Search Documents

By E. J. Gleim

This report describes a trip to Europe in the interest of safety in coal mines. It reviews the Eighth International Conference of Directors of Safety in Mines Re-search, which met in Dortmund-Derne, Germany, July 5-10, 1954, to discuss results of studies made in different countries to improve health and safety conditions under-ground. It also summarizes information on subjects of special interest in the United States gained by the writer in visits to mining experiment stations in Belgium, France, and England. The efforts being made to protect life and property underground were discussed, and ideas and experiences were interchanged freely, not only during the conference but also during visits to the several countries. Helpful information was obtained on many topics of interest, but time did not permit as thorough a discussion on some of them as might be desired.

Jan 1, 1956

By E. G. King

This publication presents original thermal data for a typical variety of perlite and supplies basic information for use in computing energy requirements in processes for expanding perlite. Perlite has been defined by Raiston 4/ as any silicious lava containing dissolved water in sufficient amount to errand into bubbles when the material is quickly heated to a suitable point in the softening range." The uses of expanded perlite in) the construction and ceramic industries have been discussed by Ralston 4/ and King. 5/ The work described here had a dual purpose: (1) It was desired to ascertain quantitatively, using a typical variety of perlite, just how firmly the contained water is held, and (2) it was desired to obtain basic thermal data sufficient for energy-requirement calculations in processes for expanding perlite.

Jan 1, 1948

By R. L. Levens

The Underground Injection Control program was promulgated in 1981 by the U.S. Environmental Protection Agency under the provisions of the Safe Drinking Water Act. Placement of mine waste backfill underground is considered underground injection under the provisions of this program. A major issue is whether mine waste that is regulated as a contaminant source on the surface should be disposed of underground. The U.S. Bureau of Mines conducted research to investigate the impacts of mine waste sandfill on the quality of ground water. Analyses of water samples collected before and after contact with sandfill in a 10-year-old stope, as well as samples of the sandfill itself, were used to ascertain the influence of the sandfill after mine closure and subsequent flooding. Computer models supported the hypothesis that oxidation of pyrite by oxygen, accompanied by dissolution of carbonates, was the predominant reaction controlling the quality of the water being discharged from the stope. Concentrations of metals released as a result of acid production remained near or below detection limits. Metals release after mine flooding is expected to remain low as a result of the buffering by the sandfill and the reduced rate of oxidation.

Jan 1, 2010

By E. E. Maust

The literature on the activation of sphalerite for flotation by short¬chain xanthates leaves unanswered the question of whether a compact surface film of activator sulfide is necessary or merely sufficient for high flotation recoveries. Studies by Guarnaschelli and Plaksin indicate that xanthate adsorption and flotation of sphalerite are increased with increasing hole/ electron ratio. These results, and the known acceptorlike behavior of many heavy-metal impurities in zinc sulfide, suggest that activation may result from a traditional semiconductor doping effect at the surface. Using the theory of chemisorption states on ionic crystals as developed by Levine and Mark, the Bureau of Mines has carried out A calculation to estimate the surface-state energies of various metals when they are substituted at zinc sites on (110) sphalerite surfaces. Based on a simple Madelung-Born treatment of ionic solids, the calculation indicates that many of the metals known to activate sphalerite for subsequent flotation have lower surface-state energies than nonactivators. The results of these calculations are discussed from the standpoint of consistency with the proposed activation mechanism and observed flotation results. The satisfactory agreement obtained is taken to be support for the proposed mechanism, and further elaboration of a surface-doping model is attempted.

Jan 1, 1976

By L. C. George

The Bureau of Mines measured vapor pressures of selected mixtures in the binary system SnCla-ZnC12 by the static pressure method. Equations expressing the vapor pressure) and the heat and free energy of vaporization) as functions of temperature were developed by numerical analysis based on the sigma-plot method. It was found that the vapor pressure of any SnCl2-ZnCl2 mixture) at any temperature within the range of this investigation) could be accurately calculated from the derived values for the heat and free energy of vaporization for the mixture, with a probable error of 0.01 cm Hg or less.

Jan 1, 1967

By K. R. Dorman

To further investigate the potential of precast concrete sets as a support medium for underground mines, the Bureau of Mines designed a five-piece precast concrete drift set for a small opening and tested it to destruction in a straining frame. Twenty-seven tests were made with three sizes of members using three loading conditions. In addition, six tests were made with sets in a distorted configuration, Test results and typical failure patterns are presented. A comparison of results with those previously reported for the three-piece set shows the five-piece set supports considerably larger total loads than does the three-piece set of equivalent cross section designed for the same size of opening. Recommendations are made for improvements in design.

Jan 1, 1969

By J. H. Wiggins

"The tests described below were conducted by the Bureau of Mines at a lease in Oklahoma on installations designed to decrease evaporation losses of crude oil Pram storage tanks. Use of the lease was granted by the Oklahoma Producing and Refining Corporation of America. Tankage was obtained through the courtesy of the Parkensburg Pig and Reel Co. The purpose of the installations and tests was to demonstrate the value of making crude-oil storage tanks gas-tight, rather than to determine the amount of evaporation in any one type of tank. None of the tanks used were absolutely gas-tight, but one of them was very nearly so. They comprised a tank of the ordinary open type with an 18-inch manhole, a tank with a ""4-inch vent"", a tank with a ""smaller vent"", and a tank which had only ""pin holes"" through which air and vapor could pass freely. On the last two tanks any excess pressure was taken care of by an automatic differential pressure regulator.The results obtained in these tests indicate that tight tankage will soon pay for itself. They will not, however, serve as a basis on which a producer can compute the actual number of days necessary for tight tankage to pay out, because the oil used was exceptionally volatile. It is probable that the average evaporation loss in the Mid-Continent field is at least one-half as great as that shown by these tests, and if this is true, the saving that would be effected by providing tight tankage on the lease will undoubtedly justify the expense. The installation of evaporation-proof tanks on the lease has been delayed by the failure of production managers to realize, first, that their evaporation losses are enormous, and, second, that they can practically eliminate these losses by a simple and inexpensive installation."

Apr 1, 1921

By H. G. Iverson

As a part of the program of investigation of domestic sources of manganese ore, mining engineers of the Bureau of Mines examined and sampled three properties in the vicinity of Winnemucca, Nev. As the ores were too low grade for direct production of ferromanganese, they were tested for their amenability to concentration by ore-dressing methods. Two samples of ore were procured by examining engineers of the Bureau of Mines from several outcrops in the Pollard Canyon area, Pershing County, about 30 miles southeast of Winnemucca. The manganese occurs in relatively small lenticular bodies as secondary replacement deposits in chert and quartzite. The first sample represented average run -of -mine ore as exposed in the Pollard Canyon deposits. Sample 2 was composed of hand-sorted, high-grade ore.

Jan 1, 1954

By Jr. Frost

Helium used as a tracer gas in petroleum reservoirs continues to show great promise as a new tool for the oil and gas industry, according to tests conducted jointly by the Bureau of Nines and The Pure Oil Co. in-the Cabin Creek field, Boone and Kanawha Counties, W. Va. Helium, when used as a, tracer gas, is mixed with natural gas being injected into a reservoir for secondary recovery of oil, recycling, pressure-maintenance, or other purposes. Three separate experimental helium tracer-gas tests were run in the Cabin Creek, W. Va., field, wherein helium was added as a tracer to the natural gas that was being injected into the oil-bearing Berea sandstone. The results obtained in each test permitted determining the direction and rate of travel of the injected gas, calculating the volume of injected gas in the gas produced at the various wells, and determining the nature of the transition from natural gas to injected gas during a gas-injection program. Data were obtained on the effects obtained from waves of injected gab containing 1 percent and containing 5 percent helium and from a wave of essentially pure helium injected into the formation.

Jan 1, 1950

By Lorenz E. Sieffert, Lawrence B. Berger, H. H. Sehrenk, Ralph W. Stewar, James A. Gale

"INTRODUCTION The purpose of the investigation discussed in this article was to evaluate the toxic hazard from gases produced when thermosetting plastic materials used for electrical insulating purposes are burned or thermally decomposed in enclosed spaces. For brevity the term ""toxicity"" is used throughout the article to refer to the nature of gases produced under these conditions. A need for immediate study of the problem was created as a re¬sult of the battle damage reports received from various United States Fleet units. These indicated that the fumes emitted when these materials were burned or thermally decomposed had, in several instances, resulted in toxic atmospheres. In attempting to develop a suitable test method for evaluating toxicity, it was recognized that no single test procedure could be expected to duplicate the variety of conditions that might exist in an actual fire aboard ship. In view of the immediate need, however, it was felt that considerable information could be obtained, at least to classify comparatively the several types of materials as to the toxic effect caused by burning or thermal decomposition, through the development of a sound empirical method which could be applied to all of the materials. On this basis, it was decided to modify the Navy flame resistance test for thermosetting plastics to render it applicable to the determination of the toxic, gases evolved when this test was employed. A wide variety of materials was tested, both molded and laminated, to cover the types commonly used by the Navy in electrical applications. Toxicity determinations were conducted at the Bureau of Mines Central Experiment Station, Pittsburgh, Pa. Parallel tests, to determine the flame resistance of the materials, were conducted at the Material Laboratory, U. S. Navy Yard, New York, N. Y."

Oct 1, 1947

By W. S. Landers

This bulletin is a detailed study of low-temperature, entrained-bed carbonization of a Texas lignite. The lignite studied was from the Sandow strip mine and is representative of the Rockdale formation of the Wilcox formational group. Carbonization was conducted in a continuous entrained-bed reactor at several temperatures in the 8801 to 1,52°C F range, and at air-coal ratios it the 0 to 10.30 scf/lb range (moisture- and ash-free basis). Carbonization rates ranged from 97.1 to 410.0 lb/hr (as-received basis), At the higher air-to-coal ratios employed, all or most of the carbonization heat was provided by internal combustion with air in the reactor. At the lower air-to-coal ratios, parts of the heat for carbonization was supplied externally. It was demonstrated that the entrained-bed carbonization of lignite is a complex reaction and that several variables, of which carbonization temperature, air-to-lignite ratio, and the average size of lignite are important, act together to influence both the carbonization yields and the properties of the resultant products, Process variables established by pant tests were used to design the industrial scale carbonizer operated at Rockdale, Texas, by the Texas Power & Light Company as agents for the Aluminum Company of America. Properties of the carbonization product obtained from the industrial scale reactor were essentially the same as those obtained from the pilot plant reactor operated under the same conditions.

Jan 1, 1968

By J. E. Tiffany

Some of the gases produced by permissible explosives on detonation are poisonous, and the probable hazard involved by the inhalation of carbon monoxide in the past has been evaluated from results of tests in the Bichel Gage. Tests have now been made in the Experimental Coal Mine of the Bureau of Mines at Bruceton, Pa., to determine the composition of the gases obtained under actual mining conditions for the purpose of comparing these, results with those found by the Bichel gage tests. Two permissible explosives were procured for these tests, one that produces a relatively low quantity of poisonous gases in the Bichel gage (24.8 liters per 1-1/2 pounds of explosive) and another that produces a relatively high quantity of poisonous gases (94.6 liters per 1-1/2 pounds). The first of these is designated by the Bureau of Mines as a class A4/ explosive and the other is designated a class B explosive. In comparison with Bichel-gage tests, the shooting of permissible explosives in a coal shot hole resulted in a large reduction in the quantity of carbon monoxide, the principal poisonous gas, which; in the mine tests, was only 22 percent of that found in Bichel-gage tests: The quantity of carbon monoxide from the class B explosive in Bichel-gage tests was 3.8 times larger than that from the class A explosive; in the coalmine tests the ratio was 4:1. The concentrations of carbon monoxide in the mine tests, as determined by analysis of the atmosphere in an enclosed space resulting from shooting 1-1/2-pound and 3-pound charges of the class A explosive, were 0.03 and 0.06 percent, respectively, and the concentrations from 1-1/2-pound and 3-pound charges of the class B explosive were 0.10 and 0.24 percent.

Jan 1, 1950

By A. D. Garman

This paper presents one of a series of digests of foreign mining legislation and court decisions which is being prepared in advance of a general report relative to the right of American citizens to explore for minerals and to own and operate mines in various foreign countries . This interpretation of the laws of Haiti has been prepared from the best available information in Washington, but is released subject to correction and amplification , if necessary , by the proper American diplomatic and consular officers to whom it is being referred through the courtesy of the Department of State .

Sep 1, 1930

By Rustu S. Kalyoncu

A major goal of the Bureau of Mines is to conserve the Nation's mineral resources by developing improved performance materials. In support of this mission, a survey of the state of the art of chemically bonded refractories has been made, covering the scientific literature, government reports, and patents. This review includes research and development results for phosphate, silicate, oxychloride, oxysulfate, and other bonding agents used in refractories manufacture. A significant finding of the review was that references on bonding mechanisms, bond formation kinetics, and other important process parameters and conditions were few and universally vague. As a result, recommendations are made to expand research efforts to investigate the kinetics and mechanisms of reactions in chemically bonded refractories.

Jan 1, 1982

By G. V. Sullivan

This report summarizes the results of a preliminary study concerning manganese extraction from low-grade dolomitic materials from the Philipsburg district in Montana by the Dean-Leute ammonium carbamate process. Studies were made to determine the relationship between the variables involved in treating these materials by a roast-leach process and the amount of manganese extracted. The variables studied were the roast temperature, the roast particle size, the molar ratio of NH3 to CO2 in the leach solution, the liquid-solid ratio in leaching, the leach time, and the size of the particles being leached. The roast-leach studies were statistically designed, and the experimental results were evaluated by an analysis of variance.

Jan 1, 1962

By R. A. Hatch

The United States depends mainly on foreign imports, principally India, for an adequate supply of sheet mica suitable for its many uses in the electrical and electronics industries. Sheet mica has, in fact, played an indispensable role in developing these industries,4/ and, in turn, the products of these industries (radio, radar, electric motors, and many others) have become indispensable to the military forces. Because or these conditions, sheet mica in its better qualities long has been classified as a strategic and critical material, and from this stems the wide-spread interest in substitute materials of which synthetic mica is one potential type. The United States Departments of the Navy and the Army entered into a cooperative agreement with the Bureau of Mines in 1947 to study ways and means of synthe-sizing and growing mica crystals. This is one of a series of reports5/ that describe the results of this program.

Jan 1, 1956

By Lucien Eaton

The mining methods described in this paper are those used in a large mine producing hard specular ore on the Marquette Range in the Upper Peninsula of Michigan. Although the conditions of mining are unique in this district, they are similar to those in many other districts, and information in regard to the methods used and the results obtained should be of interest. The methods now used are an outgrowth of those of former years which have been adapted to conform with improvements in mechanical appliances, changes in the wage scale and labor supply, and the' selling price of the product. The mine is situated' at Ishpeming, in the Upper Peninsula of Michigan, 16 miles west of Marquette, its shipping port on Lake Superior.

Jan 1, 1929

By N. P. Kripakov

The Bureau of Mines has developed a unique new mine design procedure to determine the changing static load distributions imposed on under-ground support structures during the mining cycle. The procedure reduces the complexities associated with analyzing a three-dimensional problem. A combination of the multiple-seam displacement-discontinuity model and a two-dimensional finite-element window model produces refined results for a specific area of interest by assuming displacement compat-ibility between models. Input to the procedure includes the geometry of mined-out areas in up to two adjacent seams, the rock mass characteris-tics of the surrounding geology, the in situ stress conditions, and the mining sequence. The displacement-discontinuity program calculates ex-pected loadings for mine structures affected by the mining cycle and/or by overlying or underlying seams. Pseudoelastic finite-element analysis using a yield-factor approach determines the stability of coal pillars by simulating the degree and extent of nrogressive rib failure and sub-sequent load transfer. Application of the procedure is demonstrated on a field problem. In-duced stress changes predicted from the numerical model analysis are in reasonably good agreement with stress measurements obtained from an instrumented chain pillar affected by remnant workings in an upper seam.

Jan 1, 1988

By J. H. Field

Results of studies by the Federal Bureau of Mines on a pilot-plant scale for removing hydrogen sulfide and carbonyl sulfide from gas mixtures by the hot carbonate system are given in this publication. Gases containing up to 10 pet. hydrogen sulfide and 48 grains carbonyl sulfide per 100 cu.ft. were treated. In most tests carbon dioxide also was present and was removed simultaneously with the sulfur compounds. Because the rate of absorption of hydrogen sulfide is much more rapid than that of carbon dioxide over a wide temperature range, selective removal of hydrogen sulfide occurred in the bottom section of the absorber near the point of gas entry. Hydrogen sulfide was removed to pipeline specifications with carbonate solutions by using split-stream flows in the absorber and regenerator.

Jan 1, 1960

By E. R. Palowitch

Coal wasted with mine refuse represents losses in overall recovery of merchantable coal to the mine operator and a concomitant reduction in domestic reserves of available coal. Fraser, Kelley, and Graham3/ in studying the available coal in mine refuse in the Pittsburgh district of western Pennsylvania have estimated that at least 1 ton of mine refuse is produced for each 10 tons of merchantable coal and that 20 percent of this mine refuse might be recovered as salable coal by mechanical cleaning. SUMMARY This investigation dealt with the mechanical recovery of coal from wine refuse by a dense-medium washery employing pulverized mine rock as the dense medium and operating at a rate of 175 tons per hour. Two types of mint refuse were tested: Freshly mined and that .which had been mined 2 years before and piled on a waste dump.

Jan 1, 1955