased as the field pressure decreased.

Jan 1, 1967

By Perry G. Cotter

The borides of the transition metals in Groups IV and VI exhibit, in addition to a certain degree of hardness, considerable resistance to heat and oxidation. They have high melting points (1,850°-3,060° C.) and low coefftcients of thermal expansion and can be bonded with other materials and hot-pressed to desired shape (cermets). Suggested uses for the borides include use in rockets and jet engines, as thermocouple protection tubes, as containers for molten metals in die casting, as flame-plated coatings on less refractory compositions to prevent erosion by hot gases, and as control rods and neutron shielding material in nuclear engineering, The Federal Bureau of Mines investigation of zirconium diboride started in 1950 at the Boulder City Nev,, Metallurgy Research Laboratory, Its purpose was to reduce the cost of raw materials for the production of zirconium diboride.

Jan 1, 1961

By E. Morrice, R. D. Smith

Thermal expansion and electrical resistance measurements were made on cerium metal from 4° to 300° K. The apparatus developed , including a specimen holder and a cryostat system , are described along with the experimental techniques used in obtaining the measurements . The total linear thermal expansion Data at of 99.83 weight - percent cerium metal between 4 ° K and room temperature was 4.24 percent . The resistivity at 4° K was 7.0 x 10-6 ohm- centimeter . 4° K indicate a fundamental relationship between residual resistivity and purity of cerium metal . The effects of annealing and repeated thermal cycling on resistivity were determined .

Jan 1, 1964