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By John P. Hager

This study investigated the formation of vapor complexes between aluminum chloride and the chlorides of iron, titanium, and silicon. For the A1-Fe-C1 system the proposed gaseous complex species is Al2Fe2C112(g), which is formed according to the reaction 2A1C13(s) + 2FeCl3(s) = Al2Fe2C112(g) The corresponding free energy expression was determined to be ?G° = 38091.49 - 71.45 ? T 400 < T < 600°K The vapor composition above AlC13 melts contaminated with FeC13 was calculated. In the Al-Ti-CI and Al-Si-Cl systems the proposed vapor complex species are Al2Ti2Cl14(g) and Al2Si2Cl14(g) respectively. Free energy expressions were estimated for the formation of the two complex species. Again, the vapor composition above AlCl3 melts contaiminated with TiCl4 or SiCl4 was determined. The results of this study were compared with previous studies on the three systems.

Jan 1, 1980

By Frank C. Morris

This report presents the results of a Bureau of Mines study to identify clays found in several petroleum-reservoir rocks in the Tejon-Grapevine area, Kern County, Calif., and to determine the effect of water sensitivity of the clays on the permeability of the reservoir rocks. The clays in the porous rocks were examined in detail, and the clay-mineral types were identified by differential thermal analysis, X-ray diffraction, and optical and dye-staining methods. Fresh-water damage to the permeability of the oil-reservoir rocks was indicated by a study of 125 core samples from productive formations. The study indicated that, although clays were generally less than 5 percent of the reservoir rocks, they swelled in water, particularly fresh water, and nearly blocked the flow channels through which oil flows to the well, effectively reducing the permeability of the formations. The average permeability of rock decreased from 1,600 millidarcys in air to 620 millidarcys in salt water and 120 millidarcys in fresh water. The dominant clays in the oil-bearing sandstones were members of the montmorillonite group. They were associated with smaller quantities of clays found to be in the mica or illite group. None of the cores appeared to contain clays of the kaolinite group. In the lower section of the J.V. sandstone indications of what appeared to be the mineral sepiolite were noted.

Jan 1, 1959

By G. Asai

The purpose of this Bureau of Mines investigation was to determine the properties of arc-melted iron-chromium alloys ranging in chromium content from 12 to 50 wt.-pct. Alloys were prepared by consumable-electrode arc melting of electrodes composed of high-purity chromium and high-purity iron. Alloys were fabricated to rod and sheet, and the following data were obtained: Electrical resistivity, hardness, tensile strength, and impact strength at room temperature; and creep-rupture life at 650° C. (1,200° F.). As the chromium content of the annealed alloys varied from 12 to 50 pct., the properties varied as follows: The electrical resistivity increased proportionally from 41 to 53 microhm-cm,; the Rockwell hardness varied from A 38 to A 58; the tensile strength ranged from 52,000 to 96,000 p.s.i.; the impact strength of V-notched charpy specimens varied from 140 to 405 ft.-lb., and the 100-hour creep rupture life at 1,200° F. varied from 5,000 to 16,000 p.s.i.

Jan 1, 1962

By Charles White Merrill

Silver consumption in the arts and industries of the United States during 1930 and 1931 has remained remarkably near the high level established in 1929. Undoubtedly the sharp drop in the price of silver has been an important factor in supporting consumption, but silver&apos;s peculiar properties and uses probably have been an even more compelling reason for its sustained utilization. In its most important use - sterling silverware - it seemingly has most serious competition, but well established tradition protects the demand for sterling ware and the law forbids the term "sterling" to be applied to any material not containing at least 92.5 per cent silver. The photographic industry is dependent upon properties of certain silver salts possessed by no other material. Consequently silver is indispensable to all photography, including the huge motion picture industry. Other uses for silver could be listed which, because of special features, likewise have tended to maintain the consumption of silver in the arts and industries of the United States. The figures which this report makes available for the first time are the detailed silver consumption figures for the arts and industries of the United States for 1930 and 1931. These figures have been tabulated with the previously published(3) figures for 1928 and 1929 thus presenting a 4-year statistical record of silver consumption. All quantities are given in troy ounces, 1,000 fine.

Jan 1, 1932

By Kenneth M. Earl

In its investigation of deposits of strategic minerals, the Bureau of Mines did some diamond drilling at the Almedia deposit In an endeavor to find an additional source of supply of lead and zinc. It is reported that in 1816, lead and zinc minerals were found in the limestone quarries near the boundary line between Scott and Center townships. In an attempt to develop these minerals in paying quantities, an alit was driven for several rods into a bluff Just west of the present Almedia mine, This is believed to be the Web mine, mentioned briefly by Parker Cleaveland in 1816. In 1901 the Almedia mine was developed by an open cut and three shafts. The hoisting shaft at the time of drilling by the Bureau of Mines was sounded to a depth of 115 feet. A concentrating plant reportedly made shipments to Hamburg, Germany, for reduction. The deposit is in a somewhat slaty limestone. The ore occurs in a northeast fracture zone along the strike of the limestone and dips to the southeast. Old miners state that the ore appeared as large chunks of galena and sphalerite. In 1949, to investigate the downward extension of the oreshoot, the Bureau of Mines drilled four holes aggregating 1,126.3 feet.

Jan 1, 1950

By Foster Fraas

Under a very high vacuum of 10-8 torr the transfer of terrestrial mineral beneficiation methods to the vacuum ambient of extraterrestrial locations such as the lunar surface was investigated. In the size range for the electro-static and magnetic separation of ores (minus 35 plus 150 mesh) there is no adhesion of particles produced by crushing and grinding due to the limited contact area, and for repeated contacts area size has a frequency of occurrence in accordance to the normal law. The photoelectric effect which is successful in separating a few minerals in an air ambient has a wider application in a vacuum, while the lack of air viscosity and sound transmission provides for high feed velocities and the adaptation of particle vibration to dispersion and grinding. Contact electrification is reversible upon return to atmosphere.

Jan 1, 1970

By Jr. Taylor

The following heats of solution have been measured in 1.160 molal H2SO4 at 25° C: AH298, kcal./mole Be(c) + 77.44(H2SO4?47.849 H2O) H2(g) + BeSO4 (soln) -92.83 ± 0.11 BeSO4 ?(c) + 77.44 (H2SO4?47.849 H2O) BeSO4(soln) -16.45 ± 0.02 BeSO4?2H2O(c) + 77.44(H2SO4?47.849 H2O) BeSO4?2H2O(soln) -5.395 ± 0.019 BeSO4?4H2O(c) + 77.44 (H2SO4?47.849 H2O) BeSO4?4H2O(soln) 1.513 ± 0.010 Combining these data with other experimental results and data taken from National Bureau of Standards information yielded the following heats of formation at 298° K:

Jan 1, 1966

By M. B. Shirts

Numerous alternative processes have been proposed as being potentially more economical or less polluting than the traditional smelting of copper sulfide concentrates. One such process as recently developed in the laboratory by the Bureau of Mines is composed of a two-stage fluid-bed, oxidation-reduction roasting followed by ammoniacal leaching, solvent extraction, and electrowinning. A copper-leaching recovery of 97.4 percent was obtained, and electrolysis of the acid strip solution deposited metal assaying 99.99 percent copper. The roaster gases contain over 95 percent of the sulfur at a concentration of 12 percent which is better suited for acid making or elemental sulfur production than conventional smelter gas. When considering byproduct recovery, a preliminary estimate indicates copper production costs are com-parable to the conventional smelters.

Jan 1, 1975

By A. C. Fieldner

"Purpose and Nature of Tests:The rapidly increasing use of motor vehicles and trucks in the United States is creating an entirely new problem in the proper ventilation of tunnels, subways and other confined spaces through which such machines must pass. This problem has become of immediate importance because a tunnel 3,000 ft. long is being designed to pass under the Hudson River between New York City and New Jersey. Another tunnel at Pittsburgh 5,700 ft. long through the South Hills, is already under construction, and a third tunnel, 6,000 ft. between Boston and Past Boston is proposed. It is probably that other tunnels will be started in various parts of the United States in the near future.The ventilation of such tunnels is a serious matter, on account of the poisonous nature of automobile exhaust gases. It not uncommon to read about finding a man dead in his garage. Generally this happens on a cold, winter morning, after he has been running the engine with the doors and windows closed."

Mar 1, 1920

By D. J. Parker

Before the various States began to enact workman&apos;s compensation laws accidents were considered inherent in many industries, and little or no effort was made to prevent or reduce them. The hazard was accepted by the employee with the job, and the avoidance of accidents by mental alertness or physical agility was largely his responsibility. After the employee had given evidence of enough skill inn performing his allotted task efficiently the responsibility of the employer apparently ceased with respect to the personal safety of the employee. However, following the enactment of workmen&apos;s compensation laws, at least two facts that had not before been fully appreciated soon became apparent: (1) The majority of accidents can be prevented if the management firmly determines to prevent them; (2) frog a monetary point of view alone accidents are decidedly expensive, both to employer and to employee. It is now evident that savings effected by conscientious safety effort add substantially to net profits of operation.

Jan 1, 1934

By Frank W. Sansom

This paper is one of a series of articles dealing with milling methods and costs at metal mines in the United States, written in accordance with an outline prepared by engineers of the United States Bureau of Mines and published by the bureau. The Netta mine and concentrator is the largest of the plants of the Eagle-Picher Lead Co, It is located in Ottawa County, in the extreme northeast corner of Oklahoma, and in what is known as the Tri-State zinc and lead mining district, embracing the northeast corner of Oklahoma, the southwest corner of Missouri, and the southeast corner of Kansas. A majority of the production comes from the Oklahoma section, with Kansas second, and Missouri third.

Jan 1, 1930

By G. E. McElroy

When mechanical ventilation is to supersede the natural ventilation of a mine it is desirable to determine what resistance the mine as a whole offers to the flow of air in order to specify properly the limiting duties of a ventilating fan. The relation of pressure to volume of flow for the mine as a whole may be calculated from experimental data, or it may be determined directly by measurements of volume of flow and the natural draft pressures causing flow; but in both methods the determinations are affected by many variables. With the intention of making a practical application of both methods, a small metal mine in process of development at Butte, Mont., was selected by the writers as the object of experiments planned to compare the mine resistances determined by measurements of natural draft and volume of flow with those calculated from experimental data. Four sets of teats were made with natural draft in October, 1925, December, 1925, April, .1926, and September to December, 1926; the last set consisted of a series of weekly observations. DESCRIPTION OF MINE The mine selected for the experiments was a typical vertical shaft metal mine in the development stage. No stoping had been done, and ventilation was confined to shafts, crosscuts, drifts, and raises. Figure 1 is a dia¬grammatic sketch of the main openings. All were timbered with full sets on approximately 5-foot centers. The shaft compartments were 4 by 4.5 feet, and one in each shaft was partly blocked by staggered manway landings. A pump column in the upcast shaft was discharging about 280 gallons a minute of water at 70° F. from the 1,000-foot level. The drifts were slightly sinuous, but the crosscuts were exceptionally straight and uniform in area; both drifts and crosscuts were about 5 by 7 feet in cross section. The raises were composed of vertical sections joined by frequent 450 offsets; each had three 4.5 by 4.5-foot compartments, of which two were plank-lined ore chutes and one was partly

Jan 1, 1928

By Edward L. Tullis

Numerous widely distributed pegmatites of the southern Black Hills of South Dakota contain small amounts of beryl, and two minor deposits are known in the northern Black Hills. Few mines have produced more than 50 tons, and the current, rate of production for the area is about 100 tons annually. Total production, since the first records, is 2,358 tons. Most of the deposits contain less than 1 percent beryl, although the beryl zones in several deposits contain 2 percent beryl or more. Estimated reserves of beryl total 11,824 tons, and an additional 234 tons has been measured; there are other unestimated reserves. The pegmatites are in a belt about the margin of the Harney Peak batholith in the southern Black Hills, although they fail into three districts. The most important, from the point of view of production and reserves, is the Keystone district. Many deposits also are found in the vicinity of Custer and Pringle. Small amounts of beryl occur in the dikes near Hill City. A little beryl has been produced from the Tinton district in the northern Black Hills, and an undeveloped dike has been discovered on Whitewood Peak near Deadwood. The beryl-bearing pegmatites are principally coarse-grained intergrowths or massive segregations of feldspar, quartz, and mica. Some of them contain notable amounts of lithium minerals, as well as some tantalite, columbite, and cassiterite.

Jan 1, 1952

By R. F. Abernethy

Recent investigations in the United States and in other countries have produced considerable information on the nature and occurrence of minor elements in coal. The possibility of recovering certain elements, particularly germanium and uranium, from coal ash and other coal products has received considerable attention. Some flue dusts are potential sources of germanium, and certain lignite deposits are potential sources of uranium, but industrial recovery of these elements has been limited to small quantities for technical and economic reasons. Considering the large amount of coal mined annually, a small percentage of a rare element may have industrial significance if an economical method of recovery can be developed. In 1944 information on the occurrence of rare elements in coal was reviewed in Bureau of Mines Technical Paper 669 (46).3 This report is a revision of that paper with the view of summarizing published information available for United States coals, and pertinent information concerning coals of other countries. Selected references from the original paper are retained. New references do not include all preliminary reports when more permanent literature describing complete projects is available. Consequently, the list of references should not be considered complete.

Jan 1, 1963

By C. Özgen Karacan

Methane emissions from the active face areas and from the fractured formations overlying the mined coalbed can affect safety and productivity in longwall mines. Since ventilation alone may not be sufficient to control the methane levels on a longwall operation, gob vent boreholes (GVB), horizontal and vertical drainage boreholes, and their combinations are drilled and used as supplementary methane control measures in many mines. However, in most cases, the types of degasification wellbores chosen are decided based on previous experiences without analyzing the different factors that may affect this decision. This study describes the development of an expert classification system used as a decision tool. It was built using a multilayer perceptron (MLP) type artificial neural network (ANN) structure. The ANN was trained using different geographical locations, longwall operation parameters, and coalbed characteristics as input and was tested to classify the output into four different selections, which are actual degasification designs that US longwall mines utilize. The ANN network selected no degasification, GVB, horizontal and GVB, and horizontal, vertical and GVB options with high accuracy. The results suggest that the model can be used as a decision tool for degasification system selection using site- and mine-specific conditions. Such a model can also be used as a screening tool to decide which degasification design should be investigated in detail with more complex numerical techniques.

Jan 1, 2009

By J. M. Riley

A fluorometric method using morin in an alkaline-buffered chelating solution has been developed by the Bureau of Mines for determining beryllium in ores and mill products. Apparatus for measuring fluorescence intensities of the beryllium-morin reaction is described. Preparation of the sample for analysis consists essentially of digestion with sulfuric, nitric, and hydrofluoric acids, fusion of the residue with sodium carbonate and sodium borate, Solution of the melt with sulfuric acid, and proper dilution. Chemical separation of other ions is usually unnecessary. The method rave reliable beryllium determinations on samples in the 0.01- to 0.37-percent BeO range. The method is particularly applicable to low-grade beryllium ores; however, semiquantitative beryllium determinations have been made on beryl containing 12.0 percent BeO.

Jan 1, 1956

By Thomas Gales

Longwall mining of thin shallow coal seams utilizing open pits is technically feasible. The thinnest coal seam which can be mined using available technology is 34 inches. The capital expenditure for a 1,000,000 ton per year operation is $15,494,000, and the projected rate of return is 5 percent. Similar statistics for a conventional area surface mine are S18,937,000 capital and 14 percent rate of return. The longwall surface mining method disturbs 63 acres of land per 1,000,000 tons, and the conventional area surface mine disturbs 198 acres A significant bibliography of the technology involved is included.

Jan 1, 1976

By R. T. Stull, G. A. Bole

Previous Work . The Bureau of Mines reported a survey of bond clays for graphite crucibles at the American Mining Congress which met at St. Louis in November , 1919 *** . The report contained information in regard to : (a) tests carried on to determine the effect of substituting Canadian and Alabama graphites for Ceylon graphite in varying proportions . The data indicated that Alabama graphite is superior to Canadian graphite and further , that Alabama can be substituted for Ceylon graphite to a large measure without lowering the quality of the ware . These tests were made on No. 70 size brass melting crucibles and were carried out under foundry practice . (b ) Tests were reported in which an attempt was made to modify the nature of Alabama graphite by heat treatment so as to resemble Ceylon graphite . Little advantage from the treatment was reported . With this general information as a basis , the experimental work proceeded along two lines : A study of bond clays for steel -melting crucibles and for brass -melting crucibles . Twenty- one sets of standard-size crucibles were made up of a body containing Ceylon graphite as standard , bonded with 21 bond clays . These tests were carried out under foundry practice as were the former tests . Three domestic clays proved to be superior to the standard Klingenberg clay formerly used in brass -melting practice while in the steel - melting industry , 13 domestic clays gave service superior to Klingenberg clay .

Aug 1, 1923

By T. T. Campbell

This report traces the development of techniques for the preparation of high-purity rare-earth metals. Rare-earth metals, excepting samarium, europium, and ytterbium, were prepared by converting their oxides to anhydrous chlorides or fluorides and reducing the rare-earth halides with active metals such as lithium or calcium. High-purity, anhydrous rare-earth chlorides were prepared by dissolving the rare-earth oxides in hydrochloric acid to form hydrated chlorides and by subsequently dehydrating the hydrated salts in the presence of ammonium chloride at temperatures ranging from 70° to 360° C. while under reduced pressure (50 microns to 1 inch Hg). The chlorides were also prepared by direct chlorination of rare-earth oxide-carbon mixtures. Reaction efficiencies in excess of 95 percent were obtained by either method; however, purer chlorides were prepared by the aqueous ammonium chloride conversion method. Purification of yttrium chloride by high-temperature vacuum distillation proved to be an effective method of separating, oxygen-bearing compounds from the chloride. Yttrium metal prepared from purified chloride contained significantly smaller amounts of oxygen (990 p.p.m. oxygen in yttrium metal prepared from raw chloride and 200 p.p.m. in that prepared from distilled chloride).

Jan 1, 1961

By P. L. Woolf

Three trials with oxygen-enriched unheated blast air are described. The trials were conducted in the Bureau of Mines experimental blast furnace located in Bruceton, PA. The first trial utilized moisture addition to the oxygenated blast. The second and third trial were conducted with natural gas injection. The test was basically a feasibility study and in that regard the practice was demonstrated to be feasible and also have possible advantages over hot blast operation. The testwork was conducted in 1964 and 1965 as part of a continuing study of iron making technology in cooperation with several North American Steel Companies.

Jan 1, 1985